CN104098893A - Electricity-conducting and antibacterial polyamide 6/ polypropylene composite material and preparation method thereof - Google Patents
Electricity-conducting and antibacterial polyamide 6/ polypropylene composite material and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Abstract
The invention discloses an electricity-conducting and antibacterial polyamide 6/ polypropylene composite material and a preparation method thereof. The composite material is formed by mixing and extruding the following components: 100 parts of polyamide 6, 50-100 parts of polypropylene, 5-30 parts of conductive filler, 0.6-2.8 part(s) of an antibacterial agent, 10-30 parts of a compatilizer, 0.4-1.2 part(s) of an antioxygen, and 0.3-0.6 part of a dispersing agent, wherein the conductive filler is modified graphene micro powder subjected to the surface treatment through an acid and a coupling agent-absolute ethyl alcohol solution in sequence. According to the invention, the modified graphene micro powder is compounded with an inorganic antibacterial agent for use, and the electricity-conducting and antibacterial performance of the polyamide 6/ polypropylene composite material is improved, so that the application range of the composite material is greatly expanded.
Description
Technical field
The present invention relates to modifying plastics field, relate in particular to a kind of conduction, antibacterial polyamide 6/polypropylene composite material and preparation method thereof.
background technology:
Polypropylene (be called for short PP) because it is cheap, excellent performance, source extensively, easily processing, be widely used in the every field such as automobile, household electrical appliances, packing, medical treatment, become modern Application one of plastics the most widely.Polypropylene has light weight, nontoxic, odorless, and chemical stability is good, and electrical property is excellent, and (generally, its surface resistivity is 10
16~ 10
18Ω), and be insoluble at normal temperatures common solvent, the advantage such as water-absorbent is little.
It is good that polyamide 6 (be called for short PA6) has thermomechanical property excellence, good toughness, chemical-resistant, and (generally, its surface resistivity is 10 to also have good wear resistance, self lubricity and excellent electrical property
13~ 10
16the advantage such as Ω); So it easily absorbs water, and processing characteristics is poor.
In recent years, polypropylene and polyamide 6 being carried out to blend, to prepare the research of alloy of common occurrence.But there is following defect:
One, because polypropylene and polyamide 6 all have good electrical insulating property, easily producing accumulation of static electricity with external world's friction or while peeling off, finally cause dust and dirt to be adsorbed in product surface like this, may presence of fire or blast when serious.For fear of this electrostatic phenomenon, must carry out it antistatic modified, to adapt to some specific Application Areas.Moreover for some specific field, may need electrically conductive polyamide material, and as: national defence industry etc.For macromolecular material, generally prevent and the method for eliminating static mainly contains: (1) adds organic molecule type static inhibitor; (2) add organic macromolecule type static inhibitor; (3) prepare alloy with conducting polymer composite blend; (4) add inorganic conductive material.Also have, while generally preparing conducting polymer composite, can in plastic base, add graphite, metal powder, steel fiber etc.
Two, because polypropylene and polyamide 6 neither have antibacterial effect, therefore in daily necessities, medical treatment etc., some has the technical field of particular requirement to have certain restriction to the antibacterial effect of goods for they.
In addition, Graphene is that world is the thinnest is at present the hardest nano material also, and it is almost completely transparent, and thermal conductivity is up to 5300W/mK, and higher than carbon nanotube and diamond, under normal temperature, its electronic mobility surpasses 15000cm
2/ Vs, ratio nano carbon pipe or silicon crystal are all high, and volume specific resistance only approximately 10
-6Ω cm, lower than copper or silver, be the current material of resistivity minimum in the world.Therefore because its resistivity is extremely low, the speed of electronic migration is exceedingly fast, and is expected to can be used to develop thinner, conduction speed electronic component of new generation or transistor faster.Because Graphene is in fact a kind of transparent, good conductor, be also applicable to for manufacturing transparent touch screen, tabula rasa or even solar cell.Apply it in plastics, mainly as wear-resisting, the conduction, the thermally conductive material that improve plastics, because it is easily reunited, effect is not too remarkable in recent years.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, a kind of conduction, antimicrobial polyamide 6/polypropylene composite material and preparation method thereof are provided.Polyamide 6/the polypropylene composite material of preparation has excellent conductivity and antibacterial effect.
