CN104130664A - Flame-retardant antistatic high-wear-resistance paint and manufacturing method thereof - Google Patents
Flame-retardant antistatic high-wear-resistance paint and manufacturing method thereof Download PDFInfo
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- CN104130664A CN104130664A CN201410320656.1A CN201410320656A CN104130664A CN 104130664 A CN104130664 A CN 104130664A CN 201410320656 A CN201410320656 A CN 201410320656A CN 104130664 A CN104130664 A CN 104130664A
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Abstract
The invention relates to a flame-retardant antistatic high-wear-resistance paint and a manufacturing method thereof. The invention relates to the field of surface paints used on substrates such as metal, composite materials, hard plastic, and the like, and the preparation method thereof. The paint can be widely applied in coatings of equipment in coal mines, oil tanks, coal transportation, wharfs, and the like. The paint comprises dual components of A and B. The component A is composed of epoxy resin, an active diluting agent, a levelling agent, a de-foaming agent, a silane coupling agent, a conductive filling agent, a wear-resistant filling agent, and a flame retardant. The B component comprises an amine type curing agent and an accelerator. The paint is characterized in that the component A also comprises a levelling agent c, a levelling agent D, zinc oxide whiskers, and conductive mica powder. The flame-retardant antistatic high-wear-resistance paint provided by the invention has the characteristics of normal-temperature curing and low smoke during combustion. The paint has excellent adhesion force on a polar surface, and is especially suitable for coating on polar surfaces such as glass fiber reinforced plastic and metal. The paint has excellent anti-corrosive property.
Description
Technical field
The invention belongs to a kind of topcoating and preparation field thereof that is applied to the grounds such as metal, matrix material, rigid plastics, can be widely used in the application of the equipment such as colliery, oil tank, Coal Transport, harbour.
Background technology
Superpolymer and glass fiber reinforced plastics product have very high electrical insulating property, and this is in a lot of fields performance that particularly electronics, appliance field have been.But these material surfaces easily gather static, constantly gathering of static charge, will cause spark discharge.There is the environment of combustible and explosive articles in some, as the transportation of combustible and explosive articles and and the places such as construction in coal mining, tunnel because there is methane gas, therefore will prevent that static from discharging the spark discharge initiation fire that produces or the generation of blast.In these specific occasions, just need to lead static modification to the surface of material, eliminate or avoid material surface to gather static.
On the other hand, composite material process planning is flexible, and its structure and performance have very strong designability, can select by structure design, material is selected and the selected optimized performance of giving matrix material of processing parameter.But, if that glass fiber reinforcement epoxy matrix material will guarantee to reach is fire-retardant, the requirement of antistatic surface and high abrasion simultaneously, just need to add a large amount of fire retardants, static inhibitor and anti-wear agent simultaneously, it is very poor that its manufacturability will become, and the properties such as intensity, erosion resistance, weather resistance, resistance to fatigue also can reduce greatly.
At composite material surface, applying anti-static and abrasion-resistant coating, is the effective way of eliminating composite material surface static.Current having no is suitable for the coating article that has excellent flame retardant resistance, static resistance, high-wearing feature, high-mechanical property concurrently that glass fiber reinforced plastic surface applies.Formerly patent application " high solid antistatic epoxy floor paint and production method " (publication number CN 1594470A), the preparation by ZnOw and conductive mica powder for terrace paint.But, have high abrasion concurrently, fire-retardant, anlistatig coating has no report simultaneously.Although the terrace paint that above-mentioned ZnOw and conductive mica powder make has lasting antistatic property, without flame retardant resistance, its wear resistance does not reach the requirement of underground mine use equipment high abrasion yet.
Summary of the invention
The object of the present invention is to provide a kind of flame-retardant and anti-static high wear resistance coatings and preparation method thereof, when utilizing ZnOw to strengthen resin, obtain permanent unattenuated high-antistatic performance, high flame resistance and excellent wear resisting property.
