CN104130671A - Aqueous ultrathin expansion-type fireproof coating for steel structure and preparation method thereof - Google Patents
Aqueous ultrathin expansion-type fireproof coating for steel structure and preparation method thereof Download PDFInfo
- Publication number
- CN104130671A CN104130671A CN201410341750.5A CN201410341750A CN104130671A CN 104130671 A CN104130671 A CN 104130671A CN 201410341750 A CN201410341750 A CN 201410341750A CN 104130671 A CN104130671 A CN 104130671A
- Authority
- CN
- China
- Prior art keywords
- agent
- emulsion
- aqueous
- modified
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses an aqueous ultrathin expansion-type fireproof coating for a steel structure and a preparation method thereof, and belongs to the technical field of fireproof coatings. The aqueous ultrathin expansion-type fireproof coating comprises, by mass, 10-35 parts of a modified aqueous epoxy emulsion, 1-8 parts of a curing agent, 5-15 parts of a styrene-acrylic emulsion or a silicone-acrylic emulsion, 10-20 parts of ammonium polyphosphate, 6-12 parts of melamine, 8-16 parts of pentaerythritol, 5-15 parts of a fire retardant, 5-15 parts of a pigment and a filling material, 2-8 parts of an assistant and 15-35 parts of water. The aqueous ultrathin expansion-type fireproof coating has the characteristics of low raw material cost, simple preparation process and environmental friendliness.
Description
Technical field
the invention belongs to frie retardant coating technical field, relate in particular to a kind of aqueous ultra-thin expansion type frie retardant coating for steel construction and preparation method thereof.
Background technology
steel construction is as a kind of building type, with it from heavy and light, the advantage such as intensity is high, plasticity good, short construction period and being widely adopted, especially in longspan structure and Highrise buildings, brought into play irreplaceable effect.But steel structure fire-resistant is poor, in the time that temperature reaches 600 DEG C, steel construction almost can be lost whole intensity, once presence of fire, steel construction will lose supporting capacity, by serious harm people's safety of life and property.Therefore, must carry out flameproof protection to steel construction, now widely used method is to be coated in steel structure surface with steel structure fire-proof paint.
steel structure fire-proof paint is classified and can be divided into expanded polystyrene veneer and non-expansion type from fire prevention form, classify and can be divided into water-soluble and solvent-borne type from dispersion used, classify and can be divided into thick coated type (7～45mm), scumbling type (3～7mm) and ultrathin (≤3mm) from coat-thickness; Wherein aqueous ultra-thin expansion type steel structure fire-proof coating fire resistance excellence, ornamental strong, the while meets again the requirements such as environmental protection and safety, is the developing direction of at present domestic and international steel structure fire-proof paint.
base-material emulsion for water expansion steel structure fire-proof paint mainly contains: pure-acrylic emulsion, benzene emulsion, organosilicon crylic acid latex, the tertiary emulsion of vinegar, inclined to one side chlorine emulsion and epoxy emulsion etc., above-mentioned emulsion is as filmogen, char forming catalyst, char-forming agent and whipping agent formation expansible fireproof system, be aided with various fire retardants, mineral filler and auxiliary agent and form water expansion steel structure fire-proof paint.
about the report of water expansion steel structure fire-proof paint has a lot, for example Chinese patent CN 101205441B has introduced a kind of steel structure fire-proof paint taking self-crosslinking silicone-acrylic compound emulsion as matrix, taking organopolysiloxane, self-crosslinking poly acrylate composite emulsion as filmogen, and be on the basis of composite fire-proof auxiliary agent at ammonium polyphosphate used, trimeric cyanamide and tetramethylolmethane, add melamine phosphate, previous blowing agent and other high temperature resistant filler and auxiliary agent, frie retardant coating fire endurance can reach 90min(coat-thickness 2mm); Chinese patent CN 102850905A discloses a kind of water expansion steel structure fire-proof paint, it is made up of A, B two portions, A component contains ammonium polyphosphate modifying, trimeric cyanamide, tetramethylolmethane, modification expansible black lead, modified coal ash and floats pearl, modified nano-titanium dioxide, water and a small amount of auxiliary agent, B component is made up of aqueous epoxy emulsion, waterborne curing agent and a small amount of auxiliary agent, thereby improves cohesiveness and dispersed physicochemical property and the fire resistance period that has improved frie retardant coating of material and base-material.
the shortcomings such as at present, most of Waterborne Fire Retardant Coatings for Steels have many weak points, as the charring layer foaming heterogeneity, the intensity difference, poor with steel matrix adhesive force that form in burning, have flue gas safety problem, and weathering resistance is not good.
