CN104087205B - A kind of printer material assembling Environmental-friendhot hot melt adhesive - Google Patents
A kind of printer material assembling Environmental-friendhot hot melt adhesive Download PDFInfo
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- CN104087205B CN104087205B CN201410293109.9A CN201410293109A CN104087205B CN 104087205 B CN104087205 B CN 104087205B CN 201410293109 A CN201410293109 A CN 201410293109A CN 104087205 B CN104087205 B CN 104087205B
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- hot melt
- melt adhesive
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- stirring
- printer material
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- 239000004831 Hot glue Substances 0.000 title claims abstract description 18
- 239000000463 material Substances 0.000 title claims abstract description 16
- 239000000853 adhesive Substances 0.000 claims abstract description 16
- 230000001070 adhesive effect Effects 0.000 claims abstract description 16
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 10
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 7
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 7
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 7
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 7
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 7
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 claims abstract description 4
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000013832 Valeriana officinalis Nutrition 0.000 claims abstract description 4
- 244000126014 Valeriana officinalis Species 0.000 claims abstract description 4
- FIBARIGPBPUBHC-UHFFFAOYSA-N octyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCOC(=O)CCCCCCCC1OC1CCCCCCCC FIBARIGPBPUBHC-UHFFFAOYSA-N 0.000 claims abstract description 4
- -1 phenylpropyl alcohol triazole Chemical class 0.000 claims abstract description 4
- 235000016788 valerian Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 12
- MJYQFWSXKFLTAY-OVEQLNGDSA-N (2r,3r)-2,3-bis[(4-hydroxy-3-methoxyphenyl)methyl]butane-1,4-diol;(2r,3r,4s,5s,6r)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O.C1=C(O)C(OC)=CC(C[C@@H](CO)[C@H](CO)CC=2C=C(OC)C(O)=CC=2)=C1 MJYQFWSXKFLTAY-OVEQLNGDSA-N 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 claims description 6
- 235000004426 flaxseed Nutrition 0.000 claims description 6
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 229940072033 potash Drugs 0.000 claims description 6
- 235000015320 potassium carbonate Nutrition 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 239000000344 soap Substances 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 2
- 231100001261 hazardous Toxicity 0.000 abstract description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 2
- 230000001473 noxious effect Effects 0.000 abstract description 2
- 239000008096 xylene Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of printer material assembling Environmental-friendhot hot melt adhesive, it is made up of the raw material of following weight parts: ethylene-vinyl acetate copolymer 65-72, poly-4-methyl-1-pentene 2-3, powdered nitrile rubber 0.1-0.3, thio-2 acid two octadecyl 2-3, valerian oil 1-2, phenylpropyl alcohol triazole 0.2-1, TriMethylolPropane(TMP) 0.5-1, octyl epoxy stearate 3-5, Di Iso Decyl Phthalate 4-7, Microcrystalline Wax 8-11,2-thiol group benzimidazolyl 1-2, adhesive aid 10-13; Hot melt adhesive prepared by the present invention is not containing the hazardous and noxious substances such as benzene,toluene,xylene, formaldehyde, and volatile component is few, is specially adapted to the assembling of printer material, can meet low VOC requirement.
Description
Technical field
The present invention relates generally to a kind of hot melt adhesive powder, particularly relates to a kind of printer material assembling Environmental-friendhot hot melt adhesive.
Background technology
Hot melt adhesive is a kind of plastic tackiness agent, and in certain temperature range, its physical condition changes with temperature change, and chemical property is constant, and it is nonpoisonous and tasteless, belongs to environmental-protecting chemical product.
Summary of the invention
The object of the invention is just to provide a kind of printer material assembling Environmental-friendhot hot melt adhesive.
