CN1040813A - Solid adhesive - Google Patents
Solid adhesive Download PDFInfo
- Publication number
- CN1040813A CN1040813A CN 89107611 CN89107611A CN1040813A CN 1040813 A CN1040813 A CN 1040813A CN 89107611 CN89107611 CN 89107611 CN 89107611 A CN89107611 A CN 89107611A CN 1040813 A CN1040813 A CN 1040813A
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- CN
- China
- Prior art keywords
- solid adhesive
- ethanol
- resins
- agent
- resol
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of solid adhesive, be with the polyvinyl alcohol fourth vinegar that contracts, resol, the colloid mixture of Resins, epoxy and starch is a tackiness agent, use stearic acid, lauric acid, the mixed resultant of sodium hydroxide and potassium hydroxide is forming agent and tensio-active agent, with ethanol and acetone is solvent, also add lime carbonate in addition, glycerine, polyoxyethylene glycol and sorbyl alcohol, thus it is strong to make solid adhesive of the present invention have cohesive force, water-tolerant, curing speed is fast, characteristics such as long preservative period and suitability are wide not only are suitable for boning paper, timber and fabric, also be suitable for adhesive glass, pottery and metal.
Description
The invention belongs to the tackiness agent of solid-state shape.
Existing solid adhesive, having with water-soluble synthetic resin, kollidon or polyvinyl alcohol etc. to be tackiness agent, to be forming agent with lipid acid, is the solid adhesive of solvent with water or water and ethanol.Having with methylvinylether and maleic anhydride copolymer or iso-butylene and acid/maleic acid copolymers or polyacrylic acid etc. is tackiness agent, is forming agent with lipid acid or soap, is the solid adhesive of solvent with water and organic solvent.Also having with water dispersible polymer resin emulsion and water-soluble or water dispersible synthetic resins is tackiness agent, being forming agent, containing tackifier, softening agent and antidesiccant with lipid acid or aliphatic salt, is the solid adhesive (referring to the CN88100525 patent) of solvent with water.
Above-mentioned solid adhesive, though glued effect, respectively there is its advantage aspects such as preservation period and range of application, also do not satisfy some particular matter agglutinating needs at aspects such as range of application, water tolerance and consolidation strengths.
The objective of the invention is to provide that a kind of cohesive force is strong, water-tolerant, curing speed is fast and the wider solid adhesive of subject range.Not only can bond paper, fabric and timber, but also adhesive glass, pottery and metal.
Solid adhesive of the present invention is that the colloid mixture of forming with polyvinyl butyral acetal, resol, Resins, epoxy and starch is a tackiness agent, with the mixed resultant of stearic acid, lauric acid, sodium hydroxide and potassium hydroxide is forming agent and tensio-active agent, with the organic solvent is solvent, has also added mineral filler in addition.
Described organic solvent is to select ethanol and acetone for use.
Described mineral filler is to select lime carbonate for use.
The weight of each component content and proportion by subtraction are as follows in the solid glue of the present invention:
Polyvinyl butyral acetal 12%-25%
Resol 4%-11%
Resins, epoxy 2.1%-8%
Stearic acid 3.6%-9%
Lauric acid 2.1%-7.5
Sodium hydroxide 1.1%-2.3%
Potassium hydroxide 0.2%-1.8%
Ethanol 30%-40%
Acetone 6%-12%
Glycerine 0.3%-2.2%
Polyoxyethylene glycol 0.3%-2.5%
Sorbyl alcohol 0.3%-2.6%
Starch 0.7%-13%
Lime carbonate 0.6%-2.4%
Water 22%-32%
The summation of above-mentioned each component content is 100%
The compound method of solid adhesive of the present invention is as follows:
At first use a part of dissolve with ethanol polyvinyl butyral acetal in the proportioning, add resol then, and stir, get another container acetone solution Resins, epoxy again, above-mentioned two kinds of solution are poured on are mixed together evenly, promptly be made into liquid (I).Stearic acid and lauric acid heating and melting to be splashed into the mixing solutions of sodium hydroxide and potassium hydroxide more in addition, to stir, after dripping off, add another part ethanol in the proportioning again, it is fully dissolved, promptly be made into liquid (II) while dripping.Again liquid (I) and liquid (II) are poured on and are mixed together adding glycerine, polyoxyethylene glycol, sorbyl alcohol, starch and lime carbonate will constantly stir simultaneously, till all melting to thick colloid.But should notice that temperature will be controlled at 65-85 ℃, and will under the condition of heating in water bath, carry out that the reaction times is 30-70 minute.Above-mentioned thick colloid is injected the moulding of will type container while hot, promptly be frozen into solid adhesive of the present invention after the cooling.
