CN104072210B - Trace element fertilizer and its preparation method and application in a kind of multipurpose - Google Patents

Trace element fertilizer and its preparation method and application in a kind of multipurpose Download PDF

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Publication number
CN104072210B
CN104072210B CN201410287541.7A CN201410287541A CN104072210B CN 104072210 B CN104072210 B CN 104072210B CN 201410287541 A CN201410287541 A CN 201410287541A CN 104072210 B CN104072210 B CN 104072210B
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fertilizer
trace element
oxide
multipurpose
manganese
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CN104072210A (en
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陈文哲
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Shenzhen Batian Ecotypic Engineering Co Ltd
Guigang Batian Ecology Co Ltd
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Shenzhen Batian Ecotypic Engineering Co Ltd
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Abstract

The invention provides trace element fertilizer and its preparation method and application in a kind of multipurpose, consist of: ferrum oxide 20%~50%, manganese oxide 30%~70%, sulfur 5%~10%, citric acid 5%~10%, its summation is 100%.Can be combined according to the nutrient demand of soil and Different Crop.In the present invention, trace element fertilizer is when fertilizer wraps up, need not any binding agent, easy to use, effect is obvious, contains citric acid simultaneously, can improve the effectiveness of manganese, ferrum, zinc, magnesium, thus improve yield and the disease resistance ability of crop.

