CN104146874A - Self-heating thermal-insulation facial mask - Google Patents

Self-heating thermal-insulation facial mask Download PDF

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Publication number
CN104146874A
CN104146874A CN201410381994.6A CN201410381994A CN104146874A CN 104146874 A CN104146874 A CN 104146874A CN 201410381994 A CN201410381994 A CN 201410381994A CN 104146874 A CN104146874 A CN 104146874A
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heating
self
heat
skin
facial film
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CN104146874B (en
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黄英骆
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Zhuhai Morning Enterprise Management Consulting Co ltd
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Priority to CN201410381994.6A priority Critical patent/CN104146874B/en
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Priority to KR1020177005846A priority patent/KR102111837B1/en
Priority to CA2957322A priority patent/CA2957322C/en
Priority to EP15828995.9A priority patent/EP3178453A4/en
Priority to SG11201700905YA priority patent/SG11201700905YA/en
Priority to PCT/CN2015/081597 priority patent/WO2016019762A1/en
Priority to RU2017106961A priority patent/RU2683719C2/en
Priority to JP2017506828A priority patent/JP6711816B2/en
Priority to US15/501,864 priority patent/US20170231813A1/en
Priority to HK15107464.5A priority patent/HK1204841A2/en
Priority to TW104125374A priority patent/TWI641484B/en
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Abstract

The invention discloses a self-heating thermal-insulation facial mask. A structure with at least three layers is arranged at a part corresponding to a human body facial area; the three layers are an outer layer, a heating layer and a thermal insulation layer respectively from inside to outside, wherein the outer layer is made of air-permeable material; the heating layer is load with a heating composition, which is capable of heating through being in contact with air, and at least the upper cover, in contact with the outer layer, of the heating layer is made of the air-permeable material; the thermal insulation layer is made of waterproof and thermal-insulation material. The self-heating thermal-insulation facial mask is simple in structure, free from the limitation of the environmental resources, safe, stable and uniform-heating, does not need an external energy source to provide energy, and can effectively prolong the heating time and reduce the heating peak temperature. When being applied to the facial skin, the self-heating thermal-insulation facial mask can improve blood circulation and enlarges skin pores to discharge sweat, dirt and grease; when being used together with a traditional nutrition facial mask and a skin care product, the self-heating thermal-insulation facial mask can promote the skin to absorb the effective constituents of the traditional nutrition facial mask and the skin care product and improve the skin care effect while reducing the use level of the skin care product, and is safe, healthful and low in cost.

Description

A kind of self-heating thermal insulation facial film
Technical field
The present invention relates to a kind of facial film, relate in particular to a kind of facial film that can self-heating thermal insulation.
Background technology
Facial film is a kind of carrier of face beautifying health keeping product, applies ointment or plaster at 15~30 minutes on the face, after the nutrient of skin care products is slowly absorbed by the skin, film can be unloaded.Facial film is substantially the most also that most important object is to make up makeup removing and the still cleaning of deficiency that washes one's face, and realizes on this basis other maintenance function, for example replenishing water and preserving moisture, whitening, defying age etc.
Traditional facial film is generally a diaphragm, after tiling, cover and face, it is mainly to utilize the blink that covers face, temporarily isolates extraneous air and pollution, improve skin temperature, the pore expansion of skin, promotes sweat gland secretion and metabolism, makes the oxygen content of skin increase, be conducive to skin and get rid of the oil substances of the metabolic product of epidermis cell and accumulation, moisture in facial film infiltrates the horny layer of epidermis, and it is soft that skin becomes, and skin naturally light is flexible.Such facial film effect is more single, all more limited for the cleaning action of facial skin and the assimilation effect of skin care item.
For the osmotic absorption of the nutritional labeling in facial film, traditional method can also be that facial film is first placed on to warm bubbly water once, or with steam, facial film is steamed, to increase the temperature of facial film, thereby when spreading on the face, better open face's pore, promote blowdown and cosmetic result.
In addition, in prior art, also have to use for reference the spontaneous heating paster that oxidation heating technique art is made, for example warmer is precious, on daily warming and treatment arthralgia due to cold-dampness medical market, is widely used.These pasters generally by bag, exothermic material, adhesive layer, stick on the cover layer that adhesive layer outer surface can peel off and form, during use, cover layer is peeled off, adhesive layer is attached on clothes, in the face of skin is bag air-permeable layer, exothermic material and airborne moisture and oxygen generation chemical reaction, produce heat, thereby play warming effect.But at present all there is following defect in all spontaneous heating patches: 1) initial temperature is too high or heat loss is too fast, easily causes low temperature to scald, there is histologic lesion sticking position Yin Wenre, or need warming position holding temperature low, heat production is disorderly; 2) generate heat inhomogeneously, local temperature is too high.And, this class spontaneous heating paster can not coordinate skin care item, topical drug or health product to use, because conventionally contain moisture or oil content in skin care item, topical drug or health product, the sweat that when these moisture or oil content directly contact skin with exothermic padding, skin is discharged penetrates into the air-permeable layer in the face of skin together, impact heating chemically stable, heating peak value is difficult to control.In addition, the chemical effect product of exothermic material also can with topical drug or health product in moisture/oil content or skin sweat cross-contamination or the skin infection of discharging.
