CN104127324B - A kind of self-heating thermal insulation three dimensional face mask - Google Patents

A kind of self-heating thermal insulation three dimensional face mask Download PDF

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Publication number
CN104127324B
CN104127324B CN201410382376.3A CN201410382376A CN104127324B CN 104127324 B CN104127324 B CN 104127324B CN 201410382376 A CN201410382376 A CN 201410382376A CN 104127324 B CN104127324 B CN 104127324B
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dimensional face
self
heating
heat
thermal insulation
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CN104127324A (en
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黄英骆
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Zhuhai Morning Enterprise Management Consulting Co.,Ltd.
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Priority to CN201410382376.3A priority Critical patent/CN104127324B/en
Publication of CN104127324A publication Critical patent/CN104127324A/en
Priority to US15/501,864 priority patent/US20170231813A1/en
Priority to SG11201700905YA priority patent/SG11201700905YA/en
Priority to JP2017506828A priority patent/JP6711816B2/en
Priority to CA2957322A priority patent/CA2957322C/en
Priority to KR1020177005846A priority patent/KR102111837B1/en
Priority to EP15828995.9A priority patent/EP3178453A4/en
Priority to RU2017106961A priority patent/RU2683719C2/en
Priority to PCT/CN2015/081597 priority patent/WO2016019762A1/en
Priority to HK15107464.5A priority patent/HK1204841A2/en
Priority to TW104125374A priority patent/TWI641484B/en
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Abstract

The invention discloses a kind of self-heating thermal insulation three dimensional face mask, including at least three-decker, be respectively from outside to inside be made up of gas permeable material outer layer, be mounted with by with air contact and the heat-generating composition that generates heat and with the cover of described outer layer be at least gas permeable material constitute heating layer, by having the heat-insulation layer that waterproof thermal-insulated performance material is constituted.The self-heating thermal insulation three dimensional face mask simple in construction of the present invention, is not limited by environmental resource, it is not necessary to outside resources provides energy, safe and stable, consistent heat generation, it is possible to effectively extend fever time, reduces heating peak temperature.When this self-heating thermal insulation three dimensional face mask is applied to facial skin, can improve blood circulation, make skin pore amplify, sweat is discharged with dirt grease.When being used together with traditional nourishing pack and skin care item, skin can be improved to tradition facial film and the absorption of skin care item effective ingredient, while reducing skin care item consumption, moreover it is possible to increase skin effect, use safety and sanitation, low cost.

Description

A kind of self-heating thermal insulation three dimensional face mask
Technical field
The present invention relates to a kind of three dimensional face mask, particularly relate to a kind of can the three dimensional face mask of self-heating thermal insulation.
Background technology
Facial film is a kind of carrier of face beautifying health keeping product, applies ointment or plaster on the face 15~30 minutes, when skin care products After nutrient is slowly absorbed by the skin, film can be unloaded.Facial film is most basic is also that most important purpose is Make up makeup removing and the still not enough cleaning that washes one's face, realize other maintenance function on this basis, Such as replenishing water and preserving moisture, whitening and anti-aging etc..
Traditional facial film is usually a diaphragm, covers and face after tiling, and it is mainly Utilize and cover in the of short duration time of face, be temporarily isolating air and the pollution in the external world, improve skin temperature, The pore expansion of skin, promotes sweat gland secretion and metabolism, makes the oxygen content of skin increase, favorably The metabolic product of epidermis cell and the oil substances of accumulation, the moisture in facial film is got rid of in skin Penetrating into the horny layer of epidermis, skin becomes soft, and skin light naturally is flexible.Such facial film merit Imitate more single, relatively limited for the cleaning action of facial skin and assimilation effect all ratios of skin care item.
The three dimensional face mask produced afterwards, it is mainly connected in face's centre centering by two parts diaphragm Forming, form the stereo profile of face, such three dimensional face mask is compared to traditional planar diaphragm, main If enhancing the stickiness with face so that it is can preferably be close to the face of people, difficult drop-off. Effect still seems single, do not improve the cleaning action of facial skin well and to skin protection The assimilation effect of product.
For the osmotic absorption of the nutritional labeling in facial film, traditional method can also is that first puts facial film At temperature bubbly water once, or with steam, facial film is steamed, in order to increase the temperature of facial film, thus When spreading on the face, preferably open face's pore, promote blowdown and cosmetic result.
Additionally, in prior art, also have and use for reference the spontaneous heating paster that exothermic oxidation technology art is made, example Such as warmer, daily warming and treatment arthralgia due to cold-dampness medical market is widely used.These Paster typically by bag, exothermic material, adhesive layer, be pasted onto the covering that adhesive layer outer surface can peel off Layer is constituted, and during use, is peeled off by cover layer, is attached on clothes by adhesive layer, and in the face of skin is bag Body air-permeable layer, exothermic material and the moisture in air and oxygen generation chemical reaction, produce heat, from And play warming effect.But, all there is following defect in current all of spontaneous heating patch: 1) just Beginning temperature is too high or heat scatters and disappears too fast, easily causes low temperature and scalds, and is sticking position because of warm generation Histologic lesion, or need warming position to maintain temperature low, heat production is disorderly;2) generate heat uneven, Local temperature is too high.And, this kind of spontaneous heating paster can not coordinate skin care item, topical drug or health care Product use, because usually containing moisture or oil content, these water in skin care item, topical drug or health product Divide or penetrate in the face of skin together with the oil content sweat that skin is discharged when exothermic padding directly contacts skin The air-permeable layer of skin, impact heating chemically stable, heating peak value is difficult to control to.It addition, exothermic material Chemical effect product also can be handed over the sweat that the moisture/oil in topical drug or health product point or skin are discharged Fork pollutes or skin infection.
The Chinese invention patent application of Publication No. CN101547667A, discloses a kind of oneself's heating Facial film, this facial film is mainly generated heat by the exothermic composition in its heat transfer pad, the temperature of its heating and time Between all rely on the permeability of gas permeable polymer film of Heat Transfer Control pad, thus control into The amount of oxygen contacted with exothermic composition in entering heat transfer pad, is used as exothermic composition and determines the carrier of speed. But such oneself's heating facial film is also again without overcoming the various defects of above-mentioned existence, such as heat The problem scattered and disappeared, uneven problem of generating heat, especially when having coated skin care item or health product on the face Time, still can there is the sweat that moisture, oil content or skin in skin care item or health product discharged and ooze Enter in its heat transfer pad, the impact chemically stable defect of heating;Further, the chemical effect of exothermic material The sweat cross-contamination that product also can be discharged with externally applied product or the skin with moisture or oil content, exists Burn or the hidden danger of skin infection.Further, this patent documentation does not proposes the shape combining facial film to rise yet Technical scheme to uniformly cleaning with the uniformly more preferable effect of maintenance.
