CN104120345A - Cold-rolled steel plate and preparation method thereof, and galvanized steel plate and preparation method thereof - Google Patents
Cold-rolled steel plate and preparation method thereof, and galvanized steel plate and preparation method thereof Download PDFInfo
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- CN104120345A CN104120345A CN201410336698.4A CN201410336698A CN104120345A CN 104120345 A CN104120345 A CN 104120345A CN 201410336698 A CN201410336698 A CN 201410336698A CN 104120345 A CN104120345 A CN 104120345A
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Abstract
The invention provides a cold-rolled steel plate and a preparation method thereof, and a galvanized steel plate produced by the cold-rolled steel plate and a preparation method thereof. The preparation method of the cold-rolled steel plate comprises the following steps: a plate blank is hot rolled, reeled, cold rolled and annealed successively, and the preparation method is characterized in that the reeling temperature is 690-720 DEG C; the reduction rate of the cold rolling is 70-85%; the annealing conditions include a temperature of 850-880 DEG C and a time of 40-70s; and the plate blank consists of 0.001-0.004 weight% of C, 0.01-0.04 weight% of Si, 0.08-0.3 weight% of Mn, P not higher than 0.018 weight%, S not higher than 0.02 weight%; 0.01-0.07 weight% of Al, 0.025-0.075 weight% of Ti, 0.005-0.025 weight% of Nb, and the balance of iron and inevitable impurities. The method can provide the galvanized steel plate with the yield strength of 130-170 MPa, excellent punch forming performance and better surface quality.
Description
Technical field
The present invention relates to a kind of cold-rolled steel sheet and preparation method thereof, and the hot-dip galvanizing sheet steel being made by this cold-rolled steel sheet and preparation method thereof.
Background technology
Development along with automobile industry, preparing the deep-drawing of automobile, motorcycle field and be shaped on extremely complicated corrosion resistant component, need certain yield strength and the good steel plate of impact briquetting performance, and the excellent surface quality of the hot-dip galvanizing sheet steel that need to be obtained by this steel plate.
At present, as the method for the special ultra-deep punching cold-rolling steel sheet of preparation, CN101514392A discloses the continuous annealing process of a kind of deep-draw and extra-deep drawing sheet steel.This technique comprises: steel plate through cleaning, enters continuous annealing furnace before annealing, and speed 150～350m/min adopts nitrogen hydrogen mixeding gas ejection surface of steel plate, to steel plate protect, anti-oxidation, make steel billet temperature be heated to 120～180 ℃ simultaneously; Again, to steel plate heating, make its temperature reach 750～780 ℃, and be incubated 40～70s; Then steel plate is cooled to 400～460 ℃, and is incubated 60～300s and carries out overaging processing, be cooled to subsequently normal temperature.Owing to adopting overaging annealing process, the carbide in steel is fully separated out, guaranteed household electrical appliances steel plate and auto sheet punching performance and super deep drawability.But the impact briquetting performance of the steel plate obtaining by this technique also needs further raising.
Summary of the invention
The good not enough defect of impact briquetting performance that the object of the invention is to overcome existing steel plate galvanized, provides a kind of yield strength R
eLwithin the scope of 130-170MPa, impact briquetting performance is good and the good hot-dip galvanizing sheet steel of surface quality and preparation method thereof, and for the preparation of cold-rolled steel sheet of steel plate galvanized of the present invention and preparation method thereof.
To achieve these goals, the invention provides a kind of preparation method of cold-rolled steel sheet, the method comprises: by slab successively through hot rolling, batch, cold rolling and annealing, wherein,
Described coiling temperature is 690-720 ℃;
Described cold rolling draft is 70-85%;
The condition of described annealing comprises: temperature is 850-880 ℃, and the time is 40-70s;
Consisting of of described slab: C:0.001-0.004 % by weight, Si:0.01-0.04 % by weight, Mn:0.08-0.3 % by weight, P :≤0.018 % by weight, S :≤0.02 % by weight, Al:0.01-0.07 % by weight, Ti:0.025-0.075 % by weight; Nb:0.005-0.025 % by weight, surplus is iron and inevitable impurity.
The present invention also provides the cold-rolled steel sheet being made by aforesaid method.
