CN104058613A - Waste tile furnace slag luminous cement - Google Patents
Waste tile furnace slag luminous cement Download PDFInfo
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- CN104058613A CN104058613A CN201410320264.5A CN201410320264A CN104058613A CN 104058613 A CN104058613 A CN 104058613A CN 201410320264 A CN201410320264 A CN 201410320264A CN 104058613 A CN104058613 A CN 104058613A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
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Abstract
The invention discloses waste tile furnace slag luminous cement and belongs to the technical field of production and manufacture of luminous cement for building materials and chemical products. The waste tile furnace slag luminous cement consists of caustic dross silicate, blast furnace slag fluorescent powder, rare earth element slag tile ash, ferro-silicon slag broken ceramic bowl can powder, copper slag sulfuric acid calcium molybdate overspeed hardening agent, zinc-manganese slag water glass elastic waterproof latex and negative-ion far-infrared tourmaline powder natural dry latex luminous cement. In order to overcome the defects of the cement used in buildings, construction wastes, waste tiles and waste broken bowls, basins, cans, ceramic fragments, cinder ash, furnaces and slag are utilized. The wastes are utilized and are changed into valuable materials. According to the project, negative-ion far-infrared elements which are enriched inn the waste slag and are beneficial to the human health are fully utilized to prepare the luminous cement, the market requirement is met, pollution is reduced, the human health is promoted, illumination is provided for night pass, the accidents are reduced, and the life and property safety is ensured.
Description
Technical field:
The invention discloses the luminous cement of a kind of useless brick and tile porcelain slag, is to belong to the luminous manufacture of cement compounding process of material of construction chemical preparations field.
Background technology:
Building cement used gets more and more now, original cement mill because of the seriously polluted dust that causes in air full of smoke, must not be not related to, turn and stop, the producer that produces cement is significantly reduced, in order to meet cement demand, with easy economical approach again, utilizing useless stove slag is the residue after various coal combustions, select the more sufficient quality of sintering degree better, sort out white slag and red slag wherein, Ex-all organic impurity and silt soil, then clean, dry, levigate, sieve or broken clay fragment of brick, The more the better with clay component, the roof clay tile of preferably firing with clay, bowl, the fragment of the refuses such as tank, queen closer cob brick ashes, broken broken china bowl, cylinder, basins etc. are fired the fragment of vessel with refractory materials, these materials system take bauxitic clay and obtains as body material is fired.So the cement of making, has the characteristic of some luminite cement, setting rate is fast, intensity is high.As the cement of all preparing with ceramic whiteware fragment, look white as a jade, can do pargeting.But preparation process should be as far as possible without ironware, in order to avoid mix into the pure white degree of destroying cement after iron powder.And the various industrial residues that contain various trace elements, waste liquid etc. are made the luminous cement of multi-usage abandoned mine slag for various buildings.Pavement of road, enclosure wall whitewashes.
Summary of the invention:
The object of the present invention is to provide the luminous cement of a kind of useless brick and tile porcelain slag.
The scheme that the technology of the present invention solves is:
The luminous cement of useless brick and tile porcelain slag, is characterized in that: by following quality proportioning, form %
(1) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of alkaline residue silicate, by following quality proportioning, form %
Preparation and property:
Above-mentioned mixing of materials is crushed and milled.The intensity of this cement and setting rate equate with ordinary Portland cement or are slightly high and include and can be luminous shinnyly for road enclosure wall, whitewash at various trace elements and night.
(2) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by blast furnace slag light-emitting phosphor cement, by following quality proportioning, form %
Slag ash 20-60; Lime 10-30;
Terra alba 2-6; Terra alba 2-6;
Fluorescence radiation powder 2-6; Blast furnace slag adds to 100%;
Preparation method: above-mentioned five kinds of material dry mixing are even, desiccate standby.
Cement need be used raw material:
1. slag ash, i.e. residue after various coal combustions, the more sufficient quality of sintering degree is better.Sort out white slag and red slag wherein, Ex-all organic impurity and sand, then clean → dry → levigate → cross square-bottomed bamboo basket.