Summary of the invention
For the defect of prior art, the technical problem to be solved is to provide a kind of effect Various, fever time be can effectively extend, heating peak temperature, uniform heat distribution reduced;And Skin care item effect can be obviously enhanced, it is to avoid the self-heating thermal insulation three dimensional face mask that skin of face infects.
For solving above-mentioned technical problem, the present invention adopts the technical scheme that:
A kind of self-heating thermal insulation three dimensional face mask, described three dimensional face mask is connected with each other shape by least two panels diaphragm Adult body face contour, the diaphragm position in described three dimensional face mask correspondence human body face region includes at least three Rotating fields, described three-decker from outside to inside be respectively be made up of gas permeable material outer layer, be mounted with logical Cross the heat-generating composition generated heat with air contact and be at least ventilative with the cover of described outer layer Material constitute heating layer, by having the heat-insulation layer that waterproof thermal-insulated performance material is constituted.With prior art Comparing, the technical program adds by having the heat-insulation layer that waterproof thermal-insulated performance material is constituted, in reality During use, heat-insulation layer makes the even heat distributed in heating layer stably pass on skin, and makes The heat being delivered to skin will not lose soon, it is to avoid initial temperature too high initiation low temperature is scalded Risk, and effectively stably maintain skin in suitable temperature.And, this heat-insulation layer stops The sweat that moisture, oil content or skin in external use skin care, topical drug or health product is discharged oozes Enter to air-permeable layer, thus avoid heating peak value problem rambunctious, when it also avoid use exterior-applied article The problem such as cross-contamination, skin infection.The self-heating thermal insulation three dimensional face mask of the present invention is not limited to above-mentioned The three-decker limited, in actual use, this film may also include protective layer, adhesive layer etc..? On the other hand, three-decker is used in combination by the present invention with three dimensional face mask, and three dimensional face mask can be with people's Face preferably fits, thus is more beneficial for uniformly cleaning and the uniformly maintenance of face.
As a further improvement on the present invention, described heat-insulation layer is by PET film and golden or silver color gold Belong to the PET metal coating (metallized polyethylene terephthalate (MPET)) that material is constituted. In one embodiment, heat-insulation layer is by using physical vapor coating technique that PET film is carried out gold Genusization is formed.Under vacuum, use the physical methods such as heating, make metal surface gasify, gas The metallic atom changed condenses or is deposited on the cold PET film of metal steam source of the gas.An embodiment In, the metal that PET metal coating is used is aluminum, but in other embodiments, it is possible to use other Metal, such as, nickel or chromium, it is possible to use metal mixture.This PET metal coating compares metal forming Much thinner, its thickness equals to or less than 0.5 micron.This PET metal coating is flexible good, waterproof effect The most splendid, and will not As time goes on fade or variable color.Golden or silver color metal reflective plates Film has splendid reflection heat energy function, prevents heat loss through radiation, it is possible to effectively preserve heat-insulation layer and skin Between more than 90% heat, the incorporation of metal also contributes to the even heat in heating layer, quickly Be delivered to skin, thus effectively regulate body temperature.And, golden or silver color metal coating also helps In the most more trying to please user.Except polyethylene terephthalate thin film (PET), orient poly-third Alkene thin film (OPP), nylon, polyethylene and cast polypropylene can be used for the metal coating of the present invention.
As a further improvement on the present invention, being additionally provided with grid in heating layer, heat-generating composition is by all It is loaded in each grid evenly.In actual use, heat-generating composition is generally powder or granule Shape, is transporting or is putting on skin, and these granules or powder are concentrated under gravity and send out A certain position in thermosphere, and other positions do not have heat-generating composition, such as, this film are applied to face During portion, under standing state, the heat-generating composition of graininess or powder can be concentrated and drop at heating layer Bottom, thus cause lower part heat too much, and the problem that upper part heat is very few.With the addition of net After lattice so that heat-generating composition is loaded in each grid equably, it is ensured that during use, heating Heat in Ceng can be evenly distributed, and it also avoid the Cold Iron cold danger of the too high initiation of local temperature. The particular number of grid and shape can be according to the heat-generating composition of required loading, predetermined heat preservations The factor such as area adjusts, such as, the shape of grid can be oval, circular, square, lace shape, Pentagon or other shapes, the number of grid is 2 or more than 2.
As a further improvement on the present invention, with cover and the guarantor of outer layer during grid is heating layer The lower front cover of temperature layer contact is formed by bonding seam heat bonding.Grid and the front cover material up and down of heating layer Expecting straight forming together, when producing, the bonding mould of heating layer is provided with grid pattern, by heating Mould makes place that mould protrudes by molding bonded to each other for cover material.Certainly, grid can use this Prepared by any of additive method in field.
As a further improvement on the present invention, the outer layer of the self-heating thermal insulation film of the present invention is natural fiber The non-woven fabrics of synthetic fibers or weaving cloth.Non-woven fabrics typically polyester is prepared from by meltblown, Low cost, quality are soft, good permeability, and the ventilated membrane material of non-woven fabrics and heating layer cover Similar, bi-material is easier to be combined.
In one embodiment of the invention, self-heating thermal insulation three dimensional face mask is before the use by sealed bundle Dress.In order to prevent the heat-generating composition in heating layer the most by the oxygen in air and moisture Oxidation, packing of the present invention can be made up of the impermeable any suitable material of substantially gas, Such as plastic sheeting.
Heat-generating composition in heating layer include oxidizable metal, activated carbon, inorganic metal salt, water, Macromolecule wetting agent, water absorbing agent.The ultimate principle of spontaneous heating is that the oxidizable metal in heating layer is with empty Moisture and oxygen in gas produce heat and heat skin, and utilization is chemical energy.Heating group Other compositions in compound are to promote that oxidation reaction is carried out.