Description

Trace element fertilizer and its preparation method and application in a kind of multipurpose
Technical field
Invention relates to fertilizer field, particularly relates to trace element fertilizer and its preparation method and application in a kind of multipurpose.
Background technology
The present invention be the patent of invention to Patent No. ZL01210333504.6 " a kind of multiduty fertilizer synergist and Its preparation method and application " further improvement, this invention percentage includes the zinc oxide of 20%~30%, 30% ~the magnesium oxide of 40%, the Borax of 10%~25% or boric acid, the zinc sulfate of 5%~15% and 5%~the sulfur of 10%, it is impossible to Nutrient demand according to different soils and Different Crop carries out formula adjustment.The present invention improve provide one comprise ferrum oxide and The multipurpose element of manganese oxide is fertile, and for Wrapped fertilizer to meet the nutrient demand of Different Crop on different soils, effect is bright Aobvious.
Summary of the invention
It is an object of the invention to overcome the defect of prior art, it is provided that a kind of multipurpose element is fertile, utilizes ferrum oxide The package action excellent with manganese oxide, and addition citric acid is to improve manganese, ferrum, zinc and the effectiveness of magnesium, adds crop Yield and the quality that improve crop.
In order to realize foregoing invention purpose, the present invention adopts the following technical scheme that
A kind of multiduty middle trace element fertilizer, including ferrum oxide and manganese oxide.
Preferably, a kind of multiduty middle trace element fertilizer, also include sulfur, promote that the parcel of ferrum oxide and manganese oxide is made With.
Further preferably, the middle trace element fertilizer of a variety of applications, also include citric acid, by weight percentage, composition For: ferrum oxide 20%~50%, manganese oxide 30%~70%, sulfur 5%~10%, citric acid 5%~10%, its summation is 100%.
Or further preferably, a kind of multiduty middle trace element fertilizer, also include citric acid and the water of middle trace element Soluble inorganic compound, by weight percentage, consists of: ferrum oxide 15%~35%, manganese oxide 25%~55%, sulfur 5%~10%, citric acid 5%~10%, the water-soluble inorganic compound 20%~30% of middle trace element, its summation is 100%.
The water-soluble inorganic compound of described middle trace element includes Borax, boric acid, manganese chloride, zinc sulfate, manganese sulfate, sulfur Acid ferrous iron, ferrous chloride, magnesium sulfate or magnesium chloride.
Or further preferably, also include citric acid, the water-soluble inorganic compound of middle trace element, zinc oxide and oxidation Magnesium, percentage, consist of: the zinc oxide of 10%~20%, the magnesium oxide of 20%~25%, the oxygen of 10%~15% Change ferrum, the manganese oxide of 10%~20%, the sulfur of 5%~10%, the boric acid of 10%~15%, the zinc sulfate of 5%~10%, The manganese chloride of 5%~10%, 10%~15% magnesium sulfate, the citric acid of 5%~10%, its summation is 100%.
It is a further object of the present invention to provide the preparation method of trace element fertilizer in described multipurpose.
The preparation method of the multiduty middle trace element fertilizer of the present invention: grind after weighing according to formula, crosses 150~350 mesh Sieve, mix homogeneously, obtain middle trace element fertilizer.
It is a further object of the present invention to provide the application of trace element fertilizer in multipurpose.
The invention provides the application in fertilizer wraps up of a kind of multiduty middle trace element fertilizer, by described middle trace Element fertilizer is formed containing middle amount after mixing with carbamide, phosphorus ammonium granule, potassium chloride particle, compound fertilizer, Chemical Mixed Fertilizer or bulk blended fertilizer Or the carbamide of trace element, phosphorus ammonium granule, potassium chloride particle, compound fertilizer, Chemical Mixed Fertilizer or Bulk Blending Fertilizer.
It addition, the invention provides the application in fertigation of a kind of multiduty middle trace element fertilizer, described in micro- Secondary element fertilizer grinds after weighing according to formula, crosses the sieve of 200~350 mesh, dilutes 250~350 times.
Described middle trace element fertilizer can be used for fertilizer coating agent, foliage-spray or fertigation.
Preferably, in described multipurpose trace element fertilizer at the carbamide containing middle trace element, phosphorus ammonium granule, potassium chloride Percentage by weight in grain, compound fertilizer, Chemical Mixed Fertilizer or Bulk Blending Fertilizer is 0.1%~3.5%.Described middle trace element fertilizer and carbamide, Formed containing middle amount or micro-after phosphorus ammonium granule, potassium chloride particle, compound fertilizer, complex fertilizer or the mixing of bulk blended fertilizer uniform stirring The carbamide of secondary element, phosphorus ammonium granule, potassium chloride particle, compound fertilizer, Chemical Mixed Fertilizer or Bulk Blending Fertilizer.In the present invention, micro element fertilizer is applied to Need not add binding agent during fertilizer parcel, easy to use, and compounding after fertilizer 100% be all the nutrient needed for crop, Can well supplement the middle trace element taken away by crop in soil.
Preferably, when described middle trace element fertilizer is applied to foliage-spray, cross 200~350 mesh sieve, dilution 1000~ 3000 times.