Solid adhesive of the present invention and existing solid adhesive relatively have following advantage:
1, because solid adhesive of the present invention is with polyvinyl butyral acetal, resol, Resins, epoxy and starch cooperate and work, make the cohesive force of tackiness agent of the present invention strengthen water-tolerant, range of application has enlarged, and firmly breaks off with the fingers and thumb all after agglutinating glass and the ceramic solidification and can not separate from the bonding part, this solid adhesive, not only can bond paper, timber and fabric, lower-glass, pottery and metal also can bond.
2,, make solid adhesive exquisiteness of the present invention, clinging power strong because the present invention is that to mix the back resultant with stearic acid, lauric acid, sodium hydroxide and potassium hydroxide be forming agent and tensio-active agent.
3, because solid adhesive of the present invention is that to select acetone and ethanol for use be solvent, make colloid the side loose in solvent evenly.
4, because solid adhesive of the present invention contains lime carbonate, make solid adhesive curing speed of the present invention fast, simultaneously, also overcome existing solid adhesive and solidified the bigger shortcoming of post-shrinkage ratio.
5, because solid adhesive of the present invention contains glycerine, polyoxyethylene glycol and sorbyl alcohol make solid adhesive of the present invention have prolonged preservation and are not subjected to shape and stay-in-grade characteristics.
Embodiments of the invention:
(1), prescription: polyvinyl butyral acetal 16%
Resol 6.1%
Resins, epoxy 3.6%
Ethanol 32%
Acetone 8.1%
Stearic acid 4.8%
Lauric acid 2.4%
Sodium hydroxide 1.6%
Potassium hydroxide 0.3%
Water 22%
Glycerine 0.5%
Polyoxyethylene glycol 0.5%
Sorbyl alcohol 0.6%
Starch 0.8%
Lime carbonate 0.7%
(2), manufacture method: the thick colloid that is mixed with by above-mentioned prescription and aforesaid method injects the tubular vessel of lipstick formula while hot, after the cooling, promptly is frozen into bar-shaped solid adhesive of the present invention.
Claims (4)
1, a kind of solid adhesive, it is characterized in that it being that the colloid mixture of forming with polyvinyl butyral acetal, resol, Resins, epoxy and starch is a tackiness agent, with the mixed resultant of stearic acid, lauric acid, sodium hydroxide and potassium hydroxide be forming agent and tensio-active agent, with organic solvent.In addition, also added mineral filler.
2, according to the described solid adhesive of claim 1, it is characterized in that solvent is to select ethanol and acetone for use.
3, according to the described solid adhesive of claim 1, it is characterized in that mineral filler is to select lime carbonate for use.
4, as follows according to claim 1,2 and 3 described solid adhesives, its feature at the weight percent of various component contents:
Polyvinyl butyral acetal 12%-25%
Resol 4%-11%
Resins, epoxy 2.1%-8%
Stearic acid 3.6%-9%
Lauric acid 2.1%-7.5%
Sodium hydroxide 1.1%-2.3%
Potassium hydroxide 0.2%-1.8%
Ethanol 30%-40%
Acetone 6%-12%
Glycerine 0.3%-2.2%
Polyoxyethylene glycol 0.3%-2.5%
Sorbyl alcohol 0.3%-2.6%
Starch 0.7%-13%
Lime carbonate 0.6%-2.4%
Water 22%-32%
The summation of mentioned component content is 100%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89107611 CN1040813A (en) | 1989-09-30 | 1989-09-30 | Solid adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89107611 CN1040813A (en) | 1989-09-30 | 1989-09-30 | Solid adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1040813A true CN1040813A (en) | 1990-03-28 |
Family
ID=4857262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89107611 Pending CN1040813A (en) | 1989-09-30 | 1989-09-30 | Solid adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1040813A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100387379C (en) * | 2005-12-22 | 2008-05-14 | 株洲钻石切削刀具股份有限公司 | Plasticizer for ceramet production |
