CN104072090A - Porous ceramic - Google Patents
Porous ceramic Download PDFInfo
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- CN104072090A CN104072090A CN201410303283.7A CN201410303283A CN104072090A CN 104072090 A CN104072090 A CN 104072090A CN 201410303283 A CN201410303283 A CN 201410303283A CN 104072090 A CN104072090 A CN 104072090A
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- waste ceramic
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Abstract
The invention discloses porous ceramic using waste ceramic as a raw material. The porous ceramic comprises a binder and waste ceramic, wherein the binder is magnesium oxychloride cement, and comprises the following components: magnesium oxychloride, magnesium chloride and a modifier; the weight ratio of the binder to the waste ceramic is 1:6. The waste ceramic is utilized as a filler; the magnesium oxychloride cement is taken as a cementing material; the porous ceramic with certain strength and stability can be formed without high-temperature firing; the porous ceramic not only has the advantages of low raw material price, simple and feasible production process, and low energy consumption, but also well utilizes local resources to change the waste ceramic into treasures; not only can the target of saving energy and reducing emission of buildings be solved, but also the environment pollution caused by the waste ceramic is reduced; the principle of sustainable development is accorded.
Description
Technical field
The present invention relates to a kind of material of construction, be specifically related to a kind of porous ceramics.
Background technology
At present, porous ceramics is to be generally major ingredient by high quality raw material such as emergy, silicon carbide, trichroites, be equipped with the component such as binding agent and pore former and burn till through high temperature, in production, exist that process complexity and processing condition are wayward, efficiency is low, cost is high, the problem such as starting material and article shape is restricted, process energy consumption large, heavy contamination.In addition, in Ceramic Production, use procedure, can be accompanied by and produce a large amount of discarded pottery or unacceptable products, thereby can cause serious environmental pollution and the wasting of resources.
If can recycle discarded ceramic making porous ceramics, can either reach the object of simplifying technique, reducing costs and can reach energy-saving and emission-reduction, protection of the environment.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of porous ceramics, it adopts following technical scheme to realize:
A kind of porous ceramics, is characterized in that, comprise binding agent and waste ceramic, described binding agent is magnesia cement, and described waste ceramic is particulate state, and described binding agent and waste ceramic weight ratio are 1:6.
Described magnesia cement is made up of following parts by weight component: magnesium oxychloride 80-90, magnesium chloride solution 45-55, phosphoric acid 2-3, wooden calcium 1-2.
Described magnesium chloride solution degree Beaume is 26-28 degree/20 DEG C.
Described waste ceramic is factory's electroceramics waste product, and waste ceramic grain diameter is 5-10mm, waste ceramic particle silt content≤0.5%, waste ceramic particle crush values≤10%.
beneficial effect:compared with prior art, the invention has the advantages that: the present invention utilizes discarded pottery as filler, taking magnesia cement as consolidating material, do not need can form the porous ceramics with some strength, stability through high-temperature firing, not only there are the prices of raw and semifnished materials cheap, production technique is simple, the advantage that energy consumption is low, and well utilize local resources, discarded pottery is turned waste into wealth, can not only solve the target that building energy-saving reduces discharging, also reduce the pollution of waste ceramic to environment, meet continuable development principle.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment mono-:
Be 80 parts of magnesium oxychlorides by parts by weight, 45 parts of magnesium chloride solutions, 2 parts of phosphoric acid, 1 part of mixing of wooden calcium, 20 DEG C time, magnesium chloride solution degree Beaume is 26 degree, stirs and makes binding agent; To be ground into particulate state from factory's electroceramics waste product, grain diameter is 5mm, controls porcelain particle silt content≤0.5%, particle crush values≤10%; Just binding agent and waste ceramic particle, by weight for 1:6 mixes, stir, and pour in mould, and bubble is removed in vibration, after 6h is curing, from mould taking-up, both required porous ceramics.
