CN104496250A - Concrete antifreeze pumping agent - Google Patents

Concrete antifreeze pumping agent Download PDF

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Publication number
CN104496250A
CN104496250A CN201410665775.0A CN201410665775A CN104496250A CN 104496250 A CN104496250 A CN 104496250A CN 201410665775 A CN201410665775 A CN 201410665775A CN 104496250 A CN104496250 A CN 104496250A
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CN
China
Prior art keywords
reducer
water
pumping aid
aid according
concrete
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410665775.0A
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Chinese (zh)
Inventor
李伟
庞宾
笪俊
王毅
姜海东
王高明
石宇
余韬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NANJING JINHAINING NOVEL BUILDING MATERIAL TECHNOLOGY Co Ltd
Jiangsu China Railway ARIT New Materials Co Ltd
Original Assignee
NANJING JINHAINING NOVEL BUILDING MATERIAL TECHNOLOGY Co Ltd
Jiangsu China Railway ARIT New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NANJING JINHAINING NOVEL BUILDING MATERIAL TECHNOLOGY Co Ltd, Jiangsu China Railway ARIT New Materials Co Ltd filed Critical NANJING JINHAINING NOVEL BUILDING MATERIAL TECHNOLOGY Co Ltd
Priority to CN201410665775.0A priority Critical patent/CN104496250A/en
Publication of CN104496250A publication Critical patent/CN104496250A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a concrete antifreeze pumping agent comprising the following raw material components, by weight: 15-20% of a water reducing agent, 8-12 percent of an antifreeze component, 2-5% of fluorosilicate, 0.6-1.0% of an early strength agent, 0.03-0.08% of an entraining agent, and 65-70% of tap water. The pumping agent provided by the invention is characterized in that the pumping agent can satisfy construction requirement under an environment with a temperature of -20 DEG C, and comprehensive indicators such as pumpability and early strength are substantially better than those of similar products in the market. The pumping agent provided by the invention has the advantages of high adaptability, high cost performance, no chlorine, and low alkali. The pumping agent is in a liquid state, such that the pumping agent is convenient to store, transport and utilize.

Description

A kind of concrete antifreezing pumping aid
Technical field
What the present invention relates to is a kind of research and development technology field of concrete admixture, is specifically related to a kind of concrete antifreezing pumping aid prepared for main raw material with phosphate fertilizer by-product product silicofluoride, prepares the concrete of various strength grade under being applicable to subzero temperature in winter.
Background technology
The vast northern area weather of China is usually colder, is 4 ~ 6 months winter, very large on concrete engineering construction impact.In order to ensure concrete construction quality and progress, concrete agitation station often selects hardening accelerator, frostproofer and water reducer separately to add to reach diminishing, antifreeze and early strong object, thus makes working procedure loaded down with trivial details and should not preserve, transport and use.Study a kind of liquid concrete anti-freezing pumping agents, to guarantee construction engineering quality and quickening speed of application, there is positive effect.
Summary of the invention
The object of the invention is to develop a kind of a kind of concrete antifreezing pumping aid being applicable to concrete batching under subzero temperature in winter to improve the deficiencies in the prior art.
Technical scheme of the present invention is: a kind of concrete antifreezing pumping aid, is characterized in that: the mass percent that its feed composition and each component account for raw material total amount is as follows:
Preferably above-mentioned water reducer is the one in polycarboxylate water-reducer, water soluble resin sulfonate water reducer or ligno-sulfate based plasticizer.More preferably described polycarboxylate water-reducer is the one in methacrylic acid-acrylic acid methyl esters polycarboxylate water-reducer, allyl ethers polycarboxylate water-reducer or amide-imide polycarboxylate water-reducer; More preferably described water soluble resin sulfonate water reducer is the one in sulfonated melamine compound resin water reducer, the ancient grand resin water reducer of code of sulfonation or polystyrene sulfonic acid resin water reducer.More preferably described ligno-sulfate based plasticizer is the one in calcium lignin sulfonate water depressor, sodium lignin sulfonate water reducer or magnesium lignosulfonate water reducer.
Preferably described antifreezing component is the one in Sodium Nitrite, Sulfothiorine or ethylene glycol.Preferably described silicofluoride is the one in silicofluoride magnesium, Sodium Silicofluoride or potassium silicofluoride.Preferably described hardening accelerator is the one in trolamine, tri-isopropanolamine or sodium sulfate.Preferably described air entrapment agent is the one in rosin thermopolymer air entrapment agent, sodium abietate or alkyl sodium sulfonate.
The preparation method of above-mentioned concrete antifreezing pumping aid is: take each raw material by weight percentage; Then each raw material taken is placed in forced action type mixing machine and mixes, namely obtain concrete antifreezing pumping aid.
Beneficial effect:
Concrete antifreezing pumping aid prepared by the present invention is main raw material owing to have employed phosphate fertilizer by-product product silicofluoride, thus this finished product low, decrease environmental pollution.Concrete antifreezing pumping aid of the present invention, volume is only 3% ~ 4% of gelling material, construction requirement can be met under the environment of-20 DEG C, the overall target such as pumping, early strength is obviously better than market like product, and strong adaptability, cost performance are high, without chlorine, low alkali, liquid, be convenient to storage, transport and use.
Embodiment
Embodiment 1
A kind of preparation method of concrete antifreezing pumping aid is:
Step 1: take each raw material by weight percentage;
Sodium lignin sulfonate water reducer 18%, Sodium Nitrite 10%, Sodium Silicofluoride 4%, trolamine 1%, alkyl sodium sulfonate 0.05%, tap water 66.95%;
Step 2: each raw material taken is placed in forced action type mixing machine and mixes, obtain concrete antifreezing pumping aid.Mix in concrete by gelling material 3.2% ,-20 DEG C of environment maintenances 7 days.
Embodiment 2
A kind of preparation method of concrete antifreezing pumping aid is:
Step 1: take each raw material by weight percentage;
Sulfonated melamine compound resin water reducer 20%, Sulfothiorine 8%, magnesium silicofluoride 5%, tri-isopropanolamine 0.8%, alkyl sodium sulfonate 0.06%, tap water 66.14%;
Step 2: each raw material taken is placed in forced action type mixing machine and mixes, obtain concrete antifreezing pumping aid.Mix in concrete by gelling material 3.5% ,-20 DEG C of environment maintenances 7 days.
Embodiment 3
A kind of preparation method of concrete antifreezing pumping aid is:
Step 1: take each raw material by weight percentage;
Methacrylic acid-acrylic acid methyl esters polycarboxylate water-reducer 16%, ethylene glycol 12%, potassium silicofluoride 3%, sodium sulfate 0.6%, sodium abietate 0.03%, tap water 68.37%;
Step 2: each raw material taken is placed in forced action type mixing machine and mixes, obtain concrete antifreezing pumping aid.Mix in concrete by gelling material 4.0% ,-20 DEG C of environment maintenances 7 days.
The every technical feature test result of embodiment 1 ~ 3 is as following table.