Publication number is the Chinese invention patent application of CN 101547667A, a kind of facial film of oneself's heating is disclosed, this facial film mainly generates heat by the exothermic composition in its heat transfer pad, the temperature and time of its heating all depends on the permeability of the gas permeable polymer film of Heat Transfer Control pad, thereby control, enter the amount of oxygen contacting with exothermic composition in heat transfer pad, be used as the carrier that exothermic composition is determined speed.But such oneself heats facial film does not still overcome above-mentioned various defects yet, the problem of heat loss for example, the inhomogeneous problem of generating heat, especially when when having coated skin care item or health product on the face, the sweat that still can exist moisture, oil content or skin in skin care item or health product to discharge penetrates in its heat transfer pad, the chemically stable defect of impact heating; And the sweat cross-contamination that the chemical effect product of exothermic material also can be discharged with externally applied product with moisture or oil content or skin, exists and burns or the hidden danger of skin infection.
Summary of the invention
For the defect of prior art, technical problem to be solved by this invention is to provide a kind of effect various, can effectively extend fever time, reduces heating peak temperature, uniform heat distribution; And can significantly strengthen skin care item effect, the self-heating thermal insulation facial film of avoiding skin of face to infect.
For solving the problems of the technologies described above, the technical scheme that the present invention takes is:
A kind of self-heating thermal insulation facial film, described facial film has at least three-decker at the position in corresponding human body face region, and described three-decker is respectively the skin that consists of gas permeable material from outside to inside, be mounted with by contact the heat-generating composition generating heat and the upper front cover at least contacting with described skin with air is the heating layer that forms of gas permeable material, by the heat-insulation layer that has waterproof thermal-insulated performance material and form.Compared with prior art, the technical program has increased the heat-insulation layer forming by having waterproof thermal-insulated performance material, when reality is used, heat-insulation layer makes the heat distributing in heating layer pass to uniformly and stably on skin, and the heat that is delivered to skin can not lost soon, the risk of having avoided the too high initiation low temperature of initial temperature to scald, and effectively stably kept skin in suitable temperature.And, the sweat that this heat-insulation layer has stoped moisture, oil content or the skin in external use skin care, topical drug or health product to be discharged penetrates into air-permeable layer, thereby avoided heating peak value problem rambunctious, the problems such as cross-contamination while also having avoided use exterior-applied article, skin infection.Self-heating thermal insulation facial film of the present invention is not limited to the three-decker of above-mentioned restriction, and in actual use, this film may also comprise protective layer, adhesive layer etc.
As a further improvement on the present invention, described heat-insulation layer is the PET metal coating (metallized polyethylene terephthalate (MPET)) consisting of PET thin film and gold or argentine material.In one embodiment, heat-insulation layer is by being used physical vapor coating technique to the formation of metallizing of PET thin film.Under vacuum condition, adopt the physical methods such as heating, make metal surface gasification, the metallic atom of gasification condenses or is deposited near on the cold PET film of metal steam source of the gas.In one embodiment, the metal that PET metal coating adopts is aluminum, but also can use other metals in other embodiments, and for example, nickel or chromium, also can be used metal mixture.This PET metal coating is much thinner than metal forming, and its thickness is equal to or less than 0.5 micron.This PET metal coating is flexible good, and waterproof effect is splendid, and can As time goes on not fade or variable color.The metal reflective plated film of gold or silver color has splendid reflection heat energy function, prevent heat loss through radiation, can effectively preserve more than 90% heat between heat-insulation layer and skin, mixing of metal also contributes to the heat in heating layer to be delivered to evenly, rapidly skin, thus effective regulate body temperature.And the metal coating of gold or silver color also contributes to more to try to please aesthetically user.Except polyethylene terephthalate thin film (PET), oriented polypropylene (OPP) thin film (OPP), nylon, polyethylene and cast polypropylene also can be for metal coatings of the present invention.
As a further improvement on the present invention, be also provided with grid in heating layer, heat-generating composition is loaded in each grid equably.In actual use; heat-generating composition is generally Powdered or graininess; transporting or putting on skin, these granules or powder are concentrated in a certain position in heating layer under the effect of gravity, and other positions do not have heat-generating composition; for example; when this film is applied to face, under standing state, graininess or pulverous heat-generating composition can be concentrated the bottom of dropping at heating layer; thereby cause lower part heat too much, and the very few problem of upper part heat.Added after grid, heat-generating composition is loaded in each grid equably, guaranteed in use procedure, the heat in heating layer can distribute equably, has also avoided the Cold Iron cold danger of the too high initiation of local temperature.The concrete quantity of grid and shape can be according to the heat-generating composition of required loading, predetermined factor adjustment such as heat preservation area, for example, the shape of grid can be oval, circular, square, lace shape, pentagon or other shapes, and the number of grid is more than 2 or 2.
As a further improvement on the present invention, grid is that the lower front cover that the upper front cover that contacts with skin in heating layer contacts with heat-insulation layer forms by bonding seam heat bonding.Straight forming together with the cover material up and down of grid and heating layer, when producing, the bonding mould of heating layer is provided with grid pattern, by heating mould, makes the place of mould protrusion by cover material molding bonded to each other.Certainly, grid can adopt any known additive method in this area to prepare.