| CN1962516B (en) * | 2005-11-10 | 2010-12-01 | 上海鹏业化工材料有限公司 | Environment-friendly high temperature glass wool adhesive |
| CN101941217A (en) * | 2010-06-17 | 2011-01-12 | 扎兰屯同德木业有限责任公司 | Insulating wood laminating product and preparation method thereof |
| CN102827517A (en) * | 2012-09-14 | 2012-12-19 | 惠州艺都文化用品有限公司 | Polyethylene terephthalate (PET) film frosted glue |
| CN103450828A (en) * | 2013-09-23 | 2013-12-18 | 江苏华夏制漆科技有限公司 | Glue for coating brush and preparation method of glue |
| CN105244455A (en) * | 2015-09-08 | 2016-01-13 | 深圳电丰电子有限公司 | Anti-corrosion protective film for soft package lithium battery and preparation method and application thereof |
| CN105400471A (en) * | 2015-12-11 | 2016-03-16 | 苏州冰心文化用品有限公司 | Glue rod material capable of improving low-temperature glueyness and preparation method thereof |
| CN105925216A (en) * | 2016-07-15 | 2016-09-07 | 启东市临品农副产品专业合作社 | Solid adhesive |
| CN107458054A (en) * | 2017-08-31 | 2017-12-12 | 苏州仲勉装饰有限公司 | A kind of aluminum wood composite decorating board and preparation method thereof |
| CN108435508A (en) * | 2018-04-20 | 2018-08-24 | 余其姝 | One kind is for historical relic repairing and reinforcement device of engaging in archaeological studies |
| CN110280713A (en) * | 2019-08-02 | 2019-09-27 | 承德北雁新材料科技有限公司 | Bonding agent and its preparation method and application, resin-coated sand shell mould and preparation method thereof |
| CN114479719A (en) * | 2020-10-27 | 2022-05-13 | 龙岩市锐美家装饰材料有限公司 | Temperature-controlled stirring preparation process of food-grade adhesive |
-
1989
- 1989-09-30 CN CN 89107611 patent/CN1040813A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1962516B (en) * | 2005-11-10 | 2010-12-01 | 上海鹏业化工材料有限公司 | Environment-friendly high temperature glass wool adhesive |
| CN100387379C (en) * | 2005-12-22 | 2008-05-14 | 株洲钻石切削刀具股份有限公司 | Plasticizer for ceramet production |
| CN101941217A (en) * | 2010-06-17 | 2011-01-12 | 扎兰屯同德木业有限责任公司 | Insulating wood laminating product and preparation method thereof |
| CN101941217B (en) * | 2010-06-17 | 2011-11-16 | 扎兰屯同德木业有限责任公司 | Insulating wood laminating product and preparation method thereof |
| CN102827517A (en) * | 2012-09-14 | 2012-12-19 | 惠州艺都文化用品有限公司 | Polyethylene terephthalate (PET) film frosted glue |
| CN102827517B (en) * | 2012-09-14 | 2015-11-25 | 惠州艺都文化用品有限公司 | PET film frosted glue |
| CN103450828A (en) * | 2013-09-23 | 2013-12-18 | 江苏华夏制漆科技有限公司 | Glue for coating brush and preparation method of glue |
| CN103450828B (en) * | 2013-09-23 | 2015-08-19 | 江苏华夏制漆科技有限公司 | A kind of coating hairbrush glue and preparation method thereof |
| CN105244455A (en) * | 2015-09-08 | 2016-01-13 | 深圳电丰电子有限公司 | Anti-corrosion protective film for soft package lithium battery and preparation method and application thereof |
| CN105400471A (en) * | 2015-12-11 | 2016-03-16 | 苏州冰心文化用品有限公司 | Glue rod material capable of improving low-temperature glueyness and preparation method thereof |
| CN105400471B (en) * | 2015-12-11 | 2018-03-13 | 苏州冰心文化用品有限公司 | A kind of glue stick material for improving low temperature adhesivity and preparation method thereof |
| CN105925216A (en) * | 2016-07-15 | 2016-09-07 | 启东市临品农副产品专业合作社 | Solid adhesive |
| CN107458054A (en) * | 2017-08-31 | 2017-12-12 | 苏州仲勉装饰有限公司 | A kind of aluminum wood composite decorating board and preparation method thereof |
| CN108435508A (en) * | 2018-04-20 | 2018-08-24 | 余其姝 | One kind is for historical relic repairing and reinforcement device of engaging in archaeological studies |
| CN110280713A (en) * | 2019-08-02 | 2019-09-27 | 承德北雁新材料科技有限公司 | Bonding agent and its preparation method and application, resin-coated sand shell mould and preparation method thereof |
| CN114479719A (en) * | 2020-10-27 | 2022-05-13 | 龙岩市锐美家装饰材料有限公司 | Temperature-controlled stirring preparation process of food-grade adhesive |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |