CN1040974C - Light magnesium oxychloride building material - Google Patents

Light magnesium oxychloride building material Download PDF

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Publication number
CN1040974C
CN1040974C CN93110146A CN93110146A CN1040974C CN 1040974 C CN1040974 C CN 1040974C CN 93110146 A CN93110146 A CN 93110146A CN 93110146 A CN93110146 A CN 93110146A CN 1040974 C CN1040974 C CN 1040974C
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China
Prior art keywords
weight
magnesium
composition
alum
magnesium oxide
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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CN93110146A
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Chinese (zh)
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CN1092051A (en
Inventor
俞志强
张秀茹
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Individual
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/34Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
    • C04B28/342Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders the phosphate binder being present in the starting composition as a mixture of free acid and one or more reactive oxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to a light magnesium oxychloride building material which mainly uses magnesium oxide and magnesium chloride as base materials. Raw materials of tri-alum waterproof agent water solution, phosphonic acid of 85%, quartz sand, talcum powder, sawdust, etc. are added in the base materials, and are stirred at a room temperature of 20 to 25 DEG C. The building material can be used for water resistance, moisture protection and anti-seepage. The disadvantages of porosity and easy leakage of a magnesium oxychloride material are overcome, and the problem of low strength of a later stage of the magnesium cement products is further solved. The material products have no phenomena of warping deformation and hygroscopicity, the colour is distributed uniformly, and the material products can be sawn and nailed, and has the advantages of high strength, non-toxicity, harmlessness, fire prevention and corrosion prevention. The reaction speed of magnesium oxide and magnesium chloride can be nicely controlled.

