CN104145956A - Insecticidal composition comprising tebufenozide and ZJ4042 - Google Patents
Insecticidal composition comprising tebufenozide and ZJ4042 Download PDFInfo
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- CN104145956A CN104145956A CN201410398594.6A CN201410398594A CN104145956A CN 104145956 A CN104145956 A CN 104145956A CN 201410398594 A CN201410398594 A CN 201410398594A CN 104145956 A CN104145956 A CN 104145956A
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- pesticidal combination
- worm hydrazides
- insecticide
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Abstract
The invention discloses an insecticidal composition comprising two active components. A first active component is tebufenozide and the second is 3-chloro-N<1>-(2-methyl-4-heptafluoro isopropylphenyl)-N<2>-(1-methyl-1-cyanoethyl)phthalic diamide, wherein a mass ratio of tebufenozide to 3-chloro-N<1>-(2-methyl-4-heptafluoro isopropylphenyl)-N<2>-(1-methyl-1-cyanoethyl)phthalic diamide is 1-50:20-1. The insecticidal sterilization composition provided by the invention is used for controlling lepidoptera pests.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of Pesticidal combination.
Background technology
The resistance problem of pest is a global problem.Along with Chemical Control of Harmful Insects increase and the non-science of continuity, agricultural chemicals usage amount use agricultural chemicals, pest resistance is day by day serious, the pest species that produces resistance is on the increase.The Lepidoptera class pest of particularly causing harm serious to agricultural production, its resistance level is higher, resistance development speed is relatively very fast.Simultaneously along with the use of high strength agricultural chemicals, so that Practice for Pesticide Residue in Agricultural Products exceeds standard, environmental pollution and peasant's drug cost increase, and is unfavorable for agricultural sustainable development.
In prior art, existing agricultural chemicals such as worm hydrazides etc., when it uses separately, drug cost is higher, not only limited to a certain extent it to apply, and long-term use separately easily causes pest resistance degree constantly to increase.Being mixed of different pesticide species is the common methods of the agriculture resistant insect of control.By formulation of pesticide, screening, filter out rational formula, can effectively improve actual control efficiency, reduce dosage, reduce costs, delay the generation of pest resistance to insecticide, extend the service life of medicament, is the important means of integrated pest management.
Therefore, Pesticidal combination and the insecticide of efficient, the low toxicity of research and development, environmental protection have positive effect to agricultural sustainable development.
Summary of the invention
The technical problem to be solved in the present invention can provide the Pesticidal combination of a kind of efficient, low toxicity, environmental protection, can be used in control Lepidoptera class pest.
For addressing the above problem, the technical solution adopted in the present invention is:
A Pesticidal combination, contains two kinds of active components, and the first active component is worm hydrazides, and second active ingredient is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the quality proportioning of described the first active component and second active ingredient is 1～50:20～1.
In Pesticidal combination provided by the invention, above-mentioned worm hydrazides (Tebufenozide) is on-steroidal Novel insect growth regulator, is the insect hormone insecticides of up-to-date research and development.Tebufenozide pesticide activity is high, and selectivity is strong, all effective to all lepidopterous larvaes, and antagonism insect cotton bollworm, cabbage caterpillar, diamond-back moth, beet armyworm etc. have special efficacy.And have extremely strong ovicidal activity, safer to non-target organism.Worm hydrazides is to eyes and skin nonirritant, without teratogenesis, carcinogenic, mutagenesis, all fool proof to mammal, birds, natural enemy to higher mammal.
