CN104059441A - Building interior wall coating material and preparation method thereof - Google Patents

Building interior wall coating material and preparation method thereof Download PDF

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Publication number
CN104059441A
CN104059441A CN201410281985.XA CN201410281985A CN104059441A CN 104059441 A CN104059441 A CN 104059441A CN 201410281985 A CN201410281985 A CN 201410281985A CN 104059441 A CN104059441 A CN 104059441A
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China
Prior art keywords
parts
wall
dope
high speed
polyvinyl
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Application number
CN201410281985.XA
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Chinese (zh)
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CN104059441B (en
Inventor
曹先军
王凤德
梁克俭
赵奕
李智
高川
林杉
黄茜
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Lan-Star (chengdu) New Material Co Ltd
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Lan-Star (chengdu) New Material Co Ltd
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Priority to CN201410281985.XA priority Critical patent/CN104059441B/en
Publication of CN104059441A publication Critical patent/CN104059441A/en
Application granted granted Critical
Publication of CN104059441B publication Critical patent/CN104059441B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention relates to a building interior wall coating material and a preparation method thereof, and belongs to the technical field of polymer materials. The building interior wall coating material provided by the invention comprises the following raw materials by weight: 50-80 parts of styrene acrylic emulsion, 1-5 parts of sodium naphthenate, 2-8 parts of caprolactam, 20 parts of polyvinyl formal, 10-25 parts of polyving akohol castor oil, 5-16 parts of polyvinyl acetate emulsion, 3-5 parts of a polyacrylic acid dispersant, 5-15 parts of ethylene glycol, 0.5-1.0 part of an emulsifier, 10-20 parts of titanium dioxide, 30-50 parts of calcium carbonate and 50-100 parts of deionized water. The building interior wall coating material provided by the invention significantly improves the water resistance, wear resistance and washing durability of the interior wall coating material, greatly prolongs the service life of the coating; and the added caprolactam paint endows the coating with better coating appearance.