2. lime, applies unslaked lime, and newly kiln discharge is better.Lime block water spray is made to its efflorescence voluntarily, with No. 130 sieve screenings.As be powdered lime, should first cross sieve screening, then the efflorescence of screenings water spray is crossed to square-bottomed bamboo basket.
3. gypsum, volume is few, rises and regulates the velocity function that thes cement solidifies.Available plaster stone ore, also available waste gypsum mould.These two kinds of things are all dihydrate gypsums, are heated to after 107-170 ℃.Become semi-hydrated gypsum, be also the plaster of Paris.Pulverized and levigate, upper iron pan goes to fry.Treat gypsum powder no longer bubbling in pot, till there is no water vapour and becoming yellow-gray by white.
Blast furnace slag
Be mainly derived from high boiler slag, converter slag and open hearth slag etc.
Blast furnace slag forms %
Converter slag forms %
(3) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of rare earth element slag brick dark grey, by following quality proportioning, form %
Rare earth element slag 3-9; Lime 10-30;
Gypsum 2-6; Silicic acid luminescent material 2-6;
Brickbat soil brick and tile pottery ashes adds to 100%;
Method for making: the same.
Rare earth element slag
Produce rare earth metal, annual China will discharge a large amount of rare earth element slags, its form in Table.
Rare earth element slag forms %
(4) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, by following quality proportioning, form %
Ferrosilicon ground-slag 5-15; Lime powder 5-15;
Gypsum 5-15; Silicate cement 5-15;
Sulfide luminescent material 5-15; Broken porcelain basin bowl crock pottery flour adds to 100%;
Preparation method: the same.
Need raw material: damaged china bowl, glazed earthen basin etc. are fired the fragment of vessel with refractory materials, these materials system take bauxitic clay and obtains as body material is fired.So the cement of making, has the characteristic of some luminite cement, setting rate is fast, intensity is high.As the cement of all preparing with ceramic whiteware fragment, look white as a jade, can do pargeting.But preparation process should be as far as possible without ironware, in order to avoid mix into the pure white degree of destroying cement after iron powder.The same method of its preparation method is processed.
Ferro-silicon slag
China Steel Plant, smelting ironworks produce ferrosilicon and will discharge a large amount of ferro-silicon slags, and it forms, and it is as shown in the table.
Ferro-silicon slag forms %
(5) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, by following quality proportioning, form %
Copper ashes 5-15; Calcium phosphate 10-30;
Dicalcium Phosphate (Feed Grade) 5-15; Transparent high-visibility pigment powder 5-15;
Sulphur calcium molybdate adds to 100%;
In above-mentioned formula, require SO
3/ Al
2o
3mole ratio is 0.4-17, CaO/Al
2o
3mole ratio is 0.5-1.2, and it is hard containing free CaO, can not to make hypervelocity.
Copper glance Cu
2s, color by lead ash to black.Hardness 2.5-3.0, proportion 5.5-5.8.
The copper ashes that copper smelting goes out forms %
(6) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of hetaerolite pulp water glass elastic water-proof latex, by following quality proportioning, form %
The luminous latex cement of elastic water-proof is compared and is had plurality of advantages with general cement, its water-permeable little, tough and high resilience, shockproof, resistance to repeated stock, do not peel off or burst apart, good with the clinging power of concrete, steel, timber, brick etc., and there is certain anti-chemical corrosive power.
For meeting the needs of and reducing costs, latex cement often adds various weighting agents, as fine sand, granite, rubber grain, pitch, slag powders.
High-alumina cement has alkalescence, and the latex cement after cooperation is more stable.If use silicate cement instead, during latex mixing cement, should with casein solution, be protected in advance, make latex mixing there is enough stability.Pitch can improve the water resistance of latex cement, the moistening cement of water glass energy, and sodium silicofluoride can be used to regulate latex setting time, prevents layering.Latex cement should be used while allocating, and can not put for a long time.
Zinc-manganese slag
The place of production of exploitation copper hetaerolite, will have a large amount of slags to produce every year, and it can be used as the raw material of producing zinc, manganese fertilizer, its form in Table.
Plumbous hetaerolite forms %
(7) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the elastic luminous cement of the natural dry latex of negative ion far-infrared tourmaline powder, by following quality proportioning, form %
Compound method: the same.