In Pesticidal combination provided by the invention, the chloro-N of above-mentioned 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide (hereinafter to be referred as " ZJ4042 "), is the novel pesticide that develop voluntarily Zhejiang Provincial Chemical Engineering Research Inst, shown in structural formula following (I):
The insecticidal activity of this compound and the fipronil bisamide of recent development substantially suitable.Fipronil bisamide, English common name (flubendiamide) is researched and developed by Nihon Nihyaku Co., Ltd, chemical name is the iodo-N-of 3-(2-first sulfonephthalein base-1,1-dimethyl ethyl group-N-{4-" 1; 2; 2,2-tetrafluoro-1-(trifluoromethyl) ethyl-o-tolyl } phthalamide, molecular formula is: C
23h
22f
7n
2o
4, belong to Novel ortho benzenedicarboxamide insecticides, activate calcium release channel in blue Buddhist nun's alkali recipient cell, cause the property out of control of storing calcium ion to discharge, be at present few in number compounds that acts on blue Buddhist nun's alkali (Ryanodine) acceptor of insect cell.Lepidoptera pest is had to wide spectrum preventive effect, produce without cross resistance with existing insecticide, be suitable for very much the control that existing insecticide produces the insect of resistance.
As preferred mode, the quality proportion optimization of above-mentioned the first active component and second active ingredient is 1～10:10～1, and 1～5:5～1 more preferably.
The present invention also provides a kind of insecticide, contains by weight 5～90% above-mentioned Pesticidal combinations, and all the other are the upper acceptable carrier of agricultural and auxiliary agent.As preferred embodiment, in described insecticide, contain 5～40% Pesticidal combination by weight.
Carrier of the present invention can be solid or liquid, and any carrier that is generally used for preparing insecticides all can be used.
Suitable solid carrier comprises: mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin for example, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite, talcum.Carbonate is for example: calcium carbonate, dolomite.Sulfates is as ammonium sulfate, sodium sulphate, calcium sulphate.Oxide-based as quicklime, magnesium lime, diatomite.Plant is for example: citrus pulp, corncob cellulose, rice husk powder, rice husk, large soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class is as winnofil hydrate, winnofil, white carbon.Inorganic salts is potassium chloride for example, sodium chloride.
Liquid-carrier comprises water and organic solvent.When active ingredient is suspension emulsion, organic solvent plays solubilising and antifreeze effect.Suitable organic solvent comprises aromatic hydrocarbons, for example benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, for example vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, for example petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol for example, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether for example, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidones for example; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile; Vegetable oil and the vegetable oil that methylates.Above-mentioned organic solvent both can be used alone, but also also mix together, and can also mix together with water.
Auxiliary agent of the present invention can comprise one or more in surfactant, defoamer, thickener, suspending agent and antifreezing agent as required, can also comprise as required other auxiliary agents that the industry is conventional.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ionic or nonionic.Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; In molecule, contain the fatty acid of at least 12 carbon atoms or fatty amine and oxirane and/polycondensation product of expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In molecule, at least containing the sulfuric acid of 10 carbon atoms or the alkali metal of sulfonic acid or alkali salt, is preferably sodium salt, as the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, alkylaryl sodium sulfonate and neopelex; The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifier comprises nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonylphenol ether of nonionic emulsifier, fatty alcohol-polyoxyethylene ether, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether, styryl phenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic emulsifier mainly comprises calcium dodecyl benzene sulfonate, triphen ethyl phenol polyoxy ether phosphate amine salt, polyoxyethylene nonylphenol ether phosphate amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention comprises: acrylate homopolymer sodium salt, maleic acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, triphen ethyl phenol polyoxyethylene ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid, to one or more in hydroxyphenyl lignin sulfonic acid sodium salt.
Wetting agent of the present invention comprises: fatty alcohol-polyoxyethylene ether, naphthalene sulfonate, lauryl sodium sulfate, one or more combinations in alkyl phenol resin polyoxyethylene ether sulfate.
Thickener of the present invention comprises xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, gum Arabic, gelatin, one or more in polyvinyl alcohol.Defoamer of the present invention is preferably: bubble enemy, silicone, C
8～10fatty alcohol, C
10～20saturated fat acids and acid amides etc.
Insecticide of the present invention can be mixed with missible oil, oil suspending agent, suspending agent, wetting powder or water dispersible granules according to the general method in this area.
Pesticidal combination provided by the invention and insecticide are particularly suitable for preventing and treating Lepidoptera class pest, especially be applicable to the Lepidoptera class pest in control vegetables, paddy rice or cotton, described Lepidoptera class pest comprises prodenia litura, beet armyworm, striped rice borer, rice leaf roller and cotton bollworm.