Conduction, antibacterial polyamide 6/polypropylene composite material, consist of by weight following component:
100 parts of polyamide 6s,
50 ~ 100 parts of polypropylene,
5 ~ 30 parts of conductive filler materials,
0.6 ~ 2.8 part of antiseptic-germicide,
10 ~ 30 parts of compatilizers,
0.4 ~ 1.2 part, oxidation inhibitor,
0.3 ~ 0.6 part of dispersion agent,
Described conductive filler material is for carrying out successively surface-treated modified graphene micro mist through acid and coupling agent-ethanol solution.
Further, described polypropylene is homo-polypropylene or Co-polypropylene.
Described antiseptic-germicide is inorganic antiseptic.
Described inorganic antiseptic is silver, zine series inorganic germicide.
Described compatilizer is polypropylene grafted maleic anhydride (PP-G) or ethylene-methyl acrylate-glyceryl methacrylate terpolymer (E-MA-GMA).
Described oxidation inhibitor is selected four [β-(3; 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester (antioxidant 1010), three [2; 4-di-tert-butyl-phenyl] phosphorous acid ester (irgasfos 168) and N; N'-pair-(3-(3,5-di-tert-butyl-hydroxy phenyl) propionyl) hexanediamine (oxidation inhibitor 1098) mixture.
Described dispersion agent is silicone based dispersion agent.
Another object of the present invention is to provide the preparation method of above-mentioned conduction, antibacterial polyamide 6/polypropylene composite material, comprises the following steps:
(1) prepare modified graphene micro mist:
Acid treatment: by dry ecosystem Graphene micro mist with acid solution in mass ratio for 1:6.5 mixes, under stirring action, reflux is taken out handled thing after 28 hours and is washed with distilled water to neutrality;
Modification: after above-mentioned handled thing is dried with coupling agent-ethanol solution in mass ratio for 1:6 mixes, then it is carried out to ball milling and crosses 800 mesh sieves, be then dried to obtain Graphene micro mist;
Described coupling agent-ethanol solution be by coupling agent with dehydrated alcohol in mass ratio for 1:7.5 mixes, and dripping hydrochloric acid soln, to adjust pH value be 3 ~ 6; Described coupling agent is the mixture of aluminate coupling agent, titanate coupling agent;
(2) prepare polyamide 6/polypropylene composite material
Take 100 parts of polyamide 6s, 50 ~ 100 parts of polypropylene, 5 ~ 30 parts of modified graphene micro mists, 0.6 ~ 2.8 part of antiseptic-germicide, 10 ~ 30 parts of compatilizers, 0.4 ~ 1.2 part of oxidation inhibitor, 0.3 ~ 0.6 part of dispersion agent and in high-speed mixer, mix 5 minutes, mixing machine rotating speed is 220 revs/min; Then the mixture mixing is added in twin screw extruder melt extrude, cooling
Pelletizing obtains polyamide 6/polypropylene composite material;
Wherein the temperature of twin screw extruder is followed successively by 200 ℃, 220 ℃, 220 ℃, 230 ℃, 230 ℃, 230 ℃, 230 ℃, 235 ℃ from spout to head.
Further, described in described step (1), dry ecosystem Graphene micro mist is that ecosystem Graphene micro mist is placed in to 140 ℃ of baking ovens, dry 8 hours gained; Described acid solution is that the vitriol oil and concentrated nitric acid are by volume for 3:5 mixes; The temperature of reflux is 160 ℃.