Description

A kind of dope for inner wall of architecture and preparation method thereof
Technical field
The present invention relates to a kind of coating and preparation method thereof, more particularly, the present invention relates to a kind of dope for inner wall of architecture and preparation method thereof, belong to technical field of polymer materials.
Background technology
In the use of inner wall of building coating, mainly with polyvinyl formal as tackiness agent.But such coating is due to poor water tolerance and not wear-resisting, appearance of coat is not good belongs to more low-grade coating.
It is CN102618129A that State Intellectual Property Office discloses a publication number in 2012.8.1, name is called the patent of invention of " compound coating for internal and external wall of water glass-benzene emulsion and preparation method thereof ", this patent discloses the compound coating for internal and external wall of a kind of water glass-benzene emulsion, comprise the component of following weight part ratio: 15 ~ 20 parts of water, 0.2 ~ 0.5 part of dispersion agent, 0.1 ~ 0.3 part of defoamer, 0.1 ~ 0.3 part of coating sterilant, 0.3 ~ 0.7 portion of dry film sanitas, 0.3 ~ 0.8 portion of antifreezing agent, 25 ~ 45 parts of color stuffings, 25 ~ 35 parts of benzene emulsions, 0.5 ~ 1.0 part of film coalescence aid, 18 ~ 25 parts of water glass.The compound coating for internal and external wall of water glass-benzene emulsion, owing to having replaced approximately 40% benzene emulsion with water glass as filmogen, can reduce costs greatly, and reduced VOC with water-alkali resistance performance; Simultaneously because water glass is alkalescence, and add the viscosity of rear system to increase thereupon, therefore in system without adding again pH value conditioning agent and thickening material regulation system viscosity, thereby further reduced cost and VOC.
It is CN102344722A that State Intellectual Property Office discloses a publication number in 2012.2.8, and name is called the patent of invention of " a kind of coating taking benzene emulsion as major ingredient ", and this patent relates to a kind of coating taking benzene emulsion as major ingredient.A coating taking benzene emulsion as major ingredient, is characterized in that its formula is: by weight percentage, and major ingredient: benzene emulsion 50-55%, thinner: lacquer thinner 40-50%, additive: patina 5-10%.Adopt this invention that a kind of coating taking benzene emulsion as major ingredient is provided, produce the paint of special-effect.Its paint film weather resisteant is good, gloss is high, fullness ratio is excellent, sticking power is good, hardness is high; Can reduce VOC, be conducive to environment protection.
Although above-mentioned existing coating for wall surface has used benzene emulsion, has certain water tolerance, its water tolerance is general, and wear resisting property and weather resistance neither be ideal.
Summary of the invention
The present invention is intended to solve existing coating for wall surface water tolerance, the not good problem of wear resistance, and a kind of dope for inner wall of architecture is provided, and can improve water tolerance and the wear resistance of paint coatings, improves the work-ing life of coating.
In order to realize foregoing invention object, its concrete technical scheme is as follows:
A kind of dope for inner wall of architecture, is characterized in that: comprise following according to the raw material of parts by weight meter:
Benzene emulsion 50-80 part
Sodium napthionate 1-5 part
Hexanolactam 2-8 part
Polyvinyl formal 10-20 part
Polyvinyl alcohol Viscotrol C 10-25 part
Polyvinyl acetate emulsion 5-16 part
Polyacrylic acid dispersant 3-5 part
Ethylene glycol 5-15 part
Emulsifying agent 0.5-1.0 part
Titanium dioxide 10-20 part
Calcium carbonate 30-50 part
Deionized water 50-100 part.
Preferably, a kind of dope for inner wall of architecture, is characterized in that: comprise following according to the raw material of parts by weight meter:
Benzene emulsion 55-70 part
Sodium napthionate 2-4 part
Hexanolactam 3-6 part
Polyvinyl formal 15-19 part
Polyvinyl alcohol Viscotrol C 12-21 part
Polyvinyl acetate emulsion 6-12 part
Polyacrylic acid dispersant 4-4.8 part
Ethylene glycol 6-12 part
Emulsifying agent 0.6-0.9 part
Titanium dioxide 12-19 part
Calcium carbonate 33-45 part
Deionized water 60-80 part.
The solid content of polyvinyl acetate emulsion of the present invention is 50%.
Emulsifying agent of the present invention is OP-10.
A preparation method for dope for inner wall of architecture, is characterized in that: comprise following processing step:
A, by formula requirement accurately take benzene emulsion, polyvinyl formal, polyacrylic acid dispersant, emulsifying agent, titanium dioxide, calcium carbonate and remove ionized water, high speed dispersion in high speed disperser;
B, add sodium napthionate, hexanolactam, polyvinyl alcohol Viscotrol C, polyvinyl acetate emulsion and ethylene glycol, high speed dispersion again;
C, the dispersion of further milling on two rollers or three-roller will be transferred to through the material of high speed dispersion;
D, filtration, packaging, obtains dope for inner wall of architecture.
The present invention is in steps A, and the time of described high speed dispersion is 0.5-1.0h.
The present invention is in step B, and the time of described high speed dispersion is 1-1.5h.
The useful technique effect that the present invention brings:
It is general that dope for inner wall of architecture of the present invention has solved prior art water-resistant coating, the problem that wear resisting property and weather resistance neither be ideal.Dope for inner wall of architecture provided by the invention has been selected the another kind of tackiness agent of benzene emulsion as coating, coordinate polyvinyl formal, polyvinyl alcohol Viscotrol C and polyvinyl acetate emulsion, add again sodium napthionate, water tolerance, the wear resistance of interior wall coating coating are significantly improved, also improve water-wash resistance, greatly improve the work-ing life of coating, added hexanolactam to make coating there is better appearance of coat.
Embodiment
embodiment 1
A kind of dope for inner wall of architecture, comprises following according to the raw material of parts by weight meter:
50 parts of benzene emulsions
1 part of sodium napthionate
2 parts of hexanolactams
10 parts of polyvinyl formals
10 parts of polyvinyl alcohol Viscotrol C
5 parts of polyvinyl acetate emulsions
3 parts of polyacrylic acid dispersant
5 parts of ethylene glycol
0.5 part of emulsifying agent
10 parts of titanium dioxides
30 parts, calcium carbonate
50 parts of deionized waters.
Preferred:
The solid content of described polyvinyl acetate emulsion is 50%.
Described emulsifying agent is OP-10.
embodiment 2
A kind of dope for inner wall of architecture, comprises following according to the raw material of parts by weight meter:
80 parts of benzene emulsions
5 parts of sodium napthionates
8 parts of hexanolactams
20 parts of polyvinyl formals
25 parts of polyvinyl alcohol Viscotrol C
16 parts of polyvinyl acetate emulsions
5 parts of polyacrylic acid dispersant
15 parts of ethylene glycol
1.0 parts of emulsifying agents
20 parts of titanium dioxides