Claims (9)

1. a concrete antifreezing pumping aid, is characterized in that: the mass percent that its feed composition and each component account for raw material total amount is as follows:
2. concrete antifreezing pumping aid according to claim 1, is characterized in that: described water reducer is the one in polycarboxylate water-reducer, water soluble resin sulfonate water reducer or ligno-sulfate based plasticizer.
3. concrete antifreezing pumping aid according to claim 2, is characterized in that: described polycarboxylate water-reducer is the one in methacrylic acid-acrylic acid methyl esters polycarboxylate water-reducer, allyl ethers polycarboxylate water-reducer or amide-imide polycarboxylate water-reducer.
4. concrete antifreezing pumping aid according to claim 2, is characterized in that: described water soluble resin sulfonate water reducer is the one in sulfonated melamine compound resin water reducer, the ancient grand resin water reducer of code of sulfonation or polystyrene sulfonic acid resin water reducer.
5. concrete antifreezing pumping aid according to claim 2, is characterized in that: described ligno-sulfate based plasticizer is the one in calcium lignin sulfonate water depressor, sodium lignin sulfonate water reducer or magnesium lignosulfonate water reducer.
6. concrete antifreezing pumping aid according to claim 1, is characterized in that: described antifreezing component is the one in Sodium Nitrite, Sulfothiorine or ethylene glycol.
7. concrete antifreezing pumping aid according to claim 1, is characterized in that: described silicofluoride is the one in silicofluoride magnesium, Sodium Silicofluoride or potassium silicofluoride.
8. concrete antifreezing pumping aid according to claim 1, is characterized in that: described hardening accelerator is the one in trolamine, tri-isopropanolamine or sodium sulfate.
9. concrete antifreezing pumping aid according to claim 1, is characterized in that: described air entrapment agent is the one in rosin thermopolymer air entrapment agent, sodium abietate or alkyl sodium sulfonate.
CN201410665775.0A 2014-11-19 2014-11-19 Concrete antifreeze pumping agent Pending CN104496250A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410665775.0A CN104496250A (en) 2014-11-19 2014-11-19 Concrete antifreeze pumping agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410665775.0A CN104496250A (en) 2014-11-19 2014-11-19 Concrete antifreeze pumping agent

Publications (1)

Publication Number Publication Date
CN104496250A true CN104496250A (en) 2015-04-08