As a modification of the present invention, the heating temp of the heating layer of described facial film is 38~42 DEG C, Fever time is 10~25 minutes.In the range of this temperature and time, facial skin is felt as snug as a bug in a rug, Blood circulation is accelerated, and skin pore amplifies, and sweat is discharged with dirt grease.If temperature is too low or time Between too short, do not have the effect opening pore;If temperature is too high or overlong time, face may be made The epidermis of portion's skin has scald in various degree, and the blood capillary of epidermis can be expanded rapidly or for a long time It is in expansion state, is easily caused skin dehydration, the problem such as corse sweat pore.Heating temp and time are permissible By controlling the ratio of each composition in the charging ratio of heat-generating composition, heat-generating composition and suitably setting Ventilative outer layer and the air-vent size of heating layer cover, quantity etc. adjust.In general, heating layer User's skin can be heated to enough temperature, provide the user effective heat but do not result in and appoint What discomfort, such as, the film of the present invention can make the skin temperature of user increase to about 38~45 DEG C, It keeps the time quantum of heating to be likely to be dependent on special application, such as, more than 15 minutes, more than 30 Minute, even greater than 1 hour.
As the optimal way of the present invention, the heat-generating composition in described heating layer includes in parts by weight: 30~50 parts of medical iron powders, 10~15 parts of activated carbons, the salt of 1~5 part, 3~13 parts of Vermiculitums, 1~5 Part water-absorbing resins, 1~5 part of water.In the case of using the non-woven fabrics of routine, ventilated membrane, this is joined Side is at normal environmental conditions, it is ensured that heating temp is 38~42 DEG C, and fever time is 10~25 Minute.
As present invention further optimization, the heat-generating composition in described heating layer wraps in parts by weight Include: 30~50 parts of medical iron powders, 10~15 parts of activated carbons, the salt of 1~5 part, 3~13 parts of Vermiculitums, 1~5 part of water-absorbing resins, 1~5 part of water, 1~5 part of kieselguhr.Diatomaceous ultra micro pore can be certainly The dynamic moisture absorbed in air, is stored, and the steam of excess will not be made to enter heating layer and draw Play temperature too high;When environmental wet becomes and declines, the moisture that kieselguhr can will be stored in ultra micro pore Discharge, the steam deficiency entering heating layer will not be made to cause facial film temperature too low.Pass through diatom The storage of moisture in air and slow release are made the heating-up temperature of the film of the present invention more constant by soil.
As present invention further optimization, the thickness of described facial film is 2~8mm.This thickness range is not Only can meet the three-decker of described film and above-mentioned heating temp and time, moreover it is possible to good fit in Face.The area of facial film uses the size of conventional facial film.
As a further improvement on the present invention, the heat-insulation layer of the three dimensional face mask of the present invention connects with body skin It is additionally provided with the hydrogel layer for described film being fixed to user's body position on the surface touched.Water-setting Film can be fixed on body part as body adhesives by glue (Hydrogel).
Hydrogel is with water as disperse medium, when gel is attached on skin, is affected by body temperature, Physical arrangement within gel is from solid state into liquid state, and in penetrating to the skin.Accordingly, as this Bright further improvement, can add both effectiveness raw material, such as, collagen in hydrogel matrix Albumen, hyaluronic acid, arbutin, nicotiamide, volatile oil or other health product, topical drug Active component etc..Self-heating thermal insulation film due to the present invention has the heat-insulation layer of waterproof thermal-insulated performance, water Moisture in gel cannot penetrate into heating layer, from without imitating the heating peak value of heating layer and heating Fruit has any impact.The heat that heat-insulation layer also contributes to maintain in hydrogel will not distribute rapidly.
As one embodiment of the present of invention, described three dimensional face mask is by face and the right side on the left of the most corresponding human body The left side diaphragm of side face and right side diaphragm two panels diaphragm are constituted, and described left side diaphragm and right side diaphragm are each Leading section is provided with jointing material, and mutually bonds in the midline of human body face and form three-dimensional face wheel Wide.It is said that in general, left side diaphragm and right side diaphragm are symmetrical, by left and right at the facial midline of people Two latallaes mutually bond and form three-dimensional face contour, it is possible to the preferably face with people fits, gram The facial film having taken the overall plane of traditional easily produces fold when being affixed on face, it is difficult to face Portion is uniformly adjacent to, thus affects the defect of cleaning and cosmetic result.
As the improvement of technique scheme of the present invention, described left side diaphragm and right side diaphragm respective before At the correspondence human body external nose of end, there is the most outwardly protuberance, have below described protuberance There is the opening of corresponding human body oral area, be that circular arc downwardly extends until bottom with certain radian below opening, Described left side diaphragm with in the respective leading section of right side diaphragm except the opening portion corresponding with human body oral area Scope in addition is provided with jointing material, and mutually bonds.Leading section and right side film due to left side diaphragm The leading section of sheet all has top-down protrusion at the external nose of corresponding human face, therefore, works as a left side After latallae and the bonding of right side diaphragm, can naturally be formed from top to bottom at the external nose of face Protuberance, thus well with external nose fit.In the lower section of the opening portion of corresponding human body oral area, front End is that circular arc downwardly extends until bottom with certain radian, so, and left side diaphragm and right side diaphragm After bonding, its middle and lower part can form one can be naturally adaptive, laminating with the bottom of people and jaw portion Curved surface, thus obtain and the face attached effect of more preferable note.
As a kind of improvement of technique scheme of the present invention, three dimensional face mask of the present invention can make except Corresponding oral area has opening, the closed type that remaining position all seals, it is preferred that described left side diaphragm and The leading section of right side diaphragm is positioned at position relative with human face glabella above described protuberance also have There is the concave arc slightly concaved, certainly, still there is at concave arc jointing material.Due in described prominent Position relative with human face glabella above portion also has the concave arc slightly concaved, when left side diaphragm After bonding with right side diaphragm, at this concave arc, also with regard to glabella and the nose of external nose of corresponding human face At root, a slight inside depression can be formed, thus be preferably close to face glabella and the nasion Depressed area.The three dimensional face mask of this closed type can be to the overwhelming majority in addition at the mouth and nose of face Region carries out the most omnibearing cleaning, maintenance.Further, the heating layer of three-decker and guarantor in facial film Eyes can also be kept healthy by temperature layer, plays the effect of eye hot compress, and prevents xerophthalmia.