The purposes of elastic rubber suppurative mastitis light cement: be widely used in construction work, as the waterproof layer of underground works, hydro project, airstrip, port and pier, rudder for ship, fabrication facility floor are laid.Highway, enclosure wall etc. be runway, bridge, road night lighting to ensure safety, minimizing accident.
The alkaline residue component of alkali factory is analyzed: calcium is 31.44%, magnesium 5.83%, potassium 4.02%, sodium 0.78%, aluminium 0.51%, iron 0.33%, manganese 446mg/kg, P 32 8.5mg/kg, titanium 293.9mg/kg, vanadium 18.6mg/kg, cobalt 13.51mg/kg, solvable silicon 11.6mg/kg, strontium 123.9mg/kg, zinc 220.5mg/kg, chromium 87.8mg/kg, beryllium 0.94mg/kg, cadmium 2.91mg/kg, silver < 0.1mg/kg, chlorine is 2.87%, pH=11, the fine molecule of these elements distributes with space HUMAN HEALTH is produced to extremely useful active effect.
In the material that negative ion occurs, tourmalinite is the widest a kind of natural crystal, and it is also to take the silicate of aluminium that boracic is feature, sodium, iron, magnesium, lithium ring texture, and its main component has Al
2o
3, SiO
2, Fe
2o
3, TiO
2, B
2o
5deng, applying nano tourmalinite micropowder, it has pyroelectricity and piezoelectricity, is therefore having temperature and pressure, even under the most small changing conditions, can cause the potential difference between negative ion crystal, thereby forms electric field.High-voltage ionizes the air in electric field, and the electron attachment of being hit is near water and oxygen molecule, and makes it can be converted into negative aeroion.Thisly contain water molecules and the water molecules in ambient air that negative ion far-infrared in use can distribute some and health naturally faint electrolytic action occurs, produce hydroxyl group anion, can regulate the Air quality in human body surrounding environment, and with air in the neutralization of positively charged nuisance, become macromole and the ground of landing makes air fresh clearly, make people enjoy clean space, avoid air-polluting injury.
Society is because standard of living improves constantly, the food that people take in high fat kind increases, in human body, acid base equilibrium is damaged, and causes acidic substance to deposit in a large number, and in body, excessive acidic substance are the important risk factors that cause modern civilization diseases, rich man disease.Negative ion far-infrared tourmalinite nano powder energy disperse in this product is in air, can regulate by human body respiration and vitro skin osmotic absorption the acid base equilibrium of element body fluid, be conducive to eliminate the toxin of body inner acidic meta-bolites, be conducive to supplement incessantly, adjusting, antagonist interior element balance, be conducive to strengthening immunity, prevent and cure diseases, improve the health.From biophysics viewpoint, human body is an organism, and in organism, each cell is exactly a minicell, has the potential difference of 50-90mV inside and outside cytolemma, and the bioelectric current that cell battery provides is the energy of nervous system activity.Contain negative ion far-infrared emissive material, it is because several minicells form, can accomplish incessantly to human body cell electric energy supplement, and send negative ion far-infrared, its effect never fails, and can go deep into the heating of subcutis 3-5mm automatic heating, make deep tissues activation, acceleration metabolism and cell viability can keep and produce negative ion simultaneously, are conducive to promote health, delaying skin cell aging, improves the health and lengthens one's life.This luminous cement that is rich in various trace elements anion far infrared rays can be turned waste into wealth simultaneously, and disperse is in space.These activeconstituentss can promote health, and again for night lighting provides convenience, minimizing accident, guarantees human life property safety.
