CN104072011A - Alkali-free concrete liquid quick-setting reinforcing agent - Google Patents

Alkali-free concrete liquid quick-setting reinforcing agent Download PDF

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Publication number
CN104072011A
CN104072011A CN201410339104.5A CN201410339104A CN104072011A CN 104072011 A CN104072011 A CN 104072011A CN 201410339104 A CN201410339104 A CN 201410339104A CN 104072011 A CN104072011 A CN 104072011A
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China
Prior art keywords
alkali
free
reinforcing agent
setting reinforcing
liquid quick
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CN201410339104.5A
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Chinese (zh)
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CN104072011B (en
Inventor
潘智伟
秦满义
杨存义
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Shanxi Geruite construction Polytron Technologies Inc
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SHANXI GERUITE BUILDING TECHNOLOGY Co Ltd
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Priority to CN201410339104.5A priority Critical patent/CN104072011B/en
Publication of CN104072011A publication Critical patent/CN104072011A/en
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Abstract

An alkali-free concrete liquid quick-setting reinforcing agent is prepared from the following material compositions in percentage by weight: 15% to 32.5% of aluminum sulfate, 1.5% to 5% of alcohol amine, 0.25% to 1% of magnesium silicate, 7.5% to 10% of amorphous aluminum hydroxide, 0.5% to 5% of formic acid, 0.5% to 1.5% of oxalic acid, 1.5% to 2.5% of quasi-boehmite, 5% to 10% of polyethylene diol, 0.05% to 0.15% of amide, and 50% of water. The alkali-free concrete liquid quick-setting reinforcing agent has the benefits that the alkali-free concrete liquid quick-setting reinforcing agent is a liquid, good in solubility, and strong in stability, and can be stored for a long time; the early strength can be grown rapidly, the strength in one day is more than 8MP, the loss of strength in 28 days can be avoided, and particularly the alkali-free concrete liquid quick-setting reinforcing agent can increase strength of types of cements by 10% to 30%; the alkali-free concrete liquid quick-setting reinforcing agent is totally chlorine-free, alkali-free and non-toxic, free of corrosion to steel, and small in mixing amount, and can enable the setting of the concrete to be quick.