Summary of the invention
the present invention is directed to the technical problem that existing steel structure fire-proof paint exists, a kind of aqueous ultra-thin expansion type frie retardant coating for steel construction and preparation method thereof is provided.
composition and the mass percent of a kind of aqueous ultra-thin expansion type frie retardant coating for steel construction provided by the present invention are as follows:
modified water-soluble epoxy emulsion 10～35
solidifying agent 1～8
benzene emulsion or organosilicon crylic acid latex 5～15
ammonium polyphosphate 10～20
trimeric cyanamide 6～12
tetramethylolmethane 8～16
fire retardant 5～15
face, filler 5～15
auxiliary agent 2～8
water 15～35
the modified material using is 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, and english abbreviation is DOPO, and its structural formula is:
described modified water-soluble epoxy emulsion is bisphenol A type epoxy resin emulsion, and solid content is 40wt%～55 wt %, and epoxy equivalent (weight) is 1500～2000; Aqueous epoxy emulsion has good mechanical property and chemical stability, but its disadvantage is inflammable, P=O pair of keys of P-H key in DOPO and strong electron-withdrawing group group are connected, there is certain activity, can be used as nucleophilic reagent generation nucleophilic reaction, DOPO can react with carbon-carbon double bond, epoxy bond etc., carries out modification can make aqueous epoxy emulsion have good flame retardant properties with DOPO and derivative thereof.
described solidifying agent is any one in amidation polyamines, polymeric amide, polyamines-epoxy adduct.
the solid content of described benzene emulsion or organosilicon crylic acid latex is 45wt%～55wt%, and pH value is 7～9.
described ammonium polyphosphate is as char forming catalyst, it at high temperature makes coating change nonflammable three-dimensional charcoal layer structure into by dehydration, and there is charing and expansion under whipping agent and char-forming agent effect, form the very little fine and close charring layer film of thermal conductivity, to stop the effect of burning things which may cause a fire disaster to steel construction.The polymerization degree n of described ammonium polyphosphate is that 800～1200, pH value (10wt% ammonium polyphosphate suspension) is 5～7, and heat decomposition temperature is 250～270 DEG C.
described trimeric cyanamide is whipping agent, and it can decompose generation NH at a certain temperature
3
, CO
2
, NO
2
deng non-flammable gases, thereby impel system foaming and intumescing.
described tetramethylolmethane is char-forming agent, and its structural formula is C (CH
2
oH)
4
, the effect of char-forming agent is to meet after fire in coating, can under the effect of carbonifying catalyst, dewater and form charring layer, supports for the final foaming layer forming provides skeleton; The heat decomposition temperature of described tetramethylolmethane is 260～280 DEG C.
heat decomposition temperature between described ammonium polyphosphate, trimeric cyanamide and tetramethylolmethane three should be approaching as far as possible, to bring into play better synergistic effect.
described face, filler are wantonly three kinds or the four kinds of above mixing in titanium dioxide, process white, kaolin, wollastonite powder, talcum powder, diatomite, sepiolite, glass bead, expanded vermiculite.
described fire retardant is any more than two or three mixing in aluminium hydroxide, magnesium hydroxide, magnesium oxide, zinc oxide, zinc borate, antimonous oxide, tributyl phosphate, ammonium phosphate, clorafin, tetrabromo-bisphenol, decabromodiphynly oxide.