Flame-retardant and anti-static high wear resistance coatings provided by the present invention, comprises first, second two-pack; The formula of first component comprises epoxy resin, reactive thinner, flow agent, defoamer, silane coupling agent, conductive filler material, wear resistant filler and fire retardant; Component B formula comprises amine curing agent, promotor; It is characterized in that, first component formula also comprises flow agent c, flow agent D, ZnOw and conductive mica powder.
Described conductive filler material can be graphitized carbon black and/or Graphite Powder 99.
Above-mentioned wear resistant filler can be the filler that rare earth wear resistant filler, silicon carbide, lapis amiridis, molybdenumdisulphide, tetrafluoroethylene powder and nylon powder etc. have wear-resistant effect, uses wherein any one or multiple combination all can.
Described fire retardant can be used halogenated flame retardant, chloro phosphoric acid ester, aluminium hydroxide, antimonous oxide etc., is preferably used in conjunction with zinc borate smoking agent, thus the low cigarette of putting while obtaining high flame retardant resistance and burning.
The amine curing agent of second component refers to aliphatics amine solidifying agent or phosphorus modified aliphatic amine hardener and their mixture.
Flame-retardant and anti-static high wear resistance coatings provided by the present invention, its optimum formula (parts by weight) is:
First component:
Epoxy resin 100
Reactive thinner 10～20
Flow agent 0.2～1
Defoamer 0.2～1
Silane coupling agent 0.5～5
ZnOw 20～40
Conductive mica powder 20～50
Graphitized carbon black 0～5
Graphite Powder 99 0～20
Fire retardant 30～200
Wear resistant filler 20～100
Second component:
Amine curing agent 100
Promotor 0～10
First, second component proportion is 100:5～40.
The making method of flame-retardant and anti-static high wear resistance coatings of the present invention, is characterized in that comprising the steps:
1) preparation of A component:
Step 1-1: take epoxy resin, solvent, reactive thinner and each analog assistant by formula ratio and add successively in dispersion cylinder, stirring and dissolving is complete, to obtain base-material;
Step 1-2: take all fillers, the dyestuff except ZnOw by formula ratio, under agitation drop in above-mentioned base-material, middling speed (500～800 turn/part) is disperseed 30 minutes, then (1000～1500 revs/min) disperse 30 minutes at a high speed, and ball milling or mulser are pulverized emulsification 50 minutes;
Step 1-3: take ZnOw by formula ratio, drop into again above-mentioned system under low rate mixing, disperse at a slow speed (500 revs/min following) to disperse more than 30 minutes, to filter and package after being uniformly dispersed, obtain coating A component;
2) preparation of B component:
Step 2-l: take amine curing agent and promotor and appropriate solvent by formula ratio, drop into successively and disperse in cylinder, (1000～1500 revs/min) disperse 5～15 minutes at a high speed;
Step 2-2: filter and package and can obtain B component.
Positively effect main manifestations of the present invention is in the following areas:
(1) the antistatic surface that utilizes the electroconductibility raising coating of four acicular type zinc oxide crystal whisker, is used in conjunction with conductive mica powder, gives the present invention unattenuated permanent surperficial static resistance.
(2) utilize four acicular type zinc oxide crystal whisker wear-resisting antiskid characteristic, be used in conjunction with high abrasion resisting material, give the present invention high wear resistance;
(3) the enhancement of four acicular type zinc oxide crystal whisker, gives the present invention higher body intensity and sticking power;
(4) utilize the amine curing agent of ambient temperature curable, realize normal temperature, the low-temperature curing of coating;
(5) use fire retardant, and be used in conjunction with zinc borate smoking agent, the low cigarette of putting while giving the high flame retardant resistance of the present invention and burning;
(6) use coupling agent, by matrix resin and the coupling of various filler bridge formation, improve interface bonding, further improve interface performance of the present invention, in macroscopic view, further improved intensity, sticking power and water tolerance.
In sum, flame-retardant and anti-static high wear resistance coatings disclosed in this invention and preparation method thereof, the characteristic of low cigarette is provided while providing the high wear resistance coatings of a kind of high flame retardant, high-antistatic, this coating to have ambient cure and burning.This coating is excellent to polar surfaces sticking power, be specially adapted to glass reinforced plastic, metal isopolarity surface coating, there is excellent antiseptic property.
Embodiment
In the present invention, selected the low-molecular-weight epoxy resin (epoxy equivalent (weight) 220 left and right) of bisphenol A-type, for example domestic E=44 or E=51.For the flame retardant resistance obtaining, the present invention has also used brominated bisphenol A epoxy resin with.
In the present invention compound use novel four acicular type zinc oxide crystal whisker (be called for short T-ZnOw) and nanometer coated with conductive mica powder, make both produce synergy.Conductive mica powder is to adopt nanotechnology to be composited at the coated one deck of mica surface or which floor conductive nano material, and its powder resistance rate can reach 100 Ω cm.T-ZnOw has unique solid four acicular structures, can in system, form very effective three-dimensional netted conductive channel, thereby required addition is much smaller than spherical or laminal filler when it is distributed in base material; And its electroconductibility is electronic conduction, and stability is high.Both compound uses, performance synergy, more excellent than using separately separately conductive effect.
In the present invention's formula, flow agent and defoamer compound system have been used, wherein flow agent is polyether-modified polydimethylsiloxane, as B-403 of the BYK-306 of German BIC Corp, Guangzhou Lu Ou company etc., defoamer is the solution of polyacrylic ester broken bubble polymkeric substance and polysiloxane, as the L-560 of the BYK-141 of German BIC Corp and Guangzhou Lu Ou company etc.Appropriate compound use flow agent, defoamer can anti-tangerine peels, shrinkage cavity, bubble, promote pigment wetting, improve gloss, promote the level and smooth effect that waits.
In first component formula of the present invention, can use the anti-settling agents such as aromatic hydrocarbon solvent (as toluene, dimethylbenzene etc.), ketones solvent (acetone, methylethylketone), esters solvent (ethyl acetate, butylacetate), organobentonite or white carbon black, make system there is good storage stability, good construction technology, also can add according to actual needs appropriate dyestuff modulation required color.
Amine curing agent described in second component formula of the present invention, the mixed system that it and first component form can also can be used for intermediate temperature setting in ambient cure, and viscosity is low, application property good, after solidifying, gloss of film is high, and there is excellent physicochemical property, good flame-retardant and anti-static performance, outstanding wear resistance.Depending on the requirement of ambient temperature situations and curing speed, can add the promotor of amine curing agent amount 0-10%, as 2,4,6 one three (dimethylamino methyl) phenol (trade(brand)name DMP-30) promotes to solidify.
The invention solves the shortcoming that reduces epoxy resin technology and greatly reduce curable epoxide thing hardness because of adding of various auxiliary agents, filler, can obtain the solvent-free environmental protection coating material of high abrasion of high flame retardant high-antistatic, being used in composite material surface and applying, is the effective way of eliminating composite material surface static.This sandwich structure had both retained the excellent physical and mechanical propertiess such as the high strength of glass fiber reinforced plastics product, gave again the excellent static resistance in glass fiber reinforced plastics product surface and high wear resistance.Should high strength thereby meet under specific occasion, high flame retardant, the again particular requirement of high-antistatic and high abrasion.Can greatly improve like this properties of glass fiber reinforced plastics product for the down-hole coal excavation of colliery, work reliability, safety in utilization and the work-ing life of greatly improving glass reinforced plastic equipment.
Embodiment 1:
First component is made: by lower molecular weight E44 bisphenol A epoxide resin 100phr, brominated epoxy resin 50phr, neopentyl glycol bisglycidyl ether (678 thinner) 20 phr, phosphoric acid ester fire retardant 20phr, flow agent BYK-306 0.5phr, defoamer BYK-141 0.5phr, KH560 coupling agent 5phr, is weighed in container successively, stirs lower dissolving completely.Add organobentonite anti-settling agent 2phr, conductive mica powder 25phr, antimonous oxide 5 phr, zinc borate 10 phr, silicon carbide 100 phr, middling speed (500～800 revs/min) is disperseed 30 minutes, and then (1000～1500 revs/min) disperse 30 minutes at a high speed, and ball milling or mulser are pulverized emulsification 50 minutes; Add afterwards T-ZnOw 20phr, disperse at a slow speed (500 revs/min following) to disperse more than 30 minutes, after being uniformly dispersed, to filter and package, obtain coating A component;
Second component is made: three-[2-amino-ethyl] phosphamide solidifying agent 100phr, DMP-30 curing catalyst 10phr are weighed in reactor to stirring and dissolving complete, filter and package and make B component.
By aforementioned production method, obtain after product, after mixing in the ratio of first: second=10:1, be coated on insulation asbestos plate substrate surface.After solidifying, coating surface is smoothly attractive in appearance, and without tangerine peel, shrinkage cavity phenomenon, after 48 hours, testing this model surface resistivity is 10
5～10
6Ω, abrasion≤0.01.
Embodiment 2:
First component is made: lower molecular weight bisphenol A epoxide resin E51 100phr, neopentyl glycol bisglycidyl ether (678 thinner) 20 phr, phosphoric acid ester fire retardant 20phr, flow agent BYK-306 0.5phr, defoamer BYK-141 0.5phr, KH560 coupling agent 5phr, be weighed into successively in container, stir lower dissolving completely.Add organobentonite anti-settling agent 2phr, conductive mica powder 30phr, decabromodiphynly oxide 50phr, antimonous oxide 8 phr, lapis amiridis 100 phr, molybdenumdisulphide 20 phr, flake graphite in powder 10 phr middling speeds (500～800 revs/min) are disperseed 30 minutes, then (1000～1500 revs/min) disperse 30 minutes at a high speed, and ball milling or mulser are pulverized emulsification 50 minutes; Add T-ZnOw 20phr, disperse at a slow speed (500 revs/min following) to disperse more than 30 minutes, after being uniformly dispersed, to filter and package, obtain coating A component;
Second first component is made: PAA-500 pnenolic aldehyde amine hardener 100phr, DMP-30 curing catalyst 5phr are weighed in reactor to stirring and dissolving complete, filter and package and make B component.
By aforementioned production method, obtain after product, after mixing in the ratio of first: second=15:l, with high pressure airless spray equipment spraying, after solidifying, coating surface is smoothly attractive in appearance, and without tangerine peel, shrinkage cavity phenomenon, after 48 hours, testing this wear-resistant paint surface resistivity is 10
5Ω, abrasion≤0.01.
Claims (8)
1. a flame-retardant and anti-static high wear resistance coatings, comprises first, second two-pack; The formula of first component comprises epoxy resin, reactive thinner, flow agent, defoamer, silane coupling agent, conductive filler material, wear resistant filler and fire retardant; Component B formula comprises amine curing agent, promotor; It is characterized in that, first component formula also comprises flow agent c, flow agent D, ZnOw and conductive mica powder.
2. flame-retardant and anti-static high wear resistance coatings according to claim 1, is further characterized in that, described conductive filler material is graphitized carbon black and/or Graphite Powder 99.
3. flame-retardant and anti-static high wear resistance coatings according to claim 2, is further characterized in that, described wear resistant filler is wherein any one or multiple combination of rare earth wear resistant filler, silicon carbide, lapis amiridis, molybdenumdisulphide, tetrafluoroethylene powder and nylon powder.
4. flame-retardant and anti-static high wear resistance coatings according to claim 1, is further characterized in that, described fire retardant refers to halogenated flame retardant, chloro phosphoric acid ester, aluminium hydroxide, antimonous oxide.
5. flame-retardant and anti-static high wear resistance coatings according to claim 4, is further characterized in that, has been used in conjunction with zinc borate smoking agent with described fire retardant.
6. flame-retardant and anti-static high wear resistance coatings according to claim 1, is further characterized in that, the amine curing agent of described second component refers to aliphatics amine solidifying agent or phosphorus modified aliphatic amine hardener or their mixture.
7. flame-retardant and anti-static high wear resistance coatings according to claim 2, is further characterized in that, its formula is:
First component:
Epoxy resin 100
Reactive thinner 10～20
Flow agent 0.2～1
Defoamer 0.2～1
Silane coupling agent 0.5～5
ZnOw 20～40
Conductive mica powder 20～50
Graphitized carbon black 0～5
Graphite Powder 99 0～20
Fire retardant 30～200
Wear resistant filler 20～100
Second component:
Amine curing agent 100
Promotor 0～10
First, second component proportion is 100:5～40.
8. a making method for flame-retardant and anti-static high wear resistance coatings, is characterized in that, comprises the steps:
1) preparation of A component:
Step 1-1: take epoxy resin, solvent, reactive thinner and each analog assistant by formula ratio and add successively in dispersion cylinder, stirring and dissolving is complete, to obtain base-material;
Step 1-2: take all fillers, the dyestuff except ZnOw by formula ratio, under agitation drop in above-mentioned base-material, middling speed is disperseed 30 minutes, and then high speed dispersion is 30 minutes, and ball milling or mulser are pulverized emulsification 50 minutes;
Step 1-3: take ZnOw by formula ratio, drop into again above-mentioned system under low rate mixing, disperse at a slow speed more than 30 minutes, to filter and package after being uniformly dispersed, obtain coating A component;
2) preparation of B component:
Step 2-l: take amine curing agent and promotor and appropriate solvent by formula ratio, drop into successively and disperse in cylinder, high speed dispersion 5～15 minutes;
Step 2-2: filter and package and can obtain B component.
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|---|---|---|---|---|
| CN105118562A (en) * | 2015-07-09 | 2015-12-02 | 国家电网公司 | Anticorrosion bus and manufacturing method thereof |
| CN105219219A (en) * | 2015-10-19 | 2016-01-06 | 国网浙江省电力公司湖州供电公司 | A kind of novel wear resistant, protection against corrosion, Antistatic Paint and preparation method thereof |
| CN106010126A (en) * | 2016-07-19 | 2016-10-12 | 马晓洁 | Graphene-based antistatic wear-resistant two-component epoxy resin coating |
| CN106118354A (en) * | 2016-06-29 | 2016-11-16 | 铜陵青铜时代雕塑有限公司 | A kind of antistatic bronze sculpture Super hydrophobic anticorrosive paint and preparation method thereof |
| CN106750294A (en) * | 2016-12-31 | 2017-05-31 | 南京新月材料科技有限公司 | A kind of polyimides and preparation method thereof |
| CN106995649A (en) * | 2016-01-22 | 2017-08-01 | 北京泽马新技术有限公司 | The aqueous environment friendly transparent anticorrosive coating of stainless steel |
| CN108707391A (en) * | 2018-05-31 | 2018-10-26 | 长春智享优创科技咨询有限公司 | Highly effective flame-retardant epoxy resin composite coating and preparation method thereof |
| CN108978235A (en) * | 2015-07-29 | 2018-12-11 | 李梦燕 | A kind of production method of antistatic high temperature resistant fabric |
| CN109559855A (en) * | 2018-12-24 | 2019-04-02 | 深圳市斯比特电子有限公司 | A kind of flat wire is vertical around forming jig |
| CN111534195A (en) * | 2020-06-05 | 2020-08-14 | 厦门双瑞船舶涂料有限公司 | Hydrophobic anticorrosive coating and preparation method thereof |
| CN111646110A (en) * | 2020-06-05 | 2020-09-11 | 广东博顺带业有限公司 | Conductive conveying belt and manufacturing method thereof |
| CN111849229A (en) * | 2020-07-30 | 2020-10-30 | 湖南理工学院 | Fire escape passage fireproof powder coating and preparation process thereof |
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| US11560448B2 (en) | 2016-12-14 | 2023-01-24 | Bromine Compounds Ltd. | Antimony free flame-retarded epoxy compositions |
