CN104073102B - A kind of timber structure fire-proof powdery paint - Google Patents
A kind of timber structure fire-proof powdery paint Download PDFInfo
- Publication number
- CN104073102B CN104073102B CN201410249237.3A CN201410249237A CN104073102B CN 104073102 B CN104073102 B CN 104073102B CN 201410249237 A CN201410249237 A CN 201410249237A CN 104073102 B CN104073102 B CN 104073102B
- Authority
- CN
- China
- Prior art keywords
- parts
- timber structure
- structure fire
- proof
- powdery paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003973 paint Substances 0.000 title claims abstract description 24
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 17
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 16
- 239000002131 composite material Substances 0.000 claims abstract description 16
- 239000012757 flame retardant agent Substances 0.000 claims abstract description 15
- LQAQMOIBXDELJX-UHFFFAOYSA-N 2-methoxyprop-2-enoic acid Chemical compound COC(=C)C(O)=O LQAQMOIBXDELJX-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011256 inorganic filler Substances 0.000 claims abstract description 12
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 12
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 11
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 11
- -1 antimony halides Chemical class 0.000 claims abstract description 11
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 230000031709 bromination Effects 0.000 claims description 3
- 238000005893 bromination reaction Methods 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 11
- 239000011248 coating agent Substances 0.000 abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 238000005507 spraying Methods 0.000 abstract description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052793 cadmium Inorganic materials 0.000 abstract description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052804 chromium Inorganic materials 0.000 abstract description 3
- 239000011651 chromium Substances 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- 230000009970 fire resistant effect Effects 0.000 abstract description 3
- 238000011065 in-situ storage Methods 0.000 abstract description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052753 mercury Inorganic materials 0.000 abstract description 3
- 238000011109 contamination Methods 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 230000008859 change Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 125000001246 bromo group Chemical class Br* 0.000 description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical group NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Abstract
A kind of timber structure fire-proof powdery paint, belongs to technical field of coatings, and it includes the component of following parts by weight: methoxy acrylic acid resin 15 35 parts, P N composite flame-retardant agent 10 30 parts, inorganic filler 10 45 parts, aluminium hydroxide 10 18 parts, antimony halides 5 15 parts.The present invention, by the above-mentioned technology of employing, the fireproof coating obtained, solves solvent contamination environment and reduces the problem of Coating Durability, having reached environmentally friendly requirement.Soluble lead content≤90mg/kg in coating, soluble cadmium≤75mg/kg, soluble chromium≤60mg/kg, soluble mercury≤60mg/kg, and this flame-proof finishing system fire-resistant be 15min more than the limit, there is excellent decoration functions, water resistance, in-situ spraying workability simultaneously.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to the wood knot that a kind of Heat stability is good, fire retardant effect are good
Structure fire-proof powdery paint.
Background technology
Along with people's raising to quality of life, living environment is also required that more and more higher, the house of wooden structures, floor
Deng, accepted by increasing people.Due to wooden own, once breaking out of fire, propagation of flame is rapid, brings to fire extinguishing
Great difficulty, living environment and personal safety to people bring very big hidden danger.
Summary of the invention
For the above-mentioned problems in the prior art, it is an object of the invention to provide a kind of Heat stability is good, fire-retardant
The timber structure fire-proof powdery paint that flameproof effect is good.
Described a kind of timber structure fire-proof powdery paint, it is characterised in that include the component of following parts by weight:
Methoxy acrylic acid resin 15-35 part P-N composite flame-retardant agent 10-30 part inorganic filler 10-45 part hydrogen-oxygen
Change aluminum 10-18 part antimony halides 5-15 part.
Described a kind of timber structure fire-proof powdery paint, it is characterised in that include the component of following parts by weight:
Methoxy acrylic acid resin 20-30 part P-N composite flame-retardant agent 15-25 part inorganic filler 20-40 part hydrogen-oxygen
Change aluminum 12-16 part antimony halides 6-12 part.
Described a kind of timber structure fire-proof powdery paint, it is characterised in that include the component of following parts by weight:
Methoxy acrylic acid resin 24-28 part P-N composite flame-retardant agent 20-25 part inorganic filler 25-30 part hydrogen-oxygen
Change aluminum 14-16 part antimony halides 8-10 part.
Described a kind of timber structure fire-proof powdery paint, it is characterised in that also include tripolycyanamide 1-2 part.