described auxiliary agent is any three kinds or the four kinds of above mixing in dispersion agent, defoamer, emulsifying agent, flow agent, thickening material, antisettling agent, softening agent, coupling agent.Described coupling agent is one or more in silane coupling agent KH-560, KH-561, KH-563, and its structure is:
preparation method's concrete steps of the aqueous ultra-thin expansion type frie retardant coating for steel construction provided by the present invention are as follows:
(1) prepare modified water-soluble epoxy emulsion: the reactor that takes a certain amount of aqueous epoxy emulsion and put into 100L; logical nitrogen protection; be heated to 80～120 DEG C; then add 9; mix-10-phospho hetero phenanthrene-10-oxide compound of 10-dihydro-9-oxy and a small amount of catalyzer triphenylphosphine, the mass ratio of described 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and described aqueous epoxy emulsion is 1:(5～10); progressively be warming up to 150～180 DEG C, insulation 4～8h makes described modified water-soluble epoxy emulsion.
(2) modification of part fire retardant, modification concrete steps are:
a: prepare modified silane coupler: by 9, mix-10-phospho hetero phenanthrene-10-oxide compound of 10-dihydro-9-oxy and silane coupling agent join in reactor, under nitrogen protection, heat with thermal oil, in the time that temperature rises to 150～180 DEG C, start writing time, reaction is cooling after 5～8h can make modified silane coupler, described 9, the mass ratio of mix-10-phospho hetero phenanthrene-10-oxide compound of 10-dihydro-9-oxy and described silane coupling agent is 1:(1～2), described silane coupling agent is silane coupling agent KH-560, silane coupling agent KH-561, any one or more mixing in silane coupling agent KH-563.Reaction formula is as follows:
b: by needing any in the fire retardant aluminium hydroxide, magnesium hydroxide, magnesium oxide, zinc oxide of modification, add dehydrated alcohol ultrasonic dispersion 10～30min and be placed in ball grinder; Modified silane coupler prepared by described steps A dilutes by the ratio that dehydrated alcohol is 1:1 in mass ratio, after regulating pH value to 3.5～5.0 with Glacial acetic acid, add in ball grinder, after grinding 0.5～1.5h, taking-up oven dry obtains modified flame-retardant agent, and the mass ratio of described modified silane coupler and the described fire retardant that needs modification is 1:(20～50).
(3) in reactor, add successively water, part of auxiliary, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, fire retardant and face, filler, under the rotating speed of 800～1200r/min, stir 20～40min, then proceed to grinding in ball grinder 1.0～2.0h, proceed to again reactor, adjusting rotary speed to 400～600r/min, add benzene emulsion or organosilicon crylic acid latex, and then add modified water-soluble epoxy emulsion, solidifying agent and residue auxiliary agent, stir 1.0～2.0h, fully stir evenly and obtain after filtration Waterborne Fire Retardant Coatings for Steel of the present invention.
the present invention compared with prior art, has following technical characterstic:
although 1, more with the bibliographical information of DOPO modified epoxy, but relatively less for steel structure fire-proof paint field, in addition, the present invention is first with DOPO modified water-soluble epoxy emulsion, make aqueous epoxy emulsion having on the bases such as excellent Corrosion Protection, sticking power, weathering resistance, improved the fire resistance of self, more composite with benzene emulsion or organosilicon crylic acid latex, overcome the deficiency of single emulsion performance, emulsion over-all properties is got a promotion.
, with the silane coupler modified fire retardant of DOPO type, phosphoric and element silicon are introduced in surface at fire retardant simultaneously, both improved the dispersiveness of fire retardant in coating, improve again its fire retardant performance, optimized the proportioning of silane coupling agent simultaneously, ensureing, under the prerequisite of modified effect, to have reduced the methyl alcohol that coupling agent discharges in modifying process, meet the requirement of environmental protection.
, the feature such as the present invention has that material cost is lower, preparation technology is simple, environmental protection.