Description

Light magnesium oxychloride building material
The present invention relates to a kind of light magnesium oxychloride building material.
In the prior art, magnesium cement product is because shortcoming such as itself performance of magnesium cement exists the moisture absorption, returns halogen, buckling deformation and later strength are low.
The purpose of this invention is to provide a kind of protection against the tide, waterproof, antiseepage, no buckling deformation, do not have the light magnesium oxychloride building material that returns halogen, returns white phenomenon.
The object of the present invention is achieved like this: with magnesium oxide and magnesium chloride is the chlorine oxygen magnesium light building material of base-material, and its component and content are as follows: (each component parts by weight)
Magnesium oxide: (6.5-7.5)
Magnesium chloride: (6.0-6.5)
The phosphoric acid of concentration 85%: (0.0325-0.075)
Saw foam: (0.5-0.7)
Quartz sand: (0.5-0.8)
Talcum powder: (1.8-2.5)
The three alum water-resisting agent aqueous solution (0.668-0.926), wherein magnesian purity is 75-85%, the ripple magnesium degree of magnesium chloride is 26-30 °,
The component of the three alum water-resisting agent aqueous solution:
Ferrous sulfate (green vitriol) is the 1-1.5% of magnesium oxide weight
Copper sulfate (blue alum) is the 1-1.5% of magnesium oxide weight
Potassium bichromate (arsenic) is the 1-1.5% of magnesium oxide weight
The parts by weight of water are (0.473-0.588)
The preparation method of above-mentioned chlorine oxygen magnesium light building material is: be under 20-25 ℃ the condition in envrionment temperature, at first adding incoming wave magnesium degree is the 26-30 ° of magnesium chloride that composition by weight is 6.0-65, adding then and containing three alum composition by weight is that 40-50 ℃ three alum water repellent solution (composition by weight is 0.668-0.926) stir for the 0.195-0.3375 temperature, the concentration that adds composition by weight again and be 0.0325-0.075 is that 85% phosphoric acid stirs, then add the quartz sand that composition by weight is 0.5-0.8, adding composition by weight after the stirring again is the talcum powder stirring of 1.8-2.5, adding purity is the magnesium oxide stirring of 6.5-7.5 for the 75-85% composition by weight, adding composition by weight at last is the saw foam stirring of 0.5-0.7, then carry out maintenance, promptly get this kind material of construction, the manufacture craft of the three alum water-resisting agent aqueous solution is to be that the water of 0.473-0.588 is boiled with composition by weight, adding composition by weight respectively is the equivalent ferrous sulfate of 0.065-0.1125, copper sulfate and potassium bichromate, treat that three alum dissolve fully, temperature is reduced to 40-50 ℃, promptly gets the three alum water-resisting agent aqueous solution.
Compared with prior art, the present invention is owing to add ferrous sulfate, the copper sulfate component has played protection against the tide, waterproof action, through checking water-intake rate less than 106%, again owing to adopt potassium bichromate with antiseepage function, make the present invention have the antiseepage function, overcome the porous of magnesium oxychloride material, the drawback of easy to leak, test shows, watertightness anhydrous of back side after 24 hours, freeze-thaw resistance is behind 25 freeze-thaw cycle, test specimen does not have aliquation, be full of cracks and pull out type fracture phenomenon, the present invention is owing to have protection against the tide, waterproof, barrier performance, thereby further solved the low problem of this material product later strength, and do not have buckling deformation and return halogen and return white phenomenon, use phosphoric acid to control the speed of response of magnesium oxide and magnesium chloride, it is crisp to have solved the hurried intensification and this kind material product that cause because of speed of response is too fast summer, the shortcoming that intensity is low, phosphoric acid also can make the color distribution of this material product even, and this material product also has and can saw and can follow closely in addition, high-strength light, fire prevention, anticorrosion, advantage such as nontoxic.
Describe specific embodiments of the present invention below in detail.
Embodiment 1:
With magnesium oxide and magnesium chloride is the chlorine oxygen magnesium light building material of base-material, and its component and content are as follows: (each component parts by weight)
Magnesium oxide: 6.5 (magnesium oxide purity is 76%)
Magnesium chloride: 6.0 (the ripple magnesium degree of magnesium chloride is 26 °
The phosphoric acid of concentration 85%: for 0.5% of magnesium oxide weight is 0.0325
Saw foam: 0.5
Quartz sand: 0.5
Talcum powder: 1.8
The three alum water-resisting agent aqueous solution 0.668,
The component of the three alum water-resisting agent aqueous solution:
Ferrous sulfate (green vitriol) is 1% of a magnesium oxide weight
Copper sulfate (blue alum) is 1% of magnesium oxide weight
Potassium bichromate (arsenic) is 1% of a magnesium oxide weight
The parts by weight of water are 0.473
