CN104120002A - Cutting liquid with antibacterial and antimould effects and preparation method of cutting liquid - Google Patents
Cutting liquid with antibacterial and antimould effects and preparation method of cutting liquid Download PDFInfo
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- CN104120002A CN104120002A CN201410290960.6A CN201410290960A CN104120002A CN 104120002 A CN104120002 A CN 104120002A CN 201410290960 A CN201410290960 A CN 201410290960A CN 104120002 A CN104120002 A CN 104120002A
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- cutting liquid
- sodium
- antibacterial
- auxiliary agent
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- 230000000694 effects Effects 0.000 title claims abstract description 16
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000007788 liquid Substances 0.000 title abstract 7
- 230000001046 anti-mould Effects 0.000 title abstract 3
- 239000002546 antimould Substances 0.000 title abstract 3
- 229910021538 borax Inorganic materials 0.000 claims abstract description 10
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 10
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 10
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 239000003208 petroleum Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 4
- OPGYRRGJRBEUFK-UHFFFAOYSA-L disodium;diacetate Chemical compound [Na+].[Na+].CC([O-])=O.CC([O-])=O OPGYRRGJRBEUFK-UHFFFAOYSA-L 0.000 claims abstract description 4
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 4
- 239000001632 sodium acetate Substances 0.000 claims abstract description 4
- 235000017454 sodium diacetate Nutrition 0.000 claims abstract description 4
- 239000002173 cutting fluid Substances 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 15
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- -1 Lauryl Alcohol ester Chemical class 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 6
- 239000004200 microcrystalline wax Substances 0.000 claims description 6
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- 229960004418 trolamine Drugs 0.000 claims description 3
- 238000001816 cooling Methods 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 150000002739 metals Chemical class 0.000 abstract description 2
- 239000005725 8-Hydroxyquinoline Substances 0.000 abstract 2
- 239000010647 garlic oil Substances 0.000 abstract 2
- 229960003540 oxyquinoline Drugs 0.000 abstract 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 abstract 2
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 abstract 1
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
- 229940043237 diethanolamine Drugs 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 229940068041 phytic acid Drugs 0.000 abstract 1
- 229960004889 salicylic acid Drugs 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
Landscapes
- Lubricants (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses cutting liquid with antibacterial and antimould effects. The cutting liquid is characterized by being prepared from the following raw materials in parts by weight: 2-3 parts of sodium ethylene diamine tetracetate, 2.5-3.5 parts of triethanolamine, 1-2 parts of sodium diacetate, 3-4 parts of garlic oil, 1-1.5 parts of 8-hydroxyquinoline, 3-4 parts of diethanol amine, 2-3 parts of salicylic acid, 4-5 parts of fatty alcohol-polyoxyethylene ether, 3-5 parts of inositol hexaphosphate, 3-5 parts of petroleum sodium sulfonate, 2-4 parts of borax, 5-7 parts of an assistant and 200 parts of de-ionized water. According to the cutting liquid, due to addition of 8-hydroxyquinoline and garlic oil which have antibacterial and antimould effects, the shortcomings of easy deterioration and difficulty in storage of the cutting liquid are overcome; due to addition of the assistant, the wear resistance, the dispersity, the lubricity and the film-forming property are improved; the cutting liquid contains various surfactants, and is good in permeability and cleanability, high in cooling speed, good in lubricity and rust resistance and suitable for processing various metals.
Description
Technical field
The present invention relates to cutting fluid field, particularly a kind of cutting fluid with antibacterial and mouldproof effect and preparation method thereof.
Background technology
Cutting fluid is that a kind of metal that is used in is cut, cuts, grinds in the course of processing, be used for the industrial type fluid of Cooling and Lubricator cutter and workpiece, cutting fluid is formed through the compound compatibility of science by multiple super strong functional auxiliary agent, possess good cooling performance, lubricity, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable feature simultaneously, but the traditional easily difficult dilution in smelly, winter in summer of soap base emulsion, rust-proof effect are poor, the present invention is directed to this shortcoming of cutting fluid, designed a kind of cutting fluid with good antibiosis and deodorization effects.