The present invention also provides a kind of preparation method of hot-dip galvanizing sheet steel, and wherein, the method comprises adheres to upper zinc coating by above-mentioned cold-rolled steel sheet through galvanizing.
The hot-dip galvanizing sheet steel that the present invention also provides the preparation method by above-mentioned hot-dip galvanizing sheet steel to make.
By technique scheme, the invention provides a kind of yield strength R
eLfor 130-170MPa, tensile strength R
mfor 280-320MPa, elongation after fracture A
80>=44%, plastic strain ratio r
90>=2.6, work hardening exponent n
90>=0.25 and surface quality be characterized as hot-dip galvanizing sheet steel more than FC level.And the microstructure of finished steel plate is more than ferrite 100% tissue, ferrite grain size are 7.5 grades and ferrite grain size is 19-24 μ m, be a kind of deep-drawing that is especially suitable for use as automobile, motorcycle field and the extremely steel plate of complicated corrosion resistant component (for example fuel tank) that is shaped, there are good market outlook.
Other features and advantages of the present invention partly in detail are described the embodiment subsequently.
Accompanying drawing explanation
Accompanying drawing is to be used to provide a further understanding of the present invention, and forms a part for specification sheets, is used from explanation the present invention, but is not construed as limiting the invention with embodiment one below.In the accompanying drawings:
Fig. 1 is the microstructure picture of the hot-dip galvanizing sheet steel that makes of embodiment 1.
Fig. 2 is the microstructure picture of the hot-dip galvanizing sheet steel that makes of embodiment 2.
Fig. 3 is the microstructure picture of the hot-dip galvanizing sheet steel that makes of embodiment 3.
Fig. 4 is the microstructure picture of the hot-dip galvanizing sheet steel that makes of comparative example 1.
Fig. 5 is the microstructure picture of the hot-dip galvanizing sheet steel that makes of comparative example 2.
Fig. 6 is the microstructure picture of the hot-dip galvanizing sheet steel that makes of comparative example 3.
Embodiment
Below the specific embodiment of the present invention is elaborated.Should be understood that, embodiment described herein only, for description and interpretation the present invention, is not limited to the present invention.
The preparation method of cold-rolled steel sheet provided by the invention comprises: by slab successively through hot rolling, batch, cold rolling and annealing, wherein, described coiling temperature is 690-720 ℃; Described cold rolling draft is 70-85%; The condition of described annealing comprises: temperature is 850-880 ℃, and the time is 40-70s; Consisting of of described slab: C:0.001-0.004 % by weight, Si:0.01-0.04 % by weight, Mn:0.08-0.3 % by weight, P :≤0.018 % by weight, S :≤0.02 % by weight, Al:0.01-0.07 % by weight, Ti:0.025-0.075 % by weight; Nb:0.005-0.025 % by weight, surplus is iron and inevitable impurity.
In the present invention, although just can obtain the cold-rolled steel sheet of better forming property and the hot-dip galvanizing sheet steel that is made good surface quality by this cold-rolled steel sheet when the composition of slab is in above-mentioned scope, but in order to strengthen the performance of obtained cold-rolled steel sheet and hot-dip galvanizing sheet steel, under preferable case, consisting of of described slab: C:0.002-0.004 % by weight, Si:0.01-0.03 % by weight, Mn:0.1-0.25 % by weight, P:0.005-0.015 % by weight, S :≤0.02 % by weight, Al:0.03-0.06 % by weight, Ti:0.04-0.07 % by weight; Nb:0.008-0.025 % by weight, surplus is iron and inevitable impurity.
According to the present invention, described slab can adopt the known method of preparing continuously cast bloom of this area to be prepared, for example can be by obtaining described continuously cast bloom after blast furnace ironmaking, hot metal pretreatment, converter smelting, steel ladle deoxidation, alloying furnace rear refining, LF electrically heated, RH vacuum-treat and sheet billet continuous casting.The condition of its concrete preparation is well known in the art.The thickness of described slab can suitably be selected according to product to be prepared, for example, can be 190-210mm.