Pesticidal combination of the present invention has following advantage compared to existing technology:
(1) in composition, two kinds of composite reagents show good synergistic effect in certain ratio range, and the insecticidal effect of mixed composition is significantly improved compared with its single dose, and have the advantages that quick-acting is good and lasting effect is long;
(2) utilize two kinds of active components to be reasonably mixed to the different mode of action of insect, the different mechanism of action, both extended agricultural chemicals service life, delay again the generation of pest resistance to insecticide;
(3) reduce using dosage, reduced peasant's drug cost.
Embodiment
The following examples illustrate several embodiment of the present invention for being used for, but do not limit the invention to these embodiments.One skilled in the art would recognize that the present invention contained all alternatives, improvement project and the equivalents that within the scope of claims, may comprise.
In following embodiment, material prescription is selected to suit measures to local conditions, on result without substantial impact.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
In following embodiment, with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity, evaluate SOP (insecticide volume), adopt infusion process.
Synergy adopts following method to calculate:
The content (%) of toxicity index * A of theoretical mixed toxicity index (TTI)=A in mixed
The content (%) of toxicity index * B of+B in mixed
If co-toxicity coefficient is greater than 120, showing has synergistic effect; If be less than 80, be indicated as antagonism; If be greater than 80, be less than 120, be indicated as summation action.
Embodiment 1:ZJ4042 and worm hydrazides composition
Table 1, ZJ4042 and worm hydrazides composition are to Laphygma exigua Hubner (Spodoptera exigua) synergy effect
| Formula | Proportioning | LC 50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Worm hydrazides | - | 3.54 | 10.45 | ? | ? |
| ZJ4042 | - | 0.37 | 100.00 | ? | ? |
| Worm hydrazides: ZJ4042 | 50:1 | 1.89 | 19.58 | 12.21 | 160.36 |
| Worm hydrazides: ZJ4042 | 20:1 | 1.56 | 23.72 | 14.72 | 161.17 |
| Worm hydrazides: ZJ4042 | 1:1 | 0.42 | 88.10 | 55.23 | 159.52 |
| Worm hydrazides: ZJ4042 | 1:10 | 0.25 | 148.00 | 91.86 | 161.12 |
| Worm hydrazides: ZJ4042 | 1:20 | 0.23 | 160.87 | 95.74 | 168.03 |
Table 2, ZJ4042 and worm hydrazides are to rice leaf roller (Cnaphalocrocis medinalis) synergy effect
| Formula | Proportioning | LC 50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Worm hydrazides | - | 6.25 | 20.64 | ? | ? |
| ZJ4042 | - | 1.29 | 100.00 | ? | ? |
| Worm hydrazides: ZJ4042 | 50:1 | 3.87 | 33.33 | 22.20 | 150.18 |
| Worm hydrazides: ZJ4042 | 20:1 | 3.57 | 36.13 | 24.42 | 147.98 |
| Worm hydrazides: ZJ4042 | 1:1 | 1.34 | 96.27 | 60.32 | 159.60 |
| Worm hydrazides: ZJ4042 | 1:10 | 0.88 | 146.59 | 92.79 | 157.99 |
| Worm hydrazides: ZJ4042 | 1:20 | 0.85 | 151.76 | 96.22 | 157.73 |
From table 1 table 2, can find out, the composition of worm hydrazides and ZJ4042, in the scope of (by weight) of 1～50:20～1, co-toxicity coefficient is all greater than 120, and wild cabbage striped rice borer and paddy rice rice leaf roller are all shown as to synergistic effect.
Embodiment 2 (20% worm hydrazides ZJ4042 suspending agent)
By the formula that worm hydrazides 18%, ZJ40422%, emulsifier 1601# (styryl phenol polyoxyethylene poly-oxygen propylene aether) 10%, dispersant SOPA-270 are 4%, bentonite 2%, xanthans 0.1%, silicone defoaming agent 0.4%, glycerine 5%, surplus are deionized water, pulverize in advance, add in sand mill and grind again, after high shear mixing, allotment makes 20% worm hydrazides ZJ4042 suspending agent.
The 20% worm hydrazides ZJ4042 suspending agent making is applied to prevent and treat rice-stem borer.20% worm hydrazides ZJ4042 suspending agent is watered even spraying by 10 grams/acre in rice-stem borer larva occurance peak, and after medicine, the preventive effect of 3 days, 7 days is respectively 92.9%, 95.8%.Press same method dispenser, single dose 20% Tebufenozide suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 3 days after medicine is respectively 72.7% and 88.4%, the preventive effect of 7 days is respectively 78.2% and 88.0% after medicine.After worm hydrazides and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 3 (40% worm hydrazides ZJ4042 water-dispersible granules)
By worm hydrazides 35%, ZJ40425%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus, be that kaolinic formula carries out dry pulverization process, granulation, dry, screening makes 40% worm hydrazides ZJ4042 water-dispersible granules.
The 40% worm hydrazides ZJ4042 water-dispersible granules making is applied to prevent and treat wild cabbage prodenia litura.40% worm hydrazides ZJ4042 water-dispersible granules is watered even spraying by 10 grams/acre in wild cabbage Spodoptera litura larvae occurrence in peak period, and after medicine, 3 days, 7 days preventive effects are respectively 90.5%, 91.3%.Press same method dispenser, single dose 20% Tebufenozide suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 3 days after medicine is respectively 72.7% and 86.7%, the preventive effect of 7 days is respectively 73.1% and 84.9% after medicine.After worm hydrazides and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose, and dosage reduces than single dose.
Embodiment 4 (70% worm hydrazides ZJ4042 water-dispersible granules)
By worm hydrazides 55%, ZJ404215%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus, be that kaolinic formula carries out dry pulverization process, granulation, dry, screening makes 70% worm hydrazides ZJ4042 water-dispersible granules.
The 70% worm hydrazides ZJ4042 water-dispersible granules making is applied to prevent and treat paddy rice rice leaf roller.70% worm hydrazides ZJ4042 water-dispersible granules is watered even spraying by 10 grams/acre in a rice leaf roller low instar larvae Sheng phase, and after medicine, 7 days, 14 days preventive effects are respectively 89.7%, 90.7%.Press same method dispenser, single dose 20% Tebufenozide suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 7 days after medicine is respectively 72.7% and 83.9%, the preventive effect of 14 days is respectively 74.7% and 87.7% after medicine.After worm hydrazides and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 5 (40% worm hydrazides ZJ4042 wetting powder)
By worm hydrazides 35%, ZJ40425%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus, be that kaolinic formula carries out dry pulverization process, granulation, dry, screening makes 40% worm hydrazides ZJ4042 wetting powder.
The 40% worm hydrazides ZJ4042 wetting powder making is applied to prevent and treat paddy rice rice leaf roller.40% worm hydrazides ZJ4042 wetting powder is watered even spraying by 10 grams/acre in rice leaf roller low instar larvae occurrence in peak period, and after medicine, the preventive effect of 7 days, 14 days is respectively 92.3%, 93.0%.Press same method dispenser, single dose 20% Tebufenozide suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 7 days after medicine is respectively 71.2% and 82.4%, the preventive effect of 14 days is respectively 72.7% and 86.7% after medicine.After worm hydrazides and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 6 (20% worm hydrazides ZJ4042 oil suspending agent)
By worm hydrazides 15%, ZJ40425%, castor oil polyoxyethylene ether 13%, tristyrylphenol polyoxyethylene ether phosphate 3%, organobentonite 1%, methyl oleate, mend the formula to 100%, after each component is mixed, sand milling to certain particle diameter obtains 20% worm hydrazides ZJ4042 oil suspending agent.