50 parts, calcium carbonate
100 parts of deionized waters.
Preferred:
The solid content of described polyvinyl acetate emulsion is 50%.
Described emulsifying agent is OP-10.
embodiment 3
A kind of dope for inner wall of architecture, comprises following according to the raw material of parts by weight meter:
65 parts of benzene emulsions
3 parts of sodium napthionates
5 parts of hexanolactams
15 parts of polyvinyl formals
17.5 parts of polyvinyl alcohol Viscotrol C
10.5 parts of polyvinyl acetate emulsions
4 parts of polyacrylic acid dispersant
10 parts of ethylene glycol
0.75 part of emulsifying agent
15 parts of titanium dioxides
40 parts, calcium carbonate
75 parts of deionized waters.
Preferred:
The solid content of described polyvinyl acetate emulsion is 50%.
Described emulsifying agent is OP-10.
embodiment 4
A kind of dope for inner wall of architecture, comprises following according to the raw material of parts by weight meter:
56 parts of benzene emulsions
1.2 parts of sodium napthionates
7 parts of hexanolactams
19 parts of polyvinyl formals
13 parts of polyvinyl alcohol Viscotrol C
14 parts of polyvinyl acetate emulsions
3.5 parts of polyacrylic acid dispersant
11 parts of ethylene glycol
0.8 part of emulsifying agent
17 parts of titanium dioxides
43 parts, calcium carbonate
92 parts of deionized waters.
Preferred:
The solid content of described polyvinyl acetate emulsion is 50%.
Described emulsifying agent is OP-10.
embodiment 5
A kind of dope for inner wall of architecture, comprises following according to the raw material of parts by weight meter:
55 parts of benzene emulsions
2 parts of sodium napthionates
3 parts of hexanolactams
15 parts of polyvinyl formals
12 parts of polyvinyl alcohol Viscotrol C
6 parts of polyvinyl acetate emulsions
4 parts of polyacrylic acid dispersant
6 parts of ethylene glycol
0.6 part of emulsifying agent
12 parts of titanium dioxides
33 parts, calcium carbonate
60 parts of deionized waters.
Preferred:
The solid content of described polyvinyl acetate emulsion is 50%.
Described emulsifying agent is OP-10.
embodiment 6
A kind of dope for inner wall of architecture, comprises following according to the raw material of parts by weight meter:
70 parts of benzene emulsions
4 parts of sodium napthionates
6 parts of hexanolactams
19 parts of polyvinyl formals
21 parts of polyvinyl alcohol Viscotrol C
12 parts of polyvinyl acetate emulsions
4.8 parts of polyacrylic acid dispersant
12 parts of ethylene glycol
0.9 part of emulsifying agent
19 parts of titanium dioxides
Carbonic acid Ca45 part
80 parts of deionized waters.
Preferred:
The solid content of described polyvinyl acetate emulsion is 50%.
Described emulsifying agent is OP-10.
embodiment 7
A kind of dope for inner wall of architecture, comprises following according to the raw material of parts by weight meter:
62.5 parts of benzene emulsions
3 parts of sodium napthionates
4.5 parts of hexanolactams
17 parts of polyvinyl formals
16.5 parts of polyvinyl alcohol Viscotrol C
9 parts of polyvinyl acetate emulsions
4.4 parts of polyacrylic acid dispersant
9 parts of ethylene glycol
0.75 part of emulsifying agent
15.5 parts of titanium dioxides
39 parts, calcium carbonate
70 parts of deionized waters.
Preferred:
The solid content of described polyvinyl acetate emulsion is 50%.
Described emulsifying agent is OP-10.
embodiment 8
A kind of dope for inner wall of architecture, comprises following according to the raw material of parts by weight meter:
66 parts of benzene emulsions
3.2 parts of sodium napthionates
5.5 parts of hexanolactams
17 parts of polyvinyl formals
20 parts of polyvinyl alcohol Viscotrol C
7.5 parts of polyvinyl acetate emulsions
4.2 parts of polyacrylic acid dispersant
11 parts of ethylene glycol
0.68 part of emulsifying agent
12.5 parts of titanium dioxides
42 parts, calcium carbonate
75 parts of deionized waters.
Preferred:
The solid content of described polyvinyl acetate emulsion is 50%.
Described emulsifying agent is OP-10.
embodiment 9
A preparation method for dope for inner wall of architecture, comprises following processing step:
A, by formula requirement accurately take benzene emulsion, polyvinyl formal, polyacrylic acid dispersant, emulsifying agent, titanium dioxide, calcium carbonate and remove ionized water, high speed dispersion in high speed disperser;
B, add sodium napthionate, hexanolactam, polyvinyl alcohol Viscotrol C, polyvinyl acetate emulsion and ethylene glycol, high speed dispersion again;
C, the dispersion of further milling on two rollers or three-roller will be transferred to through the material of high speed dispersion;
D, filtration, packaging, obtains dope for inner wall of architecture.
Preferred:
In steps A, the time of described high speed dispersion is 0.5h.
In step B, the time of described high speed dispersion is 1h.
embodiment 10
A preparation method for dope for inner wall of architecture, comprises following processing step:
A, by formula requirement accurately take benzene emulsion, polyvinyl formal, polyacrylic acid dispersant, emulsifying agent, titanium dioxide, calcium carbonate and remove ionized water, high speed dispersion in high speed disperser;
B, add sodium napthionate, hexanolactam, polyvinyl alcohol Viscotrol C, polyvinyl acetate emulsion and ethylene glycol, high speed dispersion again;
C, the dispersion of further milling on two rollers or three-roller will be transferred to through the material of high speed dispersion;
D, filtration, packaging, obtains dope for inner wall of architecture.
Preferred:
In steps A, the time of described high speed dispersion is 1.0h.
In step B, the time of described high speed dispersion is 1.5h.
embodiment 11
A preparation method for dope for inner wall of architecture, comprises following processing step:
A, by formula requirement accurately take benzene emulsion, polyvinyl formal, polyacrylic acid dispersant, emulsifying agent, titanium dioxide, calcium carbonate and remove ionized water, high speed dispersion in high speed disperser;
B, add sodium napthionate, hexanolactam, polyvinyl alcohol Viscotrol C, polyvinyl acetate emulsion and ethylene glycol, high speed dispersion again;
C, the dispersion of further milling on two rollers or three-roller will be transferred to through the material of high speed dispersion;
D, filtration, packaging, obtains dope for inner wall of architecture.
Preferred:
In steps A, the time of described high speed dispersion is 0.75h.
In step B, the time of described high speed dispersion is 1.25h.
embodiment 12
A preparation method for dope for inner wall of architecture, comprises following processing step:
A, by formula requirement accurately take benzene emulsion, polyvinyl formal, polyacrylic acid dispersant, emulsifying agent, titanium dioxide, calcium carbonate and remove ionized water, high speed dispersion in high speed disperser;
B, add sodium napthionate, hexanolactam, polyvinyl alcohol Viscotrol C, polyvinyl acetate emulsion and ethylene glycol, high speed dispersion again;
C, the dispersion of further milling on two rollers or three-roller will be transferred to through the material of high speed dispersion;
D, filtration, packaging, obtains dope for inner wall of architecture.
Preferred:
In steps A, the time of described high speed dispersion is 0.25h.
In step B, the time of described high speed dispersion is 1.2h.