As a further improvement on the present invention, the skin of self-heating thermal insulation film of the present invention is non-woven fabrics or the woven of natural fiber or synthetic fibers.Non-woven fabrics normally polyester is prepared from by meltblown, and cost is low, quality is soft, good permeability, and on non-woven fabrics and heating layer, the ventilated membrane material of front cover is similar, and bi-material is more compound.
In one embodiment of the invention, self-heating thermal insulation facial film sealed packing before using.In order to prevent that heat-generating composition in heating layer was oxidized by airborne oxygen and moisture before using, of the present invention packing can consist of the impermeable any suitable material of gas substantially, for example plastic sheeting.
Heat-generating composition in heating layer comprises oxidizable metal, activated carbon, inorganic metal salt, water, macromolecule wetting agent, water absorbing agent.The ultimate principle of spontaneous heating is that oxidizable metal in heating layer and airborne moisture and oxygen produce heat and skin is heated, utilization be chemical energy.Other compositions in heat-generating composition are to carry out for accelerating oxidation reaction.
As a modification of the present invention, the heating temp of the heating layer of described facial film is 38~42 ℃, and fever time is 10~25 minutes.Within the scope of this temperature and time, facial skin is felt as snug as a bug in a rug, blood circulation quickening, and skin pore amplifies, and sweat and dirt oils and fats are discharged.If temperature is too low or the time is too short, do not have the effect of opening pore; If excess Temperature or overlong time, may make the epidermis of facial skin have scald in various degree, the blood capillary of epidermis can be expanded rapidly or for a long time in expansion state, easily cause skin dehydration, the problems such as corse sweat pore.Heating temp and time can be by the adjustment such as air-vent size, quantity of controlling the ratio of each composition in the charging ratio, heat-generating composition of heat-generating composition and suitably setting front cover on ventilative skin and heating layer.In general, heating layer can be heated to user's skin enough temperature, for user provides effective heat but can not cause any discomfort, for example, film of the present invention can make user's skin temperature be increased to approximately 38~45 ℃, and it keeps the time quantum of heating may depend on special application, for example, be greater than 15 minutes, be greater than 30 minutes, be even greater than 1 hour.
As optimal way of the present invention, the heat-generating composition in described heating layer comprises in weight portion: 30~50 parts of medical iron powders, 10~15 parts of active carbons, the salt of 1~5 part, 3~13 parts of Vermiculitums, 1~5 part of water-absorbing resins, 1~5 part of water.In the situation that adopt conventional non-woven fabrics, ventilated membrane, this formula, under common environmental condition, can guarantee that heating temp is 38~42 ℃, and fever time is 10~25 minutes.
As present invention further optimization, the heat-generating composition in described heating layer comprises in weight portion: 30~50 parts of medical iron powders, 10~15 parts of active carbons, the salt of 1~5 part, 3~13 parts of Vermiculitums, 1~5 part of water-absorbing resins, 1~5 part of water, 1~5 part of kieselguhr.Diatomaceous ultra micro pore can the airborne moisture of automatic absorption, is stored, and can not make excessive steam enter heating layer and cause excess Temperature; When the wet change of environment declines, kieselguhr can discharge the moisture being stored in ultra micro pore, can not make the steam deficiency that enters heating layer cause that facial film temperature is too low.By kieselguhr, to the storage of moisture in air and slow release, make the heating-up temperature of film of the present invention more constant.
As present invention further optimization, the thickness of described facial film is 2~8mm.This thickness range not only can meet three-decker and above-mentioned heating temp and the time of described film, can also good fit in face.The area of facial film adopts the size of conventional facial film.
As a further improvement on the present invention, on the described heat-insulation layer of described film and the surface of human body face contact skin, be also provided with for described film is fixed to facial hydrogel layer.Hydrogel (Hydrogel) can be used as body adhesives, and film is fixed on to body part.
Hydrogel be take water as disperse medium, when gel is attached on skin, is subject to the impact of body temperature, and the physical arrangement of gel inside is from solid-state liquefy, and in penetrating to the skin.Therefore, as a further improvement on the present invention, can in hydrogel matrix, add the raw material of effect, for example, the active component of collagen protein, hyaluronic acid, arbutin, nicotiamide, volatile oil or other health product, topical drug etc.Because self-heating thermal insulation film of the present invention has the heat-insulation layer of waterproof thermal-insulated performance, the moisture in hydrogel cannot be penetrated into heating layer, thereby can not have any impact to the heating peak value of heating layer and heating effect.The heat that heat-insulation layer also contributes to maintain in hydrogel can not distribute rapidly.
As one embodiment of the present of invention, the corresponding human body oral area of described facial film has perforate, and corresponding nostril has opening.Corresponding human body oral area and nostril arrange corresponding opening, in order to ensure that human body is necessary breathing at application facial film, in this embodiment, corresponding human eye place does not arrange perforate, like this, can carry out almost omnibearing clean and maintenance in the absolutely large logarithm region except mouth and nose to human face.And the heating layer of three-decker and heat-insulation layer can also keep healthy to eyes in facial film, play the effect of eye hot compress, and prevent xerophthalmia.