Description

Concrete alkali-free liquid rapid hardening toughener
Technical field
The present invention relates to a kind of concrete additive, be specifically related to a kind of alkali-free and can make concrete rapid hardening and carry high-intensity additive.
Technical background
China carries out JC477-2005 " sprayed concrete accelerating chemicals " standard since on August 1st, 2005, has wherein added technical requirements, the experimental technique of liquid accelerator.Thereby embodied the development trend of accelerating chemicals, changed to liquid accelerator by solid powdery accelerating chemicals, at present, the liquid accelerator on market has the certain defect of self: place easily precipitation, cause Quality Down; Alkali content is too high, and corrosion reinforcing bar damages excessively to people, concrete strength is also had to bad impact; Volume is excessive, causes concrete indices all defective; High cost, unsuitable production in enormous quantities.
Summary of the invention
The object of the invention is to overcome the deficiency of currently available products, provides a kind of alkali-free rapid hardening to be conducive to improve the concrete alkali-free liquid rapid hardening toughener of concrete strength.
The technical solution used in the present invention is: a kind of concrete alkali-free liquid rapid hardening toughener, by Tai-Ace S 150, hydramine, Magnesium Silicate q-agent, unformed aluminium hydroxide, formic acid, oxalic acid, pseudo-boehmite, polyoxyethylene glycol, acid amides and water composition, it is characterized in that: the mass percent of preparing material therefor composition is: Tai-Ace S 150 15%~32.5%, acid amides 1.5%~5%, Magnesium Silicate q-agent 0.25%~1%, unformed aluminium hydroxide 7.5%~10%, formic acid 0.5%~5%, oxalic acid 0.5%~1.5%, pseudo-boehmite 1.5%~2.5%, polyoxyethylene glycol 5%~10%, acid amides 0.05%~0.15%, water 50%.
The invention has the beneficial effects as follows:
1. the present invention is liquid, and solvability is good, and stability is strong, and the shelf time is long.
2. early strength rapid development, 1 day intensity is all more than 8MP, and intensity free of losses in 28 days, even improves 10%~30% to some strength of cement.
3. totally chlorine free, alkali-free, nontoxic, corrosion-free to reinforcing bar.
4. volume is little, makes concrete coagulation fast.
Embodiment
Further illustrate the present invention below by embodiment.
Embodiment 1
The concrete alkali-free liquid rapid hardening toughener of preparing according to following weight per-cent: Tai-Ace S 150 22.5%, hydramine 4%, Magnesium Silicate q-agent 0.95%, unformed aluminium hydroxide 9%, formic acid 4%, oxalic acid 0.5%, pseudo-boehmite 1.5%, polyoxyethylene glycol 7.5%, acid amides 0.05%, water 50%.Present method can rapid coagulation in the situation that volume is little.
Embodiment 2
Tai-Ace S 150 25%, hydramine 4%, Magnesium Silicate q-agent 0.95%, unformed aluminium hydroxide 7.5%, formic acid 1%, oxalic acid 0.5%, pseudo-boehmite 2.5%, polyoxyethylene glycol 8.5%, acid amides 0.05%, water 50%.Present method is conducive to late strength of concrete and strengthens to some extent.
Embodiment 3
Tai-Ace S 150 30%, hydramine 1.5%, Magnesium Silicate q-agent 0.45%, unformed aluminium hydroxide 8%, formic acid 3%, oxalic acid 0.5%, pseudo-boehmite 1.5%, polyoxyethylene glycol 5%, acid amides 0.05%, water 50%.Present method is conducive to concrete strength enhancing in early stage.
The present embodiment and commercially available sample contrast table
? Initial set/min Final set/min 1d intensity/MPa 28d intensity/MPa
Example 1 2:10 6:20 7.9 78.6
Example 2 3:20 7:40 7.7 79.4
Example 3 2:50 7:10 8.4 78.8
Commercially available sample 4:00 9:15 7.1 75.5

Claims (1)

1. a concrete alkali-free liquid rapid hardening toughener, by Tai-Ace S 150, hydramine, Magnesium Silicate q-agent, unformed aluminium hydroxide, formic acid, oxalic acid, pseudo-boehmite, polyoxyethylene glycol, acid amides and water composition, it is characterized in that: the mass percent of preparing material therefor composition is: Tai-Ace S 150 15%~32.5%, acid amides 1.5%~5%, Magnesium Silicate q-agent 0.25%~1%, unformed aluminium hydroxide 7.5%~10%, formic acid 0.5%~5%, oxalic acid 0.5%~1.5%, pseudo-boehmite 1.5%~2.5%, polyoxyethylene glycol 5%~10%, acid amides 0.05%~0.15%, water 50%.
CN201410339104.5A 2014-07-11 2014-07-11 Concrete alkali-free liquid rapid hardening reinforcing agent Active CN104072011B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410339104.5A CN104072011B (en) 2014-07-11 2014-07-11 Concrete alkali-free liquid rapid hardening reinforcing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410339104.5A CN104072011B (en) 2014-07-11 2014-07-11 Concrete alkali-free liquid rapid hardening reinforcing agent

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CN104072011A true CN104072011A (en) 2014-10-01
CN104072011B CN104072011B (en) 2016-07-06