Claims (7)

1. a dope for inner wall of architecture, is characterized in that: comprise following according to the raw material of parts by weight meter:
Benzene emulsion 50-80 part
Sodium napthionate 1-5 part
Hexanolactam 2-8 part
Polyvinyl formal 10-20 part
Polyvinyl alcohol Viscotrol C 10-25 part
Polyvinyl acetate emulsion 5-16 part
Polyacrylic acid dispersant 3-5 part
Ethylene glycol 5-15 part
Emulsifying agent 0.5-1.0 part
Titanium dioxide 10-20 part
Calcium carbonate 30-50 part
Deionized water 50-100 part.
2. a kind of dope for inner wall of architecture according to claim 1, is characterized in that: comprise following according to the raw material of parts by weight meter:
Benzene emulsion 55-70 part
Sodium napthionate 2-4 part
Hexanolactam 3-6 part
Polyvinyl formal 15-19 part
Polyvinyl alcohol Viscotrol C 12-21 part
Polyvinyl acetate emulsion 6-12 part
Polyacrylic acid dispersant 4-4.8 part
Ethylene glycol 6-12 part
Emulsifying agent 0.6-0.9 part
Titanium dioxide 12-19 part
Calcium carbonate 33-45 part
Deionized water 60-80 part.
3. a kind of dope for inner wall of architecture according to claim 1 and 2, is characterized in that: the solid content of described polyvinyl acetate emulsion is 50%.
4. a kind of dope for inner wall of architecture according to claim 1 and 2, is characterized in that: described emulsifying agent is OP-10.
5. the preparation method of a kind of dope for inner wall of architecture according to claim 1 and 2, is characterized in that: comprise following processing step:
A, by formula requirement accurately take benzene emulsion, polyvinyl formal, polyacrylic acid dispersant, emulsifying agent, titanium dioxide, calcium carbonate and remove ionized water, high speed dispersion in high speed disperser;
B, add sodium napthionate, hexanolactam, polyvinyl alcohol Viscotrol C, polyvinyl acetate emulsion and ethylene glycol, high speed dispersion again;
C, the dispersion of further milling on two rollers or three-roller will be transferred to through the material of high speed dispersion;
D, filtration, packaging, obtains dope for inner wall of architecture.
6. the preparation method of a kind of dope for inner wall of architecture according to claim 5, is characterized in that: in steps A, the time of described high speed dispersion is 0.5-1.0h.
7. the preparation method of a kind of dope for inner wall of architecture according to claim 5, is characterized in that: in step B, the time of described high speed dispersion is 1-1.5h.
CN201410281985.XA 2014-06-23 2014-06-23 A kind of dope for inner wall of architecture and preparation method thereof Expired - Fee Related CN104059441B (en)