Coupling agent is that aluminate coupling agent isopropoxy distearyl acid acyloxy Aluminate (DL-411-B) and titanate coupling agent sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester (DN-201) are in mass ratio for 1:1 mixes in described step (1); Described being dried as processing 8 hours in 140 ℃ of baking ovens.
With respect to prior art beneficial effect of the present invention, have:
1, the present invention utilizes acid solution and coupling agent-ethanol solution to carry out after surface treatment Graphene, is conducive to the dispersion of Graphene in plastic substrate, thereby improves thermal conductivity and the electroconductibility of matrix material.
2, the present invention, by modified graphene micro mist and the composite use of inorganic antiseptic, makes matrix material not only possess conductivity but also possess antibacterial effect, has greatly widened polyacrylic range of application.
3, polyamide 6/polypropylene composite material that prepared by the present invention possesses conduction and antibacterial effect simultaneously, and preparation process and technique are simple, easily industrialization.
embodiment:
below in conjunction with some embodiment and comparative example, the invention will be further described.
The main raw material(s) of using in embodiment and comparative example has:
Graphene micro mist A model: XF001W(is without surface treatment) Nanjing Xian Feng Nono-material Science & Technology Ltd.;
Graphene micro mist B model: XF001H(is without surface treatment) Nanjing Xian Feng Nono-material Science & Technology Ltd.;
Polyamide 6 model: PA6 M2500 newly understands in Guangzhou U.S.A and reaches;
Co-polypropylene model: BX3900 Korea S SK;
Homo-polypropylene model: S2040 Shanghai match section;
Inorganic antiseptic model: AGZ330 Japan S.R business Co., Ltd.;
Compatilizer PP-G model: 1001 Italian Pulis are bright;
Compatilizer E-MA-GMA model: AX8900 France A Kema;
Antioxidant 1010 model: Irganox1010 Switzerland Ciba;
Oxidation inhibitor 1098 models: Irganox1098 Switzerland Ciba;
Irgasfos 168 model: Irganox168 Switzerland Ciba;
Dispersion agent model: E525 Germany Degussa;
Coupling agent A model: DL-411-B Nanjing Pin Ning coupling agent company limited;
Coupling agent B model: DN-201 Nanjing Dao Ning Chemical Co., Ltd..
In all embodiment and comparative example, if no special instructions, described umber is weight part below, surface resistivity test execution GB/T 1410, and test condition is tested for place 24 hours under 23 ℃, humidity 50% condition after; Anti-microbial property test execution QB/T 2591, test condition is tested for placing to cultivate after 24 hours under 23 ℃, humidity 50% condition.
embodiment 1
(1) prepare modified graphene micro mist:
Ecosystem Graphene A is placed in to 140 ℃ of baking ovens dry 8 hours, again by dry Graphene micro mist with the acid solution being mixed for 3:5 by volume by the vitriol oil and concentrated nitric acid in mass ratio for 1:6.5 mixes, then reflux under stirring action, Heating temperature is 160 ℃, treatment time is 28 hours, after taking-up handled thing, with distilled water repetitive scrubbing, to neutrality, puts into 140 ℃ of baking ovens dry 16 hours.
By above-mentioned dried Graphene, according to mass ratio, be that 1:6 mixes with coupling agent-ethanol solution, it is that the ball mill of 450 revs/min carries out ball milling 3.5 hours that the slurries of gained are put into rotating speed, be finally placed in dry 16 hours of 140 ℃ of baking ovens of vacuum modified graphene micro mist;
Described coupling agent-ethanol solution be by coupling agent with dehydrated alcohol in mass ratio for 1:7.5 mixes, and dripping hydrochloric acid soln, to adjust pH value be 3, coupling agent be coupling agent A with coupling agent B in mass ratio for 1:1 mixes.