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109437654A (en) * 2018-12-11 2019-03-08 湖北腾辰科技股份有限公司 A kind of preparation method of enhanced alkali-free liquid accelerator
CN109761532A (en) * 2019-01-21 2019-05-17 江苏奥莱特新材料股份有限公司 The low rebound of one kind, high early-strength alkali-free liquid accelerator and preparation method thereof
CN110963741A (en) * 2019-12-27 2020-04-07 芜湖弘马新材料有限公司 Early-strength powdery alkali-free liquid accelerator core master batch and preparation method and application thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001042165A2 (en) * 1999-12-08 2001-06-14 Mbt Holding Ag Preparation of concrete accelerator
WO2006074739A1 (en) * 2005-01-14 2006-07-20 Construction Research & Technology Gmbh Liquid accelerator
CN101182139A (en) * 2007-11-12 2008-05-21 华南理工大学 Masonry cement having higher strength and water retention
CN101423356A (en) * 2008-11-20 2009-05-06 同济大学 Environment-friendly type alkali-free liquid accelerator for sprayed concrete and preparation method thereof
CN101489958A (en) * 2006-07-14 2009-07-22 建筑研究和技术有限公司 Stable shotcrete accelerator dispersion with high content in active matter
CN102249592A (en) * 2011-06-01 2011-11-23 中国水利水电科学研究院 Alkali-free chlorine-free high-early-strength liquid accelerator and preparation method thereof
CN102531452A (en) * 2010-12-10 2012-07-04 苏笮斌 Anti-corrosion anti-cracking reinforcing agent composition and preparation method thereof
CN102992677A (en) * 2012-09-29 2013-03-27 北京东方雨虹防水技术股份有限公司 Alkali-free liquid accelerator and preparation method and application thereof
CN103819117A (en) * 2014-01-08 2014-05-28 洛阳理工学院 Alkali-free chloride-free liquid concrete enhancer and preparation method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001042165A2 (en) * 1999-12-08 2001-06-14 Mbt Holding Ag Preparation of concrete accelerator
WO2006074739A1 (en) * 2005-01-14 2006-07-20 Construction Research & Technology Gmbh Liquid accelerator
CN101489958A (en) * 2006-07-14 2009-07-22 建筑研究和技术有限公司 Stable shotcrete accelerator dispersion with high content in active matter
CN101182139A (en) * 2007-11-12 2008-05-21 华南理工大学 Masonry cement having higher strength and water retention
CN101423356A (en) * 2008-11-20 2009-05-06 同济大学 Environment-friendly type alkali-free liquid accelerator for sprayed concrete and preparation method thereof
CN102531452A (en) * 2010-12-10 2012-07-04 苏笮斌 Anti-corrosion anti-cracking reinforcing agent composition and preparation method thereof
CN102249592A (en) * 2011-06-01 2011-11-23 中国水利水电科学研究院 Alkali-free chlorine-free high-early-strength liquid accelerator and preparation method thereof
CN102992677A (en) * 2012-09-29 2013-03-27 北京东方雨虹防水技术股份有限公司 Alkali-free liquid accelerator and preparation method and application thereof
CN103819117A (en) * 2014-01-08 2014-05-28 洛阳理工学院 Alkali-free chloride-free liquid concrete enhancer and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109437654A (en) * 2018-12-11 2019-03-08 湖北腾辰科技股份有限公司 A kind of preparation method of enhanced alkali-free liquid accelerator
CN109761532A (en) * 2019-01-21 2019-05-17 江苏奥莱特新材料股份有限公司 The low rebound of one kind, high early-strength alkali-free liquid accelerator and preparation method thereof
CN109761532B (en) * 2019-01-21 2021-06-15 江苏奥莱特新材料股份有限公司 Low-resilience high-early-strength alkali-free liquid accelerator and preparation method thereof
CN110963741A (en) * 2019-12-27 2020-04-07 芜湖弘马新材料有限公司 Early-strength powdery alkali-free liquid accelerator core master batch and preparation method and application thereof

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Address after: 044000 Xingxing Avenue 9, Yanhu High-tech Industrial Development Zone, Yuncheng City, Shanxi Province

Patentee after: Shanxi Geruite construction Polytron Technologies Inc

Address before: 044000 No. 1 Xinxin Road, Yanhu Industrial Park, Yuncheng City, Shanxi Province

Patentee before: Shanxi Geruite Building Technology Co., Ltd.