As another embodiment of the present invention, described facial film removes corresponding human body oral area and has perforate, and corresponding nostril has outside opening, and also corresponding human body eye has perforate.Like this, after applying facial film on the face, do not affect walking about and the activity of eyes of people.
Further, described facial film both sides also have for facial film being fixed on to the fixing band of human body head, and the tail end of described fixing band has VELCRO.Thereby after facial film is spread on to face, can around head, fix with fixing band, and use VELCRO tighten.In the specific embodiment, the mode that facial film of the present invention is not limited to fixing band and VELCRO is fixed on head, can also adopt, and for example, the mode of frenulum, button is fixed.
The present invention also provides a kind of using method of self-heating thermal insulation facial film, before applying described facial film, in face, first applies traditional nourishing pack or skincare product, or in advance skincare product is coated in to described heat-insulation layer by the surface with contact skin; Afterwards, facial film is directly fitted in to people's face.Because self-heating thermal insulation facial film of the present invention can make skin pore, amplify, promote sweat and dirt oils and fats to discharge, therefore can improve the absorption of skin to skin care item effective ingredient, when reducing skin care item consumption, can also increase skin effect.And, heat-insulation layer makes the heat distributing in heating layer pass to uniformly and stably on skin, the heat that is delivered to skin can not lost soon, the risk of having avoided the too high initiation low temperature of initial temperature to scald, and effectively stably kept skin in suitable temperature.And, the sweat that this heat-insulation layer has stoped moisture, oil content or the skin in external use skin care, topical drug or health product to be discharged penetrates into air-permeable layer, thereby avoided heating peak value problem rambunctious, the problems such as cross-contamination while also having avoided use exterior-applied article, skin infection.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of self-heating thermal insulation facial film of the present invention embodiment mono-.
Fig. 2 be embodiment illustrated in fig. 1 in, the three-decker cutaway view in corresponding human body face region on facial film diaphragm.
Fig. 3 is the structural representation of a kind of self-heating thermal insulation facial film of the present invention embodiment bis-.
The specific embodiment
Below in conjunction with embodiment, the present invention is made a more detailed description; but only below describe for to the explanation of making an explanation property of the present invention; protection scope of the present invention is not carried out to any restriction; the equivalent structure that all utilizations description of the present invention and accompanying drawing content are done changes, all in like manner within the scope of the present invention.
Embodiment mono-
In embodiment 1, as shown in Figure 1, the corresponding human body eye of facial film 10 has perforate 11, and corresponding human body oral area has perforate 12, and corresponding human body nostril has opening 13.The both sides of facial film 10 also have for facial film being fixed on to the fixing band 14 of human body head, and the tail end of fixing band 14 has VELCRO 15.
After facial film 10 of the present invention is spread on to face, can around head, fix with fixing band 14, and use VELCRO 15 tightens.VELCRO (HOOk & LOOP), has another name called magic tape, and industry slang claims again double buckle, a kind of connection adjuvant conventional on clothes, minute male and female two sides, one side is the fiber of small, flexible, circle hair (LOOP), another side is the seta (HOOK) of harder buckle.
In the present embodiment, as shown in Figure 1, the position 16 in the corresponding human body face of described facial film 10 region has at least three-decker, as shown in Figure 2, Fig. 2 shows the profile of Liao Gaisanceng mechanism, and described three-decker is respectively the skin 161 that consists of gas permeable material from outside to inside, be mounted with by contact the heat-generating composition 1621 generating heat and the upper front cover at least contacting with described skin with air is the heating layer 162 that forms of gas permeable material, by the heat-insulation layer 163 that has waterproof thermal-insulated performance material and form.Graininess or pulverous heat-generating composition 1621 are loaded in heating layer 162, and heat-insulation layer 163 directly contacts with skin 17
In this embodiment, the three-decker of facial film 10 is bonded together, and for example, uses binding agent or by the mode of heat bonding, as an integral body, is applied directly on skin.In actual production and use procedure, heat-insulation layer may not be bonded together with outer, heating layer, that is to say, during use, first on skin, be applied with independent heat-insulation layer, and then apply heating layer and skin, also can obtain same heat preservation effect.
Use the object of facial film to be clean face, and realize on this basis other maintenance functions, such as replenishing water and preserving moisture, whitening, anti-ageing waiting for a long time, for the continuous research and development of facial film with improve towards this target.The embodiment of the present invention, the position in the corresponding human body face of facial film diaphragm region is provided with three-decker, especially on the basis of skin, heating layer, also between heating layer and facial skin, also increased the heat-insulation layer forming by thering is waterproof thermal-insulated performance material, when reality is used, heat-insulation layer makes the heat distributing in heating layer pass to uniformly and stably on skin, and the heat that is delivered to skin can not lost soon, the risk of having avoided the too high initiation low temperature of initial temperature to scald, and effectively stably kept skin in suitable temperature.And, the sweat that this heat-insulation layer has stoped moisture, oil content or the skin in external use skin care, topical drug or health product to be discharged penetrates into air-permeable layer, thereby avoided heating peak value problem rambunctious, the problems such as cross-contamination while also having avoided use exterior-applied article, skin infection.When using facial film embodiment of the present invention, the gentle heat that heating layer and heat-insulation layer distributed and maintained makes skin in comfort conditions, improves blood circulation, and skin pore amplifies, and sweat and dirt oils and fats are discharged.When the nourishing pack with traditional is used together with skin care item, improved significantly the absorption of skin to traditional facial film and skin care item effective ingredient, when reducing skin care item consumption, can also increase skin effect, convenience, saving and environmental protection.
