CN104087206A - Hot-melt adhesive for binding cable heat-shrinkable sleeves - Google Patents
Hot-melt adhesive for binding cable heat-shrinkable sleeves Download PDFInfo
- Publication number
- CN104087206A CN104087206A CN201410293110.1A CN201410293110A CN104087206A CN 104087206 A CN104087206 A CN 104087206A CN 201410293110 A CN201410293110 A CN 201410293110A CN 104087206 A CN104087206 A CN 104087206A
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- CN
- China
- Prior art keywords
- parts
- melt adhesive
- add
- shrinkable
- cable heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004831 Hot glue Substances 0.000 title claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 10
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims abstract description 8
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229960002401 calcium lactate Drugs 0.000 claims abstract description 7
- 235000011086 calcium lactate Nutrition 0.000 claims abstract description 7
- 239000001527 calcium lactate Substances 0.000 claims abstract description 7
- 239000003208 petroleum Substances 0.000 claims abstract description 7
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims abstract description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 4
- 229960002887 deanol Drugs 0.000 claims abstract description 4
- 239000012972 dimethylethanolamine Substances 0.000 claims abstract description 4
- 239000004417 polycarbonate Substances 0.000 claims abstract description 4
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 9
- 230000001070 adhesive effect Effects 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- MJYQFWSXKFLTAY-OVEQLNGDSA-N (2r,3r)-2,3-bis[(4-hydroxy-3-methoxyphenyl)methyl]butane-1,4-diol;(2r,3r,4s,5s,6r)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O.C1=C(O)C(OC)=CC(C[C@@H](CO)[C@H](CO)CC=2C=C(OC)C(O)=CC=2)=C1 MJYQFWSXKFLTAY-OVEQLNGDSA-N 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 claims description 6
- 235000004426 flaxseed Nutrition 0.000 claims description 6
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 229940072033 potash Drugs 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 235000015320 potassium carbonate Nutrition 0.000 claims description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 239000000344 soap Substances 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 3
- 229960000411 camphor oil Drugs 0.000 claims description 3
- 239000010624 camphor oil Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- 230000002349 favourable effect Effects 0.000 abstract 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 abstract 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 abstract 1
- 241000723346 Cinnamomum camphora Species 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 235000013773 glyceryl triacetate Nutrition 0.000 abstract 1
- 229960002622 triacetin Drugs 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a hot-melt adhesive for binding cable heat-shrinkable sleeves, which is prepared from the following raw materials in parts by weight: 60.2-70 parts of ethylene-vinyl acetate copolymer, 0.8-1 part of Cinnamomum camphora oil, 5-7 parts of sasol wax, 7-10 parts of C9 petroleum resin, 3-4 parts of polycarbonate, 2-3 parts of glycerol triacetate, 2-3 parts of calcium lactate, 1-2 parts of dimethylethanolamine, 0.2-0.4 part of methyl benzotriazole, 0.1-0.2 part of ethoxylated alkylphenol ammonium sulfate, 0.2-0.4 part of polyvinylpyrrolidone and 6-8 parts of binding assistant. The hot-melt adhesive has the advantages of long service life, favorable wettability for heat-shrinkable tubes, high peel strength, favorable binding property and favorable anti-adhesion effect, and can be used at low temperature.
Description
Technical field
The present invention relates generally to a kind of hot melt adhesive powder, relates in particular to a kind of bonding cable heat-shrinkable T bush hot melt adhesive.
Background technology
Hot melt adhesive is a kind of plastic tackiness agent, and in certain temperature range, its physical condition changes with temperature change, and chemical property is constant, and it is nonpoisonous and tasteless, belongs to environmental-protecting chemical product.
Summary of the invention
The object of the invention is just to provide a kind of bonding cable heat-shrinkable T bush hot melt adhesive.
The present invention is achieved by the following technical solutions:
A bonding cable heat-shrinkable T bush hot melt adhesive, it is comprised of the raw material of following weight parts:
Ethylene-vinyl acetate copolymer 60.2-70, fragrant camphor oil 0.8-1, husky rope wax 5-7, C9 petroleum resin 7-10, polycarbonate 3-4, Vanay 2-3, calcium lactate 2-3, dimethylethanolamine 1-2, methyl benzotriazazole 0.2-0.4, ethoxylated alkylphenol ammonium sulfate 0.1-0.2, polyvinylpyrrolidone 0.2-0.4, adhesive aid 6-8;
Described increasing adhesive aid is comprised of the raw material of following weight parts:
Whiteruss 24-30, flaxseed gum 2-3, fluorographite 1-2, EVA resin 4-5, dibutyl maleinate 3-4, oleic acid potash soap 0.6-2, propyl trimethoxy silicane 0.2-0.5;
By the thermoplastic of EVA resin, add dibutyl maleinate, stir, add propyl trimethoxy silicane, insulated and stirred 10-15 minute at 50-60 ℃, joins in whiteruss, stirs, and obtains binding liquid;
Flaxseed gum is mixed with oleic acid potash soap, after stirring, add fluorographite, ball milling is even, joins in above-mentioned binding liquid, and 60-80 rev/min of dispersed with stirring 3-4 minute, obtains described adhesive aid.
