CN104141239A - Wet waterproof moisture-permeable leather production method - Google Patents

Wet waterproof moisture-permeable leather production method Download PDF

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Publication number
CN104141239A
CN104141239A CN201310173416.9A CN201310173416A CN104141239A CN 104141239 A CN104141239 A CN 104141239A CN 201310173416 A CN201310173416 A CN 201310173416A CN 104141239 A CN104141239 A CN 104141239A
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minutes
wet method
artificial leather
wet
production method
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CN201310173416.9A
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CN104141239B (en
Inventor
吴月红
皇甫觉明
吴玉华
蒋华亮
张炎
丁琪
殷桂花
陈利安
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Jiangsu Xiefu New Material Technology Co.,Ltd.
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KUNSHAN XIEFU ARTIFICIAL LEATHER CO Ltd
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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a wet waterproof moisture-permeable leather production method. The method comprises the following steps: uniformly mixing 5-10 parts of dimethyl formamide with 0.5-2 parts of a color paste, and filtering; adding 80-100 parts of dimethyl formamide, 1-3 parts of a cell modifier and 1-2 parts of a bridging agent, and uniformly mixing; adding 100kg of a polyurethane wet waterproof moisture-permeable resin, uniformly stirring, and deaerating to obtain a coating; knife-coating the coating on a base cloth, solidifying, squeezing, washing with water, and drying to obtain a finished product. A wet waterproof moisture-permeable layer is formed after the wet slurry is knife-coated on the base cloth, and has good water permeability and high water pressure resistance. A result of detection shows that the water pressure resistance of the wet waterproof moisture-permeable layer is greater than 5000mm.H2O (JISL1092B standard), and the moisture permeability of the wet waterproof moisture-permeable layer is greater than 5000g/m<2>.d (JISL 1099B standard). Clothes made by using the obtained wet waterproof moisture-permeable leather have the advantages of comfortable wearing, difficult moldy damage and durability.