Summary of the invention
The object of this invention is to provide a kind of cutting fluid with antibacterial and mouldproof effect and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A cutting fluid with antibacterial and mouldproof effect, is made by the raw material of following weight part: sodium ethylene diamine tetracetate 2-3, trolamine 2.5-3.5, sodium Diacetate 1-2, Oleum Bulbus Allii 3-4, oxine 1-1.5, diethanolamine 3-4, Whitfield's ointment 2-3, fatty alcohol-polyoxyethylene ether 4-5, nucite six phosphoric acid fat 3-5, petroleum sodium sulfonate 3-5, borax 2-4, auxiliary agent 5-7, deionized water 200;
Described auxiliary agent is made by the raw material of following weight part: nano aluminum nitride 3-4, graphite 2-3, Sodium dodecylbenzene sulfonate 1-2, borax 2-4, Lauryl Alcohol ester 2-3, xitix 1-2, Microcrystalline Wax 2-3, sodium stearate 3.5-4, water 50-54; First preparation method adds nano aluminum nitride, graphite, Microcrystalline Wax, sodium stearate in the water of half amount, grind 1-2 hour, then slowly add all the other remaining components, be slowly heated to 70 ℃-80 ℃, stirring reaction 30-50 minute under 300-500 rev/min of condition, is cooled to room temperature and get final product.
A kind of cutting fluid with antibacterial and mouldproof effect of the present invention, by following concrete steps, made:
(1) petroleum sodium sulfonate, borax, Oleum Bulbus Allii, oxine are mixed, add appropriate deionized water, be heated to 30 ℃-35 ℃, stirring reaction 30-40 minute, obtains mixing A material;
(2) all the other remaining components except auxiliary agent are joined in reactor, be uniformly mixed, be slowly heated to 55 ℃-65 ℃, insulation 1-1.5 hour, obtains mixing B material;
(3) the mixing B material of insulation is slowly joined while stirring and mixed in A material, after fully stirring, add auxiliary agent, 800-900 rev/min of lower stirring reaction 40-60 minute, is cooled to room temperature and get final product.
Excellent effect of the present invention is: the present invention adds oxine, the Oleum Bulbus Allii with antibacterial and mouldproof effect, has improved the shortcoming that cutting fluid easily fouls, is difficult for preservation; Add auxiliary agent, strengthened wear-resistant, disperse, lubricated, film-forming properties; Cutting fluid of the present invention contains kinds of surface promoting agent, has good perviousness, cleaning, and speed of cooling is fast, oilness and good antirust property, is applicable to various metals processing.
Embodiment
Below by specific examples, the present invention is described in detail.
A cutting fluid with antibacterial and mouldproof effect, by following weight part (kilogram) raw material make: sodium ethylene diamine tetracetate 2, trolamine 2.5, sodium Diacetate 1, Oleum Bulbus Allii 3, oxine 1, diethanolamine 3, Whitfield's ointment 2, fatty alcohol-polyoxyethylene ether 4, nucite six phosphoric acid fat 3, petroleum sodium sulfonate 3, borax 2, auxiliary agent 5, deionized water 200;
Described auxiliary agent by following weight part (kilogram) raw material make: nano aluminum nitride 3, graphite 2, Sodium dodecylbenzene sulfonate 1, borax 2, Lauryl Alcohol ester 2, xitix 1, Microcrystalline Wax 2, sodium stearate 3.5, water 50; First preparation method adds nano aluminum nitride, graphite, Microcrystalline Wax, sodium stearate in the water of half amount, grind 1-2 hour, then slowly add all the other remaining components, be slowly heated to 70 ℃-80 ℃, stirring reaction 30-50 minute under 300-500 rev/min of condition, is cooled to room temperature and get final product.
A kind of cutting fluid with antibacterial and mouldproof effect of the present invention, by following concrete steps, made:
(1) petroleum sodium sulfonate, borax, Oleum Bulbus Allii, oxine are mixed, add appropriate deionized water, be heated to 30 ℃-35 ℃, stirring reaction 30-40 minute, obtains mixing A material;
(2) all the other remaining components except auxiliary agent are joined in reactor, be uniformly mixed, be slowly heated to 55 ℃-65 ℃, insulation 1-1.5 hour, obtains mixing B material;
(3) the mixing B material of insulation is slowly joined while stirring and mixed in A material, after fully stirring, add auxiliary agent, 800-900 rev/min of lower stirring reaction 40-60 minute, is cooled to room temperature and get final product.
After tested, cutting fluid of the present invention can reach following technical requirements:
Claims (2)
1. a cutting fluid with antibacterial and mouldproof effect, it is characterized in that, by the raw material of following weight part, made: sodium ethylene diamine tetracetate 2-3, trolamine 2.5-3.5, sodium Diacetate 1-2, Oleum Bulbus Allii 3-4, oxine 1-1.5, diethanolamine 3-4, Whitfield's ointment 2-3, fatty alcohol-polyoxyethylene ether 4-5, nucite six phosphoric acid fat 3-5, petroleum sodium sulfonate 3-5, borax 2-4, auxiliary agent 5-7, deionized water 200;
Described auxiliary agent is made by the raw material of following weight part: nano aluminum nitride 3-4, graphite 2-3, Sodium dodecylbenzene sulfonate 1-2, borax 2-4, Lauryl Alcohol ester 2-3, xitix 1-2, Microcrystalline Wax 2-3, sodium stearate 3.5-4, water 50-54; First preparation method adds nano aluminum nitride, graphite, Microcrystalline Wax, sodium stearate in the water of half amount, grind 1-2 hour, then slowly add all the other remaining components, be slowly heated to 70 ℃-80 ℃, stirring reaction 30-50 minute under 300-500 rev/min of condition, is cooled to room temperature and get final product.