The present invention is achieved by the following technical solutions:
A kind of printer material assembling Environmental-friendhot hot melt adhesive, it is made up of the raw material of following weight parts:
Ethylene-vinyl acetate copolymer 65-72, poly-4-methyl-1-pentene 2-3, powdered nitrile rubber 0.1-0.3, thio-2 acid two octadecyl 2-3, valerian oil 1-2, phenylpropyl alcohol triazole 0.2-1, TriMethylolPropane(TMP) 0.5-1, octyl epoxy stearate 3-5, Di Iso Decyl Phthalate 4-7, Microcrystalline Wax 8-11,2-thiol group benzimidazolyl 1-2, adhesive aid 10-13;
Described increasing adhesive aid is made up of the raw material of following weight parts:
Whiteruss 24-30, flaxseed gum 2-3, fluorographite 1-2, EVA resin 4-5, dibutyl maleinate 3-4, oleic acid potash soap 0.6-2, propyl trimethoxy silicane 0.2-0.5;
By EVA resin thermoplastic, add dibutyl maleinate, stir, add propyl trimethoxy silicane, insulated and stirred 10-15 minute at 50-60 DEG C, join in whiteruss, stir, obtain binding liquid;
Mixed with oleic acid potash soap by flaxseed gum, add fluorographite after stirring, ball milling is even, and join in above-mentioned binding liquid, 60-80 rev/min of dispersed with stirring 3-4 minute, obtains described adhesive aid.
A preparation method for printer material assembling Environmental-friendhot hot melt adhesive, comprises the following steps:
By powdered nitrile rubber, the two octadecyl mixing of thio-2 acid, add TriMethylolPropane(TMP) after stirring, 60-100 rev/min is uniformly mixed 6-10 minute, obtains Preblend;
Above-mentioned Preblend is added by after Microcrystalline Wax heat fused, 2-thiol group benzimidazolyl is added after stirring, stir 20-30 minute, add each raw material except adhesive aid, at 25-30 DEG C, insulation leaves standstill 1-2 hour, adds adhesive aid, sends into mixing roll, be heated to 90-100 DEG C, mixing 20-30min; By mixing evenly after product after vacuum defoamation, join twin screw extruder, extrude product through cooling, granulation, obtain described printer material assembling Environmental-friendhot hot melt adhesive.
Advantage of the present invention is:
Hot melt adhesive prepared by the present invention is not containing the hazardous and noxious substances such as benzene,toluene,xylene, formaldehyde, and volatile component is few, is specially adapted to the assembling of printer material, can meet low VOC requirement.
Embodiment
Embodiment 1
A kind of printer material assembling Environmental-friendhot hot melt adhesive, it is made up of the raw material of following weight parts (kilogram):
Ethylene-vinyl acetate copolymer 72, poly-4-methyl-1-pentene 2, powdered nitrile rubber 0.3, thio-2 acid two octadecyl 2, valerian oil 1, phenylpropyl alcohol triazole 0.2, TriMethylolPropane(TMP) 0.5, octyl epoxy stearate 5, Di Iso Decyl Phthalate 4, Microcrystalline Wax 11,2-thiol group benzimidazolyl 1, adhesive aid 13;
Described increasing adhesive aid is made up of the raw material of following weight parts:
Whiteruss 24, flaxseed gum 2, fluorographite 2, EVA resin 5, dibutyl maleinate 3, oleic acid potash soap 0.6, propyl trimethoxy silicane 0.5;
By EVA resin thermoplastic, add dibutyl maleinate, stir, add propyl trimethoxy silicane, at 50 DEG C, insulated and stirred 15 minutes, joins in whiteruss, stirs, obtain binding liquid;
Mixed with oleic acid potash soap by flaxseed gum, add fluorographite after stirring, ball milling is even, joins in above-mentioned binding liquid, and 80 revs/min of dispersed with stirring 4 minutes, obtain described adhesive aid.
A preparation method for printer material assembling Environmental-friendhot hot melt adhesive, comprises the following steps:
By powdered nitrile rubber, the two octadecyl mixing of thio-2 acid, add TriMethylolPropane(TMP) after stirring, 100 revs/min are uniformly mixed 10 minutes, obtain Preblend;
Add above-mentioned Preblend by after Microcrystalline Wax heat fused, after stirring, add 2-thiol group benzimidazolyl, stir 30 minutes, add each raw material except adhesive aid, at 30 DEG C, insulation leaves standstill 2 hours, adds adhesive aid, send into mixing roll, be heated to 100 DEG C, mixing 30min; By mixing evenly after product after vacuum defoamation, join twin screw extruder, extrude product through cooling, granulation, obtain described printer material assembling Environmental-friendhot hot melt adhesive.
Performance test
Softening temperature 96 DEG C;
Stripping strength: 93N/25mm.