The 20% worm hydrazides ZJ4042 oil suspending agent making is applied to prevent and treat cotton cotton bollworm.20% worm hydrazides ZJ4042 oil suspending agent is watered even spraying by 10 grams/acre in cotton bollworm larvae occurance peak, and after medicine, 3 days, 7 days preventive effects are respectively 91.7%, 93.9%.Press same method dispenser, single dose 20% Tebufenozide suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 3 days after medicine is respectively 71.8% and 85.7%, the preventive effect of 7 days is 74.2% and 88.4% after medicine.After worm hydrazides and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 7 (20% worm hydrazides ZJ4042 missible oil)
The formula that is dimethylbenzene by worm hydrazides 15%, ZJ40425%, calcium dodecyl benzene sulfonate 6%, triphen ethyl phenol APEO 6%, NMP 8%, surplus, obtains 20% worm hydrazides ZJ4042 missible oil after each component is mixed.
The 20% worm hydrazides ZJ4042 missible oil making is applied to prevent and treat Laphygma exigua Hubner.20% worm hydrazides ZJ4042 oil suspending agent is watered even spraying by 10 grams/acre in beet exigua larvae occurance peak, and after medicine, 3 days, 7 days preventive effects are respectively 92.7%, 95.7%.Press same method dispenser, single dose 20% Tebufenozide suspending agent (formulation rate is 15 grams/acre) and 20%ZJ4042 suspending agent (formulation rate the is 10 grams/acre) preventive effect of 3 days after medicine is respectively 71.6% and 82.7%, the preventive effect of 7 days is 74.1% and 85.0% after medicine.After worm hydrazides and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose.
Claims (8)
1. a Pesticidal combination, is characterized in that described Pesticidal combination contains two kinds of active components, and the first active component is worm hydrazides, and second active ingredient is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the quality proportioning of described the first active component and second active ingredient is 1～50:20～1.
2. according to Pesticidal combination claimed in claim 1, the quality proportioning that it is characterized in that described the first active component and second active ingredient is 1～10:10～1.
3. according to Pesticidal combination claimed in claim 2, the quality proportioning that it is characterized in that described the first active component and second active ingredient is 1～5:5～1.
4. according to the application of Pesticidal combination claimed in claim 1, it is characterized in that described Pesticidal combination is formulated into insecticide, contain 5～90% Pesticidal combination by weight in described insecticide, all the other are the upper acceptable carrier of agricultural and auxiliary agent.
5. according to the application of Pesticidal combination claimed in claim 4, it is characterized in that containing in described insecticide 5～40% Pesticidal combination by weight.
6. according to the application of Pesticidal combination claimed in claim 4, it is characterized in that described insecticide is formulated into missible oil, oil suspending agent, suspending agent, wetting powder or water dispersible granules.
7. according to the application of Pesticidal combination claimed in claim 1, it is characterized in that described Pesticidal combination is used to prevent and treat Lepidoptera class pest.
8. according to the application of Pesticidal combination claimed in claim 7, it is characterized in that described Pesticidal combination is used to prevent and treat the Lepidoptera class pest in vegetables, paddy rice or cotton, described Lepidoptera class pest comprises prodenia litura, beet armyworm, striped rice borer, rice leaf roller and cotton bollworm.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008077922A2 (en) * | 2006-12-22 | 2008-07-03 | Bayer Cropscience Ag | Pesticidal composition comprising fenamidone and an insecticide compound |
| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | Cyano phthalic diamide compounds, preparation method thereof and use thereof as agricultural chemical pesticide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
| CN102626077A (en) * | 2012-04-01 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low-volume liquid containing flubendiamide |
-
2014
- 2014-08-13 CN CN201410398594.6A patent/CN104145956B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008077922A2 (en) * | 2006-12-22 | 2008-07-03 | Bayer Cropscience Ag | Pesticidal composition comprising fenamidone and an insecticide compound |
| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | Cyano phthalic diamide compounds, preparation method thereof and use thereof as agricultural chemical pesticide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
| CN102626077A (en) * | 2012-04-01 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low-volume liquid containing flubendiamide |
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Denomination of invention: Insecticidal composition containing tebufenozide and zj4042 Effective date of registration: 20211011 Granted publication date: 20160316 Pledgee: Industrial and Commercial Bank of China Limited Hangzhou Zhaohui sub branch Pledgor: SINOCHEM LANTIAN Co.,Ltd. Registration number: Y2021330001830 |
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