According to the present invention, described hot rolling comprises roughing and finish rolling.Preferably, the start rolling temperature of described roughing is 1185-1220 ℃, more preferably 1190-1210 ℃.Preferably, the finishing temperature of described roughing is 1155-1190 ℃, more preferably 1160-1180 ℃.In addition, in order to reach the needed starting temperature of roughing of hot rolling, can before roughing, first continuously cast bloom be heated in heater to required temperature when being heated to continuously cast bloom and carrying out roughing.
Preferably, the thickness of the intermediate slab after described roughing is 33-36mm, more preferably 34-35mm.
Preferably, the start rolling temperature 1140-1175 ℃ of described finish rolling, more preferably 1145-1170 ℃.Preferably, the finishing temperature of described finish rolling is 900-930 ℃, more preferably 905-920 ℃.
Preferably, the thickness of the intermediate slab after described finish rolling is 2-5mm, more preferably 3-5mm.
According to the present invention, under preferable case, the method also comprises: after described finish rolling and before batching, the intermediate slab obtaining after hot rolling is carried out to two steps cooling, first the speed of cooling with 75-90 ℃/s is cooled to 740-760 ℃ by the intermediate slab obtaining after finish rolling, then is cooled to the temperature of batching with the speed of cooling of 15-25 ℃/s; More preferably, after described finish rolling and before batching, first the speed of cooling with 78-85 ℃/s is cooled to 745-755 ℃ by the intermediate slab obtaining after finish rolling, then is cooled to the temperature of batching with the speed of cooling of 15-23 ℃/s.
According to the present invention, under preferable case, the above-mentioned cooling type of cooling of first carrying out is that ultrafast cold water is cooling, the more cooling type of cooling of carrying out is air cooling or laminar flow water cooling.More preferably, the cooling type of cooling of first carrying out is that ultrafast cold water is cooling, the more cooling type of cooling of carrying out is laminar flow water cooling.
According to the present invention, under preferable case, described in the temperature of batching be 700-720 ℃.
According to the present invention, under preferable case, described cold rolling draft is 72-82%, more preferably 73-78%.
According to the present invention, under preferable case, the condition of described annealing comprises: temperature is 860-875 ℃, and the time is 45-65s.
In the present invention, in order to obtain the hot-dip galvanizing sheet steel that surface quality is more superior, preferably before annealing, the cold-rolled steel sheet to gained cleans.Described cleaning can adopt the purging method of the steel plate of this area routine, and for example alkali cleaning and electrolytic cleaning its objective is that greasy dirt in order to remove surface of cold-rolled steel plate, iron scale, iron powder etc. affect the impurity of plate surface quality.Preferably, the condition optimization of described alkali cleaning comprises: the free alkalinity of scavenging solution is 60-90Pt, and temperature is 65-80 ℃, and the time is 40-70s.More preferably, the condition optimization of described alkali cleaning comprises: the free alkalinity of scavenging solution is 72-83Pt, and temperature is 73-78 ℃, and the time is 45-65s.Preferably, the condition optimization of described electrolytic cleaning comprises: the free alkalinity of scavenging solution is 65-85Pt, and temperature is 70-90 ℃, and electric current is 6500-7500A, and the time is 45-75s.More preferably, the condition optimization of described electrolytic cleaning comprises: the free alkalinity of scavenging solution is 80-83Pt, and temperature is 75-87 ℃, and electric current is 6900-7300A, and the time is 50-70s.
The present invention also provides the cold-rolled steel sheet being made by above-mentioned preparation method.
The present invention also provides a kind of preparation method of hot-dip galvanizing sheet steel, and wherein, the method comprises adheres to upper zinc coating by above-mentioned cold-rolled steel sheet through galvanizing.
According to the present invention, described galvanizing can adopt continous way hot dipping method, also can adopt intermittent type hot dipping method, but in order to boost productivity and lumber recovery, the present invention preferably adopts continous way hot dipping method.The condition of the preferred described galvanizing of the present invention comprises: the temperature of zinc pot is 440-480 ℃, more preferably 455-465 ℃.
The present invention there is no special restriction to the amount of the zinc coating of hot-dip galvanizing sheet steel, can adjust according to the concrete requirement to steel plate galvanized, preferably, on every square metre of described hot-dip galvanizing sheet steel, the weight of described zinc coating is 80-120g, and the zinc coating on the described hot-dip galvanizing sheet steel of here every square metre refers to the double-edged zinc coating of steel plate galvanized.