A preparation method for hot melt adhesive for the cable heat-shrinkable T bush that bonds, comprises the following steps:
Above-mentioned husky rope wax, C9 petroleum resin are mixed, be uniformly mixed 2-3 minute at 70-80 ℃, add calcium lactate, Vanay, be stirred to normal temperature, add each raw material of residue, at 25-30 ℃, be incubated standing 1-2 hour, send into mixing roll, be heated to 90-100 ℃, mixing 20-30min; Mixing product after is evenly joined to twin screw extruder, extrude product through cooling, granulation, obtain described bonding cable heat-shrinkable T bush hot melt adhesive.
Advantage of the present invention is:
Hot melt adhesive prepared by the present invention has very long time limit of service, and heat-shrink tube is had to good wetting property, and stripping strength is high, and cohesiveness is good, can low temperature use and antiblocking effective.
Embodiment
Embodiment 1
A bonding cable heat-shrinkable T bush hot melt adhesive, it by following weight parts (kilogram) raw material form:
Ethylene-vinyl acetate copolymer 60.2, fragrant camphor oil 0.8, husky rope wax 5, C9 petroleum resin 10, polycarbonate 3, Vanay 2, calcium lactate 3, dimethylethanolamine 2, methyl benzotriazazole 0.4, ethoxylated alkylphenol ammonium sulfate 0.2, polyvinylpyrrolidone 0.4, adhesive aid 8;
Described increasing adhesive aid is comprised of the raw material of following weight parts:
Whiteruss 30, flaxseed gum 2, fluorographite 2, EVA resin 5, dibutyl maleinate 3, oleic acid potash soap 0.6, propyl trimethoxy silicane 0.5;
By the thermoplastic of EVA resin, add dibutyl maleinate, stir, add propyl trimethoxy silicane, at 60 ℃, insulated and stirred is 15 minutes, joins in whiteruss, stirs, and obtains binding liquid;
Flaxseed gum is mixed with oleic acid potash soap, after stirring, add fluorographite, ball milling is even, joins in above-mentioned binding liquid, and 60 revs/min of dispersed with stirring 4 minutes, obtain described adhesive aid.
A preparation method for hot melt adhesive for the cable heat-shrinkable T bush that bonds, is characterized in that comprising the following steps:
Above-mentioned husky rope wax, C9 petroleum resin are mixed, be uniformly mixed 3 minutes at 80 ℃, add calcium lactate, Vanay, be stirred to normal temperature, add each raw material of residue, at 30 ℃, be incubated standing 1 hour, send into mixing roll, be heated to 100 ℃, mixing 30min; Mixing product after is evenly joined to twin screw extruder, extrude product through cooling, granulation, obtain described bonding cable heat-shrinkable T bush hot melt adhesive.
Performance test
97 ℃ of softening temperatures;
Stripping strength: 94N/25mm.
Claims (2)
1. a bonding cable heat-shrinkable T bush hot melt adhesive, is characterized in that what it was comprised of the raw material of following weight parts:
Ethylene-vinyl acetate copolymer 60.2-70, fragrant camphor oil 0.8-1, husky rope wax 5-7, C9 petroleum resin 7-10, polycarbonate 3-4, Vanay 2-3, calcium lactate 2-3, dimethylethanolamine 1-2, methyl benzotriazazole 0.2-0.4, ethoxylated alkylphenol ammonium sulfate 0.1-0.2, polyvinylpyrrolidone 0.2-0.4, adhesive aid 6-8;
Described increasing adhesive aid is comprised of the raw material of following weight parts:
Whiteruss 24-30, flaxseed gum 2-3, fluorographite 1-2, EVA resin 4-5, dibutyl maleinate 3-4, oleic acid potash soap 0.6-2, propyl trimethoxy silicane 0.2-0.5;
By the thermoplastic of EVA resin, add dibutyl maleinate, stir, add propyl trimethoxy silicane, insulated and stirred 10-15 minute at 50-60 ℃, joins in whiteruss, stirs, and obtains binding liquid;
Flaxseed gum is mixed with oleic acid potash soap, after stirring, add fluorographite, ball milling is even, joins in above-mentioned binding liquid, and 60-80 rev/min of dispersed with stirring 3-4 minute, obtains described adhesive aid.