(2) prepare the preparation of polyamide 6/polypropylene composite material;
Take modified graphene micro mist, 0.6 part of antiseptic-germicide AGZ330,1001,0.1 part of antioxidant 1010 of 10 parts of compatilizers, 1098,0.2 part of irgasfos 168 of 0.1 part of oxidation inhibitor, 0.3 part of dispersion agent E525 prepared by 100 parts of PA6 M2500,50 parts of polypropylene BX3900,5 parts of step 1 and in high-speed mixer, mix 5 minutes, mixing machine rotating speed is 220 revs/min; Then the mixture mixing is added in twin screw extruder melt extrude, cooling, pelletizing obtains polyamide 6/polypropylene composite material; Wherein the temperature of forcing machine is followed successively by 200 ℃, 220 ℃, 220 ℃, 230 ℃, 230 ℃, 230 ℃, 230 ℃, 235 ℃ from spout to head.Performance is as table-1.
comparative example 1
Take 100 parts of PA6 M2500,50 parts of polypropylene BX3900,5 parts of Graphene A, 0.6 part of antiseptic-germicide AGZ330,1001,0.1 part of antioxidant 1010 of 10 parts of compatilizers, 1098,0.2 part of irgasfos 168 of 0.1 part of oxidation inhibitor, 0.3 part of dispersion agent E525 mix 5 minutes in high-speed mixer, mixing machine rotating speed is 220 revs/min; Then the mixture mixing is added in twin screw extruder melt extrude, cooling, pelletizing, dress bag, wherein the temperature of forcing machine is followed successively by 200 ℃, 220 ℃, 220 ℃, 230 ℃, 230 ℃, 230 ℃, 230 ℃, 235 ℃ from spout to head.Performance is as table-1.
comparative example 2
The modified graphene micro mist, 1001,0.1 part of antioxidant 1010 of 10 parts of compatilizers, 1098,0.2 part of irgasfos 168 of 0.1 part of oxidation inhibitor, the 0.3 part of dispersion agent E525 that take 100 parts of PA6 M2500,50 parts of polypropylene BX3900,5 parts of embodiment 1 preparations mix 5 minutes in high-speed mixer, and mixing machine rotating speed is 220 revs/min; Then the mixture mixing is added in twin screw extruder melt extrude, cooling, pelletizing, dress bag, wherein the temperature of forcing machine is followed successively by 200 ℃, 220 ℃, 220 ℃, 230 ℃, 230 ℃, 230 ℃, 230 ℃, 235 ℃ from spout to head.Performance is as table-1.
From above embodiment 1 and comparative example 1 ~ 2 relatively can obviously find out, matrix material of the present invention is by modified graphene micro mist and the composite use of inorganic antiseptic, makes matrix material have good conductivity and antibacterial effect.The modified graphene micro mist of processing with the present invention can significantly reduce material surface resistivity, the 6.7*10 of the resistivity of its material surface from comparative example 1 than directly adding Graphene
13Ω drops to the 3.9*10 in embodiment 1
10Ω, so the modified graphene micro mist that the present invention processes is more remarkable to the reduction of composite material surface resistivity, improves its conductivity; In the present invention, increase inorganic antiseptic in addition, improved the antibacterial effect of matrix material.
embodiment 2
(1) prepare modified graphene micro mist:
Ecosystem Graphene B is placed in to 140 ℃ of baking ovens dry 8 hours, again by dry Graphene micro mist with the acid solution being mixed for 3:5 by volume by the vitriol oil and concentrated nitric acid in mass ratio for 1:6.5 mixes, then reflux under stirring action, Heating temperature is 160 ℃, treatment time is 28 hours, after taking-up handled thing, with distilled water repetitive scrubbing, to neutrality, puts into 140 ℃ of baking ovens dry 16 hours.
By above-mentioned dried Graphene, according to mass ratio, be that 1:6 mixes with coupling agent-ethanol solution, it is that the ball mill of 450 revs/min carries out ball milling 3.5 hours that the slurries of gained are put into rotating speed, be finally placed in dry 16 hours of 140 ℃ of baking ovens of vacuum modified graphene micro mist;
Described coupling agent-ethanol solution be by coupling agent with dehydrated alcohol in mass ratio for 1:7.5 mixes, and dripping hydrochloric acid soln, to adjust pH value be 6, coupling agent be coupling agent A with coupling agent B in mass ratio for 1:1 mixes.