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105503013A (en) * 2015-12-22 2016-04-20 河南科之杰新材料有限公司 Liquid concrete early strength anti-freezing agent and preparation method thereof
CN106396458A (en) * 2016-09-28 2017-02-15 四会市恒星智能科技有限公司 Highly efficient composite concrete anti-freezing agent and preparation method thereof
CN106830735A (en) * 2017-01-18 2017-06-13 江苏中铁奥莱特新材料股份有限公司 A kind of concrete antifreezing pumping aid and preparation method thereof
CN107082593A (en) * 2017-05-25 2017-08-22 胡祥丽 A kind of concrete and preparation method thereof
CN107188452A (en) * 2017-06-28 2017-09-22 常州建轩纺织品有限公司 A kind of concrete pumping antifreezing agent and preparation method thereof
CN108821639A (en) * 2018-06-28 2018-11-16 江苏百瑞吉新材料有限公司 A kind of anti-freeze type concrete pump-feed agent
CN108863156A (en) * 2018-08-09 2018-11-23 马永胜 A kind of concrete pump-feed agent
CN109879623A (en) * 2019-03-26 2019-06-14 江苏百瑞吉新材料有限公司 It is a kind of to protect the anti-chamotte mould polycarboxylic acids and preparation method thereof that collapses
CN114031324A (en) * 2021-11-30 2022-02-11 贵州兴达兴建材股份有限公司 Special pumping agent for pumping recycled aggregate concrete

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0650941A1 (en) * 1993-10-29 1995-05-03 Sandoz Ltd. Water-reducing admixtures for cementitious compositions
CN102060463A (en) * 2010-12-03 2011-05-18 山东宏艺科技股份有限公司 Low-cost concrete antifreezing pumping aid and preparation method thereof
CN102795806A (en) * 2012-08-14 2012-11-28 山东大元实业股份有限公司 Chlorine salt-free ammonia-free liquid concrete anti-freezing pumping agent
CN104030599A (en) * 2014-05-23 2014-09-10 中国水电十一局有限公司混凝土外加剂厂 Antifreezing polycarboxylic acid composite pumping water reducing agent and application thereof
CN104086113A (en) * 2014-06-25 2014-10-08 江苏奥莱特新材料有限公司 Concrete synergist

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0650941A1 (en) * 1993-10-29 1995-05-03 Sandoz Ltd. Water-reducing admixtures for cementitious compositions
CN102060463A (en) * 2010-12-03 2011-05-18 山东宏艺科技股份有限公司 Low-cost concrete antifreezing pumping aid and preparation method thereof
CN102795806A (en) * 2012-08-14 2012-11-28 山东大元实业股份有限公司 Chlorine salt-free ammonia-free liquid concrete anti-freezing pumping agent
CN104030599A (en) * 2014-05-23 2014-09-10 中国水电十一局有限公司混凝土外加剂厂 Antifreezing polycarboxylic acid composite pumping water reducing agent and application thereof
CN104086113A (en) * 2014-06-25 2014-10-08 江苏奥莱特新材料有限公司 Concrete synergist

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105503013A (en) * 2015-12-22 2016-04-20 河南科之杰新材料有限公司 Liquid concrete early strength anti-freezing agent and preparation method thereof
CN105503013B (en) * 2015-12-22 2017-12-19 河南科之杰新材料有限公司 A kind of liquid concrete early strength antifreezing agent and preparation method thereof
CN106396458A (en) * 2016-09-28 2017-02-15 四会市恒星智能科技有限公司 Highly efficient composite concrete anti-freezing agent and preparation method thereof
CN106830735A (en) * 2017-01-18 2017-06-13 江苏中铁奥莱特新材料股份有限公司 A kind of concrete antifreezing pumping aid and preparation method thereof
CN107082593A (en) * 2017-05-25 2017-08-22 胡祥丽 A kind of concrete and preparation method thereof
CN107188452A (en) * 2017-06-28 2017-09-22 常州建轩纺织品有限公司 A kind of concrete pumping antifreezing agent and preparation method thereof
CN108821639A (en) * 2018-06-28 2018-11-16 江苏百瑞吉新材料有限公司 A kind of anti-freeze type concrete pump-feed agent
CN108863156A (en) * 2018-08-09 2018-11-23 马永胜 A kind of concrete pump-feed agent
CN109879623A (en) * 2019-03-26 2019-06-14 江苏百瑞吉新材料有限公司 It is a kind of to protect the anti-chamotte mould polycarboxylic acids and preparation method thereof that collapses
CN114031324A (en) * 2021-11-30 2022-02-11 贵州兴达兴建材股份有限公司 Special pumping agent for pumping recycled aggregate concrete

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