According to the present invention, described preparation method also comprises that the zinc melt on the steel plate to taking out from zinc pot purges, and makes the zinc coating on steel plate distribute more evenly, preferably adopts air knife to purge.The condition optimization that described air knife purges comprises: pressure 12-25KPa is highly 260-350mm, apart from the vertical range of steel plate, is 22-30mm.
According to the present invention, described preparation method also comprises the hot-dip galvanizing sheet steel after purging carried out to straightening, and described straightening can adopt the method for this area routine, and preferably, described straightening unit elongation is 0.1-0.5%.
According to the present invention, the preparation method of described hot-dip galvanizing sheet steel conventionally also comprises the steel plate of gained carried out to passivation, and the present invention preferably adopts chromium-free deactivation.Method to described passivation is not particularly limited, and can be the passivating method of this area routine.Preferably, described passivation, for adopting environmental protection chromium-free passivation liquid, is carried out surface treatment by roll coating model to band steel, and the condition of described passivation comprises: roller coat application roll is 120:(55-70 with the roller speed ratio that dips in liquid roller), be preferably 120:65; Top roll roll-in is 55-120daN; Lower roll roll-in is 65-130daN.Under this condition, can guarantee that uniform film thickness is stable, there is no obvious aberration.
The present invention also provides the hot-dip galvanizing sheet steel being made by aforesaid method.
By method of the present invention, by technique scheme, the invention provides a kind of yield strength R
eLfor 130-170MPa (being preferably 130-160MPa), tensile strength R
mfor 270-320MPa (being preferably 280-310MPa), elongation after fracture A
80>=44% (being preferably 44-49%), plastic strain ratio r
90>=2.5 (being preferably 2.5-3.0), work hardening exponent n
90>=0.25 (being preferably 0.25-0.29) and surface quality are characterized as hot-dip galvanizing sheet steel more than FC level.And the microstructure of finished steel plate is more than ferrite 100% tissue, ferrite grain size are 7.5 grades and ferrite grain size is 19-24 μ μ m, be a kind of deep-drawing that is especially suitable for use as automobile, motorcycle field and the extremely steel plate of complicated corrosion resistant component (for example fuel tank) that is shaped, there are good market outlook.
Below will describe the present invention by embodiment.
In following examples and comparative example, yield strength R
eL, tensile strength R
m, elongation after fracture A
80testing method according to GBT228-2002 metallic substance tensile test at room temperature method, carry out; Plastic strain ratio r
90testing method according to the measuring method of GBT5027-2007 metal sheet and strip plastic strain ratio (r value), carry out; Work hardening exponent n
90testing method according to GBT5028-2008 metal sheet and strip tension strain hardenability value (n value) test method, carry out; Adopt the method for stipulating in GB/T2518-2008 to judge the surface quality feature of hot-dip galvanizing sheet steel.
Embodiment 1
The present embodiment is used for illustrating cold-rolled steel sheet of the present invention and preparation method thereof and hot-dip galvanizing sheet steel and preparation method thereof.