(2) prepare polyamide 6/polypropylene composite material;
Take modified graphene micro mist, 2.8 parts of antiseptic-germicide AGZ330,1001,0.3 part of antioxidant 1010 of 30 parts of compatilizers, 1098,0.6 part of irgasfos 168 of 0.3 part of oxidation inhibitor, 0.6 part of dispersion agent E525 prepared by 100 parts of PA6 M2500,100 parts of polypropylene S2040,30 parts of step 1 and in high-speed mixer, mix 5 minutes, mixing machine rotating speed is 220 revs/min; Then the mixture mixing is added in twin screw extruder melt extrude, cooling, pelletizing obtains polyamide 6/polypropylene composite material; Wherein the temperature of forcing machine is followed successively by 200 ℃, 220 ℃, 220 ℃, 230 ℃, 230 ℃, 230 ℃, 230 ℃, 235 ℃ from spout to head.Performance is as table-2.
embodiment 3
(1) prepare modified graphene micro mist:
Ecosystem Graphene B is placed in to 140 ℃ of baking ovens dry 8 hours, again by dry Graphene micro mist with the acid solution being mixed for 3:5 by volume by the vitriol oil and concentrated nitric acid in mass ratio for 1:6.5 mixes, then reflux under stirring action, Heating temperature is 160 ℃, treatment time is 28 hours, after taking-up handled thing, with distilled water repetitive scrubbing, to neutrality, puts into 140 ℃ of baking ovens dry 16 hours.
By above-mentioned dried Graphene, according to mass ratio, be that 1:6 mixes with coupling agent-ethanol solution, it is that the ball mill of 450 revs/min carries out ball milling 3.5 hours that the slurries of gained are put into rotating speed, be finally placed in dry 16 hours of 140 ℃ of baking ovens of vacuum modified graphene micro mist;
Described coupling agent-ethanol solution be by coupling agent with dehydrated alcohol in mass ratio for 1:7.5 mixes, and dripping hydrochloric acid soln, to adjust pH value be 4, coupling agent be coupling agent A with coupling agent B in mass ratio for 1:1 mixes.
(2) prepare polyamide 6/polypropylene composite material;
Take modified graphene micro mist, 1.0 parts of antiseptic-germicide AGZ330,18 parts of compatilizer AX8900,0.2 part of antioxidant 1010,1098,0.6 part of irgasfos 168 of 0.2 part of oxidation inhibitor, 0.45 part of dispersion agent E525 prepared by 100 parts of PA6 M2500,60 parts of polypropylene BX3900,10 parts of step 1 and in high-speed mixer, mix 5 minutes, mixing machine rotating speed is 220 revs/min; Then the mixture mixing is added in twin screw extruder melt extrude, cooling, pelletizing obtains polyamide 6/polypropylene composite material; Wherein the temperature of forcing machine is followed successively by 200 ℃, 220 ℃, 220 ℃, 230 ℃, 230 ℃, 230 ℃, 230 ℃, 235 ℃ from spout to head.Performance is as table-2.
embodiment 4
(1) prepare modified graphene micro mist:
Ecosystem Graphene A is placed in to 140 ℃ of baking ovens dry 8 hours, again by dry Graphene micro mist with the acid solution being mixed for 3:5 by volume by the vitriol oil and concentrated nitric acid in mass ratio for 1:6.5 mixes, then reflux under stirring action, Heating temperature is 160 ℃, treatment time is 28 hours, after taking-up handled thing, with distilled water repetitive scrubbing, to neutrality, puts into 140 ℃ of baking ovens dry 16 hours.