Embodiment
prepare steel structure fire-proof paint of the present invention according to the composition of listing below and mass percent:
modified water-soluble epoxy emulsion 20
solidifying agent 3
organosilicon crylic acid latex 8
ammonium polyphosphate 13
trimeric cyanamide 7
tetramethylolmethane 9
modified aluminium hydroxide 4
modified zinc oxide 2
zinc borate 3
titanium dioxide 3
wollastonite powder 3
expanded vermiculite 2
various auxiliary agents 5
water 18
the preparation process of frie retardant coating of the present invention is: the each component that takes aequum, in reactor, add successively water, part of auxiliary, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, modified aluminium hydroxide, modified zinc oxide, zinc borate, titanium dioxide, wollastonite powder and expanded vermiculite, under the rotating speed of 1000r/min, stir 30min, then proceed in ball mill and mill, until be ground to the fineness of regulation, proceed to again reactor, adjusting rotary speed is to 500r/min, add organosilicon crylic acid latex, and then add modified water-soluble epoxy emulsion, solidifying agent and residue auxiliary agent, stir 1.5h, fully stir evenly and be adjusted to suitable viscosity scope, make frie retardant coating of the present invention finally by filtering.
frie retardant coating prepared by the present invention detects with reference to correlation test method in GB12441-2005 (" finishing fire retardant paint "), and its key technical indexes sees the following form:
Claims (4)
1.
for an aqueous ultra-thin expansion type frie retardant coating for steel construction, it is characterized in that the composition of this frie retardant coating and mass percent are as follows:
modified water-soluble epoxy emulsion 10～35
solidifying agent 1～8
benzene emulsion or organosilicon crylic acid latex 5～15
ammonium polyphosphate 10～20
trimeric cyanamide 6～12
tetramethylolmethane 8～16
fire retardant 5～15
face, filler 5～15
auxiliary agent 2～8
water 15～35
described modified water-soluble epoxy emulsion is bisphenol A type epoxy resin emulsion, and solid content is 40wt%～55wt%, and epoxy equivalent (weight) is 1500～2000;
described solidifying agent is any in amidation polyamines, polymeric amide, polyamines-epoxy adduct;
described face, filler are wantonly three kinds or the four kinds of above mixing in titanium dioxide, process white, kaolin, wollastonite powder, talcum powder, diatomite, sepiolite, glass bead, expanded vermiculite;
described fire retardant is any more than two or three mixing in aluminium hydroxide, magnesium hydroxide, magnesium oxide, zinc oxide, zinc borate, antimonous oxide, tributyl phosphate, ammonium phosphate, clorafin, tetrabromo-bisphenol, decabromodiphynly oxide;
described auxiliary agent is any three kinds or the four kinds of above mixing in dispersion agent, defoamer, emulsifying agent, flow agent, thickening material, antisettling agent, softening agent, coupling agent.
2.
according to claim 1, for an aqueous ultra-thin expansion type frie retardant coating for steel construction, the solid content that it is characterized in that described benzene emulsion or organosilicon crylic acid latex is 45wt%～55wt%, and pH value is 7～9.
3.
a kind of aqueous ultra-thin expansion type frie retardant coating for steel construction according to claim 1, the polymerization degree n that it is characterized in that described ammonium polyphosphate is 800～1200, the pH value of described ammonium polyphosphate 10wt% suspension is 5～7, and heat decomposition temperature is 250 DEG C～270 DEG C.
4.
a kind of preparation method of the aqueous ultra-thin expansion type frie retardant coating for steel construction described in claim 1, is characterized in that these preparation method's concrete steps are as follows:
(1) prepare modified water-soluble epoxy emulsion: the reactor that takes a certain amount of aqueous epoxy emulsion and put into 100L, logical nitrogen protection, be heated to 80～120 DEG C, then add 9, mix-10-phospho hetero phenanthrene-10-oxide compound of 10-dihydro-9-oxy and a small amount of catalyzer triphenylphosphine, the mass ratio of described 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and described aqueous epoxy emulsion is 1:(5～10), progressively be warming up to 150～180 DEG C, insulation 4～8h makes described modified water-soluble epoxy emulsion;
(2) modification of part fire retardant, the concrete steps of modification are:
a: prepare modified silane coupler: by 9, mix-10-phospho hetero phenanthrene-10-oxide compound of 10-dihydro-9-oxy and silane coupling agent join in reactor, under nitrogen protection, heat with thermal oil, in the time that temperature rises to 150～180 DEG C, start writing time, reaction is cooling after 5～8h can make modified silane coupler, described 9, the mass ratio of mix-10-phospho hetero phenanthrene-10-oxide compound of 10-dihydro-9-oxy and described silane coupling agent is 1:(1～2), described silane coupling agent is silane coupling agent KH-560, silane coupling agent KH-561, any one or more mixing in silane coupling agent KH-563,
b: by needing any in the fire retardant aluminium hydroxide, magnesium hydroxide, magnesium oxide, zinc oxide of modification, add dehydrated alcohol ultrasonic dispersion 10～30min and be placed in ball grinder; Modified silane coupler prepared by described steps A dilutes by the ratio that dehydrated alcohol is 1:1 in mass ratio, after regulating pH value to 3.5～5.0 with Glacial acetic acid, add in ball grinder, after grinding 0.5～1.5h, taking-up oven dry obtains modified flame-retardant agent, and the mass ratio of described modified silane coupler and the described fire retardant that needs modification is 1:(20～50);
(3) in reactor, add successively water, part of auxiliary, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, fire retardant and face, filler, under the rotating speed of 800～1200r/min, stir 20～40min, then proceed to grinding in ball grinder 1.0～2.0h, proceed to again reactor, adjusting rotary speed to 400～600r/min, add benzene emulsion or organosilicon crylic acid latex, and then add modified water-soluble epoxy emulsion, solidifying agent and residue auxiliary agent, stir 1.0～2.0h, fully stir evenly and make after filtration described frie retardant coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410341750.5A CN104130671B (en) | 2014-07-18 | 2014-07-18 | A kind of aqueous ultra-thin expansion type fireproof coating for steel construction and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410341750.5A CN104130671B (en) | 2014-07-18 | 2014-07-18 | A kind of aqueous ultra-thin expansion type fireproof coating for steel construction and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104130671A true CN104130671A (en) | 2014-11-05 |
| CN104130671B CN104130671B (en) | 2016-06-22 |
Family
ID=51803535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410341750.5A Active CN104130671B (en) | 2014-07-18 | 2014-07-18 | A kind of aqueous ultra-thin expansion type fireproof coating for steel construction and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104130671B (en) |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861823A (en) * | 2015-05-29 | 2015-08-26 | 黄强 | High temperature resistant anticorrosive coating for automobile outer parts |
| CN104927545A (en) * | 2015-07-12 | 2015-09-23 | 赵彬 | Anti-corrosion fireproof coating |
| CN105385311A (en) * | 2015-12-17 | 2016-03-09 | 常熟市方塔涂料化工有限公司 | Environmentally friendly high temperature resistant anticorrosion paint and preparation method thereof |
| CN105400308A (en) * | 2015-12-06 | 2016-03-16 | 康明哲 | Fireproof coating and preparing method thereof |
| CN105419541A (en) * | 2015-12-31 | 2016-03-23 | 王丽萍 | Coating material used for an oil conveying pipe |
| CN105542266A (en) * | 2015-12-16 | 2016-05-04 | 宁国市开源橡塑汽车零部件有限公司 | High-elasticity environmentally-friendly flame-retardant rubber material |
