CN104151722A - Modified composite polybutylene material - Google Patents
Modified composite polybutylene material Download PDFInfo
- Publication number
- CN104151722A CN104151722A CN201410394717.9A CN201410394717A CN104151722A CN 104151722 A CN104151722 A CN 104151722A CN 201410394717 A CN201410394717 A CN 201410394717A CN 104151722 A CN104151722 A CN 104151722A
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- China
- Prior art keywords
- parts
- polybutene
- compound
- modification
- polybutylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/24—Crystallisation aids
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a modified composite polybutylene material. The modified composite polybutylene material consists of the following components in parts by weight: 30-52 parts of polybutylene, 5-9 parts of a metallocene polyolefin elastomer, 1-3 parts of a nucleating agent, 2-3 parts of a thermal stabilizer, 3-5 parts of a compatibilizer, 20-25 parts of glass fibers, 1-5 parts of a flame retardant and 16-20 parts of inorganic filler. The modified composite polybutylene material provided by the invention has the beneficial effects that by adding the nucleating agent into a polybutylene formula provided by the invention, the forming rate and the forming strength are increased; the mechanical performance of the polybutylene is improved by adding the metallocene polyolefin elastomer and the glass fibers; and meanwhile, a prepared polybutylene resin has a flame retarding property, and has a wide application range.
Description
Technical field
The present invention relates to a kind of polymeric material field, particularly the compound polybutene resin of a kind of modification.
Background technology
Polybutene (Polybutene, PB) is a kind of polymer inert polymer, is mainly to be formed by butene polymerization.Be all the plastic material of frequent use with polypropylene and polyethylene.Current domestic polybutene industrialization is less, and to the higher part of some dimensional precisioies, technique is also difficult to reach requirement.Interpolation by properties-correcting agent often can be optimized its performance.
Based on the above, a kind of exploitation of enhancing modified polybutylene composite material is by necessary property.
Summary of the invention
For defect of the prior art, the invention provides a kind of enhancing modified polybutene material, the performance that is intended to improve by adding of additive polybutene.
In order to realize above-mentioned target, the present invention adopts following technical scheme:
The compound polybutene material of a kind of modification, is made up of the component of following parts by weight:
Polybutene, 30～52 parts;
Metallocene polyolefin elastomers, 5～9 parts;
Nucleator, 1～3 part;
Thermo-stabilizer, 2～3 parts;
Compatilizer, 3～5 parts;
Glass fibre, 20～25 parts;
Fire retardant, 1～5 part;
Mineral filler, 16～20 parts.
Preferably, the compound polybutene material of described modification, wherein, the melting index of described polybutene is 10～100g/10min.
Preferably, the compound polybutene material of described modification, wherein, described nucleator is two benzal fork glucitol derivatives.
Preferably, the compound polybutene material of described modification, wherein, described thermo-stabilizer is amine thermo-stabilizer.
Preferably, the compound polybutene material of described modification, wherein, described glass fibre is high strength glass fiber.
Preferably, the compound polybutene material of described modification, wherein, described fire retardant is halogen-free expansion fire retardant.
Preferably, the compound polybutene material of described modification, wherein, described compatilizer is EVOH-PPMA macromole compatilizer.
Preferably, the compound polybutene material of described modification, wherein, described mineral filler is one or more combination in talcum powder, mica powder, kaolin.
The beneficial effect of the compound polybutene material of modification provided by the invention: polybutene formula provided by the invention improves molding rate and shaping strength by adding nucleator, improve polybutene mechanical property by adding metallocene polyolefin elastomers and glass fibre, the polybutene resin simultaneously making has fire-retardant characteristic, applied widely.
Embodiment
The present invention is described in further detail below, to make those skilled in the art can implement according to this with reference to specification sheets word.
Embodiment 1
The compound polybutene material of a kind of modification, is made up of the component of following parts by weight: polybutene, 30 parts; The melting index of described polybutene is 100g/10min.Metallocene polyolefin elastomers, 9 parts; Nucleator, 3 parts; Described nucleator is two benzal fork glucitol derivatives.Thermo-stabilizer, 3 parts; Described thermo-stabilizer is amine thermo-stabilizer.Compatilizer, 5 parts; Described compatilizer is EVOH-PPMA macromole compatilizer.Glass fibre, 25 parts; Described glass fibre is high strength glass fiber.Fire retardant, 5 parts; Described fire retardant is halogen-free expansion fire retardant.Mineral filler, 20 parts.Described mineral filler is talcum powder.