By above-mentioned dried Graphene, according to mass ratio, be that 1:6 mixes with coupling agent-ethanol solution, it is that the ball mill of 450 revs/min carries out ball milling 3.5 hours that the slurries of gained are put into rotating speed, be finally placed in dry 16 hours of 140 ℃ of baking ovens of vacuum modified graphene micro mist;
Described coupling agent-ethanol solution be by coupling agent with dehydrated alcohol in mass ratio for 1:7.5 mixes, and dripping hydrochloric acid soln, to adjust pH value be 5.5, coupling agent be coupling agent A with coupling agent B in mass ratio for 1:1 mixes.
(2) prepare polyamide 6/polypropylene composite material;
Take modified graphene micro mist, 1.6 parts of antiseptic-germicide AGZ330,1001,0.2 part of antioxidant 1010 of 23 parts of compatilizers, 1098,0.6 part of irgasfos 168 of 0.2 part of oxidation inhibitor, 0.5 part of dispersion agent E525 prepared by 100 parts of PA6 M2500,70 parts of polypropylene S2040,18 parts of step 1 and in high-speed mixer, mix 5 minutes, mixing machine rotating speed is 220 revs/min; Then the mixture mixing is added in twin screw extruder melt extrude, cooling, pelletizing obtains polyamide 6/polypropylene composite material; Wherein the temperature of forcing machine is followed successively by 200 ℃, 220 ℃, 220 ℃, 230 ℃, 230 ℃, 230 ℃, 230 ℃, 235 ℃ from spout to head.Performance is as table-2.
embodiment 5
(1) prepare modified graphene micro mist:
Ecosystem Graphene B is placed in to 140 ℃ of baking ovens dry 8 hours, again by dry Graphene micro mist with the acid solution being mixed for 3:5 by volume by the vitriol oil and concentrated nitric acid in mass ratio for 1:6.5 mixes, then reflux under stirring action, Heating temperature is 160 ℃, treatment time is 28 hours, after taking-up handled thing, with distilled water repetitive scrubbing, to neutrality, puts into 140 ℃ of baking ovens dry 16 hours.
By above-mentioned dried Graphene, according to mass ratio, be that 1:6 mixes with coupling agent-ethanol solution, it is that the ball mill of 450 revs/min carries out ball milling 3.5 hours that the slurries of gained are put into rotating speed, be finally placed in dry 16 hours of 140 ℃ of baking ovens of vacuum modified graphene micro mist;
Described coupling agent-ethanol solution be by coupling agent with dehydrated alcohol in mass ratio for 1:7.5 mixes, and dripping hydrochloric acid soln, to adjust pH value be 4.5, coupling agent be coupling agent A with coupling agent B in mass ratio for 1:1 mixes.
(2) prepare polyamide 6/polypropylene composite material;
Take modified graphene micro mist, 2.6 parts of antiseptic-germicide AGZ330,27 parts of compatilizer AX8900,0.25 part of antioxidant 1010,1098,0.6 part of irgasfos 168 of 0.25 part of oxidation inhibitor, 0.55 part of dispersion agent E525 prepared by 100 parts of PA6 M2500,85 parts of polypropylene BX3900,25 parts of step 1 and in high-speed mixer, mix 5 minutes, mixing machine rotating speed is 220 revs/min; Then the mixture mixing is added in twin screw extruder melt extrude, cooling, pelletizing obtains polyamide 6/polypropylene composite material; Wherein the temperature of forcing machine is followed successively by 200 ℃, 220 ℃, 220 ℃, 230 ℃, 230 ℃, 230 ℃, 230 ℃, 235 ℃ from spout to head.Performance is as table-2.
From above embodiment 2 ~ 5, can find out, conduction prepared by the present invention, the conductive effect of antimicrobial polyamide 6/polypropylene composite material is remarkable, antibacterial effect is excellent.From embodiment 2, can obviously find out, composite material surface resistivity is 10
4the Ω order of magnitude,, along with the increase of modified graphene micro mist consumption, its surface resistivity reduces thereupon, and makes the conductivity of material better; In embodiment 2, the antibacterium rate of matrix material is up to more than 99.9%, and antifungal grade is 0 grade of highest ranking.