2. a preparation method for hot melt adhesive for bonding cable heat-shrinkable T bush as claimed in claim 1, is characterized in that comprising the following steps:
Above-mentioned husky rope wax, C9 petroleum resin are mixed, be uniformly mixed 2-3 minute at 70-80 ℃, add calcium lactate, Vanay, be stirred to normal temperature, add each raw material of residue, at 25-30 ℃, be incubated standing 1-2 hour, send into mixing roll, be heated to 90-100 ℃, mixing 20-30min; Mixing product after is evenly joined to twin screw extruder, extrude product through cooling, granulation, obtain described bonding cable heat-shrinkable T bush hot melt adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293110.1A CN104087206B (en) | 2014-06-26 | 2014-06-26 | A kind of bonding cable heat shrinkage bush hot melt adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293110.1A CN104087206B (en) | 2014-06-26 | 2014-06-26 | A kind of bonding cable heat shrinkage bush hot melt adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104087206A true CN104087206A (en) | 2014-10-08 |
| CN104087206B CN104087206B (en) | 2016-03-23 |
Family
ID=51634972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410293110.1A Active CN104087206B (en) | 2014-06-26 | 2014-06-26 | A kind of bonding cable heat shrinkage bush hot melt adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104087206B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104694022A (en) * | 2015-03-13 | 2015-06-10 | 霍山县雁江印务有限公司 | Hot melt adhesive for gluing high temperature resistant cartons |
| CN105463983A (en) * | 2016-01-28 | 2016-04-06 | 柳州欧维姆结构检测技术有限公司 | Electrical hot melting waterproof cover and method for achieving waterproof sealing of cable waterproof cover |
| CN105969306A (en) * | 2016-06-23 | 2016-09-28 | 巢湖鹏远金属焊管有限公司 | Heat-insulating jacket adhesive for heating/cooling steel pipe |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4497936A (en) * | 1983-04-11 | 1985-02-05 | Exxon Research & Engineering Co. | Elastomer-ethylene copolymer hot melt systems |
| CN103468167A (en) * | 2013-08-13 | 2013-12-25 | 安徽东方金河精密机械制造有限公司 | Anti-ultraviolet EVA hot melt adhesive |
| CN103571393A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-ultraviolet hot melt adhesive for automobile interior parts |
| CN103788894A (en) * | 2014-01-14 | 2014-05-14 | 安徽金门工贸有限公司 | EVA (Ethylene-Vinyl Acetate) hot melt adhesive |
-
2014
- 2014-06-26 CN CN201410293110.1A patent/CN104087206B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4497936A (en) * | 1983-04-11 | 1985-02-05 | Exxon Research & Engineering Co. | Elastomer-ethylene copolymer hot melt systems |
| CN103468167A (en) * | 2013-08-13 | 2013-12-25 | 安徽东方金河精密机械制造有限公司 | Anti-ultraviolet EVA hot melt adhesive |
| CN103571393A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-ultraviolet hot melt adhesive for automobile interior parts |
| CN103788894A (en) * | 2014-01-14 | 2014-05-14 | 安徽金门工贸有限公司 | EVA (Ethylene-Vinyl Acetate) hot melt adhesive |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104694022A (en) * | 2015-03-13 | 2015-06-10 | 霍山县雁江印务有限公司 | Hot melt adhesive for gluing high temperature resistant cartons |
| CN105463983A (en) * | 2016-01-28 | 2016-04-06 | 柳州欧维姆结构检测技术有限公司 | Electrical hot melting waterproof cover and method for achieving waterproof sealing of cable waterproof cover |
| CN105463983B (en) * | 2016-01-28 | 2017-05-10 | 柳州欧维姆结构检测技术有限公司 | Electrical hot melting waterproof cover and method for achieving waterproof sealing of cable waterproof cover |
| CN105969306A (en) * | 2016-06-23 | 2016-09-28 | 巢湖鹏远金属焊管有限公司 | Heat-insulating jacket adhesive for heating/cooling steel pipe |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104087206B (en) | 2016-03-23 |
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Effective date of registration: 20240718 Address after: 239000 No.51 Laiyang Road, Xin'an Town, Laian County, Chuzhou City, Anhui Province Patentee after: Lai'an County Yongzi Industrial Investment Co.,Ltd. Country or region after: China Address before: No. 2 Huayuan East Road, Lai'an County, Chuzhou City, Anhui Province, China 239200 Patentee before: CHUZHOU GUANGWEI CHEMICAL Co.,Ltd. Country or region before: China |
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| TR01 | Transfer of patent right |