Embodiment 2
The compound polybutene material of a kind of modification, is made up of the component of following parts by weight: polybutene, 52 parts; The melting index of described polybutene is 10g/10min.Metallocene polyolefin elastomers, 5 parts; Nucleator, 1 part; Described nucleator is two benzal fork glucitol derivatives.Thermo-stabilizer, 2 parts; Described thermo-stabilizer is amine thermo-stabilizer.Compatilizer, 3 parts; Described compatilizer is EVOH-PPMA macromole compatilizer.Glass fibre, 20 parts; Described glass fibre is high strength glass fiber.Fire retardant, 1 part; Described fire retardant is halogen-free expansion fire retardant.Mineral filler, 16 parts.Described mineral filler is mica powder.
Embodiment 3
The compound polybutene material of a kind of modification, is made up of the component of following parts by weight: polybutene, 40 parts; The melting index of described polybutene is 50g/10min.Metallocene polyolefin elastomers, 7 parts; Nucleator, 2 parts; Described nucleator is two benzal fork glucitol derivatives.Thermo-stabilizer, 2 parts; Described thermo-stabilizer is amine thermo-stabilizer.Compatilizer, 4 parts; Described compatilizer is EVOH-PPMA macromole compatilizer.Glass fibre, 22 parts; Described glass fibre is high strength glass fiber.Fire retardant, 4 parts; Described fire retardant is halogen-free expansion fire retardant.Mineral filler, 19 parts.Described mineral filler is kaolin.
Although embodiment of the present invention are open as above, but it is not restricted to listed utilization in specification sheets and embodiment, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details.
Claims (8)
1. the compound polybutene material of modification, is made up of the component of following parts by weight:
2. the compound polybutene material of modification as claimed in claim 1, is characterized in that, the melting index of described polybutene is 10～100g/10min.
3. the compound polybutene material of modification as claimed in claim 1, is characterized in that, described nucleator is two benzal fork glucitol derivatives.
4. the compound polybutene material of modification as claimed in claim 1, is characterized in that, described thermo-stabilizer is amine thermo-stabilizer.
5. the compound polybutene material of modification as claimed in claim 1, is characterized in that, described glass fibre is high strength glass fiber.
6. the compound polybutene material of modification as claimed in claim 1, is characterized in that, described fire retardant is halogen-free expansion fire retardant.
7. the compound polybutene material of modification as claimed in claim 1, is characterized in that, described compatilizer is EVOH-PPMA macromole compatilizer.
8. the compound polybutene material of modification as claimed in claim 1, is characterized in that, described mineral filler is one or more combination in talcum powder, mica powder, kaolin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410394717.9A CN104151722A (en) | 2014-08-12 | 2014-08-12 | Modified composite polybutylene material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410394717.9A CN104151722A (en) | 2014-08-12 | 2014-08-12 | Modified composite polybutylene material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104151722A true CN104151722A (en) | 2014-11-19 |
Family
ID=51877359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410394717.9A Pending CN104151722A (en) | 2014-08-12 | 2014-08-12 | Modified composite polybutylene material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104151722A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105968592A (en) * | 2016-05-31 | 2016-09-28 | 苏州市奎克力电子科技有限公司 | Flame-retardant cable jacket masterbatch and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333417A (en) * | 2013-06-24 | 2013-10-02 | 北京化工大学 | Intumescent halogen-free flame retardant high isotactic polybutene-1 material and preparation method thereof |
-
2014
- 2014-08-12 CN CN201410394717.9A patent/CN104151722A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333417A (en) * | 2013-06-24 | 2013-10-02 | 北京化工大学 | Intumescent halogen-free flame retardant high isotactic polybutene-1 material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘建桥等: "iPB/ POE 热塑性弹性体的性能研究", 《橡胶工业》, vol. 58, no. 6, 31 December 2011 (2011-12-31), pages 343 - 346 * |
| 刘珍等: "聚丁烯－１的改性研究进展", 《现代塑料加工应用》, vol. 25, no. 3, 31 December 2013 (2013-12-31), pages 60 - 63 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105968592A (en) * | 2016-05-31 | 2016-09-28 | 苏州市奎克力电子科技有限公司 | Flame-retardant cable jacket masterbatch and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20141119 |
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| RJ01 | Rejection of invention patent application after publication |