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CN104059441B CN104059441B (en) 2016-07-13

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449315A (en) * 2014-12-01 2015-03-25 昌利锻造有限公司 Aqueous abrasion-resistant antirust paint applied to various device shells and preparation method of paint
CN105368112A (en) * 2015-12-30 2016-03-02 辛范范 Interior wall paint and preparation method thereof
CN105482030A (en) * 2016-01-19 2016-04-13 卓达新材料科技集团有限公司 Latex for water-based interior wall priming paint as well as preparation method and application of latex
CN106280804A (en) * 2016-08-27 2017-01-04 苏州雅晟建筑装饰工程有限公司 A kind of decorating interior wall emulsion paint
CN107141903A (en) * 2017-07-07 2017-09-08 佛山领新信息科技有限公司 A kind of scrubbable interior wall coating and preparation method thereof
CN107163704A (en) * 2017-07-07 2017-09-15 佛山领新信息科技有限公司 Strong and wear-resisting interior wall coating of a kind of adhesion property and preparation method thereof
CN107189569A (en) * 2017-05-25 2017-09-22 中国建筑股份有限公司 The net road surface cooling coating of super-hydrophobic self-cleaning and its preparation and application
WO2018202830A1 (en) * 2017-05-05 2018-11-08 Basf Se Fluidically applicable vapor retarder

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101113270A (en) * 2006-07-28 2008-01-30 中宏(天津)实业有限公司 Method for making interior wall paint having moisture-proof and steam-proof performances
CN103409010A (en) * 2013-07-03 2013-11-27 安徽真信涂料有限公司 Anti-scrubbing interior wall coating material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101113270A (en) * 2006-07-28 2008-01-30 中宏(天津)实业有限公司 Method for making interior wall paint having moisture-proof and steam-proof performances
CN103409010A (en) * 2013-07-03 2013-11-27 安徽真信涂料有限公司 Anti-scrubbing interior wall coating material and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449315A (en) * 2014-12-01 2015-03-25 昌利锻造有限公司 Aqueous abrasion-resistant antirust paint applied to various device shells and preparation method of paint
CN105368112A (en) * 2015-12-30 2016-03-02 辛范范 Interior wall paint and preparation method thereof
CN105482030A (en) * 2016-01-19 2016-04-13 卓达新材料科技集团有限公司 Latex for water-based interior wall priming paint as well as preparation method and application of latex
CN106280804A (en) * 2016-08-27 2017-01-04 苏州雅晟建筑装饰工程有限公司 A kind of decorating interior wall emulsion paint
WO2018202830A1 (en) * 2017-05-05 2018-11-08 Basf Se Fluidically applicable vapor retarder
CN107189569A (en) * 2017-05-25 2017-09-22 中国建筑股份有限公司 The net road surface cooling coating of super-hydrophobic self-cleaning and its preparation and application
CN107141903A (en) * 2017-07-07 2017-09-08 佛山领新信息科技有限公司 A kind of scrubbable interior wall coating and preparation method thereof
CN107163704A (en) * 2017-07-07 2017-09-15 佛山领新信息科技有限公司 Strong and wear-resisting interior wall coating of a kind of adhesion property and preparation method thereof

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