As the another kind of improvement of technique scheme of the present invention, three dimensional face mask of the present invention can be made into Except corresponding human body oral area and eyes are respectively provided with the through hole type of opening, after applying facial film, the eyes of people can With exposed out, now, the leading section of described left side diaphragm and right side diaphragm is positioned at described protuberance The position relative with glabella with human body eye, top also has the recess concaved, and this recess can be Approximation semiellipse shape, or semicircular shape, as long as left and right diaphragm can expose after connecting suitably Eyes, are unlikely to again to cause the more skin of face not covered by facial film.Now, a described left side Latallae is not provided with except the opening portion corresponding with human body oral area with in the respective leading section of right side diaphragm Outside jointing material, the notch part corresponding with eyes is also not provided with jointing material, say, that front end Except the opening portion corresponding with human body oral area and the notch portion corresponding with human body eye and glabella in portion Scope beyond Fen is provided with jointing material, and mutually bonds.
Further, the rear end of described left side facial film and right side facial film also has for being fixed on by facial film The fixing band of human body head, the tail end of described fixing band has VELCRO.Thus the present invention is three-dimensional After facial film spreads on face, can fix around head with fixing band, and use VELCRO to tighten.? In detailed description of the invention, the facial film of the present invention is not limited to the mode of fixing band and VELCRO and is fixed on head Portion, it is also possible to using, such as, frenulum, the mode of button are fixed.
Present invention also offers the using method of a kind of self-heating thermal insulation three dimensional face mask, apply described Before film, first apply traditional nourishing pack or skincare product in face, or in advance skincare product is coated with Overlay on described heat-insulation layer by with on the surface of contact skin;Left side facial film and right side facial film are bonded in one Rise, and the three dimensional face mask after bonding is fitted in the face of people.Owing to the self-heating thermal insulation of the present invention stands Dignity film can make skin pore amplify, and promotes that sweat is discharged with dirt grease, therefore, it is possible to improve skin The skin absorption to skin care item effective ingredient, can also increase skin effect while reducing skin care item consumption. Further, the even heat distributed during heat-insulation layer makes heating layer stably passes on skin so that transmission Heat to skin will not lose soon, it is to avoid the wind that initial temperature too high initiation low temperature is scalded Danger, and effectively stably maintain skin in suitable temperature.And, outside this heat-insulation layer prevents The sweat discharged with the moisture in skin care item, topical drug or health product, oil content or skin penetrates into Air-permeable layer, thus avoid heating peak value problem rambunctious, intersect when it also avoid use exterior-applied article The problems such as pollution, skin infection.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention a kind of self-heating thermal insulation three dimensional face mask embodiment one.
Fig. 2 is that the self-heating thermal insulation three dimensional face mask shown in Fig. 1 is after left side diaphragm and right side diaphragm bond Structural representation.
Fig. 3 is in embodiment illustrated in fig. 1, and three-dimensional diaphragm fits in the profile schematic diagram of human body face.
Fig. 4 is in embodiment illustrated in fig. 1, on three dimensional face mask diaphragm three layers of corresponding human body face region Structure sectional view.
Fig. 5 is the structural representation of the present invention a kind of self-heating thermal insulation three dimensional face mask embodiment two.
Fig. 6 is that the self-heating thermal insulation three dimensional face mask shown in Fig. 5 is after left side diaphragm and right side diaphragm bond Structural representation.
Fig. 7 is in embodiment illustrated in fig. 5, and three-dimensional diaphragm fits in the profile schematic diagram of human body face.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is made a more detailed description, but following description is only used for Explaining property of the present invention is illustrated, protection scope of the present invention is not carried out any restriction, all Use the equivalent structure change that description of the invention and accompanying drawing content are made, be the most in like manner included in the present invention In the range of.
Present invention relates generally to a kind of three dimensional face mask, it is interconnected to form human body by least two panels diaphragm Face contour, compared to a traditional overall planar diaphragm, it can be formed more with the face of people Good laminating such that it is able to face is cleaned uniformly and maintains uniformly.
Embodiment one
In embodiment 1, as it is shown in figure 1, three dimensional face mask 10 is by corresponding to face on the left of human body and right side face Left side diaphragm 11 and right side diaphragm 12 two panels diaphragm constitute, described left side diaphragm 11 and right side diaphragm 12 Each leading section 111,121 is provided with jointing material, and mutually bonds formation in the midline of human body face Three-dimensional face contour.The overall shape of the three dimensional face mask that Fig. 2 is formed after showing the bonding of two panels diaphragm Shape.
In this embodiment, left side diaphragm 11 and right side diaphragm 12 are symmetrical at the facial midline of people, Certainly, left side diaphragm 11 and right side diaphragm 12 are not limited to symmetry by the present invention, it is not excluded that at it In his embodiment, left side diaphragm 11 and right side diaphragm 12 are asymmetric, for the angle of ergonomics, Two latallaes, mutually to this, are beneficial to fit at face.Formation is mutually bonded vertical by left and right sides diaphragm The face contour of body, it is possible to the preferably face with people fits, overcomes overall the putting down of traditional The facial film in face easily produces fold when being affixed on face, it is difficult to be uniformly adjacent to face, thus impact is clear The clean defect with cosmetic result.
As it is shown in figure 1, the respective leading section 111,121 of described left side diaphragm 11 and right side diaphragm 12 is corresponding There is at human body external nose the most outwardly protuberance 112,122, protuberance 112,122 Lower section has the opening 113,123 of corresponding human body oral area, after the bonding of left and right sides diaphragm, and opening 113 It is integrated into a whole with opening 123, forms oral area shape substantially, now, left side diaphragm 11 and the right side 113 and 123 positions of examining of the leading section of latallae 12 need not arrange jointing material.Opening 113 and opening It is that circular arc downwardly extends until bottom with certain radian below mouthfuls 123, arc section 114 bottom formation, 124.Owing to the leading section 111 of left side diaphragm 11 and the leading section 121 of right side diaphragm 12 are all at corresponding human body There is top-down protrusion, therefore, when left side diaphragm 11 and right side diaphragm 12 glue at the external nose of face After conjunction, understand at the external nose of face, naturally form top-down protuberance, thus well Fit with external nose.In the lower section of the opening portion 113,123 of corresponding human body oral area, leading section 111,121 It is that circular arc downwardly extends until bottom with certain radian, so, left side diaphragm 11 and right side diaphragm 12 After bonding, its middle and lower part can form one can be naturally adaptive, laminating with the bottom of people and jaw portion Curved surface, thus obtain and the face attached effect of more preferable note.