In this embodiment, outer 161 weave cotton cloth for fibre, and what the upper and lower front cover of heating layer 162 all adopted is breathable films, the metal coating that the medical heat-insulating and cold film that heat-insulation layer 163 adopts and gold or argentine material form.In concrete use, only need to guarantee that on skin 161 and heating layer 162, front cover (also may comprise lower front cover) consists of gas permeable material, for gas permeable material, be not specifically limited, so long as air fully can be imported to the heat-generating composition in heating layer.The breathability of gas permeable material can, according to the kind of heat-generating composition, amount, predetermined heating temp etc., be adjusted by suitable setting air-vent size, quantity etc.The thickness of gas permeable material, as long as do not hinder the scope of effect of the present invention.Meeting under the condition of ventilative and support function, more Bao Yuehao.
Heat-insulation layer 166 is the PET metal coatings (metallized polyethylene terephthalate (MPET)) that consist of PET thin film and gold or argentine material.As in the present embodiment, heat-insulation layer is by being used physical vapor coating technique to the formation of metallizing of PET thin film.Under vacuum condition, adopt the physical methods such as heating, make metal surface gasification, the metallic atom of gasification condenses or is deposited near on the cold PET film of metal steam source of the gas.In the present embodiment, the metal that PET metal coating adopts is aluminum, and under vacuum condition, solid aluminum is easily converted into gaseous state by mode of heating, and PET thin film is with respect to other thin polymer films, and thermostability is better, and good with the binding ability of metallic aluminium.Aluminum PET film plating layer is rich in metallic luster, and reflectance is high, and the reflectance of the aluminum film plating layer of thickness 400A ° reaches 90%, and heat insulation effect is good, and very good to the barrier of moisture and gas.Certainly, in other embodiments, also can use other metals, for example, nickel or chromium, also can be used metal mixture.This PET metal coating is much thinner than metal forming, and its thickness is equal to or less than 0.5 micron.This PET metal coating is flexible good, and waterproof effect is splendid, and can As time goes on not fade or variable color.The metal reflective plated film of gold or silver color has splendid reflection heat energy function, prevent heat loss through radiation, can effectively preserve more than 90% heat between heat-insulation layer and skin, mixing of metal also contributes to the heat in heating layer to be delivered to evenly, rapidly skin, thus effective regulate body temperature.And the metal coating of gold or silver color also contributes to more to try to please aesthetically user.Except polyethylene terephthalate thin film (PET), oriented polypropylene (OPP) thin film (OPP), nylon, polyethylene and cast polypropylene also can be for metal coatings of the present invention.
Further, in this embodiment, heating layer 162 is also provided with grid 1622.Graininess or pulverous heat-generating composition 1621 are closed in each grid 1622.By grid 1622 is set, in transportation and actual use procedure, granular heat-generating composition 1621 can not concentrate on certain part in heating layer 162 under external force, thereby causes hot-spot, generates heat inhomogeneous.
In this embodiment, grid 1622 is that the lower front cover contacting with heat-insulation layer 163 with the outer 161 upper front covers that contact in heating layer 162 forms by bonding seam heat bonding.Straight forming together with the cover material up and down of grid 1622 and heating layer 162, when producing, the bonding mould of heating layer is provided with grid pattern, by heating mould, makes the place of mould protrusion by cover material molding bonded to each other.Certainly, grid can adopt any known additive method in this area to prepare.
In this embodiment, self-heating thermal insulation facial film is sealed packing before using, in order to prevent that the heat-generating composition in heating layer was oxidized by airborne oxygen and moisture before using, of the present invention packing can consist of the impermeable any suitable material of gas substantially, for example plastic sheeting.
In this embodiment, heat-generating composition comprises in weight portion: 50 parts of medical iron powders, 15 parts of active carbons, the salt of 5 parts, 3 parts of Vermiculitums, 1 part of water-absorbing resins, 5 parts of water, 1 part of kieselguhr.In actual use, the heat-generating composition generating heat as contacting with airborne oxygen adopts the mixture of oxidability metal, activated carbon, inorganic metal salt, water and macromolecule wetting agent etc.
Oxidability metal powder is iron powder, aluminium powder etc., still, conventionally adopts iron powder, uses reduced iron powder, atomized iron powder, electrolytic iron powder etc.As long as the particle diameter of iron powder can be brought into play the scope of warm effect, be generally 10~300 μ m left and right, preferably 10~100 μ m left and right.The content of iron powder is preferably 30~80wt% left and right, more preferably 30~50wt% left and right.