The preparation method of above-mentioned chlorine oxygen magnesium light building material is: be under 23 ℃ the condition in envrionment temperature, at first adding incoming wave magnesium degree is that 26 ° of composition by weight are 6.0 magnesium chloride, adding then and containing three alum composition by weight is that 0.195 temperature is 45 ℃ three alum water repellent solution (composition by weight is 0.668) stirring, adding composition by weight again and be 0.0325 concentration and be 85% phosphoric acid stirs, then add composition by weight and be 0.5 quartz sand, adding composition by weight after the stirring again and be 1.8 talcum powder stirs, adding purity is that 76% composition by weight is 6.5 magnesium oxide stirring, adding composition by weight at last and be 0.5 saw foam stirs, then carry out maintenance, promptly get this kind material of construction, the manufacture craft of the three alum water-resisting agent aqueous solution is to be that 0.473 water is boiled with composition by weight, add composition by weight respectively and be 0.065 equivalent ferrous sulfate, copper sulfate and potassium bichromate, treat that three alum dissolve fully, temperature is reduced to 45 ℃, promptly gets the three alum water-resisting agent aqueous solution.
Embodiment 2:
With magnesium oxide and magnesium chloride is the chlorine oxygen magnesium light building material of base-material, and its component and content are as follows: (each component parts by weight)
Magnesium oxide: 7.5 (magnesium oxide purity is 80%)
Magnesium chloride: 6.5 (magnesium chloride ripple magnesium degree is 27 °)
The phosphoric acid of concentration 85%: 0.075
Saw foam: 0.7
Quartz sand: 0.8
Talcum powder: 2.5
The component of the three alum water-resisting agent aqueous solution, 0.926, the three alum water-resisting agent aqueous solution:
Ferrous sulfate (green vitriol) is 1.5% of a magnesium oxide weight
Copper sulfate (blue alum) is 1.5% of magnesium oxide weight
Potassium bichromate (arsenic) is 1.5% of a magnesium oxide weight
The parts by weight of water are 0.588
The preparation method of above-mentioned chlorine oxygen magnesium light building material is: be under 24 ℃ the condition in envrionment temperature, at first adding incoming wave magnesium degree is that 27 ° of composition by weight are 6.5 magnesium chloride, adding then and containing three alum composition by weight is that 0.3375 temperature is 43 ℃ three alum water repellent solution (composition by weight is 0.926) stirring, adding composition by weight again and be 0.075 concentration and be 85% phosphoric acid stirs, then add composition by weight and be 0.8 quartz sand, adding composition by weight after the stirring again and be 2.5 talcum powder stirs, adding purity is that 80% composition by weight is 7.5 magnesium oxide stirring, adding composition by weight at last and be 0.7 saw foam stirs, then carry out maintenance, promptly get this kind material of construction, the manufacture craft of the three alum water-resisting agent aqueous solution is to be that 0.588 water is boiled with composition by weight, add composition by weight respectively and be 0.1125 equivalent ferrous sulfate, copper sulfate and potassium bichromate, treat that three alum dissolve fully, temperature is reduced to 43 ℃, promptly gets the three alum water-resisting agent aqueous solution.
Embodiment 3:
With magnesium oxide and magnesium chloride is the chlorine oxygen magnesium light building material of base-material, and its component and content are as follows: (each component parts by weight)
Magnesium oxide: 7.25 (magnesium oxide purity is 77%)
Magnesium chloride: 6.1 (magnesium chloride ripple magnesium degree is 27 °)
The phosphoric acid of concentration 85%: 0.058
Saw foam: 0.6
Quartz sand: 0.7
Talcum powder: 2.3
The three alum water-resisting agent aqueous solution 0.792,
The component of the three alum water-resisting agent aqueous solution:
Ferrous sulfate (green vitriol) is 1.2% of a magnesium oxide weight
Copper sulfate (blue alum) is 1.2% of magnesium oxide weight
Potassium bichromate (arsenic) is 1.2% of a magnesium oxide weight
The parts by weight of water are 0.531
The preparation method of above-mentioned chlorine oxygen magnesium light building material is: be under 23 ℃ the condition in envrionment temperature, at first adding incoming wave magnesium degree is that 27 ° of composition by weight are 6.1 magnesium chloride, adding then and containing three alum composition by weight is that 0.261 temperature is 43 ℃ three alum water repellent solution (composition by weight is 0.792) stirring, adding composition by weight again and be 0.058 concentration and be 85% phosphoric acid stirs, then add composition by weight and be 0.7 quartz sand, adding composition by weight after the stirring again and be 2.3 talcum powder stirs, adding purity is that 77% composition by weight is 7.25 magnesium oxide stirring, adding composition by weight at last and be 0.6 saw foam stirs, then carry out maintenance, promptly get this kind material of construction, the manufacture craft of the three alum water-resisting agent aqueous solution is to be that 0.531 water is boiled with composition by weight, add composition by weight respectively and be 0.087 equivalent ferrous sulfate, copper sulfate and potassium bichromate, treat that three alum dissolve fully, temperature is reduced to 43 ℃, promptly gets the three alum water-resisting agent aqueous solution.