Claims (2)
1. a printer material assembling Environmental-friendhot hot melt adhesive, is characterized in that what it was made up of the raw material of following weight parts:
Ethylene-vinyl acetate copolymer 65-72, poly-4-methyl-1-pentene 2-3, powdered nitrile rubber 0.1-0.3, thio-2 acid two octadecyl 2-3, valerian oil 1-2, phenylpropyl alcohol triazole 0.2-1, TriMethylolPropane(TMP) 0.5-1, octyl epoxy stearate 3-5, Di Iso Decyl Phthalate 4-7, Microcrystalline Wax 8-11,2-thiol group benzimidazolyl 1-2, adhesive aid 10-13;
Described adhesive aid is made up of the raw material of following weight parts:
Whiteruss 24-30, flaxseed gum 2-3, fluorographite 1-2, EVA resin 4-5, dibutyl maleinate 3-4, oleic acid potash soap 0.6-2, propyl trimethoxy silicane 0.2-0.5;
By EVA resin thermoplastic, add dibutyl maleinate, stir, add propyl trimethoxy silicane, insulated and stirred 10-15 minute at 50-60 DEG C, join in whiteruss, stir, obtain binding liquid;
Mixed with oleic acid potash soap by flaxseed gum, add fluorographite after stirring, ball milling is even, and join in above-mentioned binding liquid, 60-80 rev/min of dispersed with stirring 3-4 minute, obtains described adhesive aid.
2. a preparation method for printer material assembling Environmental-friendhot hot melt adhesive as claimed in claim 1, is characterized in that comprising the following steps:
By powdered nitrile rubber, the two octadecyl mixing of thio-2 acid, add TriMethylolPropane(TMP) after stirring, 60-100 rev/min is uniformly mixed 6-10 minute, obtains Preblend;
Above-mentioned Preblend is added by after Microcrystalline Wax heat fused, 2-thiol group benzimidazolyl is added after stirring, stir 20-30 minute, add each raw material except adhesive aid, at 25-30 DEG C, insulation leaves standstill 1-2 hour, adds adhesive aid, sends into mixing roll, be heated to 90-100 DEG C, mixing 20-30min; By mixing evenly after product after vacuum defoamation, join twin screw extruder, extrude product through cooling, granulation, obtain described printer material assembling Environmental-friendhot hot melt adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293109.9A CN104087205B (en) | 2014-06-26 | 2014-06-26 | A kind of printer material assembling Environmental-friendhot hot melt adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410293109.9A CN104087205B (en) | 2014-06-26 | 2014-06-26 | A kind of printer material assembling Environmental-friendhot hot melt adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104087205A CN104087205A (en) | 2014-10-08 |
| CN104087205B true CN104087205B (en) | 2016-03-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410293109.9A Active CN104087205B (en) | 2014-06-26 | 2014-06-26 | A kind of printer material assembling Environmental-friendhot hot melt adhesive |
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| Country | Link |
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| CN (1) | CN104087205B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509488A (en) * | 2013-09-06 | 2014-01-15 | 芜湖市正通电气设备有限公司 | High speed cigarette lap hot melt adhesive |
| CN103571377A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-aging hot melt adhesive |
| CN103571376A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3778459B2 (en) * | 1995-06-13 | 2006-05-24 | 田岡化学工業株式会社 | Hot melt adhesive composition |
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2014
- 2014-06-26 CN CN201410293109.9A patent/CN104087205B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509488A (en) * | 2013-09-06 | 2014-01-15 | 芜湖市正通电气设备有限公司 | High speed cigarette lap hot melt adhesive |
| CN103571377A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-aging hot melt adhesive |
| CN103571376A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive |
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| Publication number | Publication date |
|---|---|
| CN104087205A (en) | 2014-10-08 |
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Effective date of registration: 20240719 Address after: 239000 No.51 Laiyang Road, Xin'an Town, Laian County, Chuzhou City, Anhui Province Patentee after: Lai'an County Yongzi Industrial Investment Co.,Ltd. Country or region after: China Address before: No. 2 Huayuan East Road, Lai'an County, Chuzhou City, Anhui Province, China 239200 Patentee before: CHUZHOU GUANGWEI CHEMICAL Co.,Ltd. Country or region before: China |