| CN105567043A (en) * | 2016-02-19 | 2016-05-11 | 徐冉 | Fireproof paint and preparing method thereof |
| CN105885629A (en) * | 2016-05-25 | 2016-08-24 | 马鞍山市顺达环保设备有限公司 | Fire-resistant coating for high-temperature environmental protection equipment and preparation method thereof |
| CN105949887A (en) * | 2016-07-18 | 2016-09-21 | 安徽朗凯奇建材有限公司 | High-brightness butadiene-styrene-rubber heat-insulation and waterproof coating and preparing method thereof |
| CN106147454A (en) * | 2016-08-04 | 2016-11-23 | 潍坊鑫洋化工有限公司 | A kind of environment-friendly polypropylene acid esters water flame-proof paint and preparation technology thereof |
| CN106398458A (en) * | 2016-07-26 | 2017-02-15 | 苏州明轩地坪涂料有限公司 | Fireproof coating |
| CN106752702A (en) * | 2016-12-15 | 2017-05-31 | 天长市金陵电子有限责任公司 | A kind of water-fast high fire-retardance radiating electrostatic spraying coating |
| CN107629607A (en) * | 2016-07-05 | 2018-01-26 | 广东广山新材料股份有限公司 | A kind of fireproof coating |
| CN107760172A (en) * | 2017-11-29 | 2018-03-06 | 镇江兴润土石方工程有限公司 | A kind of new derusting preparation method for coating suitable for excavator |
| CN107858093A (en) * | 2017-11-24 | 2018-03-30 | 湖南太子化工涂料有限公司 | A kind of monocomponent waterborne polyurethane coating, preparation method and application |
| CN108034332A (en) * | 2017-12-28 | 2018-05-15 | 湖北楚禾新材料有限公司 | A kind of Waterborne Fire Retardant Coatings for Steel and preparation method thereof |
| CN109161281A (en) * | 2018-07-11 | 2019-01-08 | 张培磊 | A kind of environment-friendlyfireproof fireproof paint and preparation method thereof |
| CN109825136A (en) * | 2019-01-17 | 2019-05-31 | 北京理工大学珠海学院 | A kind of boracic flame-retarded resin steel construction expanding fire-proof paint |
| CN110294996A (en) * | 2019-07-05 | 2019-10-01 | 辽宁大学 | A kind of fire extinguishing coating and preparation method thereof for power equipment |
| CN110760244A (en) * | 2019-11-20 | 2020-02-07 | 应急管理部四川消防研究所 | Epoxy steel structure fireproof coating |
| CN110982372A (en) * | 2018-09-30 | 2020-04-10 | 常州大学 | Efficient anticorrosive flame-retardant epoxy graphene coating and preparation method thereof |
| CN111500161A (en) * | 2020-05-29 | 2020-08-07 | 竺浩亮 | Water-based intumescent low-smoke fireproof coating material |
| CN111675968A (en) * | 2020-03-24 | 2020-09-18 | 山东华韵新材料有限公司 | Flame-retardant paint for fireproof, non-combustible and high-corrosion-resistance color-coated plate and preparation method thereof |
| CN111675952A (en) * | 2020-07-04 | 2020-09-18 | 上海暄洋化工材料科技有限公司 | Self-repairing water-based epoxy fireproof coating and preparation process thereof |
| CN112940576A (en) * | 2021-03-16 | 2021-06-11 | 国家电网有限公司 | Intumescent flame-retardant coating for cable and preparation method thereof |
| CN113088145A (en) * | 2021-03-31 | 2021-07-09 | 上海安翼新材料发展合伙企业(有限合伙) | Modified high-temperature fiber resin-based fireproof coating and preparation method thereof |
| US20220089016A1 (en) * | 2019-04-03 | 2022-03-24 | Sika Technology Ag | Intumescent coated vent for large passenger vehicles |
| CN114904739A (en) * | 2022-06-16 | 2022-08-16 | 广东百安环保新材料有限公司 | Water-based fireproof coating for steel structure and preparation method thereof |
| CN115785719A (en) * | 2022-07-27 | 2023-03-14 | 重庆清徽节能环保科技有限公司 | Tannic acid metal hydroxide modified core-shell flame retardant and intumescent flame retardant coating thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002301A (en) * | 2010-11-10 | 2011-04-06 | 同济大学 | Fire-proof and corrosion-proof dual-function paint for water-based ultrathin expansion steel structure and preparation method thereof |
| CN102675895A (en) * | 2012-06-15 | 2012-09-19 | 沈阳化工大学 | Flame-retardant composite material with DOPO (9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) modified nano mesoporous molecular sieve |
-
2014
- 2014-07-18 CN CN201410341750.5A patent/CN104130671B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002301A (en) * | 2010-11-10 | 2011-04-06 | 同济大学 | Fire-proof and corrosion-proof dual-function paint for water-based ultrathin expansion steel structure and preparation method thereof |