| CN115785764A (en) * | 2022-12-22 | 2023-03-14 | 上海海隆赛能新材料有限公司 | Quick-drying protective coating for ships and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1475339A (en) * | 2002-08-15 | 2004-02-18 | 孙建宁 | Flame-retardant antistatic polyvinyl chloride composite pipe and preparation method thereof |
| CN1594470A (en) * | 2003-09-12 | 2005-03-16 | 上海秀珀化工有限公司 | High solid anti-static epoxy floor coating and method for producing same |
| CN101372601A (en) * | 2008-10-17 | 2009-02-25 | 洛阳七维防腐工程材料有限公司 | Oil resistant (solvent), heatproof static conducting anti-corrosive paint and preparation thereof |
| CN102808334A (en) * | 2012-08-17 | 2012-12-05 | 杭州玖合新材料有限公司 | Thermosetting resin composite facing material and preparation method thereof |
-
2014
- 2014-07-08 CN CN201410320656.1A patent/CN104130664A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1475339A (en) * | 2002-08-15 | 2004-02-18 | 孙建宁 | Flame-retardant antistatic polyvinyl chloride composite pipe and preparation method thereof |
| CN1594470A (en) * | 2003-09-12 | 2005-03-16 | 上海秀珀化工有限公司 | High solid anti-static epoxy floor coating and method for producing same |
| CN101372601A (en) * | 2008-10-17 | 2009-02-25 | 洛阳七维防腐工程材料有限公司 | Oil resistant (solvent), heatproof static conducting anti-corrosive paint and preparation thereof |
| CN102808334A (en) * | 2012-08-17 | 2012-12-05 | 杭州玖合新材料有限公司 | Thermosetting resin composite facing material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| [加]GEORGE WYPYCH: "《填料手册（第二版）》", 28 February 2003, 北京：中国石化出版社 * |
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| CN108978235B (en) * | 2015-07-29 | 2021-06-11 | 湖北东源电力服装有限公司 | Manufacturing method of anti-static high-temperature-resistant fabric |
| CN108978235A (en) * | 2015-07-29 | 2018-12-11 | 李梦燕 | A kind of production method of antistatic high temperature resistant fabric |
| CN105219219A (en) * | 2015-10-19 | 2016-01-06 | 国网浙江省电力公司湖州供电公司 | A kind of novel wear resistant, protection against corrosion, Antistatic Paint and preparation method thereof |
| CN106995649A (en) * | 2016-01-22 | 2017-08-01 | 北京泽马新技术有限公司 | The aqueous environment friendly transparent anticorrosive coating of stainless steel |
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| CN106010126A (en) * | 2016-07-19 | 2016-10-12 | 马晓洁 | Graphene-based antistatic wear-resistant two-component epoxy resin coating |
| US11560448B2 (en) | 2016-12-14 | 2023-01-24 | Bromine Compounds Ltd. | Antimony free flame-retarded epoxy compositions |
| CN106750294A (en) * | 2016-12-31 | 2017-05-31 | 南京新月材料科技有限公司 | A kind of polyimides and preparation method thereof |
| CN108707391A (en) * | 2018-05-31 | 2018-10-26 | 长春智享优创科技咨询有限公司 | Highly effective flame-retardant epoxy resin composite coating and preparation method thereof |
| CN109559855A (en) * | 2018-12-24 | 2019-04-02 | 深圳市斯比特电子有限公司 | A kind of flat wire is vertical around forming jig |
| CN109559855B (en) * | 2018-12-24 | 2023-09-12 | 深圳市斯比特电子有限公司 | Flat wire vertical winding jig |
| CN111534195A (en) * | 2020-06-05 | 2020-08-14 | 厦门双瑞船舶涂料有限公司 | Hydrophobic anticorrosive coating and preparation method thereof |
| CN111646110A (en) * | 2020-06-05 | 2020-09-11 | 广东博顺带业有限公司 | Conductive conveying belt and manufacturing method thereof |
| CN111849229A (en) * | 2020-07-30 | 2020-10-30 | 湖南理工学院 | Fire escape passage fireproof powder coating and preparation process thereof |
| CN114773962A (en) * | 2022-05-30 | 2022-07-22 | 中国铁建重工集团股份有限公司 | Antistatic paint for anchor rod, and preparation method and application thereof |
| CN115785764A (en) * | 2022-12-22 | 2023-03-14 | 上海海隆赛能新材料有限公司 | Quick-drying protective coating for ships and preparation method thereof |
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