Described a kind of timber structure fire-proof powdery paint, it is characterised in that described P-N composite flame-retardant agent is MPP.
Described a kind of timber structure fire-proof powdery paint, it is characterised in that described inorganic filler is Pulvis Talci, activated carbon
Acid calcium, wollastonite in powder or bentonite.
Described a kind of timber structure fire-proof powdery paint, it is characterised in that described antimony halides is antimony chloride or bromination antimony.
The present invention, by using above-mentioned technology, compared with prior art, has the advantages that
1) present invention is by introducing methoxyl group on acrylic resin, carries out composite modified to acrylic resin, modified
Acrylic resin, its adhesive force, resistance to water, weatherability, resistant to chemical media and thermostability etc. are more excellent, improve coating
Environmental-protection decorative barrier propterty；
2) present invention is by adding P-N composite flame-retardant agent, has preferable phosphorus nitrogen cooperative effect, high temperature resistant, thermally-stabilised
Property is good, and flame retardant effect is good；Simultaneously as it is the phosphate of a kind of alkalescence, the passivating film of densification can be formed on surface, be used for
In coating, there is again environmental-protection decorative function, the most inflatable and form the uniformly cellular or spongiform carbon of densification
Matter froth bed, froth bed has not only completely cut off oxygen, and has had good heat-proof quality because its quality is loose, can retardation heat
Amount is transmitted to be protected the speed of base material, avoids flame simultaneously and base material is protected in the direct attack of high temperature, plays efficient fire prevention
Thermal insulation protection effect；
3) present invention is by adding inorganic filler, and owing to inorganic filler itself is not fired, its heat conductivity is low, Ke Yiyan
Stagnant heat is transmitted to the speed of protected base material；Add aluminium hydroxide and effectively make the temperature reduction etc. of system；Add antimony halides,
There is dual flame retardant activity, make the combustion process of system and flame propagation velocity reduce, reach fire-retardant purpose；
4) fireproof coating that the present invention obtains, solves solvent contamination environment and reduces the problem of Coating Durability, reaching
Environmentally friendly requirement.Soluble lead content≤90mg/kg in coating, soluble cadmium≤75mg/kg, soluble chromium≤60mg/
Kg, soluble mercury≤60mg/kg, and this flame-proof finishing system fire-resistant be 15min more than the limit, there is excellent decoration merit simultaneously
Energy, water resistance, in-situ spraying workability.
Detailed description of the invention
The invention will be further described below:
1 one kinds of timber structure fire-proof powdery paints of embodiment, including the component of following parts by weight:
Methoxy acrylic acid resin 15 parts of MPP (melamine pyrophosphate), 25 parts of aluminium hydroxide of 30 parts of Pulvis Talci
10 parts of antimony chlorides 15 parts, above-mentioned component is sufficiently mixed uniformly, obtains the fire-proof powdery paint of the present invention, adds the water of 2 times amount
Stir, carry out spraying.
Inorganic filler activated Calcium carbonate, wollastonite in powder or bentonite replace Pulvis Talci, and antimony chloride bromination antimony replaces, all
Same technique effect can be obtained.
2 one kinds of timber structure fire-proof powdery paints of embodiment, including the component of following parts by weight:
25 parts of bentonite of 35 parts of P-N composite flame-retardant agents of methoxy acrylic acid resin, 14 parts of bromines of 10 parts of aluminium hydroxide
Change 5 parts of antimony.
3 one kinds of timber structure fire-proof powdery paints of embodiment, including the component of following parts by weight:
10 parts of wollastonites in powder of 20 parts of P-N composite flame-retardant agents of methoxy acrylic acid resin, 12 parts of bromines of 25 parts of aluminium hydroxide
Change 6 parts of antimony.
4 one kinds of timber structure fire-proof powdery paints of embodiment, including the component of following parts by weight:
30 parts of P-N composite flame-retardant agents of methoxy acrylic acid resin, 10 parts of aluminium hydroxide of 15 parts of activated Calcium carbonates 16 parts
Antimony chloride 12 parts, tripolycyanamide 2 parts.
5 one kinds of timber structure fire-proof powdery paints of embodiment, including the component of following parts by weight:
20 parts of wollastonites in powder of 28 parts of P-N composite flame-retardant agents of methoxy acrylic acid resin, 16 parts of bromines of 10 parts of aluminium hydroxide
Change 8 parts of antimony.