| CN102675895A (en) * | 2012-06-15 | 2012-09-19 | 沈阳化工大学 | Flame-retardant composite material with DOPO (9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) modified nano mesoporous molecular sieve |
Non-Patent Citations (1)
| Title |
|---|
| 王新龙等: "含磷环氧树脂/ 纳米氢氧化铝阻燃体系的研究", 《绝缘材料》 * |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861823A (en) * | 2015-05-29 | 2015-08-26 | 黄强 | High temperature resistant anticorrosive coating for automobile outer parts |
| CN104927545A (en) * | 2015-07-12 | 2015-09-23 | 赵彬 | Anti-corrosion fireproof coating |
| CN105400308A (en) * | 2015-12-06 | 2016-03-16 | 康明哲 | Fireproof coating and preparing method thereof |
| CN105542266A (en) * | 2015-12-16 | 2016-05-04 | 宁国市开源橡塑汽车零部件有限公司 | High-elasticity environmentally-friendly flame-retardant rubber material |
| CN105385311A (en) * | 2015-12-17 | 2016-03-09 | 常熟市方塔涂料化工有限公司 | Environmentally friendly high temperature resistant anticorrosion paint and preparation method thereof |
| CN105419541A (en) * | 2015-12-31 | 2016-03-23 | 王丽萍 | Coating material used for an oil conveying pipe |
| CN105567043A (en) * | 2016-02-19 | 2016-05-11 | 徐冉 | Fireproof paint and preparing method thereof |
| CN105885629A (en) * | 2016-05-25 | 2016-08-24 | 马鞍山市顺达环保设备有限公司 | Fire-resistant coating for high-temperature environmental protection equipment and preparation method thereof |
| CN107629607A (en) * | 2016-07-05 | 2018-01-26 | 广东广山新材料股份有限公司 | A kind of fireproof coating |
| CN105949887A (en) * | 2016-07-18 | 2016-09-21 | 安徽朗凯奇建材有限公司 | High-brightness butadiene-styrene-rubber heat-insulation and waterproof coating and preparing method thereof |
| CN106398458A (en) * | 2016-07-26 | 2017-02-15 | 苏州明轩地坪涂料有限公司 | Fireproof coating |
| CN106147454A (en) * | 2016-08-04 | 2016-11-23 | 潍坊鑫洋化工有限公司 | A kind of environment-friendly polypropylene acid esters water flame-proof paint and preparation technology thereof |
| CN106752702A (en) * | 2016-12-15 | 2017-05-31 | 天长市金陵电子有限责任公司 | A kind of water-fast high fire-retardance radiating electrostatic spraying coating |
| CN107858093A (en) * | 2017-11-24 | 2018-03-30 | 湖南太子化工涂料有限公司 | A kind of monocomponent waterborne polyurethane coating, preparation method and application |
| CN107760172A (en) * | 2017-11-29 | 2018-03-06 | 镇江兴润土石方工程有限公司 | A kind of new derusting preparation method for coating suitable for excavator |
| CN108034332A (en) * | 2017-12-28 | 2018-05-15 | 湖北楚禾新材料有限公司 | A kind of Waterborne Fire Retardant Coatings for Steel and preparation method thereof |
| CN109161281A (en) * | 2018-07-11 | 2019-01-08 | 张培磊 | A kind of environment-friendlyfireproof fireproof paint and preparation method thereof |
| CN110982372A (en) * | 2018-09-30 | 2020-04-10 | 常州大学 | Efficient anticorrosive flame-retardant epoxy graphene coating and preparation method thereof |
| CN109825136A (en) * | 2019-01-17 | 2019-05-31 | 北京理工大学珠海学院 | A kind of boracic flame-retarded resin steel construction expanding fire-proof paint |
| US20220089016A1 (en) * | 2019-04-03 | 2022-03-24 | Sika Technology Ag | Intumescent coated vent for large passenger vehicles |
| CN110294996A (en) * | 2019-07-05 | 2019-10-01 | 辽宁大学 | A kind of fire extinguishing coating and preparation method thereof for power equipment |
| CN110760244A (en) * | 2019-11-20 | 2020-02-07 | 应急管理部四川消防研究所 | Epoxy steel structure fireproof coating |
| CN111675968A (en) * | 2020-03-24 | 2020-09-18 | 山东华韵新材料有限公司 | Flame-retardant paint for fireproof, non-combustible and high-corrosion-resistance color-coated plate and preparation method thereof |
| CN111500161A (en) * | 2020-05-29 | 2020-08-07 | 竺浩亮 | Water-based intumescent low-smoke fireproof coating material |
| CN111675952A (en) * | 2020-07-04 | 2020-09-18 | 上海暄洋化工材料科技有限公司 | Self-repairing water-based epoxy fireproof coating and preparation process thereof |