Claims (2)

1, a kind of is the chlorine oxygen magnesium light building material of base-material with magnesium oxide and magnesium chloride, it is characterized in that its component and content are as follows: (each component parts by weight)
Magnesium oxide: (6.5-7.5)
Magnesium chloride: (6.0-6.5)
The phosphoric acid of concentration 85%: (0.0325-0.075)
Saw foam: (0.5-0.7)
Quartz sand: (0.5-0.8)
Talcum powder: (1.8-2.5)
The three alum water-resisting agent aqueous solution (0.668-0.926), wherein magnesian purity is 75-85%, the ripple magnesium degree of magnesium chloride is 26-30 °,
The component of the three alum water-resisting agent aqueous solution:
Ferrous sulfate (green vitriol) is the 1-1.5% of magnesium oxide weight
Copper sulfate (blue alum) is the 1-1.5% of magnesium oxide weight
Potassium bichromate (arsenic) is the 1-1.5% of magnesium oxide weight
The parts by weight of water are (0.473-0.588)
2, a kind of preparation method of chlorine oxygen magnesium light building material as claimed in claim 1: it is characterized in that under envrionment temperature is 20-25 ℃ condition, at first adding incoming wave magnesium degree is the 26-30 ° of magnesium chloride that composition by weight is 6.0-6.5, adding then and containing three alum composition by weight is that 40-50 ℃ three alum water repellent solution (composition by weight is 0.668-0.926) stir for the 0.195-0.3375 temperature, the concentration that adds composition by weight again and be 0.0325-0.075 is that 85% phosphoric acid stirs, then add the quartz sand that composition by weight is 0.5-0.8, adding composition by weight after the stirring again is the talcum powder stirring of 1.8-2.5, adding purity is the magnesium oxide stirring of 6.5-7.5 for the 75-85% composition by weight, adding composition by weight at last is the saw foam stirring of 0.5-0.7, then carry out maintenance, promptly get this kind material of construction, the manufacture craft of the three alum water-resisting agent aqueous solution is to be that the water of 0.473-0.588 is boiled with composition by weight, adding composition by weight respectively is the equivalent ferrous sulfate of 0.065-0.1125, copper sulfate and potassium bichromate, treat that three alum dissolve fully, temperature is reduced to 40-50 ℃, promptly gets the three alum water-resisting agent aqueous solution.
CN93110146A 1993-03-05 1993-03-05 Light magnesium oxychloride building material Expired - Lifetime CN1040974C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN93110146A CN1040974C (en) 1993-03-05 1993-03-05 Light magnesium oxychloride building material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN93110146A CN1040974C (en) 1993-03-05 1993-03-05 Light magnesium oxychloride building material

Publications (2)

Publication Number Publication Date
CN1092051A CN1092051A (en) 1994-09-14
CN1040974C true CN1040974C (en) 1998-12-02

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CN93110146A Expired - Lifetime CN1040974C (en) 1993-03-05 1993-03-05 Light magnesium oxychloride building material

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560861B (en) * 2009-04-18 2012-03-28 浙江采丰防火技术有限公司 Method for manufacturing flame-retardant composite door frame or window frame and door frame or window frame

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1323218C (en) * 2005-01-11 2007-06-27 任文平 Fiber composite partition wall board
CN103896550A (en) * 2014-03-07 2014-07-02 沈阳建宝丽新型建材有限公司 Light-weight high-strength roofing board prepared from needle-like wollastonite waste residues and preparation method thereof
US10167231B1 (en) 2017-11-07 2019-01-01 Jet Products, Llc Process for making ultra stable tile backer board
US11117836B2 (en) 2017-11-07 2021-09-14 Mitek Holdings, Inc. Ultra stable structural laminate
CN115057685A (en) * 2022-06-02 2022-09-16 福建鸿钧家具用品有限公司 Light terrazzo stove made of composite magnesite material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560861B (en) * 2009-04-18 2012-03-28 浙江采丰防火技术有限公司 Method for manufacturing flame-retardant composite door frame or window frame and door frame or window frame

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CN1092051A (en) 1994-09-14

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Expiration termination date: 20130305

Granted publication date: 19981202