Description

Wet method Water-proof artificial leather production method
Technical field
The present invention relates to a kind of artificial leather preparation method, particularly a kind of wet method Water-proof artificial leather production method.
Background technology
In haberdashery, usually use artificial leather material, conventional artificial leather is all on base cloth, to be coated with to scrape wet-mixing thing formation wet method bass, then on wet method bass, pasting dry method veneer forms, its poisture-penetrability is poor, in dress, because movement human is usually perspired, give people a kind of vexed wet air-locked sensation, affect snugness of fit, wear for a long time moist dress ornament and also easily cause human body skin bacterial infection, also easily cause the dress ornament damage of going mouldy.
Summary of the invention
In order to overcome above-mentioned defect, the invention provides a kind of wet method Water-proof artificial leather production method, this wet method Water-proof artificial leather production method technique is simple, and the water pressure resistance of product performance of producing is high, and poisture-penetrability is good.
The present invention for the technical scheme that solves its technical problem and adopt is: a kind of wet method Water-proof artificial leather production method, and concrete steps are as follows:
Step 1: wet-mixing batching:
A. by 5~10kg dimethyl formamide and 0.5~2kg mill base high-speed stirred 80~100 minutes, then filter stand-by;
B. by the bridging agent mix and blend of 80~100kg dimethyl formamide, 1~3kg abscess conditioning agent and 1~2kg 20~30 minutes, then add the mixture having filtered in step a to stir stand-by;
C. 100kg polyurethane wet method Waterproof Breathable resin is joined in the mixture that step b forms, stir 30~40 minutes, deaeration 40~50 minutes;
Step 2: coating is produced:
By in step 1 the slurry of deaeration be coated with scrape on base cloth, in the dimethyl formamide aqueous solution that to immerse mass percentage concentration be 15-20%, solidify, then through at least one squezzing operation, obtain a kind of wet method Water-proof artificial leather finished product after washing and being dried again.
As a further improvement on the present invention, dimethyl formamide and stock white high-speed stirred 90 minutes in described step a.
As a further improvement on the present invention, in described step a, use 240 order nylon wires to filter the mixed liquor of dimethyl formamide and mill base.
As a further improvement on the present invention, in described step a, mill base used is stock white.
As a further improvement on the present invention, in described step b, mixture stirs 30 minutes.
As a further improvement on the present invention, in described step c, polyurethane wet method Waterproof Breathable resin is joined in the mixture that step b forms, stir 40 minutes, deaeration 45 minutes.
As a further improvement on the present invention, in step 2, base cloth is woven nylon measuring fiber.
As a further improvement on the present invention, not 20-25 rice/min of the speed of a motor vehicle in step 2.
The invention has the beneficial effects as follows: after wet method slurry of the present invention is coated with and scrapes on base cloth, form the wet method Waterproof Breathable layer of one deck with moisture-inhibiting aperture, it has good poisture-penetrability, and its water pressure resistance is high, through detecting, its water pressure resistance >5000mm.H2O (JISL 1092B standard), moisture-inhibiting >5000g/m2.d (JISL 1099B standard), it is processed into after dress ornament, comfortable and easy to wear, the damage that is difficult for going mouldy, durable in use.
Detailed description of the invention
Embodiment 1: a kind of wet method Water-proof artificial leather production method, concrete steps are as follows:
Step 1: wet-mixing batching:
A. by 5kg dimethyl formamide and 0.5kg stock white high-speed stirred 80 minutes, then use 240 order nylon wires to filter stand-by;
B. by the bridging agent mix and blend of 80kg dimethyl formamide, 1kg abscess conditioning agent and 1kg 20 minutes, then add the mixture having filtered in step a to stir stand-by;
C. 100kg polyurethane wet method Waterproof Breathable resin is joined in the mixture that step b forms, stir 30 minutes, deaeration 40 minutes;
Step 2: coating is produced:
By in step 1 the slurry of deaeration be coated with scrape on woven nylon measuring fiber, in the dimethyl formamide aqueous solution that immersion mass percentage concentration is 15%, solidify, then through at least one squezzing operation, wash and be dried again, the speed of a motor vehicle is 20-25 rice/min, obtains a kind of wet method Water-proof artificial leather finished product.
Embodiment 2: a kind of wet method Water-proof artificial leather production method, concrete steps are as follows:
Step 1: wet-mixing batching:
A. by 8kg dimethyl formamide and 1kg stock white high-speed stirred 90 minutes, then use 240 order nylon wires to filter stand-by;
B. by the bridging agent mix and blend of 90kg dimethyl formamide, 2kg abscess conditioning agent and 1.5kg 25 minutes, then add the mixture having filtered in step a to stir stand-by;
C. 100kg polyurethane wet method Waterproof Breathable resin is joined in the mixture that step b forms, stir 35 minutes, deaeration 45 minutes;
Step 2: coating is produced:
By in step 1 the slurry of deaeration be coated with scrape on woven nylon measuring fiber, in the dimethyl formamide aqueous solution that immersion mass percentage concentration is 18%, solidify, then through at least one squezzing operation, wash and be dried again, the speed of a motor vehicle is 20-25 rice/min, obtains a kind of wet method Water-proof artificial leather finished product.
Embodiment 3: a kind of wet method Water-proof artificial leather production method, concrete steps are as follows:
Step 1: wet-mixing batching:
A. by 10kg dimethyl formamide and 2kg stock white high-speed stirred 100 minutes, then use 240 order nylon wires to filter stand-by;
B. by the bridging agent mix and blend of 100kg dimethyl formamide, 3kg abscess conditioning agent and 2kg 30 minutes, then add the mixture having filtered in step a to stir stand-by;
C. 100kg polyurethane wet method Waterproof Breathable resin is joined in the mixture that step b forms, stir 40 minutes, deaeration 50 minutes;
Step 2: coating is produced:
By in step 1 the slurry of deaeration be coated with scrape on woven nylon measuring fiber, in the dimethyl formamide aqueous solution that immersion mass percentage concentration is 20%, solidify, then through at least one squezzing operation, wash and be dried again, the speed of a motor vehicle is 20-25 rice/min, obtains a kind of wet method Water-proof artificial leather finished product.

Claims (8)