| CN112940576A (en) * | 2021-03-16 | 2021-06-11 | 国家电网有限公司 | Intumescent flame-retardant coating for cable and preparation method thereof |
| CN113088145A (en) * | 2021-03-31 | 2021-07-09 | 上海安翼新材料发展合伙企业(有限合伙) | Modified high-temperature fiber resin-based fireproof coating and preparation method thereof |
| CN114904739A (en) * | 2022-06-16 | 2022-08-16 | 广东百安环保新材料有限公司 | Water-based fireproof coating for steel structure and preparation method thereof |
| CN115785719A (en) * | 2022-07-27 | 2023-03-14 | 重庆清徽节能环保科技有限公司 | Tannic acid metal hydroxide modified core-shell flame retardant and intumescent flame retardant coating thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104130671B (en) | 2016-06-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104130671A (en) | Aqueous ultrathin expansion-type fireproof coating for steel structure and preparation method thereof | |
| CN112961528B (en) | Environment-friendly fireproof coating and preparation method thereof | |
| CN106752681B (en) | A kind of Water-borne inflation type refractory coating and preparation method thereof based on modified graphene oxide | |
| CN103045037B (en) | Water-based expandable fireproof steel structure coating and preparation method | |
| CN104177965B (en) | A kind of Organic-inorganic composite nano heat-insulating fireproof coating and preparation method thereof | |
| CN103740231B (en) | A kind of water expansion cable nano fire-retardant coating and preparation method thereof | |
| JP6338681B2 (en) | Phosphorus-nitrogen based expansive flame retardant, synthesis method thereof, and use thereof | |
| CN102585652B (en) | Fire retardant coating | |
| CN101280142B (en) | Preparation method of environment-friendly aqueous nanometer fireproof flame-retardant coating | |
| CN102675992B (en) | Expanded type aqueous facing fireproof coating and preparation method thereof | |
| CN102134432A (en) | Water-borne ultrathin intumescent fireproof and anticorrosive double-function coating for steel structure and preparation method thereof | |
| CN101323727A (en) | Environment-friendly aqueous expansion type fireproof coating and preparation thereof | |
| CN102002301A (en) | Fire-proof and corrosion-proof dual-function paint for water-based ultrathin expansion steel structure and preparation method thereof | |
| CN109370288A (en) | A kind of wood materials expanded water-based fireproof anti-flaming dope and preparation method thereof | |
| CN109439083A (en) | A kind of ultrathin expansion type steel structure aqueous fire-proof coating and preparation method thereof | |
| CN102329549A (en) | Water-borne inflation type refractory coating and preparation method thereof | |
| CN109836941A (en) | A kind of Organic-inorganic composite nano heat-insulating fireproof coating and preparation method thereof | |
| CN104530946A (en) | Sound-insulation fireproof moistureproof paint and preparation method thereof | |
| CN108485351B (en) | Modified hydrotalcite-based water-based smoke suppression expansion type fireproof coating and preparation method thereof | |
| CN104449316A (en) | Thermal-insulation and sound-insulation coating | |
| CN101659833A (en) | Fireproofing paint for steel structure and preparation method thereof | |
| CN102977710A (en) | Acrylic acid fireproof coating and method for preparing same | |
| CN104745071A (en) | Polyurethane waterproof flame-retardant paint and preparation method thereof | |
| CN104341956A (en) | Fire retardant coating | |
| CN108948911A (en) | A kind of fireproof coating and preparation method thereof for door and window |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200413 Address after: 110000 No.56, Qibei street, Xihe, economic and Technological Development Zone, Shenyang, Liaoning Province Patentee after: Shenyang Taifeng Chemical Co., Ltd Address before: 243000 No.5 workshop of Ma'anshan industrial transfer demonstration park, Anhui Province Patentee before: ANHUI QIANHE NEW MATERIAL SCIENCE & TECHNOLOGY DEVELOPMENT Co.,Ltd. |