The main effect of activated carbon, for more uniform distribute heat, makes surface temperature average, avoids local temperature too high or too low.Active carbon is water suction well not only, and absorbs the water vapour evaporating because of the heat of heat-generating composition generation, contributes to the escape of anti-sealing.Therefore, active carbon can play a role as water conservation material.Active carbon can also absorb the foul smell being produced by oxidation of iron powder.As above-mentioned active carbon, for example, can be applicable to using the active carbon from preparations such as Exocarpium cocois (Cocos nucifera L), timber, Linesless charcoal, coal, bone black.As long as the particle diameter of active carbon can be brought into play the scope of warm effect, be generally 10~300 μ m left and right, preferably 10~100 μ m left and right.The content of activated carbon is preferably 3~25wt% left and right, more preferably 10~15wt% left and right.
Inorganic metal salt can make the oxidation reaction of iron powder and air easily carry out, and by the surface activation of iron powder, thereby can promote the oxidation reaction of ferrum.Can use the slaine using in known heat-generating composition, for example, the sulfate such as iron sulfate, potassium sulfate, sodium sulfate, manganese sulfate, magnesium phosphate; The chlorides such as copper chloride, potassium chloride, sodium chloride, calcium chloride, manganese chloride, magnesium chloride, Cu-lyt. etc.In addition, also can use carbonate, acetate, nitrate and other salt.These slaines can be used separately use in combinations of two or more.As long as the particle diameter of above-mentioned slaine, for not hindering the scope of effect of the present invention, is generally 100~700um left and right, is preferably 200~600 μ m left and right.The content of slaine is preferably 0.5~10wt% left and right, more preferably 1~5wt% left and right.
Water in heat-generating composition can be used distilled water, tap water etc., and its content is preferably 1~20wt% left and right, more preferably 1~5wt% left and right.
Except above-mentioned iron powder, active carbon, slaine and water, as required, heat-generating composition also can contain other additives.For example, heat-generating composition may contain water-absorbing resins, and water-absorbing resins evenly stores the internal moisture of heating layer in the situation that of sealing anoxia, after sealing bag to be opened, and the moisture accelerating oxidation chemical effect that in airborne oxygen and heating layer, resin discharges.Water-absorbing resins includes but not limited to the liquor-saturated copolymer of isobutene .-maleic acid, polyvinyl alcohol-acrylic copolymer, Starch with Acrylic Acid salt graft copolymer, polyacrylate cross-linking agent, acrylates-propylene vinegar copolymer, acrylates-propylene phthalein amine copolymer thing, polyacrylonitrile cross-linking agent etc.These water-absorbing resins, can be used separately use in combinations of two or more.As long as the particle diameter of above-mentioned water-absorbing resins, for not hindering the scope of effect of the present invention, is generally 100~500um left and right, is preferably 200~400 μ m left and right.The content of water-absorbing resins is preferably 0.5~10wt% left and right, more preferably 1~5wt% left and right.Heat-generating composition also may contain Vermiculitum, and Vermiculitum mainly plays insulation, heat insulation effect, makes temperature more lasting.As long as the particle diameter of Vermiculitum, for not hindering the scope of effect of the present invention, is generally below 300um left and right, is preferably below 200um left and right.The content of Vermiculitum is preferably 1~20wt% left and right, more preferably 3~13wt% left and right.
In this embodiment, what skin and heat-insulation layer all adopted is thin film, the thickness of facial film is mainly determined by heating layer, while being used on skin of face in order to meet, heating temp is 38~42 ℃, and fever time is 10~25 minutes, the thickness of this facial film is 2~8mm, the general thickness that is loaded in the graininess heat-generating composition in heating layer is about 2~8mm, and when this thickness, facial film can be fitted in face well.
Embodiment bis-
As Fig. 3, be another embodiment of self-heating thermal insulation facial film of the present invention, the difference of itself and embodiment mono-is, facial film 20 corresponding human eyes' position does not arrange perforate, in other words, is the closed type facial film of eyes position sealing.
In this embodiment, because corresponding human eye place does not arrange perforate, like this, can carry out almost omnibearing clean and maintenance in the absolutely large logarithm region except mouth and nose to human face.And the heating layer of three-decker and heat-insulation layer can also keep healthy to eyes in facial film, play the effect of eye hot compress, and prevent xerophthalmia.
Embodiment tri-
In this embodiment, on the surface that the heat-insulation layer of facial film contacts with body skin, be also provided with for described film being fixed to the hydrogel layer at user's body position.Hydrogel (Soluble Hydrogel) can be used as body adhesives, and film is fixed on to body part.
Hydrogel be take water as disperse medium, when gel is attached on skin, is subject to the impact of body temperature, and the physical arrangement of gel inside is from solid-state liquefy, and in penetrating to the skin.Therefore, as a further improvement on the present invention, can in hydrogel matrix, add the raw material of effect, for example, the active component of collagen protein, hyaluronic acid, arbutin, nicotiamide, volatile oil or other health product, topical drug etc.Because self-heating thermal insulation film of the present invention has the heat-insulation layer of waterproof thermal-insulated performance, the moisture in hydrogel cannot be penetrated into heating layer, thereby can not have any impact to the heating peak value of heating layer and heating effect.The heat that heat-insulation layer also contributes to maintain in hydrogel can not distribute rapidly.
Embodiment tetra-
In this embodiment, the difference of itself and embodiment mono-is only, the formula of heat-generating composition is different, and the formula of heat-generating composition is by weight: 30 parts of medical iron powders, 10 parts of active carbons, the salt of 1 part, 13 parts of Vermiculitums, 5 parts of water-absorbing resins, 1 part of water, 5 parts of kieselguhr.
Invention effect
In order to test self-heating thermal insulation facial film of the present invention in the effect aspect beauty treatment and health care, 50 experimenters have been collected, in experimenter face, first apply traditional facial film of so-and-so brand of selling on market, then at experimenter's a left side half face or right half face, be applied with self-heating thermal insulation facial film prepared by the embodiment of the present invention four, with have gentle hands, be gently fixed on the face, after 15 minutes, take off facial film of the present invention and traditional facial film, the result of use of inquiry and viewing test person's two parts face.Result, that a part of face that the common expression of experimenter has applied self-heating thermal insulation facial film of the present invention is more comfortable, through the moisture detection of face, half of appearance ratio with the traditional facial film of independent use, the water content of half of face that has applied self-heating thermal insulation facial film of the present invention is generally higher, and perusal also shows half of face more smooth and moist that has applied self-heating thermal insulation facial film of the present invention.
Self-heating thermal insulation facial mask structure of the present invention is simple, not limited by environmental resource, without outside resources, provides energy, and safety, stable, evenly heating, can extend fever time effectively, reduces heating peak temperature.The gentle heat that heating layer and heat-insulation layer distributed and maintained makes skin in comfort conditions, improves blood circulation, and skin pore amplifies, and sweat and dirt oils and fats are discharged.When the nourishing pack with traditional is used together with skin care item, can improve the absorption of skin to traditional facial film and skin care item effective ingredient, when reducing skin care item consumption, can also increase skin effect, convenience, saving and environmental protection.Traditional facial film effect is single, do not possess spontaneous heating function, do not there is heat insulation function yet, its effective ingredient is difficult to be absorbed by the skin (especially lower in ambient temperature, in the situation that face's pore shrinks), the ice-cold discomfort of bringing while using traditional lamellar and mud shape facial film under dry season or cold region environment in the winter time, make user abandon continuing to use, can not when skin needs most moisturizing, be moistened, facial film of the present invention has made up blank and the defect of facial film skin care field in prior art.
And, self-heating thermal insulation facial film cost of the present invention is low, for disposable use, safety and sanitation when face or other skin sensitivity positions are used in contact, have avoided the sterilization demand of reusable contact skin physics electro-heat equipment and the potential hygienic risk of sterilizing operation lack of standardization.After use, can not produce endotoxin contamination, exothermic material can reclaim in environmental protection, as the material that improves earth quality.

Claims (18)

1. a self-heating thermal insulation facial film, it is characterized in that: described facial film has at least three-decker at the position in corresponding human body face region, described three-decker is respectively the skin that consists of gas permeable material from outside to inside, be mounted with by contact the heat-generating composition generating heat and the upper front cover at least contacting with described skin with air is the heating layer that forms of gas permeable material, by the heat-insulation layer that has waterproof thermal-insulated performance material and form.
2. self-heating thermal insulation facial film as claimed in claim 1, is characterized in that: described heat-insulation layer is the PET metal coating consisting of PET thin film and gold or argentine material.
3. self-heating thermal insulation facial film as claimed in claim 2, is characterized in that: the metal adopting in described PET metal coating is one or more the mixture in aluminum, nickel or chromium.
4. self-heating thermal insulation facial film as claimed in claim 1, is characterized in that: in described heating layer, be provided with grid, described heat-generating composition is loaded in each grid equably.
5. self-heating thermal insulation facial film as claimed in claim 4, is characterized in that: described grid is that the lower front cover that the upper front cover that contacts with described skin in described heating layer contacts with described heat-insulation layer forms by bonding seam heat bonding.
6. self-heating thermal insulation facial film as claimed in claim 1, is characterized in that: described skin is non-woven fabrics or the woven of natural fiber or synthetic fibers.
7. self-heating thermal insulation facial film as claimed in claim 1, is characterized in that: described facial film is sealed packing before using.
8. self-heating thermal insulation facial film as claimed in claim 1, is characterized in that: the heat-generating composition in described heating layer comprises oxidizable metal, activated carbon, inorganic metal salt, water, macromolecule wetting agent, water absorbing agent.
9. self-heating thermal insulation facial film as claimed in claim 8, is characterized in that: the heating temp of the described heating layer of described facial film is 38~42 ℃, and fever time is 10~25 minutes.
10. self-heating thermal insulation facial film as claimed in claim 9, is characterized in that: the heat-generating composition in described heating layer comprises in weight portion: 30~50 parts of medical iron powders, 10~15 parts of active carbons, the salt of 1~5 part, 3~13 parts of Vermiculitums, 1~5 part of water-absorbing resins, 1~5 part of water.
11. self-heating thermal insulation facial films as claimed in claim 9, is characterized in that: the heat-generating composition in described heating layer comprises in weight portion: 30~50 parts of medical iron powders, 10~15 parts of active carbons, the salt of 1~5 part, 3~13 parts of Vermiculitums, 1~5 part of water-absorbing resins, 1~5 part of water, 1~5 part of kieselguhr.