This conduction of the present invention, antimicrobial polyamide 6/polypropylene composite material, have conductive effect, antibiotic rate high, can be widely used in defending the fields such as food, daily necessities, medical treatment, electric, household electrical appliances, automobile, national defence.
Claims (10)
1. conduction, antibacterial polyamide 6/polypropylene composite material, is characterized in that: following component, consist of by weight:
100 parts of polyamide 6s,
50 ~ 100 parts of polypropylene,
5 ~ 30 parts of conductive filler materials,
0.6 ~ 2.8 part of antiseptic-germicide,
10 ~ 30 parts of compatilizers,
0.4 ~ 1.2 part, oxidation inhibitor,
0.3 ~ 0.6 part of dispersion agent,
Described conductive filler material is for carrying out successively surface-treated modified graphene micro mist through acid and coupling agent-ethanol solution.
2. conduction according to claim 1, antimicrobial polyamide 6/polypropylene composite material, is characterized in that: described polypropylene is homo-polypropylene or Co-polypropylene.
3. conduction according to claim 1, antimicrobial polyamide 6/polypropylene composite material, is characterized in that: described antiseptic-germicide is inorganic antiseptic.
4. conduction according to claim 3, antimicrobial polyamide 6/polypropylene composite material, is characterized in that: described inorganic antiseptic is silver, zine series inorganic germicide.
5. conduction according to claim 1, antimicrobial polyamide 6/polypropylene composite material, is characterized in that: described compatilizer is polypropylene grafted maleic anhydride or ethylene-methyl acrylate-glyceryl methacrylate terpolymer.
6. conduction according to claim 1, antimicrobial polyamide 6/polypropylene composite material; it is characterized in that: described oxidation inhibitor is selected four [β-(3; 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, three [2; 4-di-tert-butyl-phenyl] phosphorous acid ester and N; N'-pair-(3-(3,5-di-tert-butyl-hydroxy phenyl) propionyl) hexanediamine mixture.
7. conduction according to claim 1, antimicrobial polyamide 6/polypropylene composite material, is characterized in that: described dispersion agent is silicone based dispersion agent.
8. a method of preparing conduction as claimed in claim 1, antibacterial polyamide 6/polypropylene composite material, is characterized in that: comprise the following steps:
(1) prepare modified graphene micro mist:
Acid treatment: by dry ecosystem Graphene micro mist with acid solution in mass ratio for 1:6.5 mixes, under stirring action, reflux is taken out handled thing after 28 hours and is washed with distilled water to neutrality;
Modification: after above-mentioned handled thing is dried with coupling agent-ethanol solution in mass ratio for 1:6 mixes, then it is carried out to ball milling and crosses 800 mesh sieves, be then dried to obtain Graphene micro mist;
Described coupling agent-ethanol solution be by coupling agent with dehydrated alcohol in mass ratio for 1:7.5 mixes, and dripping hydrochloric acid soln, to adjust pH value be 3 ~ 6; Described coupling agent is the mixture of aluminate coupling agent, titanate coupling agent;
(2) prepare polyamide 6/polypropylene composite material
Take 100 parts of polyamide 6s, 50 ~ 100 parts of polypropylene, 5 ~ 30 parts of modified graphene micro mists, 0.6 ~ 2.8 part of antiseptic-germicide, 10 ~ 30 parts of compatilizers, 0.4 ~ 1.2 part of oxidation inhibitor, 0.3 ~ 0.6 part of dispersion agent and in high-speed mixer, mix 5 minutes, mixing machine rotating speed is 220 revs/min; Then the mixture mixing is added in twin screw extruder melt extrude, cooling
Pelletizing obtains polyamide 6/polypropylene composite material;
Wherein the temperature of twin screw extruder is followed successively by 200 ℃, 220 ℃, 220 ℃, 230 ℃, 230 ℃, 230 ℃, 230 ℃, 235 ℃ from spout to head.