Converter smelting, through LF stove Ca process, RH decarburization and continuous casting obtain slab of the present invention (thickness is 200mm), its moiety is in Table 1.This heating of plate blank to 1208 ℃ is carried out to roughing, the finishing temperature of roughing is 1176 ℃, the thickness of the intermediate slab after roughing is 34.5mm, intermediate slab after roughing is batched by Coil Box, then carry out finish rolling, the start rolling temperature of finish rolling is 1164 ℃, and the finishing temperature of finish rolling is 908 ℃, and the thickness of the intermediate slab after finish rolling is 4mm; The cooling rate of 81 ℃/s of first take is subsequently cooled to after 752 ℃ (type of cooling as ultrafast cold water cooling), then take the cooling rate of 18 ℃/s and be cooled to 709 ℃ and batch (type of cooling is laminar flow water cooling); Then be cooled to after room temperature (25 ℃), on cold-rolling mill, with 75% draft, be cold-rolled to the thickness of 1mm.Then this steel plate is carried out to alkali cleaning and electrolytic cleaning, alkali cleaning condition is: free alkalinity is controlled at 75Pt, and temperature is 78 ℃, and the time is 55s; The condition of electrolytic cleaning is: free alkalinity is controlled at 80Pt, and temperature is 75 ℃, and Faradaic current is controlled at 7000A, and the time is 60s.Then the 62s that anneals at 868 ℃, obtains cold-rolled steel sheet after cooling.Then, the cold-rolled steel sheet that makes to obtain enters the zinc pot of 460 ℃.Steel plate goes out the laggard promoting the circulation of qi cutter of zinc pot and purges, and the condition that air knife purges is: pressure 20KPa is highly 290mm, apart from the vertical range of steel plate, is 28mm.Carry out again straightening and chromium-free deactivation, wherein, straightening unit elongation 0.33%; The condition of passivation comprises: roller coating machine is delivered to application roll by dipping in liquid roller by environment-friendly chromium-free passivating solution, then is rotated and be evenly coated in surface of steel plate by application roll.Roller coat application roll and the roller speed ratio 120:65 that dips in liquid roller, top roll roll-in is 85daN, lower roll roll-in is 100daN.Obtain thus hot-dip galvanizing sheet steel, wherein, with respect to the cold-rolled steel sheet of every square metre, the weight of described zinc coating is 100g (zinc coating on two sides).The strong R of surrender of gained hot-dip galvanizing sheet steel
eL, tensile strength R
m, elongation after fracture A
80, plastic strain ratio r
90, work hardening exponent n
90in Table 2, Fig. 1 is shown in by the photo of its microstructure, the results are shown in Table 2 with the measurement result of surface quality feature.
Embodiment 2
The present embodiment is used for illustrating cold-rolled steel sheet of the present invention and preparation method thereof and hot-dip galvanizing sheet steel and preparation method thereof.
Converter smelting, through LF stove Ca process, RH decarburization and continuous casting obtain slab of the present invention (thickness is 200mm), its moiety is in Table 1.This heating of plate blank to 1203 ℃ is carried out to roughing, the finishing temperature of roughing is 1173 ℃, the thickness of the intermediate slab after roughing is 34.8mm, intermediate slab after roughing is batched by Coil Box, then carry out finish rolling, the start rolling temperature of finish rolling is 1153 ℃, and the finishing temperature of finish rolling is 917 ℃, and the thickness of the intermediate slab after finish rolling is 4.5mm; The cooling rate of 78 ℃/s of first take is subsequently cooled to after 755 ℃ (type of cooling as ultrafast cold water cooling), then take the cooling rate of 16 ℃/s and be cooled to 719 ℃ and batch (type of cooling is laminar flow water cooling); Then be cooled to after room temperature (25 ℃), on cold-rolling mill, with 73.3% draft, be cold-rolled to the thickness of 1.2mm.Then this cold-rolled steel sheet is carried out to alkali cleaning and electrolytic cleaning, alkali cleaning condition is: free alkalinity is controlled at 83Pt, and temperature is 78 ℃, and the time is 45s; The condition of electrolytic cleaning is: free alkalinity is controlled at 80Pt, and temperature is 85 ℃, and Faradaic current is controlled at 7300A, and the time is 70s.Then the 65s that anneals at 874 ℃, obtains cold-rolled steel sheet after cooling.Then, the cold-rolled steel sheet that makes to obtain enters the zinc pot of 455 ℃.Steel plate goes out the laggard promoting the circulation of qi cutter of zinc pot and purges, and the condition that air knife purges is: pressure 23KPa is highly 280mm, apart from the vertical range of steel plate, is 25mm.Carry out again straightening and chromium-free deactivation, wherein, straightening unit elongation 0.35%; The condition of passivation comprises: roller coating machine is delivered to application roll by dipping in liquid roller by environment-friendly chromium-free passivating solution, then is rotated and be evenly coated in surface of steel plate by application roll.Roller coat application roll and the roller speed ratio 120:65 that dips in liquid roller, top roll roll-in is 90daN, lower roll roll-in is 95daN.Obtain thus hot-dip galvanizing sheet steel, wherein, with respect to the cold-rolled steel sheet of every square metre, the weight of described zinc coating is 90g (zinc coating on two sides).The strong R of surrender of gained hot-dip galvanizing sheet steel
eL, tensile strength R
m, elongation after fracture A
80, plastic strain ratio r
90, work hardening exponent n
90in Table 2, Fig. 2 is shown in by the photo of its microstructure, the results are shown in Table 2 with the measurement result of surface quality feature.