In fertilizer such as carbamide, phosphorus ammonium granule, potassium chloride particle, compound fertilizer, complex fertilizer, the mistake of production of bulk blended fertilizer Cheng Zhong, by trace element fertilizer in multipurpose of the present invention by a certain percentage with carbamide, phosphorus ammonium granule, potassium chloride particle, compound fertilizer, The fertilizer uniform stirring such as complex fertilizer, bulk blended fertilizer, need not any binding agent.Execute at foliage-spray and the present invention is used for multiple use In Tu, trace element fertilizer dilution 1000~3000 times sprays.When fertigation, the present invention is used for the fertilizer of multiple use Material synergist mixes with fertilizer by a certain percentage or is administered alone, and dilutes 250-350 times in conjunction with facility and is administered.
The present invention is relative to the beneficial effect of prior art:
(1) in the present invention, trace element fertilizer can carry out formula adjustment according to different soils, Different Crop, and formula is flexible, makes With convenient.
(2) when in the present invention, trace element fertilizer is as the coating agent of fertilizer, need not any binding agent, easy to use.
(3) in the present invention, trace element fertilizer both can be as the coating agent of fertilizer, again can be as foliage fertilizer or irrigation fertilizer, letter Easy operation.
(4) in the present invention, trace element fertilizer contains citric acid, can improve the effectiveness of manganese, ferrum, zinc, magnesium, thus improve The yield of crop and disease resistance ability.
Detailed description of the invention
In multipurpose of the present invention, trace element fertilizer is by ferrum oxide, manganese oxide, zinc oxide, magnesium oxide, sulfur, Borax, boric acid, The different types of middle trace element such as manganese chloride, zinc sulfate, manganese sulfate, ferrous sulfate, ferrous chloride, magnesium sulfate or magnesium chloride are pressed Certain proportion mixed preparing together, provides amount or trace element in crop magnesium, sulfur, zinc, boron, ferrum, manganese etc. respectively, the most permissible Increase the yield of crop, it is also possible to improve quality and the resistance of crop.
In order to preferably explain the practicality of the present invention, illustrating, the scope of the present invention is not limited.Hereinafter own Numerical value in embodiment refers to weight ratio.
Embodiment 1
By weight percentage, consisting of manganese oxide 60%, ferrum oxide 40%, every kind of raw material crosses 200 mesh sieves, uniformly respectively Mixing, obtains a kind of multiduty containing manganese, the trace element fertilizer of ferrum.
Within 3 minutes, obtain being enclosed with fertilizer with the trace element fertilizer in embodiment 1 and compound fertilizer (15-15-15) uniform stirring The compound fertilizer of synergist, the weight of trace element fertilizer is the 0.2% of compound fertilizer (15-15-15) weight.And trace will be enclosed with The fertile compound fertilizer of element with do not wrap up the compound fertilizer of trace element fertilizer respectively to potato fertilization of the same area, fertilising time Number and time are homogeneously same.Potato yield, starch and disease resistance ability compare, and result is as shown in table 1:
Table 1
Embodiment 2
By weight percentage, ferrum oxide 20%, manganese oxide 70%, sulfur 5%, citric acid 5% are consisted of.Every kind of raw material Cross 150 mesh sieves respectively, uniformly mix, obtain a kind of multiduty containing manganese, ferrum, the middle trace element fertilizer of sulfur.
In within 1 minute, being enclosed with the middle trace element fertilizer in embodiment 2 and compound fertilizer (15-15-15) uniform stirring The compound fertilizer of trace element, the weight of middle trace element fertilizer is the 0.1% of compound fertilizer (15-15-15) weight.And will be enclosed with The compound fertilizer of middle trace element fertilizer be not enclosed with the compound fertilizer (15-15-15) of middle trace element fertilizer respectively to equal area Potato fertilization, fertilizer application frequency and time homogeneously with.Potato yield, starch and disease resistance ability compare, result such as table 2 institute Showing: comparative example 1, it is seen that add citric acid, improve crop yield, crop disease-resistant evil ability strengthens.
Table 2
Embodiment 3
By weight percentage, ferrum oxide 20%, manganese oxide 35%, zinc sulfate 30%, sulfur 10%, citric acid are consisted of 5%.150 mesh sieves crossed respectively by every kind of raw material, uniformly mix, obtain a kind of multiduty containing manganese, ferrum, zinc, the middle trace element of sulfur Fertile.
In within 2 minutes, being enclosed with the middle trace element fertilizer in embodiment 3 and Bulk Blending Fertilizer (26-12-10) uniform stirring The bulk blended fertilizer of trace element, this bulk blended fertilizer is blended according to a certain percentage by carbamide, particle phosphorus ammonium and granule potassium chloride and forms, The weight of middle trace element fertilizer is the 0.15% of Bulk Blending Fertilizer (26-12-10) weight.And the compound of middle trace element fertilizer will be enclosed with Fertilizer be not enclosed with the Bulk Blending Fertilizer (26-12-10) of middle trace element fertilizer respectively to identical wheat fertilizing, fertilizer application frequency and time The most identical.Table 3 is that wheat yield, crude protein content and disease resistance capability result compare, and result is as shown in table 3:
Table 4
Embodiment 4
By weight percentage, ferrum oxide 25%, manganese oxide 25%, sulfur 10%, magnesium sulfate 30%, citric acid are consisted of 10%, 350 mesh sieves crossed respectively by every kind of raw material, uniformly mix, obtain a kind of multiduty containing manganese, ferrum, sulfur, the middle trace element of magnesium Fertile.
Middle trace element fertilizer in embodiment 3 is when foliage-spray, and every mu of consumption is 20 grams, and the weight of water is middle trace 3000 times of element fertilizer weight, spray after stirring with water.And with compound fertilizer (15-6-8) respectively to Herba Spinaciae of the same area Apply fertilizer, on the basis of identical conventional fertilizer application, spray 3 times.Table 3 is Herba Spinaciae yield, Vitamin C content and disease resistance ability Relatively, result is as shown in table 3:
Table 5
Embodiment 5:
By weight percentage, zinc oxide 10%, magnesium oxide 25%, ferrum oxide 10%, manganese oxide 10%, sulfur are consisted of 5%, boric acid 10%, zinc sulfate 5%, manganese chloride 5%, magnesium sulfate 15%, citric acid 5%.200 mesh sieves crossed respectively by every kind of raw material, Uniformly mixing, obtains a kind of multiduty containing manganese, ferrum, boron, sulfur, magnesium, the middle trace element fertilizer of zinc.
Middle trace element fertilizer in embodiment 5 is when fertigation, equal with the compound fertilizer (15-15-15) of good water solubility Even be dissolved in water after obtain irrigate fertilizer.In field test, the middle trace element fertilizer of embodiment 5 is designated as A.Another one contains middle trace The fertilizer of element is designated as B, and its component is zinc oxide 10%, magnesium oxide 25%, ferrum oxide 10%, manganese oxide 10%, sulfur 10%, Boric acid 10%, zinc sulfate 5%, manganese chloride 5%, magnesium sulfate 15%.First group of good water solubility being not add middle trace element fertilizer Compound fertilizer (15-15-15), second group be the compound fertilizer (15-15-15) of the good water solubility adding A, the 3rd group be the water solublity adding B Good compound fertilizer (15-15-15), the weight of A and B is all the 1% of the compound fertilizer (15-15-15) of good water solubility, and it is right to be respectively used to Citrullus vulgaris fertigation of the same area, fertilizer application frequency and time are homogeneously the yield of watermelon, soluble sugar content and disease-resistant with, table 5 Evil ability compares, and result is as shown in table 5, it is seen that adds and adds the yield of Citrullus vulgaris, soluble sugar content and disease-resistant after citric acid Evil ability.
Table 5
Embodiment 6:
Zinc oxide 10%, magnesium oxide 20%, ferrum oxide 15%, manganese oxide 10%, sulfur 10%, boric acid 15%, zinc sulfate 5%, manganese chloride 5%, magnesium sulfate 10%, citric acid 5%.200 mesh sieves crossed respectively by every kind of raw material, uniformly mix, obtain one many Purposes containing zinc, manganese, ferrum, boron, sulfur, the middle trace element fertilizer of magnesium.
Middle trace element fertilizer in embodiment 6 is when fertigation, equal with the compound fertilizer (15-15-15) of good water solubility Even be dissolved in water after obtain irrigate fertilizer.The weight of middle trace element fertilizer is compound fertilizer (15-15-15) weight of good water solubility 1.5%.It is not added with the compound fertilizer (15-15-15) of the good water solubility of middle trace element fertilizer and adds the water solublity of middle trace element fertilizer Good compound fertilizer (15-15-15) is respectively used to Fructus Cucumidis sativi fertigation of the same area, fertilizer application frequency and time homogeneously same, table 6 Comparing for cucumber yield, soluble sugar content and disease resistance ability, result is as shown in table 6.
Table 6
Embodiment 7:
Zinc oxide 10%, magnesium oxide 20%, ferrum oxide 10%, manganese oxide 10%, sulfur 5%, boric acid 10%, zinc sulfate 5%, manganese chloride 10%, magnesium sulfate 10%, citric acid 10%.150 mesh sieves crossed respectively by every kind of raw material, uniformly mix, obtain one Multiduty containing zinc, manganese, ferrum, boron, sulfur, the middle trace element fertilizer of magnesium.
In within 2 minutes, being enclosed with compound fertilizer (15-15-15) uniform stirring with the middle trace element fertilizer of embodiment 7 micro- The compound fertilizer of secondary element, the weight of middle trace element fertilizer is the 3.5% of compound fertilizer (15-15-15) weight.And in being enclosed with The compound fertilizer of trace element fertilizer be not enclosed with the compound fertilizer (15-15-15) of middle trace element fertilizer respectively to of the same area Fructus Lycopersici esculenti is applied fertilizer, and fertilizer application frequency and time are homogeneously same.Tomato yield, vitamin C and disease resistance ability compare, and result is as shown in table 7.
Table 7
The announcement of book and teaching according to the above description, those skilled in the art in the invention can also be to above-mentioned embodiment party Formula changes and revises.Therefore, the invention is not limited in detailed description of the invention disclosed and described above, to the present invention's Some modifications and changes should also be as falling in the scope of the claims of the present invention.Although additionally, this specification using Some specific terms, but these terms are merely for convenience of description, the present invention does not constitute any restriction.