12. self-heating thermal insulation facial films as described in claim 9 or 10, is characterized in that: the position thickness in described facial film diaphragm with described three-decker is 2~8mm.
13. self-heating thermal insulation facial films as claimed in claim 1, is characterized in that: on the described heat-insulation layer of described film and the surface of human body face contact skin, be also provided with for described film is fixed to facial hydrogel layer.
14. self-heating thermal insulation facial films as claimed in claim 13, is characterized in that: in described hydrogel layer, also contain medicine for external use active component and/or externally-applied health-care products active component and/or skin care item active component.
15. self-heating thermal insulation facial films as claimed in claim 1, is characterized in that: the corresponding human body oral area of described facial film has perforate, and corresponding nostril has opening.
16. self-heating thermal insulation facial films as claimed in claim 15, is characterized in that: described facial film also corresponding human body eye has perforate.
17. self-heating thermal insulation facial films as described in claim 15 or 16, is characterized in that: described facial film both sides also have for facial film being fixed on to the fixing band of human body head, and the tail end of described fixing band has VELCRO.
The using method of 18. self-heating thermal insulation facial films as described in claim 15 or 18, it is characterized in that: before applying described facial film, in face, first apply traditional nourishing pack or skincare product, or in advance skincare product is coated in to described heat-insulation layer by the surface with contact skin; Afterwards, facial film is directly fitted in to people's face.
CN201410381994.6A 2014-08-06 2014-08-06 A kind of self-heating thermal insulation facial film Active CN104146874B (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
CN201410381994.6A CN104146874B (en) 2014-08-06 2014-08-06 A kind of self-heating thermal insulation facial film
RU2017106961A RU2683719C2 (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
US15/501,864 US20170231813A1 (en) 2014-08-06 2015-06-17 Self-heating thermal-insulation film and face mask and eye mask manufactured therefrom
EP15828995.9A EP3178453A4 (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
SG11201700905YA SG11201700905YA (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
PCT/CN2015/081597 WO2016019762A1 (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
KR1020177005846A KR102111837B1 (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
JP2017506828A JP6711816B2 (en) 2014-08-06 2015-06-17 Self-heating and heat retaining film, and face mask and eye sheet produced by the film
CA2957322A CA2957322C (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
HK15107464.5A HK1204841A2 (en) 2014-08-06 2015-08-04 Self heat-generating thermal insulation film and facial and eye masks produced therefrom
TW104125374A TWI641484B (en) 2014-08-06 2015-08-05 Self-heating insulation film and application thereof

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WO2016019762A1 (en) * 2014-08-06 2016-02-11 陈蕾 Self-heating insulating film and face mask and eye mask manufactured therefrom
CN105709330A (en) * 2016-01-19 2016-06-29 上海沪户实业发展有限公司 Self heating type nursing mat and preparation method thereof
CN105878129A (en) * 2016-06-08 2016-08-24 瑞福祥药业(广西)有限公司 Light wave mask and preparation method thereof
CN106137893A (en) * 2015-03-31 2016-11-23 佛山市禾才科技服务有限公司 A kind of whitening heating facial film
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CN108096039A (en) * 2017-12-29 2018-06-01 上海指谱智能科技有限公司 A kind of automatic heating MASQUE APAISANT HYDRATANT and preparation method thereof
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CN112176525A (en) * 2020-09-24 2021-01-05 浙江王金非织造布有限公司 One-way water guide mask base material and preparation method thereof
CN112498978A (en) * 2020-11-08 2021-03-16 万允志 Low-cost extremely-portable constant-temperature nursing patch technology
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WO2016019762A1 (en) * 2014-08-06 2016-02-11 陈蕾 Self-heating insulating film and face mask and eye mask manufactured therefrom
WO2016019764A1 (en) * 2014-08-06 2016-02-11 陈蕾 Multi-purpose self-temperature control film and face mask and eye mask manufactured therefrom
CN106137893A (en) * 2015-03-31 2016-11-23 佛山市禾才科技服务有限公司 A kind of whitening heating facial film
CN108135735A (en) * 2015-10-05 2018-06-08 花王株式会社 Vapor generates body and warm utensil
CN105709330A (en) * 2016-01-19 2016-06-29 上海沪户实业发展有限公司 Self heating type nursing mat and preparation method thereof
CN105878129A (en) * 2016-06-08 2016-08-24 瑞福祥药业(广西)有限公司 Light wave mask and preparation method thereof
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CN108096039A (en) * 2017-12-29 2018-06-01 上海指谱智能科技有限公司 A kind of automatic heating MASQUE APAISANT HYDRATANT and preparation method thereof
CN115916923A (en) * 2020-06-05 2023-04-04 株式会社韩明爱唯斯 Heating element composition, method for producing eye mask, and apparatus for producing eye mask
CN112176525A (en) * 2020-09-24 2021-01-05 浙江王金非织造布有限公司 One-way water guide mask base material and preparation method thereof
CN112498978A (en) * 2020-11-08 2021-03-16 万允志 Low-cost extremely-portable constant-temperature nursing patch technology
CN114522108A (en) * 2022-03-28 2022-05-24 左点健康产业(深圳)有限公司 Self-heating steam mask capable of promoting skin absorption

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