Below in conjunction with embodiment, the present invention is further described
Specific implementation method:
Embodiment 1:
(1) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of alkaline residue silicate, by following quality proportioning, form %
(2) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by blast furnace slag light-emitting phosphor cement, by following quality proportioning, form %
Slag ash 20-60; Lime 10-30;
Terra alba 2-6; Terra alba 2-6;
Fluorescence radiation powder 2-6; Blast furnace slag adds to 100%;
(3) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of rare earth element slag brick dark grey, by following quality proportioning, form %
Rare earth element slag 3-9; Lime 10-30;
Gypsum 2-6; Silicic acid luminescent material 2-6;
Brickbat soil brick and tile pottery ashes adds to 100%;
(4) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, by following quality proportioning, form %
Ferrosilicon ground-slag 5-15; Lime powder 5-15;
Gypsum 5-15; Silicate cement 5-15;
Sulfide luminescent material 5-15; Broken porcelain basin bowl crock pottery flour adds to 100%;
(5) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, by following quality proportioning, form %
Copper ashes 5-15; Calcium phosphate 10-30;
Dicalcium Phosphate (Feed Grade) 5-15; Transparent high-visibility pigment powder 5-15;
Sulphur calcium molybdate adds to 100%;
(6) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of hetaerolite pulp water glass elastic water-proof latex, by following quality proportioning, form %
(7) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the elastic luminous cement of the natural dry latex of negative ion far-infrared tourmaline powder, by following quality proportioning, form %
The luminous cement of a kind of useless brick and tile porcelain slag, by the luminous cement of alkaline residue silicate, blast furnace slag light-emitting phosphor cement, the luminous cement of rare earth element slag brick dark grey, the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, the luminous cement of hetaerolite pulp water glass elastic water-proof latex, the elastic luminous cement composition of the natural dry latex of negative ion far-infrared tourmaline powder, it is characterized in that: by following quality proportioning, form %
Embodiment 2: the luminous cement of a kind of useless brick and tile porcelain slag, by the luminous cement of alkaline residue silicate, blast furnace slag light-emitting phosphor cement, the luminous cement of rare earth element slag brick dark grey, the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, the luminous cement of hetaerolite pulp water glass elastic water-proof latex, the elastic luminous cement composition of the natural dry latex of negative ion far-infrared tourmaline powder, it is characterized in that: by following quality proportioning, form %
Embodiment 3: the luminous cement of a kind of useless brick and tile porcelain slag, by the luminous cement of alkaline residue silicate, blast furnace slag light-emitting phosphor cement, the luminous cement of rare earth element slag brick dark grey, the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, the luminous cement of hetaerolite pulp water glass elastic water-proof latex, the elastic luminous cement composition of the natural dry latex of negative ion far-infrared tourmaline powder, it is characterized in that: by following quality proportioning, form %
Embodiment 4: the luminous cement of a kind of useless brick and tile porcelain slag, by the luminous cement of alkaline residue silicate, blast furnace slag light-emitting phosphor cement, the luminous cement of rare earth element slag brick dark grey, the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, the luminous cement of hetaerolite pulp water glass elastic water-proof latex, the elastic luminous cement composition of the natural dry latex of negative ion far-infrared tourmaline powder, it is characterized in that: by following quality proportioning, form %
Embodiment 5: the luminous cement of a kind of useless brick and tile porcelain slag, by the luminous cement of alkaline residue silicate, blast furnace slag light-emitting phosphor cement, the luminous cement of rare earth element slag brick dark grey, the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, the luminous cement of hetaerolite pulp water glass elastic water-proof latex, the elastic luminous cement composition of the natural dry latex of negative ion far-infrared tourmaline powder, it is characterized in that: by following quality proportioning, form %
Embodiment 6: the luminous cement of a kind of useless brick and tile porcelain slag, by the luminous cement of alkaline residue silicate, blast furnace slag light-emitting phosphor cement, the luminous cement of rare earth element slag brick dark grey, the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, the luminous cement of hetaerolite pulp water glass elastic water-proof latex, the elastic luminous cement composition of the natural dry latex of negative ion far-infrared tourmaline powder, it is characterized in that: by following quality proportioning, form %