6 one kinds of timber structure fire-proof powdery paints of embodiment, including the component of following parts by weight:
24 parts of P-N composite flame-retardant agents of methoxy acrylic acid resin, 20 parts of aluminium hydroxide of 15 parts of activated Calcium carbonates 14 parts
Antimony chloride 10 parts, tripolycyanamide 1 part.
The performance test results of above-described embodiment 1-6 is as shown in table 1 below.
The performance test results of table 1 embodiment 1-6
As can be seen from the above table, content of beary metal≤90mg/kg in the coating of the present invention, soluble cadmium≤58mg/kg,
Soluble chromium≤49mg/kg, soluble mercury≤49mg/kg, powder flame-proof finishing system is fire-resistant is 15min more than the limit, simultaneously
There is excellent decoration functions, water resistance, in-situ spraying workability.
Claims (5)
1. a timber structure fire-proof powdery paint, it is characterised in that include the component of following parts by weight:
Methoxy acrylic acid resin 15-35 part P-N composite flame-retardant agent 10-30 part inorganic filler 10-45 part aluminium hydroxide
10-18 part antimony halides 5-15 part tripolycyanamide 1-2 part, described P-N composite flame-retardant agent is MPP.
A kind of timber structure fire-proof powdery paint the most according to claim 1, it is characterised in that include following parts by weight
Component:
Methoxy acrylic acid resin 20-30 part P-N composite flame-retardant agent 15-25 part inorganic filler 20-40 part aluminium hydroxide
12-16 part antimony halides 6-12 part.
A kind of timber structure fire-proof powdery paint the most according to claim 1, it is characterised in that include following parts by weight
Component:
Methoxy acrylic acid resin 24-28 part P-N composite flame-retardant agent 20-25 part inorganic filler 25-30 part aluminium hydroxide
14-16 part antimony halides 8-10 part.
A kind of timber structure fire-proof powdery paint the most according to claim 1, it is characterised in that described inorganic filler is for sliding
Stone powder, activated Calcium carbonate, wollastonite in powder or bentonite.
A kind of timber structure fire-proof powdery paint the most according to claim 1, it is characterised in that described antimony halides is chlorination
Antimony or bromination antimony.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410249237.3A CN104073102B (en) | 2014-06-06 | A kind of timber structure fire-proof powdery paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410249237.3A CN104073102B (en) | 2014-06-06 | A kind of timber structure fire-proof powdery paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104073102A CN104073102A (en) | 2014-10-01 |
| CN104073102B true CN104073102B (en) | 2016-11-30 |
Family
ID=
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4179535A (en) * | 1976-06-04 | 1979-12-18 | Battelle Memorial Institute | Method of forming a fire-resistant silicate coating |
| CN1786093A (en) * | 2005-11-30 | 2006-06-14 | 北京北航天汇科技孵化器有限公司 | Expansion type fire retarding epoxide resin powder paint suitable for steel structure and its preparation method |
| CN101885859A (en) * | 2009-05-11 | 2010-11-17 | 中国科学院化学研究所 | Flame retardant microcapsule and application thereof |
| CN102153937A (en) * | 2011-05-13 | 2011-08-17 | 惠东美新塑木型材制品有限公司 | Surface fireproof coating of wood plastic composite material and preparation method of surface fireproof coating |
| CN103540211A (en) * | 2013-09-30 | 2014-01-29 | 安徽华印机电股份有限公司 | Organosilicon modifying acrylic resin fireproof coating |
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4179535A (en) * | 1976-06-04 | 1979-12-18 | Battelle Memorial Institute | Method of forming a fire-resistant silicate coating |
| CN1786093A (en) * | 2005-11-30 | 2006-06-14 | 北京北航天汇科技孵化器有限公司 | Expansion type fire retarding epoxide resin powder paint suitable for steel structure and its preparation method |
| CN101885859A (en) * | 2009-05-11 | 2010-11-17 | 中国科学院化学研究所 | Flame retardant microcapsule and application thereof |
| CN102153937A (en) * | 2011-05-13 | 2011-08-17 | 惠东美新塑木型材制品有限公司 | Surface fireproof coating of wood plastic composite material and preparation method of surface fireproof coating |
| CN103540211A (en) * | 2013-09-30 | 2014-01-29 | 安徽华印机电股份有限公司 | Organosilicon modifying acrylic resin fireproof coating |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20161130 |