Fig. 3 can show the three-dimensional shape after face's laminating of the present embodiment and people more intuitively.Protuberance 112, after 122 bondings, being formed can the protuberance of laminating intact with nose;Opening 113,123 is surrounded Approximate ellipsoidal then relative with the face of people;And arc section 114,124 the most also forms one Three-dimensional curved surface, thus preferably with bottom and the laminating of jaw portion of people.As can be seen here, the present invention implements Example, compared to traditional plane facial film, it more meets the stereo profile of face, such that it is able to and people Face attach equably, bind, and be conducive to cleaning uniform to face and maintenance.
Further, the leading section 111,121 of described left side diaphragm 11 and right side diaphragm 12 is positioned at institute State position relative with glabella with human body eye above protuberance 112,122 and also there is the recess concaved 114,124, this recess can be approximation semiellipse shape, or semicircular shape, if left and right Diaphragm can expose eyes after connecting suitably, is unlikely to again to cause the more face not covered by facial film Portion's skin.Now, the respective leading section 111,121 of described left side diaphragm 11 and right side diaphragm 12 In in addition to opening 113,123 part corresponding with human body oral area is not provided with jointing material, with eyes pair Recess 114,124 part answered also is not provided with jointing material, say, that in leading section except with people Opening 113,123 part that body oral area is corresponding and the recess 114,124 corresponding with glabella with human body eye Scope beyond part is provided with jointing material, and mutually bonds.
Further, as it is shown in figure 1, the rear end of described left side facial film 11 and right side facial film 12 also has use In facial film being fixed on the fixing band 118,128 of human body head, further, described fixing band 118, The tail end of 128 has VELCRO 119,129.Thus after three dimensional face mask of the present invention is spread on face, Can fix around head with fixing band, and use VELCRO to tighten.VELCRO (HOOk&LOOP), Having another name called magic tape, industry slang, also known as double buckle, is a kind of connection adjuvant conventional on clothes, point public affairs Female two sides, one side is the fiber of small, flexible, and circle hair (LOOP), another side is the seta of harder buckle (HOOK)。
In the present embodiment, as it is shown in figure 1, the left side diaphragm 11 of described three dimensional face mask 10 and right side The diaphragm position 116,126 in the most corresponding human body face region of diaphragm 12 includes at least three-decker, As shown in Figure 4, Fig. 4 shows that the profile of these three layers of mechanisms, described three-decker divide from outside to inside Not for the outer layer 131 being made up of gas permeable material, be mounted with by with air contact and the heating generated heat is combined Thing 1321 and at least cover with described outer layer be gas permeable material constitute heating layer 132, by There is the heat-insulation layer 133 that waterproof thermal-insulated performance material is constituted.Graininess or the heat-generating composition of powder 1321 are loaded in heating layer 132, and heat-insulation layer 133 directly contacts with skin 14
In this embodiment, the three-decker of three dimensional face mask is bonded together, and such as, uses viscous Mixture or by the way of heat bonding, is applied directly on skin as an entirety.Raw in reality During producing and using, heat-insulation layer may not be bonded together with outer layer, heating layer, say, that During use, first on skin, it is applied with single heat-insulation layer, applies heating layer and outer layer the most again, also Same heat preservation effect can be obtained.
The purpose using facial film is to clean face, and realizes other maintenance functions on this basis, than Such as replenishing water and preserving moisture, whitening and anti-aging etc., constantly research and development and improvement for facial film are i.e. towards this mesh Mark.The embodiment of the present invention, the position in the diaphragm correspondence human body face region of three dimensional face mask is provided with three layers Structure, especially also also increases on the basis of outer layer, heating layer between heating layer and facial skin By having the heat-insulation layer that waterproof thermal-insulated performance material is constituted, when actually used, heat-insulation layer makes to send out The even heat distributed in thermosphere stably passes on skin, and makes the heat being delivered to skin will not Lose soon, it is to avoid the risk that initial temperature too high initiation low temperature is scalded, and the most stably Maintain skin in suitable temperature.And, this heat-insulation layer prevents external use skin care, medicine for external use The sweat that moisture, oil content or skin in product or health product is discharged penetrates into air-permeable layer, thus avoids Heating peak value problem rambunctious, cross-contamination, skin infection etc. when it also avoid use exterior-applied article Problem.When using facial film embodiment of the present invention, the gentleness that heating layer and heat-insulation layer distributed and maintained Heat makes skin be in comfort conditions, improves blood circulation, and skin pore amplifies, sweat and dirt oil Fat is discharged.When being used together with traditional nourishing pack and skin care item, considerably improve skin pair Tradition facial film and the absorption of skin care item effective ingredient, while reducing skin care item consumption, moreover it is possible to increases Skin effect, convenient, saving and environmental protection.Further, the present invention except above-mentioned three-decker it Outward, using herein in connection with three dimensional face mask, three dimensional face mask preferably can be fitted with the face of people, thus more Be conducive to uniformly cleaning and the uniformly maintenance of face.It may be said that the embodiment of the present invention, in facial film field, Target towards cleaning with maintenance has strided forward major step.
In this embodiment, outer layer 131 is weaved cotton cloth for fibre, and the upper and lower front cover of heating layer 132 all uses Be breathable films, the medical heat-insulating and cold film that heat-insulation layer 33 uses and golden or argentine material structure The metal coating become.In specifically used, it is only necessary to ensure outer layer 131 and heating layer 132 cover (being likely to include lower front cover) is made up of gas permeable material, is not specifically limited for gas permeable material, only If air fully can be imported the heat-generating composition in heating layer.The breathability of gas permeable material Can be ventilative by suitably setting according to the kind of heat-generating composition, amount, predetermined heating temp etc. Hole size, quantity etc. adjust.The thickness of gas permeable material, as long as not hindering the model of the effect of the present invention Enclose.Breathe freely and under conditions of support function meeting, more Bao Yuehao.
Heat-insulation layer 133 is the PET metal coating being made up of with golden or argentine material PET film (metallized polyethylene terephthalate(MPET)).As in the present embodiment, heat-insulation layer is By using physical vapor coating technique that PET film carries out what metallization was formed.Under vacuum, Using the physical methods such as heating, make metal surface gasify, the metallic atom of gasification condenses or is deposited on and leans on On the cold PET film of nearly metal steam source of the gas.In the present embodiment, the metal that PET metal coating is used Being aluminum, under vacuum, solid aluminum is converted into gaseous state, PET film phase easily by mode of heating For other thin polymer films, thermostability is more preferably, and good with the binding ability of metallic aluminium.Aluminum PET Film plating layer is rich in metallic luster, and reflectance is high, and the reflectance of the aluminum film plating layer of thickness 400A ° reaches 90%, Heat insulation effect is good, and the best to the barrier of moisture and gas.Certainly, in other embodiments, It is used as other metals, such as, nickel or chromium, it is possible to use metal mixture.This PET metal Plated film is than metal forming much thinner, and its thickness equals to or less than 0.5 micron.This PET metal coating is flexible Well, waterproof effect is splendid, and will not As time goes on fade or variable color.Gold or silver color Metal reflective plated film there is splendid reflection heat energy function, prevent heat loss through radiation, it is possible to effectively preserve The heat of more than 90% between heat-insulation layer and skin, the incorporation of metal also contributes to the heat in heating layer Amount is uniform, be rapidly transferred to skin, thus effectively regulates body temperature.And, the golden or gold of silver color Belong to plated film and also contribute to the most more try to please user.Except polyethylene terephthalate thin film (PET), orient polypropylene film (OPP), nylon, polyethylene and cast polypropylene can be used for The metal coating of the present invention.
Further, in this embodiment, heating layer 132 is additionally provided with grid 1322.Graininess or The heat-generating composition 1321 of powder is closed in each grid 1322.By arranging grid 1322, Transport and actually used during, granular heat-generating composition 1321 will not under external force and Concentrate on certain local in heating layer 132, thus cause hot-spot, generate heat uneven.
In this embodiment, the cover contacted with outer layer 131 during grid 1322 is heating layer 132 with The lower front cover of heat-insulation layer 133 contact is formed by bonding seam heat bonding.Grid 1322 and heating layer 132 The straight forming together of cover material up and down, produce time, the bonding mould of heating layer is provided with grid chart Shape, makes place that mould protrudes by molding bonded to each other for cover material by heating mould.Certainly, net Lattice can use any of additive method in this area to prepare.
In this embodiment, self-heating thermal insulation three dimensional face mask is sealed by packaging before the use, in order to anti- Only the heat-generating composition in heating layer is aoxidized by the oxygen in air and moisture the most, this Bright packing can be made up of the impermeable any suitable material of substantially gas, such as plastics Thin film.
In this embodiment, heat-generating composition includes in parts by weight: 50 parts of medical iron powders, 15 parts of work Property charcoal, the salt of 5 parts, 3 parts of Vermiculitums, 1 part of water-absorbing resins, 5 parts of water, 1 part of kieselguhr.In reality In using, the heat-generating composition that generates heat as contacting with the oxygen in air use oxidability metal, The mixture of activated carbon, inorganic metal salt, water and macromolecule wetting agent etc..
Oxidability metal powder is iron powder, aluminium powder etc., but, generally use iron powder, use reduced iron Powder, atomized iron powder, electrolytic iron powder etc..As long as the particle diameter of iron powder can play the scope of warm effect i.e. Can, usually about 10~300 μm, about preferably 10~100 μm.The content of iron powder is preferably 30~about 80wt%, more preferably 30~about 50wt%.
The primary efficacy of activated carbon, for distribute heat more uniformly, makes surface temperature average, it is to avoid office Portion is too high or too low for temperature.Activated carbon absorbs water the most well, and absorbs because heat-generating composition produces Raw heat and the water vapour that evaporates, contribute to preventing the escape of water.Therefore, activated carbon can be as guarantor Water substance plays a role.Activated carbon can also absorb the foul smell produced by oxidation of iron powder.As above-mentioned Activated carbon, prepares for instance, it is possible to be suitable for using from Exocarpium cocois (Cocos nucifera L), timber, Linesless charcoal, coal, bone black etc. Activated carbon.As long as the particle diameter of activated carbon can play warm effect scope, usually 10~ About 300 μm, about preferably 10~100 μm.It is left that the content of activated carbon is preferably 3~25wt% The right side, more preferably 10~about 15wt%.
Inorganic metal salt can make iron powder easily carry out with the oxidation reaction of air, is lived on the surface of iron powder Property such that it is able to promote the oxidation reaction of ferrum.Can use and be made in known heat-generating composition Slaine, such as, the sulfate such as iron sulfate, potassium sulfate, sodium sulfate, manganese sulfate, magnesium phosphate; The chlorides such as copper chloride, potassium chloride, sodium chloride, calcium chloride, manganese chloride, magnesium chloride, Cu-lyt. Deng.Alternatively, it is also possible to use carbonate, acetate, nitrate and other salt.These slaines can To be used alone use in combinations of two or more.As long as the particle diameter of above-mentioned slaine is not for hindering this The scope of invention effect, usually 100~about 700um, preferably 200~600 μm are left Right.The content of slaine is preferably 0.5~about 10wt%, more preferably 1~about 5wt%.
Water in heat-generating composition can use distilled water, tap water etc., and its content is preferably 1~20 About wt%, more preferably 1~about 5wt%.
In addition to above-mentioned iron powder, activated carbon, slaine and water, as required, heat-generating composition is also Other additives can be contained.Such as, heat-generating composition may contain water-absorbing resins, water absorption tree Fat uniformly stores the internal moisture of heating layer in the case of sealing anoxia, after sealing bag to be opened, empty In oxygen in gas and heating layer, the moisture of resin release promotes oxidation chemistry effect.Water-absorbing resins bag Include but be not limited to the liquor-saturated copolymer of isobutylene maleic, polyvinyl alcohol-acrylic copolymer, starch-propylene Hydrochlorate graft copolymer, polyacrylate cross-linking agent, acrylates-propylene vinegar copolymer, acrylic acid Salt-propylene phthalein amine copolymer thing, polyacrylonitrile cross-linking agent etc..These water-absorbing resins, can be used alone Use in combinations of two or more.As long as the particle diameter of above-mentioned water-absorbing resins is not for hinder the present invention to imitate The scope of fruit, usually about 100~about 500um, preferably 200~400 μm.Inhale The content of water-base resin is preferably 0.5~about 10wt%, more preferably 1~about 5wt%.Heating Compositions is also possible to containing Vermiculitum, and Vermiculitum primarily serves insulation, heat insulation effect, makes temperature more longlasting. As long as the particle diameter of Vermiculitum is the scope not hindering effect of the present invention, usually about 300um with Under, preferably below about 200um.The content of Vermiculitum is preferably 1~about 20wt%, more excellent Elect 3~about 13wt% as.
In this embodiment, outer layer and heat-insulation layer all use thin film, the thickness of facial film mainly by Heating layer determines, when being used on skin of face to meet, heating temp is 38~42 DEG C, sends out The heat time is 10~25 minutes, and the thickness of this facial film is 2~8mm, is i.e. loaded in the granule in heating layer The general thickness of shape heat-generating composition is about 2~8mm, and when this thickness, facial film can be fitted well In face.
Embodiment two
Such as Fig. 5, being another embodiment of three dimensional face mask of the present invention, it is with the difference of embodiment one, The three dimensional face mask of the present embodiment, is a to have opening except corresponding oral area, and remaining position all seals Three dimensional face mask, in other words, different from embodiment one, left side diaphragm 21 and the leading section of right side diaphragm 22 211,221 do not have recess in the position of corresponding human eye with glabella.The present embodiment, described left side The leading section 211,221 of diaphragm 21 and right side diaphragm 22 is positioned at above described protuberance 212,222 with The position that human face glabella is relative has the concave arc 215,225 slightly concaved, concave arc 215,225 Place still has jointing material.Due to position relative with human face glabella above described protuberance Also there is the concave arc 215,225 slightly concaved, after left side diaphragm 21 and right side diaphragm 22 bond, At this concave arc 215,225, also just at the corresponding glabella of human face and the nasion of external nose, can shape Become a slight inside depression, thus be preferably close to the depressed area of face glabella and the nasion. From shown in Fig. 6, this three dimensional face mask embodiment is spread in the schematic diagram after face high-visible.
Using the three dimensional face mask of the present embodiment, only oral area has opening (including the bottom in people nostril), Other positions are all enclosed type, face can be carried out the most omnibearing cleaning and maintenance.Further, In facial film, eyes can also be kept healthy by heating layer and the heat-insulation layer of three-decker, plays eye hot compress Effect, and prevent xerophthalmia.
Embodiment three
In this embodiment, the surface that the heat-insulation layer of three dimensional face mask contacts with body skin is additionally provided with For described film being fixed to the hydrogel layer at user's body position.Hydrogel (Soluble Hydrogel) As body adhesives, film can be fixed on body part.
Hydrogel is with water as disperse medium, when gel is attached on skin, is affected by body temperature, Physical arrangement within gel is from solid state into liquid state, and in penetrating to the skin.Accordingly, as this Bright further improvement, can add both effectiveness raw material, such as, collagen in hydrogel matrix Albumen, hyaluronic acid, arbutin, nicotiamide, volatile oil or other health product, topical drug Active component etc..Self-heating thermal insulation film due to the present invention has the heat-insulation layer of waterproof thermal-insulated performance, water Moisture in gel cannot penetrate into heating layer, from without imitating the heating peak value of heating layer and heating Fruit has any impact.The heat that heat-insulation layer also contributes to maintain in hydrogel will not distribute rapidly.
Embodiment four
In this embodiment, it the difference is that only with embodiment one, the formula of heat-generating composition Different, the formula of heat-generating composition is by weight: 30 parts of medical iron powders, 10 parts of activated carbons, 1 The salt of part, 13 parts of Vermiculitums, 5 parts of water-absorbing resins, 1 part of water, 5 parts of kieselguhr.
Invention effect
In order to test self-heating thermal insulation three dimensional face mask of the present invention effect in terms of beauty treatment and health care, collection 50 experimenters, first apply traditional facial film of so-and-so brand sold on market in experimenter face, Then a left side half face or right half face experimenter are applied with self-heating thermal insulation prepared by the embodiment of the present invention four Three dimensional face mask, is fixed on the face gently with hands, after 15 minutes, takes off facial film and the tradition face of the present invention Film, inquiry and the using effect of viewing test person's two parts face.As a result, experimenter commonly represents applying That a part of face of the self-heating thermal insulation three dimensional face mask of the present invention is more comfortable, through face's water-bearing survey, Be used alone the half of appearance ratio of tradition facial film, be applied with the present invention self-heating thermal insulation facial film half The water content of limit face is the highest, and perusal displays that the self-heating thermal insulation facial film being applied with the present invention Half of face more smooth and moist.
The self-heating thermal insulation three dimensional face mask simple in construction of the present invention, is not limited by environmental resource, it is not necessary to outer Boundary's energy provides energy, safe and stable, consistent heat generation, it is possible to effectively extend fever time, fall Low heating peak temperature.It is easypro that the gentle heat that heating layer and heat-insulation layer distributed and maintained makes skin be in Suitable state, improves blood circulation, and skin pore amplifies, and sweat is discharged with dirt grease.When with tradition Nourishing pack and skin care item when being used together, skin can be improved effective to tradition facial film and skin care item The absorption of composition, while reducing skin care item consumption, moreover it is possible to increases skin effect, convenient, saving And environmental protection.Traditional facial film effect is single, does not possess spontaneous heating function, does not the most have heat insulation function, Its effective ingredient be difficult to be absorbed by the skin (especially relatively low in ambient temperature, feelings that face's pore shrinks Under condition), carried when using traditional flake and pureed facial film under dry season or cold region environment in the winter time The ice-cold discomfort come, makes user abandon being continuing with, it is impossible to be grown when skin needs most moisturizing Profit, the facial film of the present invention compensate for blank and the defect of facial film skin care field in prior art.
And, the self-heating thermal insulation three dimensional face mask low cost of the present invention, for single use, contact makes Safety and sanitation when being used in face or other skin sensitivity positions, it is to avoid reusable contact skin thing The sterilization demand of haircut thermal and the potential hygienic risk of sterilizing operation lack of standardization.Will not produce after using Raw endotoxin contamination, exothermic material can reclaim, as the material improving earth quality in environmental protection.

Claims (20)

1. a self-heating thermal insulation three dimensional face mask, described three dimensional face mask is connected with each other by least two panels diaphragm Form human facial profile, it is characterised in that: the diaphragm in described three dimensional face mask correspondence human body face region Position includes at least three-decker, and described three-decker is respectively made up of gas permeable material from outside to inside Outer layer, be mounted with the heat-generating composition by generating heat with air contact and at least with described outer layer Cover be gas permeable material constitute heating layer, by having the insulation that waterproof thermal-insulated performance material is constituted Layer;
Described heat-insulation layer be by polyethylene terephthalate thin film, orient polypropylene film, nylon film, The metal coating that polyethylene film or cast polypropylene film are constituted with metal material.
2. self-heating thermal insulation three dimensional face mask as claimed in claim 1, it is characterised in that: described insulation Layer is the PET metal coating being made up of with golden or argentine material PET film.
3. self-heating thermal insulation three dimensional face mask as claimed in claim 2, it is characterised in that: described PET gold Belonging to the metal employed in plated film is the mixture of one or more in aluminum, nickel or chromium.
4. self-heating thermal insulation three dimensional face mask as claimed in claim 1, it is characterised in that: described heating Being provided with grid in Ceng, described heat-generating composition is loaded in each grid equably.
5. self-heating thermal insulation three dimensional face mask as claimed in claim 4, it is characterised in that: described grid It is that the lower front cover contacted with described heat-insulation layer with the cover of described outer layer in described heating layer passes through Bonding seam heat bonding is formed.
6. self-heating thermal insulation three dimensional face mask as claimed in claim 1, it is characterised in that: described outer layer is Natural fiber or the non-woven fabrics of synthetic fibers or cloth of weaving.
7. self-heating thermal insulation three dimensional face mask as claimed in claim 1, it is characterised in that: described solid Facial film is sealed by packaging before the use.
8. self-heating thermal insulation three dimensional face mask as claimed in claim 1, it is characterised in that: described heating Heat-generating composition in Ceng includes that oxidizable metal, activated carbon, inorganic metal salt, water, macromolecule are protected Humectant, water absorbing agent.
9. self-heating thermal insulation three dimensional face mask as claimed in claim 8, it is characterised in that: described facial film The heating temp of described heating layer be 38~42 DEG C, fever time is 10~25 minutes.
10. self-heating thermal insulation three dimensional face mask as claimed in claim 9, it is characterised in that: described heating Heat-generating composition in Ceng includes in parts by weight: 30~50 parts of medical iron powders, 10~15 parts of activated carbons, The salt of 1~5 part, 3~13 parts of Vermiculitums, 1~5 part of water-absorbing resins, 1~5 part of water.
11. self-heating thermal insulation three dimensional face masks as claimed in claim 9, it is characterised in that: described heating Heat-generating composition in Ceng includes in parts by weight: 30~50 parts of medical iron powders, 10~15 parts of activated carbons, The salt of 1~5 part, 3~13 parts of Vermiculitums, 1~5 part of water-absorbing resins, 1~5 part of water, 1~5 part of kieselguhr.
The 12. self-heating thermal insulation three dimensional face masks as described in claim 9 or 10, it is characterised in that: described The part thickness in facial film diaphragm with described three-decker is 2~8mm.
13. self-heating thermal insulation three dimensional face masks as claimed in claim 1, it is characterised in that: described film It is additionally provided with on the surface that described heat-insulation layer contacts with body skin for described film is fixed to user's body The hydrogel layer of body region.
14. self-heating thermal insulation three dimensional face masks as claimed in claim 13, it is characterised in that: described water Gel layer is lived possibly together with medicine for external use active component and/or externally-applied health-care products active component and/or skin care item Property composition.
15. self-heating thermal insulation three dimensional face masks as claimed in claim 1, it is characterised in that: described solid Facial film is by face on the left of the most corresponding human body and the left side diaphragm of right side face and right side diaphragm two panels diaphragm structure Becoming, described left side diaphragm and right side diaphragm each leading section are provided with jointing material, and at human body face Midline mutually bonds and forms three-dimensional face contour.
16. self-heating thermal insulation three dimensional face masks as claimed in claim 15, it is characterised in that: described left side Diaphragm with have at the respective leading section corresponding human body external nose of right side diaphragm the most outwardly prominent Go out portion, there is the opening of corresponding human body oral area, with certain radian below opening below described protuberance Downwardly extend in circular arc until in the respective leading section of bottom, described left side diaphragm and right side diaphragm except Scope opening portion beyond corresponding with human body oral area is provided with jointing material, and mutually bonds.
17. self-heating thermal insulation three dimensional face masks as claimed in claim 16, it is characterised in that: described left side Diaphragm is positioned at portion relative with human face glabella above described protuberance with in the leading section of right side diaphragm Position also has the concave arc slightly concaved.
18. self-heating thermal insulation three dimensional face masks as claimed in claim 16, it is characterised in that: described left side Diaphragm with the leading section of right side diaphragm is positioned at above described protuberance relative with glabella with human body eye Position also have in the respective leading section of the recess concaved, described left side diaphragm and right side diaphragm except Beyond the opening portion corresponding with human body oral area and the notch part corresponding with human body eye and glabella Scope is provided with jointing material, and mutually bonds.
The 19. self-heating thermal insulation three dimensional face masks as described in any one of claim 15 to 18, its feature exists In: the rear end of described left side facial film and right side facial film also has for facial film is fixed on human body head Fixing band, the tail end of described fixing band has VELCRO.
The using method of the 20. self-heating thermal insulation three dimensional face masks as described in any one of claim 15 to 18, It is characterized in that: before applying described facial film, first apply traditional nourishing pack or skin protection in face Articles for use, or in advance skincare product is coated in described heat-insulation layer by with on the surface of contact skin;By a left side Together with side film is bonded in right side facial film, and the three dimensional face mask after bonding is fitted in the face of people.
CN201410382376.3A 2014-08-06 2014-08-06 A kind of self-heating thermal insulation three dimensional face mask Active CN104127324B (en)

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CN201410382376.3A CN104127324B (en) 2014-08-06 2014-08-06 A kind of self-heating thermal insulation three dimensional face mask
EP15828995.9A EP3178453A4 (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
PCT/CN2015/081597 WO2016019762A1 (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
JP2017506828A JP6711816B2 (en) 2014-08-06 2015-06-17 Self-heating and heat retaining film, and face mask and eye sheet produced by the film
CA2957322A CA2957322C (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
KR1020177005846A KR102111837B1 (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
US15/501,864 US20170231813A1 (en) 2014-08-06 2015-06-17 Self-heating thermal-insulation film and face mask and eye mask manufactured therefrom
RU2017106961A RU2683719C2 (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
SG11201700905YA SG11201700905YA (en) 2014-08-06 2015-06-17 Self-heating insulating film and face mask and eye mask manufactured therefrom
HK15107464.5A HK1204841A2 (en) 2014-08-06 2015-08-04 Self heat-generating thermal insulation film and facial and eye masks produced therefrom
TW104125374A TWI641484B (en) 2014-08-06 2015-08-05 Self-heating insulation film and application thereof

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