9. preparation method according to claim 8, is characterized in that: dry ecosystem Graphene micro mist described in described step (1) is that ecosystem Graphene micro mist is placed in to the dry 8 hours gained of 140 ℃ of baking ovens; Described acid solution is that the vitriol oil and concentrated nitric acid are by volume for 3:5 mixes; The temperature of reflux is 160 ℃.
10. preparation method according to claim 8, is characterized in that: in described step (1), coupling agent is that aluminate coupling agent isopropoxy distearyl acid acyloxy Aluminate and titanate coupling agent sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester are in mass ratio for 1:1 mixes; Described being dried as processing 8 hours in 140 ℃ of baking ovens.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105694442A (en) * | 2016-01-27 | 2016-06-22 | 苏州翠南电子科技有限公司 | Preparation method of high-temperature-resisting and high-conductivity conductive plastic |
| CN105802207A (en) * | 2016-04-22 | 2016-07-27 | 柳州蓓蒂芬科技有限公司 | Plastic for automobile interior trim part and manufacturing method thereof |
| CN108822539A (en) * | 2018-07-10 | 2018-11-16 | 芜湖市元奎新材料科技有限公司 | Environmental-protection fire-resistant nylon composite material and preparation method |
| CN109438854A (en) * | 2018-11-12 | 2019-03-08 | 南通壹选工业设计有限公司 | A kind of polypropylene anti-bacterial plastic and preparation method thereof |
| CN111393744A (en) * | 2020-03-26 | 2020-07-10 | 南京京锦元科技实业有限公司 | TPE material with antibacterial conductivity and preparation method thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1900162A (en) * | 2006-07-12 | 2007-01-24 | 扬州大学 | Polyamide/graphite nano conductive composite material and its prepairng method |
| CN102464882A (en) * | 2010-11-18 | 2012-05-23 | 合肥杰事杰新材料股份有限公司 | Material for toilet lid and toilet seat and preparation method thereof |
-
2014
- 2014-07-03 CN CN201410314328.0A patent/CN104098893A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1900162A (en) * | 2006-07-12 | 2007-01-24 | 扬州大学 | Polyamide/graphite nano conductive composite material and its prepairng method |
| CN102464882A (en) * | 2010-11-18 | 2012-05-23 | 合肥杰事杰新材料股份有限公司 | Material for toilet lid and toilet seat and preparation method thereof |
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|---|---|---|---|---|
| CN105694442A (en) * | 2016-01-27 | 2016-06-22 | 苏州翠南电子科技有限公司 | Preparation method of high-temperature-resisting and high-conductivity conductive plastic |
| CN105802207A (en) * | 2016-04-22 | 2016-07-27 | 柳州蓓蒂芬科技有限公司 | Plastic for automobile interior trim part and manufacturing method thereof |
| CN108822539A (en) * | 2018-07-10 | 2018-11-16 | 芜湖市元奎新材料科技有限公司 | Environmental-protection fire-resistant nylon composite material and preparation method |
| CN109438854A (en) * | 2018-11-12 | 2019-03-08 | 南通壹选工业设计有限公司 | A kind of polypropylene anti-bacterial plastic and preparation method thereof |
| CN111393744A (en) * | 2020-03-26 | 2020-07-10 | 南京京锦元科技实业有限公司 | TPE material with antibacterial conductivity and preparation method thereof |
| CN113831595A (en) * | 2020-06-24 | 2021-12-24 | 合肥杰事杰新材料股份有限公司 | Modified graphene, heat-conducting PBT material and preparation method thereof |
| CN114214746A (en) * | 2021-12-16 | 2022-03-22 | 宜宾丽雅新材料有限责任公司 | Antibacterial melt-blown material auxiliary agent and application thereof |
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Application publication date: 20141015 |