Embodiment bis-:
Substantially the same manner as Example 1, difference is, 85 parts of magnesium oxychlorides, and 50 parts of magnesium chloride solutions, 2.5 parts of phosphoric acid, 1.5 parts of wooden calcium, 20 DEG C time, magnesium chloride solution degree Beaume is 27 degree, waste ceramic grain diameter is 8mm.
Embodiment tri-:
Substantially the same manner as Example 1, difference is, 90 parts of magnesium oxychlorides, and 55 parts of magnesium chloride solutions, 3 parts of phosphoric acid, 2 parts of wooden calcium, 20 DEG C time, magnesium chloride solution degree Beaume is 28 degree, waste ceramic grain diameter is 10mm.
Detect data in table 1.
Table 1 detects data
? | Percentage of open area/% | Unit weight/kgm -3 | Ultimate compression strength | Set time |
Embodiment 1 | 30.1 | 634 | 4.75 | 6h |
Embodiment 2 | 29.3 | 647 | 5.23 | 6h |
Embodiment 3 | 28.5 | 663 | 6.49 | 6h |
Common porous ceramics | 28-40 | 675-900 | 3.50-4.5 | ? |
detection method is GB 1964-1980 " porous ceramics compressive strength test method " and GB/T 1966-1996 " Porosity of Porous Ceramics, capacity test method ".
Claims (7)
1. a porous ceramics, is characterized in that, comprises binding agent and waste ceramic, and described binding agent is magnesia cement, and described waste ceramic is particulate state, and described binding agent and waste ceramic weight ratio are 1:6.
2. a kind of porous ceramics according to claim 1, is characterized in that, described magnesia cement is made up of following parts by weight: magnesium oxychloride 80-90 part, magnesium chloride solution 45-55 part, phosphoric acid 2-3 part, wooden calcium 1-2 part.
3. a kind of porous ceramics according to claim 2, is characterized in that, described magnesium chloride solution degree Beaume is 26-28 degree/20 DEG C.
4. a kind of porous ceramics according to claim 1, is characterized in that, described waste ceramic is factory's electroceramics waste product.
5. a kind of porous ceramics according to claim 1, is characterized in that, described waste ceramic grain diameter is 5-10mm.
6. a kind of porous ceramics according to claim 1, is characterized in that, described waste ceramic particle silt content≤0.5%.
7. a kind of porous ceramics according to claim 1, is characterized in that, described waste ceramic particle crush values≤10%.
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CN201410303283.7A CN104072090B (en) | 2014-06-30 | 2014-06-30 | A kind of porous ceramics |
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CN201410303283.7A CN104072090B (en) | 2014-06-30 | 2014-06-30 | A kind of porous ceramics |
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CN104072090A true CN104072090A (en) | 2014-10-01 |
CN104072090B CN104072090B (en) | 2016-08-24 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3951885A (en) * | 1971-11-01 | 1976-04-20 | Thompson Chemicals, Inc. | Method of making magnesium oxychloride cement cofoamed with synthetic resin |
CN1962554A (en) * | 2005-11-07 | 2007-05-16 | 环境技术公司 | Porous ceramic and method for manufacturing the same |
CN101186519A (en) * | 2007-12-14 | 2008-05-28 | 华南理工大学 | Porous ceramic material and preparation method thereof |
CN103204663A (en) * | 2012-01-12 | 2013-07-17 | 广东东鹏控股股份有限公司 | Artificial stone made through using solid waste residues |
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2014
- 2014-06-30 CN CN201410303283.7A patent/CN104072090B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3951885A (en) * | 1971-11-01 | 1976-04-20 | Thompson Chemicals, Inc. | Method of making magnesium oxychloride cement cofoamed with synthetic resin |
CN1962554A (en) * | 2005-11-07 | 2007-05-16 | 环境技术公司 | Porous ceramic and method for manufacturing the same |
CN101186519A (en) * | 2007-12-14 | 2008-05-28 | 华南理工大学 | Porous ceramic material and preparation method thereof |
CN103204663A (en) * | 2012-01-12 | 2013-07-17 | 广东东鹏控股股份有限公司 | Artificial stone made through using solid waste residues |
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CN104072090B (en) | 2016-08-24 |
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