Embodiment 3
The present embodiment is used for illustrating cold-rolled steel sheet of the present invention and preparation method thereof and hot-dip galvanizing sheet steel and preparation method thereof.
Converter smelting, through LF stove Ca process, RH decarburization and continuous casting obtain slab of the present invention (thickness is 200mm), its moiety is in Table 1.This heating of plate blank to 1190 ℃ is carried out to roughing, the finishing temperature of roughing is 1161 ℃, the thickness of the intermediate slab after roughing is 34.2mm, intermediate slab after roughing is batched by Coil Box, then carry out finish rolling, the start rolling temperature of finish rolling is 1147 ℃, and the finishing temperature of finish rolling is 910 ℃, and the thickness of the intermediate slab after finish rolling is 3.5mm; The cooling rate of 84 ℃/s of first take is subsequently cooled to after 745 ℃ (type of cooling as ultrafast cold water cooling), then take the cooling rate of 22 ℃/s and be cooled to 702 ℃ and batch (type of cooling is laminar flow water cooling); Then be cooled to after room temperature (25 ℃), on cold-rolling mill, with 77.1% draft, be cold-rolled to the thickness of 0.8mm.Then this cold-rolled steel sheet is carried out to alkali cleaning and electrolytic cleaning, alkali cleaning condition is: free alkalinity is controlled at 72Pt, and temperature is 73 ℃, and the time is 60s; The condition of electrolytic cleaning is: free alkalinity is controlled at 83Pt, and temperature is 87 ℃, and Faradaic current is controlled at 6900A, and the time is 50s.Then the 50s that anneals at 860 ℃, obtains cold-rolled steel sheet after cooling.Then, the cold-rolled steel sheet that makes to obtain enters the zinc pot of 465 ℃.Steel plate goes out the laggard promoting the circulation of qi cutter of zinc pot and purges, and the condition that air knife purges is: pressure 15KPa is highly 320mm, apart from the vertical range of steel plate, is 28mm.Carry out again straightening and chromium-free deactivation, wherein, straightening unit elongation 0.40%; The condition of passivation comprises: roller coating machine is delivered to application roll by dipping in liquid roller by environment-friendly chromium-free passivating solution, then is rotated and be evenly coated in surface of steel plate by application roll.Roller coat application roll and the roller speed ratio 120:65 that dips in liquid roller, top roll roll-in is 75daN, lower roll roll-in is 78daN.Obtain thus hot-dip galvanizing sheet steel, wherein, with respect to the cold-rolled steel sheet of every square metre, the weight of described zinc coating is 115g (zinc coating on two sides).The strong R of surrender of gained hot-dip galvanizing sheet steel
eL, tensile strength R
m, elongation after fracture A
80, plastic strain ratio r
90, work hardening exponent n
90in Table 2, Fig. 3 is shown in by the photo of its microstructure, the results are shown in Table 2 with the measurement result of surface quality feature.
Comparative example 1
According to the method for embodiment 1, carry out, difference is that the moiety of slab is different, is specifically shown in Table 1 the strong R of surrender of gained hot-dip galvanizing sheet steel
eL, tensile strength R
m, elongation after fracture A
80, plastic strain ratio r
90, work hardening exponent n
90in Table 2, Fig. 4 is shown in by the photo of its microstructure, the results are shown in Table 2 with the measurement result of surface quality feature.
Comparative example 2
According to the method for embodiment 1, carry out, difference is that coiling temperature is 600 ℃, the strong R of surrender of gained hot-dip galvanizing sheet steel
eL, tensile strength R
m, elongation after fracture A
80, plastic strain ratio r
90, work hardening exponent n
90in Table 2, Fig. 5 is shown in by the photo of its microstructure, the results are shown in Table 2 with the measurement result of surface quality feature.
Comparative example 3
According to the method for embodiment 1, carry out, difference is, the 40s that anneals at 780 ℃, the strong R of surrender of gained hot-dip galvanizing sheet steel
eL, tensile strength R
m, elongation after fracture A
80, plastic strain ratio r
90, work hardening exponent n
90in Table 2, Fig. 6 is shown in by the photo of its microstructure, the results are shown in Table 2 with the measurement result of surface quality feature.
Table 1
Note: surplus is iron and inevitable impurity
Table 2
Note :-
* 1represent that tension specimen testing process sample is disconnected in advance, cannot measure n value and r value;-
* 2represent to be organized as not perfect recrystallization tissue, cannot measure grain fineness number and grain-size.
By the data in table 1 and table 2, can find out, adopt preparation method of the present invention, can obtain and there is finished product mechanical property and reach yield strength R
eLfor 130-170MPa, tensile strength R
mfor 270-320MPa, elongation after fracture A
80>=44%, plastic strain ratio r
90>=2.5, work hardening exponent n
90>=0.25, surface quality feature FC level ferritic structure, ferrite grain size above, that microstructure is 100% is that 7.5 grades of above and ferrite grain sizes are the hot-dip galvanizing sheet steel of 19-24 μ m.
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characterictic described in above-mentioned embodiment, in reconcilable situation, can combine by any suitable mode, for fear of unnecessary repetition, the present invention is to the explanation no longer separately of various possible array modes.
In addition, between various embodiment of the present invention, also can carry out arbitrary combination, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (12)
1. a preparation method for cold-rolled steel sheet, the method comprises: by slab successively through hot rolling, batch, cold rolling and annealing, it is characterized in that,
Described coiling temperature is 690-720 ℃;
Described cold rolling draft is 70-85%;
The condition of described annealing comprises: temperature is 850-880 ℃, and the time is 40-70s;
Consisting of of described slab: C:0.001-0.004 % by weight, Si:0.01-0.04 % by weight, Mn:0.08-0.3 % by weight, P :≤0.018 % by weight, S :≤0.02 % by weight, Al:0.01-0.07 % by weight, Ti:0.025-0.075 % by weight; Nb:0.005-0.025 % by weight, surplus is iron and inevitable impurity.
2. method according to claim 1, wherein, consisting of of described slab: C:0.002-0.004 % by weight, Si:0.01-0.03 % by weight, Mn:0.1-0.25 % by weight, P:0.005-0.015 % by weight, S :≤0.02 % by weight, Al:0.03-0.06 % by weight, Ti:0.04-0.07 % by weight; Nb:0.008-0.025 % by weight, surplus is iron and inevitable impurity.
3. method according to claim 1, wherein, described hot rolling comprises roughing and finish rolling, and the start rolling temperature of described roughing is 1185-1220 ℃, and the finishing temperature of described roughing is 1155-1190 ℃; The start rolling temperature 1140-1175 ℃ of described finish rolling, the finishing temperature of described finish rolling is 900-930 ℃.
4. method according to claim 3, wherein, the thickness of the intermediate slab after described finish rolling is 2-5mm.
5. method according to claim 3, wherein, the method also comprises: after described finish rolling and before batching, first the speed of cooling with 75-90 ℃/s is cooled to 740-760 ℃ by the intermediate slab obtaining after finish rolling, then is cooled to the temperature of batching with the speed of cooling of 15-25 ℃/s.
6. method according to claim 1 or 5, wherein, described in the temperature of batching be 700-720 ℃.
7. method according to claim 1, wherein, described cold rolling draft is 72-82%.
8. method according to claim 1, wherein, the condition of described annealing comprises: temperature is 860-875 ℃, the time is 45-65s.
9. the cold-rolled steel sheet that the method described in any one makes in claim 1-8.
10. a preparation method for hot-dip galvanizing sheet steel, is characterized in that, the method comprises adheres to upper zinc coating by cold-rolled steel sheet claimed in claim 9 through galvanizing.
11. preparation methods according to claim 10, wherein, on every square metre of described hot-dip galvanizing sheet steel, the weight of described zinc coating is 80-120g.
12. the hot-dip galvanizing sheet steel being made by the preparation method described in claim 10 or 11.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410336698.4A CN104120345B (en) | 2014-07-16 | 2014-07-16 | Cold-rolled steel sheet and preparation method thereof and hot-dip galvanizing sheet steel and preparation method thereof |
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| CN201410336698.4A CN104120345B (en) | 2014-07-16 | 2014-07-16 | Cold-rolled steel sheet and preparation method thereof and hot-dip galvanizing sheet steel and preparation method thereof |
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| CN104120345A true CN104120345A (en) | 2014-10-29 |
| CN104120345B CN104120345B (en) | 2016-03-02 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104651715A (en) * | 2015-02-06 | 2015-05-27 | 攀钢集团攀枝花钢铁研究院有限公司 | Cold-rolled steel plate, preparation method of cold-rolled steel plate, hot-dip galvanized steel plate, and preparation method of hot-dip galvanized steel plate |
| CN105466129A (en) * | 2015-12-19 | 2016-04-06 | 丹阳市宸兴环保设备有限公司 | Steel plate for refrigerator rear panel |
| CN112828041A (en) * | 2020-12-25 | 2021-05-25 | 山东德坊新材料科技有限公司 | Preparation method of high-strength light-weight elevator guide rail |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040168753A1 (en) * | 2000-06-20 | 2004-09-02 | Nkk Corporation | Steel sheet and method for manufacturing the same |
| JP2005154906A (en) * | 2000-02-29 | 2005-06-16 | Jfe Steel Kk | High tensile strength cold-rolled steel sheet having excellent strain age hardening property, and its production method |
| CN101684533A (en) * | 2008-09-27 | 2010-03-31 | 鞍钢股份有限公司 | High-strength cold-rolled sheet having excellent formability and method for producing same |
| CN101956133A (en) * | 2010-10-29 | 2011-01-26 | 攀钢集团钢铁钒钛股份有限公司 | Low-yield strength anti-ageing continuous annealing cold-roll steel sheet and production method thereof |
| CN103045833A (en) * | 2011-10-11 | 2013-04-17 | 攀钢集团攀枝花钢铁研究院有限公司 | Steel plate and galvanizing steel plate, and preparation method thereof |
-
2014
- 2014-07-16 CN CN201410336698.4A patent/CN104120345B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005154906A (en) * | 2000-02-29 | 2005-06-16 | Jfe Steel Kk | High tensile strength cold-rolled steel sheet having excellent strain age hardening property, and its production method |
| US20040168753A1 (en) * | 2000-06-20 | 2004-09-02 | Nkk Corporation | Steel sheet and method for manufacturing the same |
| CN101684533A (en) * | 2008-09-27 | 2010-03-31 | 鞍钢股份有限公司 | High-strength cold-rolled sheet having excellent formability and method for producing same |
| CN101956133A (en) * | 2010-10-29 | 2011-01-26 | 攀钢集团钢铁钒钛股份有限公司 | Low-yield strength anti-ageing continuous annealing cold-roll steel sheet and production method thereof |
| CN103045833A (en) * | 2011-10-11 | 2013-04-17 | 攀钢集团攀枝花钢铁研究院有限公司 | Steel plate and galvanizing steel plate, and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 郑之旺等: "卷取温度和冷轧压下率对高强度IF钢力学性能的影响", 《钢铁钒钛》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104651715A (en) * | 2015-02-06 | 2015-05-27 | 攀钢集团攀枝花钢铁研究院有限公司 | Cold-rolled steel plate, preparation method of cold-rolled steel plate, hot-dip galvanized steel plate, and preparation method of hot-dip galvanized steel plate |
| CN105466129A (en) * | 2015-12-19 | 2016-04-06 | 丹阳市宸兴环保设备有限公司 | Steel plate for refrigerator rear panel |
| CN112828041A (en) * | 2020-12-25 | 2021-05-25 | 山东德坊新材料科技有限公司 | Preparation method of high-strength light-weight elevator guide rail |
| CN112828041B (en) * | 2020-12-25 | 2022-10-04 | 山东德坊新材料科技有限公司 | Preparation method of high-strength light-weight elevator guide rail |
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| CN104120345B (en) | 2016-03-02 |
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