2. a kind of cutting fluid with antibacterial and mouldproof effect according to claim 1, is characterized in that, by following concrete steps, is made:
(1) petroleum sodium sulfonate, borax, Oleum Bulbus Allii, oxine are mixed, add appropriate deionized water, be heated to 30 ℃-35 ℃, stirring reaction 30-40 minute, obtains mixing A material;
(2) all the other remaining components except auxiliary agent are joined in reactor, be uniformly mixed, be slowly heated to 55 ℃-65 ℃, insulation 1-1.5 hour, obtains mixing B material;
(3) the mixing B material of insulation is slowly joined while stirring and mixed in A material, after fully stirring, add auxiliary agent, 800-900 rev/min of lower stirring reaction 40-60 minute, is cooled to room temperature and get final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410290960.6A CN104120002B (en) | 2014-06-25 | 2014-06-25 | A kind of cutting fluid with antibacterial and mouldproof effect and preparation method thereof |
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CN201410290960.6A CN104120002B (en) | 2014-06-25 | 2014-06-25 | A kind of cutting fluid with antibacterial and mouldproof effect and preparation method thereof |
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CN104120002A true CN104120002A (en) | 2014-10-29 |
CN104120002B CN104120002B (en) | 2016-06-29 |
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CN201410290960.6A Active CN104120002B (en) | 2014-06-25 | 2014-06-25 | A kind of cutting fluid with antibacterial and mouldproof effect and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106665684A (en) * | 2016-11-22 | 2017-05-17 | 唐林元 | Preparation method of aqueous cutting fluid environment-friendly antibacterial agent |
CN106854484A (en) * | 2016-11-28 | 2017-06-16 | 四川正梁机械有限公司 | A kind of automobile workpiece punching press multifunctional additive for lubricating oil |
CN107794106A (en) * | 2017-11-06 | 2018-03-13 | 安徽燎原电器设备制造有限公司 | A kind of good antibacterial transformer oil of heat endurance |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102766510A (en) * | 2012-08-16 | 2012-11-07 | 温州宝罗润滑材料有限公司 | Super-high extreme pressure type micro-emulsification cutting fluid and preparation method thereof |
CN102766520A (en) * | 2012-08-16 | 2012-11-07 | 温州宝罗润滑材料有限公司 | Long carbon chain dicarboxylic acid total synthesis cutting fluid and preparation method thereof |
CN103031196A (en) * | 2012-09-21 | 2013-04-10 | 上海韬鸿化工科技有限公司 | Emulsion type metal cutting fluid |
-
2014
- 2014-06-25 CN CN201410290960.6A patent/CN104120002B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102766510A (en) * | 2012-08-16 | 2012-11-07 | 温州宝罗润滑材料有限公司 | Super-high extreme pressure type micro-emulsification cutting fluid and preparation method thereof |
CN102766520A (en) * | 2012-08-16 | 2012-11-07 | 温州宝罗润滑材料有限公司 | Long carbon chain dicarboxylic acid total synthesis cutting fluid and preparation method thereof |
CN103031196A (en) * | 2012-09-21 | 2013-04-10 | 上海韬鸿化工科技有限公司 | Emulsion type metal cutting fluid |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106665684A (en) * | 2016-11-22 | 2017-05-17 | 唐林元 | Preparation method of aqueous cutting fluid environment-friendly antibacterial agent |
CN106854484A (en) * | 2016-11-28 | 2017-06-16 | 四川正梁机械有限公司 | A kind of automobile workpiece punching press multifunctional additive for lubricating oil |
CN107794106A (en) * | 2017-11-06 | 2018-03-13 | 安徽燎原电器设备制造有限公司 | A kind of good antibacterial transformer oil of heat endurance |
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Publication number | Publication date |
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CN104120002B (en) | 2016-06-29 |
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Denomination of invention: A cutting fluid with antibacterial and anti mold effects and its preparation method Granted publication date: 20160629 Pledgee: Lai An county Jinan financing Company limited by guarantee Pledgor: ANHUI HAODING METAL PRODUCT LIMED CO. Registration number: Y2024980033788 |