1. a wet method Water-proof artificial leather production method, is characterized in that: concrete steps are as follows:
Step 1: wet-mixing batching:
A. by 5~10kg dimethyl formamide and 0.5~2kg mill base high-speed stirred 80~100 minutes, then filter stand-by;
B. by the bridging agent mix and blend of 80~100kg dimethyl formamide, 1~3kg abscess conditioning agent and 1~2kg 20~30 minutes, then add the mixture having filtered in step a to stir stand-by;
C. 100kg polyurethane wet method Waterproof Breathable resin is joined in the mixture that step b forms, stir 30~40 minutes, deaeration 40~50 minutes;
Step 2: coating is produced:
By in step 1 the slurry of deaeration be coated with scrape on base cloth, in the dimethyl formamide aqueous solution that to immerse mass percentage concentration be 15-20%, solidify, then through at least one squezzing operation, obtain a kind of wet method Water-proof artificial leather finished product after washing and being dried again.
2. wet method Water-proof artificial leather production method according to claim 1, is characterized in that: dimethyl formamide and stock white high-speed stirred 90 minutes in described step a.
3. wet method Water-proof artificial leather production method according to claim 1, is characterized in that: in described step a, use 240 order nylon wires to filter the mixed liquor of dimethyl formamide and mill base.
4. wet method Water-proof artificial leather production method according to claim 1, is characterized in that: in described step a, mill base used is stock white.
5. wet method Water-proof artificial leather production method according to claim 1, is characterized in that: in described step b, mixture stirs 30 minutes.
6. wet method Water-proof artificial leather production method according to claim 1, is characterized in that: in described step c, polyurethane wet method Waterproof Breathable resin is joined in the mixture that step b forms, stir 40 minutes, deaeration 45 minutes.
7. wet method Water-proof artificial leather production method according to claim 1, is characterized in that: in step 2, base cloth is woven nylon measuring fiber.
8. according to the wet method Water-proof artificial leather production method described in claim 1 or 7, it is characterized in that: not 20-25 rice/min of the speed of a motor vehicle in step 2.
CN201310173416.9A 2013-05-10 2013-05-10 Wet method Water-proof artificial leather production method Active CN104141239B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110670375A (en) * 2019-09-19 2020-01-10 昆山协孚新材料股份有限公司 Environment-friendly conductive synthetic leather for labor protection gloves and production process thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0525780A (en) * 1991-06-26 1993-02-02 Dainippon Ink & Chem Inc Highly durable leathery sheet and its production
JP2000265379A (en) * 1999-03-19 2000-09-26 Kuraray Co Ltd Production of leather like sheet having good ventilation
CN101284937A (en) * 2008-05-19 2008-10-15 苏州宝泽高分子材料有限公司 Processing agent for wet-method chemical leather
CN102174211A (en) * 2011-03-04 2011-09-07 昆山华富合成皮革有限公司 Polyurethane microporous water-proof and moisture permeable film prepared by using solidification method and preparation method thereof
CN102899916A (en) * 2011-07-29 2013-01-30 昆山协孚人造皮有限公司 Manufacturing method for hydrolysis-resistant clothing leather
CN102899921A (en) * 2011-07-29 2013-01-30 昆山协孚人造皮有限公司 Manufacturing method of powder-wax synthetic leather

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0525780A (en) * 1991-06-26 1993-02-02 Dainippon Ink & Chem Inc Highly durable leathery sheet and its production
JP2000265379A (en) * 1999-03-19 2000-09-26 Kuraray Co Ltd Production of leather like sheet having good ventilation
CN101284937A (en) * 2008-05-19 2008-10-15 苏州宝泽高分子材料有限公司 Processing agent for wet-method chemical leather
CN102174211A (en) * 2011-03-04 2011-09-07 昆山华富合成皮革有限公司 Polyurethane microporous water-proof and moisture permeable film prepared by using solidification method and preparation method thereof
CN102899916A (en) * 2011-07-29 2013-01-30 昆山协孚人造皮有限公司 Manufacturing method for hydrolysis-resistant clothing leather
CN102899921A (en) * 2011-07-29 2013-01-30 昆山协孚人造皮有限公司 Manufacturing method of powder-wax synthetic leather

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110670375A (en) * 2019-09-19 2020-01-10 昆山协孚新材料股份有限公司 Environment-friendly conductive synthetic leather for labor protection gloves and production process thereof

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Address after: Suzhou City, Jiangsu province 215300 Yushan town Kunshan City Yuhe Road No. 111

Patentee after: Kunshan Fu Xin new material Limited by Share Ltd

Address before: Suzhou City, Jiangsu province 215300 Yushan town Kunshan City Yuhe Road No. 111

Patentee before: Kunshan Xiefu Artificial Leather Co.,Ltd.

TR01 Transfer of patent right

Effective date of registration: 20211210

Address after: 226000 No. 11, Gangfeng Road, Yangkou Port Lingang Industrial Zone, Rudong County, Nantong City, Jiangsu Province

Patentee after: Jiangsu Xiefu New Material Technology Co.,Ltd.

Address before: 215300 No.111 dayuhe Road, Yushan Town, Kunshan City, Suzhou City, Jiangsu Province

Patentee before: KUNSHAN XIEFU NEW MATERIALS LIMITED BY SHARE LTD.

TR01 Transfer of patent right