Embodiment 7: the luminous cement of a kind of useless brick and tile porcelain slag, by the luminous cement of alkaline residue silicate, blast furnace slag light-emitting phosphor cement, the luminous cement of rare earth element slag brick dark grey, the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, the luminous cement of hetaerolite pulp water glass elastic water-proof latex, the elastic luminous cement composition of the natural dry latex of negative ion far-infrared tourmaline powder, it is characterized in that: by following quality proportioning, form %
Claims (1)
1. the luminous cement of useless brick and tile porcelain slag, is characterized in that: by following quality proportioning, form %
(1) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of alkaline residue silicate, by following quality proportioning, form %
(2) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by blast furnace slag light-emitting phosphor cement, by following quality proportioning, form %
Slag ash 20-60; Lime 10-30;
Terra alba 2-6; Terra alba 2-6;
Fluorescence radiation powder 2-6; Blast furnace slag adds to 100%;
(3) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of rare earth element slag brick dark grey, by following quality proportioning, form %
Rare earth element slag 3-9; Lime 10-30;
Gypsum 2-6; Silicic acid luminescent material 2-6;
Brickbat soil brick and tile pottery ashes adds to 100%;
(4) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of the broken porcelain basin of ferro-silicon slag bowl tank, by following quality proportioning, form %
Ferrosilicon ground-slag 5-15; Lime powder 5-15;
Gypsum 5-15; Silicate cement 5-15;
Sulfide luminescent material 5-15; Broken porcelain basin bowl crock pottery flour adds to 100%;
(5) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the hard luminous cement of copper ashes sulphur calcium molybdate hypervelocity, by following quality proportioning, form %
Copper ashes 5-15; Calcium phosphate 10-30;
Dicalcium Phosphate (Feed Grade) 5-15; Transparent high-visibility pigment powder 5-15;
Sulphur calcium molybdate adds to 100%;
(6) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the luminous cement of hetaerolite pulp water glass elastic water-proof latex, by following quality proportioning, form %
(7) the luminous cement of useless brick and tile porcelain slag, is characterized in that: by the elastic luminous cement of the natural dry latex of negative ion far-infrared tourmaline powder, by following quality proportioning, form %
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105948608A (en) * | 2016-04-16 | 2016-09-21 | 南通蛇类治疗研究所 | Ecologically healthy environment-friendly cement |
| CN107586078A (en) * | 2016-07-08 | 2018-01-16 | 南通蛇类治疗研究所 | The environmentally friendly cement of useless brick and tile porcelain clinker production anion |
| CN108529916A (en) * | 2018-04-27 | 2018-09-14 | 济南大学 | A kind of autofluorescence sulphoaluminate cement clinker and preparation method thereof |
| CN108751754A (en) * | 2018-05-28 | 2018-11-06 | 湖南三恒建设园林工程有限公司 | A kind of preparation method of noctilucence cement and noctilucence road surface |
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| CN1660712A (en) * | 2004-02-25 | 2005-08-31 | 李明禹 | Storing up and luminous dimension stoney and manufacturing method |
| CN101328043A (en) * | 2008-05-23 | 2008-12-24 | 中建三局建设工程股份有限公司 | Preparation of high brilliant white high weatherability white concrete |
| CN101805608A (en) * | 2010-03-08 | 2010-08-18 | 南昌大学 | Luminescent transparent cement-based material |
| CN103570320A (en) * | 2013-11-12 | 2014-02-12 | 安斌斌 | Artificial marble raw material composition |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1660712A (en) * | 2004-02-25 | 2005-08-31 | 李明禹 | Storing up and luminous dimension stoney and manufacturing method |
| CN101328043A (en) * | 2008-05-23 | 2008-12-24 | 中建三局建设工程股份有限公司 | Preparation of high brilliant white high weatherability white concrete |
| CN101805608A (en) * | 2010-03-08 | 2010-08-18 | 南昌大学 | Luminescent transparent cement-based material |
| CN103570320A (en) * | 2013-11-12 | 2014-02-12 | 安斌斌 | Artificial marble raw material composition |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105948608A (en) * | 2016-04-16 | 2016-09-21 | 南通蛇类治疗研究所 | Ecologically healthy environment-friendly cement |
| CN107586078A (en) * | 2016-07-08 | 2018-01-16 | 南通蛇类治疗研究所 | The environmentally friendly cement of useless brick and tile porcelain clinker production anion |
| CN108529916A (en) * | 2018-04-27 | 2018-09-14 | 济南大学 | A kind of autofluorescence sulphoaluminate cement clinker and preparation method thereof |
| CN108751754A (en) * | 2018-05-28 | 2018-11-06 | 湖南三恒建设园林工程有限公司 | A kind of preparation method of noctilucence cement and noctilucence road surface |
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Application publication date: 20140924 |