Claims (7)

1. trace element fertilizer in a multipurpose, it is characterised in that include ferrum oxide, manganese oxide, sulfur and citric acid, with weight Percentages, consists of: ferrum oxide 20%~50%, manganese oxide 30%~70%, sulfur 5%~10%, citric acid 5%~ 10%, its summation is 100%.
2. trace element fertilizer in a multipurpose, it is characterised in that include ferrum oxide, manganese oxide, sulfur, citric acid, middle trace The water-soluble inorganic compound of element, by weight percentage, consists of: ferrum oxide 15%~35%, manganese oxide 25%~ 55%, sulfur 5%~10%, citric acid 5%~10%, the water-soluble inorganic compound 20%~30% of middle trace element, its Summation is 100%.
Trace element fertilizer in multipurpose the most according to claim 2, it is characterised in that the water solublity of described middle trace element Inorganic compound includes Borax, boric acid, manganese chloride, zinc sulfate, manganese sulfate, ferrous sulfate, ferrous chloride, magnesium sulfate or magnesium chloride In one or more mixing.
4. trace element fertilizer in a multipurpose, it is characterised in that include ferrum oxide, manganese oxide, sulfur, citric acid, middle trace The water-soluble inorganic compound of element, zinc oxide and magnesium oxide, percentage, consist of: the oxidation of 10%~20% Zinc, the magnesium oxide of 20%~25%, the ferrum oxide of 10%~15%, the manganese oxide of 10%~20%, the sulfur of 5%~10%, The boric acid of 10%~15%, the zinc sulfate of 5%~10%, the manganese chloride of 5%~10%, 10%~15% magnesium sulfate, 5%~ The citric acid of 10%, its summation is 100%.
5. the preparation method of trace element fertilizer in a kind of multipurpose that one of Claims 1-4 is described, it is characterised in that: according to Formula grinds after weighing, and crosses the sieve of 150~350 mesh, mix homogeneously, obtains trace element fertilizer in multipurpose.
6. trace element fertilizer application in fertilizer wraps up in a kind of multipurpose that one of Claims 1-4 is described, its feature exists In: trace element fertilizer and carbamide, phosphorus ammonium granule, potassium chloride particle, compound fertilizer, complex fertilizer or Bulk Blending Fertilizer in described multipurpose Formed containing the carbamide of middle trace element, phosphorus ammonium granule, potassium chloride particle, compound fertilizer, Chemical Mixed Fertilizer or Bulk Blending Fertilizer after material mixing.
Application the most according to claim 6, it is characterised in that in described multipurpose, trace element fertilizer is containing middle trace unit Element carbamide, phosphorus ammonium granule, potassium chloride particle, compound fertilizer, Chemical Mixed Fertilizer or Bulk Blending Fertilizer in percentage by weight be 0.1%~ 3.5%.
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CN104446990A (en) * 2014-11-25 2015-03-25 营口菱镁化工集团有限公司 High-efficiency slow-release type granular magnesium sulfate and preparation method thereof
CN105110890B (en) * 2015-07-31 2019-05-03 深圳市芭田生态工程股份有限公司 A kind of anti-caking fertilizer and preparation method thereof
CN105110892B (en) * 2015-07-31 2019-04-05 深圳市芭田生态工程股份有限公司 A kind of a great number of elements Water soluble fertilizer and preparation method thereof

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CN1800115A (en) * 2006-01-26 2006-07-12 中国农业大学 Composite long-acting iron fertilizer, its preparation method and uses
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CN102368910A (en) * 2009-02-03 2012-03-07 钱德里卡·瓦拉达查里 Micronutrient fertilizers and methods of making and using the same
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CN102850124A (en) * 2012-09-04 2013-01-02 深圳市芭田生态工程股份有限公司 Sulphate-potassium magnesium fertilizer and preparation method thereof
CN102850129A (en) * 2012-09-11 2013-01-02 深圳市芭田生态工程股份有限公司 Multipurpose fertilizer synergistic agent, and preparation method and application thereof
CN102898244A (en) * 2012-11-08 2013-01-30 广西新方向化学工业有限公司 Polybasic chelate fertilizer synergist
CN103159532A (en) * 2011-12-08 2013-06-19 东北林业大学 Porous lignin particle composite fertilizer preparation method
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CN1040975A (en) * 1988-09-09 1990-04-04 谢宏年 The leaf fertilizer and the making method of controlling plant diseases
CN1800115A (en) * 2006-01-26 2006-07-12 中国农业大学 Composite long-acting iron fertilizer, its preparation method and uses
CN102368910A (en) * 2009-02-03 2012-03-07 钱德里卡·瓦拉达查里 Micronutrient fertilizers and methods of making and using the same
CN102126873A (en) * 2011-04-14 2011-07-20 石家庄正中科技有限公司 Special trace element fertilizer and preparation method thereof
CN103159532A (en) * 2011-12-08 2013-06-19 东北林业大学 Porous lignin particle composite fertilizer preparation method
CN102584385A (en) * 2012-01-11 2012-07-18 深圳中航资源有限公司 Preparation method of anti-aging, long-acting and multifunctional phosphate fertilizer
CN102850124A (en) * 2012-09-04 2013-01-02 深圳市芭田生态工程股份有限公司 Sulphate-potassium magnesium fertilizer and preparation method thereof
CN102850129A (en) * 2012-09-11 2013-01-02 深圳市芭田生态工程股份有限公司 Multipurpose fertilizer synergistic agent, and preparation method and application thereof
CN102898244A (en) * 2012-11-08 2013-01-30 广西新方向化学工业有限公司 Polybasic chelate fertilizer synergist
CN103819261A (en) * 2013-11-06 2014-05-28 马鞍山科邦生态肥有限公司 Soil regulating type fertilizer and preparation method thereof

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