CN104058544B - Method and device for preparing small molecular hydrogen-rich water - Google Patents
Method and device for preparing small molecular hydrogen-rich water Download PDFInfo
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- CN104058544B CN104058544B CN201410335775.4A CN201410335775A CN104058544B CN 104058544 B CN104058544 B CN 104058544B CN 201410335775 A CN201410335775 A CN 201410335775A CN 104058544 B CN104058544 B CN 104058544B
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Abstract
The invention discloses a method and a device for preparing small molecular hydrogen-rich water. The method comprises the steps of carrying out primary balance mixing on hydrogen and drinking water to form a primary hydrogen-water mixed solution, enabling the primary hydrogen-water mixed solution to enter a centrifugal pump to complete secondary mixing, enabling the secondly mixed hydrogen-water mixed solution to pass through a high-precision electrical automatic washing filter and a shower-type controller nozzle to allow the hydrogen-water mixed solution to form a high-speed ordered linear motion and collide with each other to complete third mixing, enabling thirdly mixed hydrogen-water mixed solution to flow through a small molecular water preparation device to obtain the small molecular water, delivering the small molecular water to an anti-impulse bubble releaser to generate micro-nanometer bubbles of which the diameters are 200nm-4 microns by virtue of the anti-impulse bubble releaser and further to form a bubble solution containing micro-nanometer hydrogen, delivering the bubble solution containing micro-nanometer hydrogen into the bottom of a storage container, and dissolving hydrogen in the micro-nanometer bubbles in the small molecular water to prepare the small molecular hydrogen-rich water. The small molecular hydrogen-rich water preparation technology disclosed by the invention can provide a new level of healthy living for human.
Description
Technical field
The invention belongs to the preparation field of tap water, be specifically related to preparation method and the equipment of the rich hydrogen water of a kind of small molecules.
Background technology
Rich hydrogen water due to its nourishing function by people's widespread use, but the general efficiency of existing rich hydrogen tap water preparation method is low, the particle diameter of conventional bubble is at more than 1--8mm, lift velocity is 450mm--1200mm/s, bubble only has a small amount of gas dissolving in water in uphill process, and the bubble of final more than 75% reverts in air after floating on the surface of the water and breaking.Which kind of method no matter the bubble of artificial manufacture adopt all need consumed energy or as chemical substance, is therefore very low by the efficiency that the method for conventional bubble aeration prepares rich hydrogen water.
Summary of the invention
The present invention is intended to for deficiency of the prior art, the preparation method of the rich hydrogen water of the small molecules providing a kind of preparation efficiency high and equipment.
Technical scheme of the present invention is as follows: the preparation method of the rich hydrogen water of a kind of small molecules, comprises the following steps:
1.1, by hydrogen and tap water in mass ratio 3-8% carry out preliminary balanced mixing forming elementary mixing wastewater with air liquid afterwards;
1.2, make elementary mixing wastewater with air liquid enter in impeller pump, form the secondary mixing wastewater with air liquid of 0.35--0.65MPa pressure;
1.3, make the mixing wastewater with air liquid after secondary mixing wastewater with air by high precision electro automatic backwash filter and shower nozzle type controller spout, make mixing wastewater with air liquid form the motion of high speed ordered linear, and the third time mixing that collided with each other;
1.4, make three mixed mixing wastewater with air liquid flow through from micromolecular water preparing device, perpendicular cuts magnetic line of force, makes water molecules bundle be crushed to 0.5-1.5 nanometers, obtains micromolecular water;
1.5, micromolecular water is transported to recoil to swash bubble reliever and swash by recoil the micro-nano bubble that bubble reliever produces bubble diameter 200 nanometer to 4 micron, forms the bubble liquid containing micro-nano hydrogen;
1.6, micro-nano hydrogen gas bubbles liquid is sent into bottom storage vessel, the hydrogen in micro-nano bubble is dissolved in micromolecular water and prepares the rich hydrogen water of small molecules;
By oxygen and tap water in mass ratio 3-8% carry out preliminary balanced mixing forming primary oxygen and water mixed liquid afterwards, then what a process for preparing is small molecules heavy-oxygen-enriched water.
The Preparation equipment of the rich hydrogen water of a kind of small molecules that the present invention adopts, comprises drinking water container, hydrogen gas tank and air water hybrid equalizer, and drinking water container outlet is connected with mixing wastewater with air equalizer, and hydrogen gas tank is connected with mixing wastewater with air equalizer by hydrogen reducing valve;
The outlet of mixing wastewater with air equalizer is connected with impeller pump, outlet of centrifugal pump enters shower nozzle type controller by high precision electro automatic backwash filter and is connected with high-density air water mixing tank entrance, the outlet of high-density air water mixing tank is provided with micromolecular water transfer lime, and micromolecular water transfer lime surrounding is provided with micromolecular water preparing device;
The outlet of micromolecular water transfer lime is connected with storage vessel, is provided with recoil and swashs bubble reliever in small molecules rich hydrogen water stainless steel storage vessel lower entrances.
Described mixing wastewater with air equalizer, there is a tube of pressure-stabilizing, it is tube of pressure-stabilizing upper cover above tube of pressure-stabilizing, tube of pressure-stabilizing upper cover and tube of pressure-stabilizing are connected with joint flange and seal, water-in is provided with in the lower right of tube of pressure-stabilizing, water-in stretches into centre upwards 90 degree of connection charging tubes of tube of pressure-stabilizing, porous web plate is had at the upper and lower ends of charging tube, charging tube is built with porous ceramics material, open a pipeline to be connected with the negative pressure Self inhaling device be provided with outside tube of pressure-stabilizing on the top of water-in, high-pressure water inlet is communicated with at the right-hand member of negative pressure Self inhaling device, gas inlet is had above negative pressure Self inhaling device, mixing wastewater with air liquid is had in tube of pressure-stabilizing, the outlet of mixing wastewater with air liquid is provided with in the lower left of tube of pressure-stabilizing.
Described high precision electro automatic backwash filter comprises lower cover, filter cylinder, filter vat, cartridge type hairbrush, filter inlet, shaft coupling sleeve, electric motor, speed reduction unit, upper cover inlet segment and water outlet, joint flange is had at the two ends of filter cylinder, bottom connects lower cover, top connects upper cover inlet segment, filter vat and cartridge type hairbrush are equipped with in inside, the upper and lower ends of cartridge type hairbrush inserts in the groove of upper cover inlet segment and lower cover respectively, seal with O-ring seal, the hairbrush external diameter of cartridge type hairbrush is greater than the internal diameter 3 to 5 millimeters of filter vat, self-align tubular hairbrush is in the internal diameter of filter vat and pressing force is scrubbed in formation, on the top of upper cover inlet segment, electric motor and speed reduction unit are housed, electric motor and speed reduction unit pass to cartridge type hairbrush by shaft coupling sleeve and universal coupling pivot pin rotary torque.
Described speed reduction unit and cartridge type hairbrush are by universal coupling transmission.
The filter inlet place of described filter cylinder is provided with inlet pressure sensor.
The order number of described filter vat can improve filtering accuracy by replacing or improve filtering traffic.
The water outlet of described filter cylinder is provided with outlet pressure sensor.
All seal with O-ring seal with lower cover, top and upper cover inlet segment bottom described filter cylinder, fastening with bolt and nut.
Described high-density air water mixing tank, comprise the upright closed cylinder arranged, the bottom of closed cylinder is provided with mixed solution water outlet, is provided with inserts into the inner the water inlet pipe of portion's transfer pressure water and the inlet pipe of feeds air under pressure on the top of described closed cylinder; The water side of described water inlet pipe is fixedly connected with outlet shower nozzle type controller spout upwards, and the outlet side of described inlet pipe is communicated with water inlet pipe; In described closed cylinder, the top of shower nozzle type controller spout is provided with the cover body of arc surfaced, falls in closed cylinder after the water of described shower nozzle type controller spout ejection clashes into cover body.
The face that described cover body is relative with shower nozzle type controller spout is uneven surface.
Described cover body is semisphere.
Described cover body is made up of pottery.
Described closed cylinder is provided with liquidometer.
Described recoil swashs bubble reliever, comprise body, be arranged at the deflection cone be sealed and matched with body in body and the reverse deflection cone be fixedly connected with deflection cone, described deflection cone has acceleration mouth, described reverse deflection cone has an excitation cavity, the bottom of described excitation cavity is V-arrangement, top smooth contraction transition forms the less opening of a cross-sectional area, and the cross-sectional area of this opening is greater than the acceleration mouth of deflection cone; The opening part of described reverse deflection cone has the guide face of the first spination projection along the body formation one that extends radially outwardly, end face relative with guide face on described deflection cone is provided with the second spination protruding, described first spination is protruding and the second spination is protruding forms zig-zag shearing passage.
Described first spination is protruding to be crisscross arranged with the second spination projection.
The mating surface roll form of described body and deflection cone is fastening.
O RunddichtringO is provided with between described body and the mating surface of deflection cone.
Described reverse deflection cone is fixedly connected with deflection cone by connecting arm.
The present invention only uses an electric motor, complete: improve liquid pressure, air-breathing, supply gas, three second compression, four speed-raisings, stir for four times, once filter, high-intensity magnetic field prepares small-micelle water, 17 work such as rich hydrogen water preparation, make brief electromechanical machine, the present invention adopts the water column of high-speed motion by in-plant fixing orifice ring, gas is between the two impelled to produce negative pressure, principle of differential pressure is used gas to be sucked and sends in a negative-pressure container, in this embodiment gas carried out balanced mixing with water and form balanced mixing wastewater with air liquid, lay the foundation for pump not easily produces cavitation erosion, small molecules of the present invention rich hydrogen water technology of preparing will provide the healthy living of brand-new height for the mankind.
Accompanying drawing explanation
Fig. 1 is preparation method's technological process block-diagram of the present invention;
Fig. 2 is Preparation equipment schematic diagram of the present invention;
Fig. 3 is the structural representation of mixing wastewater with air equalizer of the present invention;
Fig. 4 is the structural representation of high precision electro automatic backwash filter of the present invention;
Fig. 5 is the structural representation of high-density air water mixing tank of the present invention;
Fig. 6 is the structural representation that recoil of the present invention swashs bubble reliever;
In figure: 1, drinking water container, 2, clean water transfer lime, 3, hydrogen delivery tube, 4, clean water under meter, 5, mixing wastewater with air equalizer, 6, stainless steel centrifugal pump, 7, high precision electro automatic backwash filter, 8, shower nozzle type controller, 9, high-density air water mixing tank, 10, micromolecular water preparing device, 11, micromolecular water transfer lime, 12, recoil swashs bubble reliever, and 13, storage vessel, 14, hydrogen reducing valve, 15, food grade hydrogen gas tank with pressure, 16, hydrogen flowmeter, 17, to dress filling machine or user's small molecules rich hydrogen water transfer lime, 18, water-in, 19, high-pressure water inlet, 20, negative pressure Self inhaling device, 21, gas inlet, 22, tube of pressure-stabilizing, 23, charging tube, 24, porous ceramics material, 25, porous web plate, joint flange, 26, tube of pressure-stabilizing upper cover, 27, mixing wastewater with air liquid, 28, mixing wastewater with air liquid exports, and 29, lower cover, 30, filter cylinder, 31, filter vat, 32, cartridge type hairbrush, 33, cross water round, 34, universal coupling pivot pin, 35, filter inlet, 36, O-ring seal, 37, shaft coupling sleeve, 38, electric motor, 39, speed reduction unit, 40, inlet pressure sensor, 41, upper cover inlet segment, 42, bolt and nut, 43, joint flange, 44, water outlet, 45, outlet pressure sensor, 46, cylindrical shell, 47, mixed solution finished product, 48, mixed solution water outlet, 49, liquidometer, 50, inlet pipe, 51, shower nozzle type controller spout, 52, cover body, 53, water inlet pipe, 54, body, 55, deflection cone, 56, accelerate mouth, 57, reverse deflection cone, 58, zig-zag shears passage, and 59, excitation cavity.
Embodiment
Below in conjunction with accompanying drawing 1-2 and embodiment, the preparation system to the rich hydrogen water of small molecules of the present invention further illustrates by technical process:
First from stainless steel drinking water container 1, extract qualified tap water, enter in the mixing wastewater with air equalizer 5 in system.
High pressure hydrogen simultaneously in food grade hydrogen gas tank 15 with pressure through hydrogen reducing valve 14, then through hydrogen flowmeter 16 in the mixing wastewater with air equalizer 5 in qualified food grade hydrogen feeding system.
Tap water and hydrogen are in mixing wastewater with air equalizer 5, quality due to gas is less than liquid, the coefficient of friction of gas is also less than liquid, therefore in porous ceramics material, the movement velocity of gas is faster than liquid, and this physical differences impels gas and liquid to form mutual friction, crumple to move and fuse and generate primary equalization mixed solution entering the initial stage athletic meeting in porous ceramics.
Balanced mixed mixing wastewater with air liquid enters in stainless steel centrifugal pump 6.Make mixing wastewater with air liquid produce centrifugal force in the pump impeller of high speed rotating, then be converted into pressure by the collection of the evolvent type pump housing, pressure brings up to the pressure of the 0.35--0.65MPa needed for preparation system gradually from negative pressure.And complete secondary mixing.
After being filtered by high precision electro automatic backwash filter 7 with the mixing wastewater with air liquid of pressure energy, deliver into shower nozzle type controller 8 from top, make mixing wastewater with air liquid form high speed ordered linear upwards cross motion, and the third time mixing that collided with each other.Store in the cylindrical shell 46 of high-density air water mixing tank 9.
Export at high-density air water mixing tank 9, micromolecular water transfer lime 11 is outside equipped with micromolecular water preparing device 10, mixing wastewater with air liquid is from micromolecular water preparing device 10 high speed perpendicular cuts magnetic line of force from high-intensity magnetic field, water molecules bundle is made to be crushed to 0.5-1.5 nanometer, obtain micromolecular water, and be negative potential, weakly alkaline.There is sterilization, algae removal simultaneously, except poison, can directly drink raw.Micromolecular water preparing device 10 selects existing golden section water height Magnetized running water apparatus or purple light lucky beautiful source, Tianjin height magnetization small molecules hydrophone.
The mixing wastewater with air liquid of micromolecular water is mixed and makes through three times, delivering into device by micromolecular water transfer lime 11 swashs in bubble reliever 12 in the recoil of the bottom of small molecules rich hydrogen water stainless steel storage vessel 13, the initial velocity that mixing wastewater with air liquid swashs in bubble reliever 12 in recoil reaches 35-45 meter per second, be increased to 60-75 meter per second gradually, when the ring-type entering into reliever shears narrow slit, flow velocity reaches 120-150 meter per second, form high speed kinetic energy, and mixed solution is sheared in narrow slit in annular and is sheared, arrive outlet position time space sudden enlargement, high speed kinetic energy during narrow slit outlet ejection is suddenly released, produce the effect of blast, thus produce the micro-nano bubble of bubble diameter 200 nanometer to 4 micron, form the bubble liquid containing micro-nano hydrogen.
When being contained in after the recoil bottom small molecules rich hydrogen water stainless steel storage vessel 13 swashs the bubble liquid producing micro-nano hydrogen in bubble reliever 12, the bubble liquid of micro-nano hydrogen is just dissolved into the hydrogen in micro-nano bubble in micromolecular water in storage vessel, prepares the rich hydrogen water of small molecules.
Finally, to dress filling machine or user's small molecules rich hydrogen water transfer lime.
When the micro-nano bubble formation of hydrogen and when being released in water body, micro-nano bubble is no longer arranged by simple buoyancy, liquid-gas interface becomes thickness, and make the rising of micro-nano bubble and move as slow in paste, its lift velocity is the 1/100-1/200 of grade bubble.Self there is due to micro-nano bubble the characteristics such as high interior pressure, high surface energy, high interfacial activity, the micro-nano bubble of about 90% destroys in uphill process, can atomic little spatial dimension produce the high temperature of 1900-5200K and be greater than the partial high pressure of 50Mpa around nano bubble, the high temperature and high pressure produced in molecular level aspect will significantly improve for the solvability of hydrogen molecule, with majority of gas unlike, the solubility with temperature of hydrogen increases and increases, and solubleness is directly proportional to pressure.According to law of gas diffusion, the square root of gas velocity of diffusion in a liquid and this gas relative molecular mass is inversely proportional to, and the velocity of diffusion of hydrogen in liquid and tissue is 3.74 times of nitrogen, 1.41 times of helium.
The small molecules of the present invention rich hydrogen water technology of preparing creativity and innovation perfect adaptation product of energy-conserving and environment-protective technology advanced in recent years and small molecules rich hydrogen water technology of preparing, will provide the healthy living of brand-new height for the mankind.
In the present system:
1, micromolecular water (H
2o) numerator value of n, n value is 3-6, its movement velocity is fast, there is extremely strong seepage force, diffusive force, solvency power, metabolism power, more easily by the exchange of intraor extracellular water, scavenging free radicals, noxious acidic metabolite and various refuse, promote growing of cell, keeps the vitality of cell.Small molecules bundle ￠ <1nm, and be negative potential, weakly alkaline, its half-amplitude duration < 90 hertz,
17o nucleus magnetic resonance (NMR) half aspect ratio ortho-water reduces by more than 50, and its fluctuation ratio is 299000 Gausses/second, and fluctuation ratio is close with body cell.Its preparation method comprises: utilize mixing wastewater with air fluid to pass rapidly through permanent magnetic strong magnetic field, make fluid orthogonal cutting magnetic line, obtain small-micelle water.
2, rich hydrogen water
2-1, specific heat are large, and good heat-transfer, because hydrogen thermal conductivity under identical pressure condition is 7 times of air, 13.6 times of nitrogen, 2.72 times of helium, therefore the thermal conductivity of rich hydrogen water is maximum in all gas solution, and namely acoustic speed is greater than the water of not hydrogen under the same conditions.
2-2, velocity of diffusion are fast, and according to law of gas diffusion, the square root of gas velocity of diffusion in a liquid and this gas relative molecular mass is inversely proportional to.Hydrogen is the minimum element of molecular mass, and hydrogen velocity of diffusion in liquid and tissue is 3.74 times of nitrogen, 1.41 times of helium, and therefore the velocity of diffusion of rich hydrogen water can infiltrate tissue quickly than the water of not hydrogen, enters cell ion channel;
2-3, in normal conditions, the acoustic speed of air is 331 meter per seconds, and the acoustic speed of helium is 972 meter per seconds, and the acoustic speed of hydrogen is 1286 meter per seconds, therefore rich hydrogen water under the same conditions acoustic speed be greater than the water of not hydrogen.
3, hydrogen more than concentration of ordinary dissolution > 2.5ppm under standard environment.
4, under standard state, dissolved oxygen concentration below < 2.0ppm.
5, under standard state, redox potential ORP value is between-500--800mv.
6, under standard state, its high stability shows that preserving type only needs the aluminium ring pull end packaging of comparative maturity or the Lilezhen packaging of liner aluminium foil, the feature such as can to preserve at normal temperatures and pressures for a long time, at the mark internal oxidition quality guarantee period reduction potential ORP value ascensional range < 5% of product.
7, need under standard state to obtain mass-producing have high reactivity, hypertonicity, high-dissolvability, high stability, high reductibility " small molecules rich hydrogen water ".No matter its range of application all can meet as a kind of healthy beverage or other biological, industrial use.
The manufacture method of the rich hydrogen water of the small molecules 8, described in technical solution of the present invention, electric energy, mechanical energy, magnetic force energy is adopted to be converted into pressure, the shearing force of G&W, thus realize the conversion of energy, induction gas-liquid two-phase merges mutually, power transfer also promotes step by step, the physics finally realizing molecule aspect changes, and brings following unforeseeable technique effect:
Enter air water equalizer after hydrogen decompression in 8-1, hydrogen gas tank, the water simultaneously in high-level container flows automatically and enters hybrid equalizer under natural pressure, makes air water equilibrium mixing, overcome the difficult problem that pump produces cavitation erosion in equalizer;
Mixing wastewater with air liquid in 8-2, mixing wastewater with air equalizer enters impeller pump under negative pressure, and because liquids and gases make high speed rotating in impeller, gas is carried out secondary stirring forcefully with water and mixes;
8-3, mixing wastewater with air liquid by the built-in nozzle of feeding mixing wastewater with air tank with pressure, formed high speed wire water and interlaced, collision, force liquids and gases carry out three times mixing;
8-4, in the excitation cavity of reliever, gas and water obtain the 4th high-speed stirring and inspire more highdensity mixing wastewater with air liquid, the ring-type entering reliever is again sheared in narrow slit, flow velocity in narrow slit reaches 120-150 meter per second and forms high speed kinetic energy, forms the 5th high-speed stirring;
8-5, high speed kinetic energy arrive narrow slit outlet position time space sudden enlargement, energy is suddenly released and produces blast, create the micro-nano bubble of micro-nano hydrogen of bubble diameter 200 nanometer to 4 micron, use micro-nano bubble aeration, in water, the hydrogen gas of 84-90% is dissolved in water, reach high-level efficiency aeration in water and hydrogen is dissolved in the object in water;
8-6, due to hydrogen nano bubble lift velocity extremely slow 4-12mm/ second in water, therefore in uphill process the micro-nano gas bubble of the hydrogen of 84-90% in water, because the formula that crumbles and fall of micro-nano bubble is dissolved, simultaneously with the generation of high temperature and high pressure, therefore to be driven and final with gaseous form dissipation at the micro-nano gas bubble of hydrogen dissolved oxygen in this process of water, oxygen solubility DO value going reduction, micro-nano bubble is formed to the whole process of oyster white bubble collapse about 10 minutes from water body and hydrogen mixed flow, hydrogen solubleness rises to more than 2.5ppm by 0, oxygen solubility is dropped rapidly to below 2.5ppm by 5-7ppm, redox potential (ORP value) is by being dropped rapidly between-500mv to-800mv between+500mv to+700mv,
8-7, mixing wastewater with air liquid from high-intensity magnetic field with the flow velocity of 60 to 65 meter per seconds fast, pass perpendicularly through cutting magnetic line, make water molecules bundle be crushed to 0.5-1.5 nanometers, obtain micromolecular water.Because micromolecular water has superpower activity and solvability, for becoming the hydrogen molecule of micro-nano state to have stronger pardon, form highly stable mutual solubility and interpenetrating property in molecule aspect.The efficiency manufacturing rich hydrogen water is more than the hundred times of conventional aeration method.Have outstanding environmental protection and energy saving and high efficiency, this invention achieves following breakthrough:
As everyone knows, human body be by
cellforming, the disease of people finally can be summed up as cell damage, and the aging of people is also because cell senescence or necrosis caused; Cytopathic or aging main arch-criminal is caused to be exactly superfluous " oxyradical ".
How does oxyradical produce? oxygen enters in body by the breathing of people, is transported in each cell by the red blood corpuscle in blood.Wherein having 2% can become combustion residue, is exactly " active oxygen ".Because foodstuff additive, the reason such as sweet water containing chlorine, gut microflora is lacked of proper care, and causes abnormal fermentation in stomach, and now, active oxygen can produce in a large number.
Hydrogen is a kind of colourless, tasteless, nontoxic, and odorless gas.The peculiar property of hydrogen, determines hydrogen on biology, has many advantages.An obvious feature is exactly powerful penetrance, can enter intracellular any position easily.This has established the key character that hydrogen may be used for disease therapy.
The primary efficacy of hydrogen is: anti-oxidant, optionally and hydroxyl radical free radical, and nitrous acid negatively charged ion etc." hydrogen ion is combined with active oxygen and is reduced into water " excretes.Briefly " rich hydrogen water " is exactly a kind of hydrogeneous water having strong reducing power in water that allows, by the anti-oxidant reducing power of its selectivity " active oxygen superfluous in purged body " be one efficiently, naturally functional tap water.
The security of rich hydrogen water: the large intestinal bacterium of human body can produce hydrogen, illustrates that hydrogen belongs to endogenous gas, is the home of human body cell.Therefore hydrogen has safe prerequisite.But hydrogen is difficult to be dissolved in water, if calculated according to volumetric molar concentration, when 20 DEG C, the concentration of water dissolution 101.325kPa pure hydrogen is 0.92mmoI/L.
How to promote concentration and the stability of hydrogen water, be only the scientific research difficult problem in hydrogen medical use." micro-nano gas-liquid mixed technology " that the present invention proposes has been captured hydrogen and has been insoluble in the science bottleneck of water and a difficult problem for industrially scalable production.
The method of physics is adopted to prepare micromolecular water and allow micromolecular water evenly wrap up hydrogen molecule, hydrogen reaches highly stable combined with micromolecular water in formation micro/nano level hydrogen gas bubbles situation under molecular level state, the rich hydrogen glassware for drinking water of small molecules of such preparation has density of hydrogen high, the features such as stability is good.
The effect of the generation of negative pressure and Self inhaling and mixing wastewater with air equalizer: when swiftly passing object is by in-plant fixed object, air pressure between the two will produce negative pressure, negative pressure Self inhaling device fully uses this physical phenomenon, gas is sucked and sends into a negative-pressure container, gas carries out balanced mixing with water and designs and become mixing wastewater with air equalizer in this embodiment, and the liquid of mixed equilibrium is had laid a good foundation for preventing pump from producing cavitation erosion.
The cavitation of conventional centrifugal pump: when there being gas to be mixed into conventional centrifugal pump inlet in liquid, must cavitation be there is in conventional pumps, cavitation can destroy the normal operation of conventional centrifugal pump, causes pump to can not form centrifugal force or pressure time serious, is the common difficult problem of general user.
Anti-cavitation stainless steel centrifugal pump: adopt a certain proportion of gas with liquid and fully mix, impeller eye is entered with the flow velocity arranged lower than conventional pumps, keep the stability of pump impeller entrance negative pressure, thus keep pump impeller to suck the stability of liquid, overcome cavitation, impeller selects cavitation stainless steel.
Pump impeller high speed rotating keeps constantly producing centrifugal force, and the flow velocity in pump impeller, by evenly accelerating slowly, impels the pressure of mixing wastewater with air liquid in pump impeller, to bring up to the pressure needed for system gradually by negative pressure.
Due to the high speed rotating of pump impeller, under the influence of centrifugal force, outwards impinge upon on spirochete involute urve that the pump housing is arranged, in flow velocity and the fast-changing process of pressure, gas and water are uniformly mixed liquid further.
Accumulation of energy pipe: when the mixing wastewater with air liquid mixed by secondary enters accumulation of energy pipe with low speed, with the form of pressure savings energy in accumulation of energy pipe, accumulation of energy pipe is not only put aside energy and is had shock absorption in the present system, ensures system run all right.
High-density air water mixing tank: energy is released when the pressure water put aside sprays from the spout of shower nozzle type controller from the end of accumulation of energy pipe again, liquid impacts top tank structure with the flow velocity of 25 to 35 meter per seconds, form the globule of small particle size, the specific surface area that the globule of globule small particle size compared with water column of small particle size contacts with gas expands several thousand times, therefore obtains highdensity mixing wastewater with air liquid after third time mixing;
Micro-nano bubble reliever: when being entered secondary accumulation of energy pipe by the mixing wastewater with air liquid of three mixing with low speed, this energy and pressure enter micro-nano bubble reliever from accumulation of energy pipe, and mixing wastewater with air liquid pours in excitation cavity with the flow velocity of 35 to 45 meter per seconds in reliever;
In narrow excitation cavity, mixed solution is subject to the stop formation mixed flow body of V-arrangement wall, in the mixed flow body of high speed and high pressure, hydrogen and water obtain the 4th high-speed stirring and inspire more highdensity mixing wastewater with air liquid, because high speed and high pressure and mixed flow produce strong friction effect, mixeding liquid temperature in excitation cavity increases, first time temperature rising, gas produces the swollen phenomenon of Peng, because in the swollen promotion of Peng rapidly of gas, pressure improves further.
After the more highdensity mixing wastewater with air liquid of the 4th high speed and high pressure stirring is formed, just with the form of high speed and high pressure, the ring-type pouring micro-nano bubble reliever with the flow velocity of 60 to 75 meter per seconds is sheared in narrow slit, and the flow velocity in narrow slit reaches 120 ~ 150 meter per seconds, forms high speed kinetic energy;
High speed kinetic energy arrives outlet position time space sudden enlargement, the energy during ejection of narrow slit spout is suddenly released, for secondary release produces blast effectiveness release of heat, namely second time temperature raises, thus creates the micro-nano bubble of bubble diameter 200 nanometer to 4 micron.
Micro-nano bubble reliever principle of work: the application of fluid dynamic energy law, bubble is through that water produces object gas cutting action, gas-vapor mix liquid is produced after cutting, bubble is along with the accelerated motion in micro-nano bubble reliever of the cutting aqueous solution, because the feature of accelerating system is " water inlet total amount with eject water inventory equal ", and the sectional area of water-in caliber is far longer than the sectional area of water outlet bore, so the aqueous solution flow velocity of water outlet will increase substantially;
Fluid dynamic energy law calculation formula is as follows:
L
1S
1＝L
2S
2
L
1for water-in aqueous solution flow velocity, S
1for water-in sectional area
L
2for water outlet aqueous solution flow velocity, S
2for water outlet sectional area
S
1=π d
1 2/ 4 d
1for water-in diameter
S
2=π d
2 2/ 4 d
2for water outlet diameter
Then water outlet aqueous solution flow velocity L
2calculating formula is as follows:
L
2＝L
1d
1 2/2d
2 2
As the water-in diameter d of accelerating system in micro-nano bubble reliever
1=G1/2 ",
The water outlet diameter d of accelerating system in micro-nano bubble reliever
2=G1/16 "
Then L
2=64L
1, particle kinetic energy E=1/2mL
2 2, velocity of discharge improves 64 times, and particle kinetic energy is by increase by 4096 times, and energy level creates transition, and this transition energy level is enough to break any chemical bond and connects, and the first step breaks hydrogen bond, and macromole is changed to small molecules.
General water-in flow velocity L
1selected scope be 4-10 meter per seconds, be up to 20 meter per seconds, therefore water outlet flow velocity L
2speedup scope be 256-640 meter per seconds, the highest water outlet flow velocity can reach 1280 meter per seconds.
When air bubble flow rate reaches after more than 256 meter per seconds, bubble is just provided with very high kinetic energy, this kinetic energy is enough at effective propagation path, general effective propagation path is 0.5-0.8 meter, when air bubble flow rate reach 640 meter per seconds even higher time, bubble is compressed less, and the kinetic energy that bubble has will double, effective propagation path in water will bring up to more than 3 meters, further increase the effect of bubble to water.
The reference value of micro-nano bubble and several typical objects movement velocity:
| Kind | Speed |
| Hydrogen molecule | 1768 meter per seconds |
| Rifle bullet | 700-1000 meter per seconds |
| Active oxygen bubble | 256-1280 meter per seconds |
| Jet plane | 278 meter per seconds |
| High-speed railway | 83 meter per second ≈ 298.8KM/ hour |
The preparation of high-intensity magnetic field and small water molecule water: be designed with highdensity mixing wastewater with air liquid and pass rapidly through from high-intensity magnetic field and the device of perpendicular cuts magnetic line of force in this preparation system, this device can make water molecules bundle be crushed to 0.5-1.5 nanometer, the broken hydrogen bond of second time, water molecules is decomposed to the smallest molecule state of liquid water molecules;
Along with micromolecular water (H
2o) numerator value of n reaches minimum, and n value is 3-6, has extremely strong seepage force, diffusive force, solvency power, metabolism power, and is negative potential, weakly alkaline.
Water flow faster, magnetic field is stronger, and molecular grouping is pulverized less, and its movement velocity is faster, and biological activity is higher.Carry out sterilization, algae removal simultaneously, except poison, qualified tap water direct can have been made to deliver a child drink.
How to distinguish small-micelle water and common pure water: oxygen 17 nuclear magnetic resonance spectroscopy is the scientific approach differentiating small-micelle water, user oneself can be in and do a little little experiment in addition, and some other being used for distinguishes large sub some experiment and measuring methods rolled into a ball water and do such as small-micelle water and common pure water/mineral water.
The preparation of micromolecular water: the intrinsic pressure that make use of mixing wastewater with air liquid, improves the velocity of flow of mixing wastewater with air liquid, therefore on the basis not increasing energy consumption, obtains small water molecule water, more aobvious energy-conserving and environment-protective.
The preparation of rich hydrogen water: the bubble generated in a liquid, it is therefore inevitable to floating that proportion is less than water, the particle diameter of conventional bubble is at more than 1--8mm, lift velocity is 450mm--1200mm/s, bubble only has a small amount of gas dissolving in water in uphill process, and the bubble of final more than 75% reverts in air after floating on the surface of the water and breaking.The bubble of artificial manufacture no matter adopts which kind of method all to need consumed energy or as chemical substance, therefore the efficiency of this aeration method is very low.
In this preparation system, use micro-nano bubble aeration, the lift velocity that micro-nano gas ducks in drink is 4mm-8mm/s, and bubble inclusion rate reaches 84-90%.When after micro-nano bubble formation, water is creamy white.
Nano grade air bubbles aeration molten gas efficiency compared with grade bubble aeration of high bubble inclusion rate improves more than hundred times, contrast as follows: when molten tolerance one timing, square being inversely proportional to of the total surface area of bubble and its diameter, therefore the total area of micro/nano level bubble increases several thousand times with grade bubble phase than at least, and intensity then increases several ten thousand times;
Test proves that the diameter of microbubble is less, lift velocity in water is slower, the ability discharging gas dissolved in water is stronger, this can explain by interfacial energy theory, when the total area of microbubble is the increase of geometry number, then be equivalent to gas in water, water two-phase total face is that geometry number increases, so in intensive bubble uphill process, bubble diameter its intensity more tiny is higher, impel the lift velocity of microbubble in water slower, the residence time is longer, therefore the microbubble formed also does not rise to the water surface, the water surface is steam condition, in water, the gas of 84-90% is dissolved in water, reach the object of high-level efficiency aeration in water, the method of dealing with problems:
According to Henry's law: at certain temperature and pressure, the solubleness of gas in liquid is directly proportional to the equilibrium pressure of this gas.That is gas solubleness in a liquid proportional increase along with the dividing potential drop increase of this gas.In this preparation system, use pure hydrogen, in normal conditions, pure hydrogen equilibrium pressure in a liquid reaches optimization, makes the preparation of rich hydrogen water have the guarantee of quality and quantity.
The present invention adopts the method for pure physics that gas dissolving is entered in water, when the gas using micro-nano gas bubble aeration method to suck in this preparation system is for hydrogen, due to micro-nano bubble crumbling and fall in the process risen, the hydrogen gas of about 84-90% dissolves in water, simultaneously with the high temperature of molecule aspect, the generation of third time intensification release and high pressure;
When the micro-nano bubble formation of hydrogen and when being released in water body, micro-nano bubble is no longer arranged by the buoyancy of classical physics, liquid-gas interface becomes thickness, and make the rising of micro-nano bubble and move as slow in paste, its lift velocity is the 1/100-1/200 of grade bubble.
Self there is due to micro-nano bubble the characteristics such as high interior pressure, high surface energy, high interfacial activity, the micro-nano bubble of about 84%-90% is crumbled and fall in uphill process, can atomic little spatial dimension produce the high temperature of 1900-5200KJ and be greater than the partial high pressure of 50MPa around nano bubble while crumbling and fall, the high temperature and high pressure produced in molecular level aspect will become decades of times to improve for the solvability of hydrogen molecule;
With the solvability of majority of gas unlike, the solubility with temperature of hydrogen increases and increases, and solubleness is directly proportional to pressure, other gas, as the solubility with temperature of oxygen rising and reduce, according to law of gas diffusion, the square root of gas velocity of diffusion in a liquid and this gas relative molecular mass is inversely proportional to, the velocity of diffusion of hydrogen in liquid and tissue is 3.74 times of nitrogen, 1.41 times of helium.
Therefore to be driven and final with gaseous form dissipation at the micro-nano gas bubble of hydrogen dissolved oxygen in this process of water, oxygen solubility (DO value) going reduction, form gas-liquid mixture fluid to micromolecular water from water body and hydrogen mixed flow formed and be finally released into terminal container and form the micro-nano bubble of oyster white, arrive the whole process of bubble collapse more about 10 minutes, hydrogen solubleness rises to more than 2.5ppm by 0, and oxygen solubility is dropped rapidly to below 2.5ppm by 5-7ppm;
Redox potential ORP value, when fresh tap water, mountain spring water, pure water state, ORP value is+500mv to+700mv, oxygen level is 5 to 7ppm, illustrate that water quality has good oxidisability, after the micro-nano gas bubble of hydrogen is in water, ORP value is dropped rapidly to below-500mv, and the quick decline of adjoint dissolved oxygen content, ORP value reflects the rising of hydrogen solubility indirectly, show that water quality reductibility improves intuitively, and redox potential negative value larger explanation dissolved oxygen is lower, otherwise redox potential is less on the occasion of larger explanation hydrogen solubility;
Therefore in Production Flow Chart, by the method for physics, by mechanical energy and magnetic force energy twice, broken hydrogen bond in water makes macromole water prepare to become small molecule active water technology of preparing scheme of the present invention, twice with changes mechanical energy be heat energy and high energy physics the physical behavior of hydrogen can be made to reach to gaseous state ultimate attainment, form micro-nano bubble and soluble in water expeditiously, utilize the proportional relation of hydrogen and temperature to accelerate the dissolving of hydrogen simultaneously, the inverse relation of oxygen and temperature is utilized to accelerate the removal of oxygen, make finally to become the rich hydrogen water of high reductibility, the efficiency manufacturing rich hydrogen water is more than the hundred times of conventional aeration method.
Claims (2)
1. a preparation method for the rich hydrogen water of small molecules, is characterized in that, comprise the following steps:
1.1, hydrogen and tap water in mass ratio 3-8% undertaken preliminary balanced mixing forming elementary mixing wastewater with air liquid afterwards by mixing wastewater with air equalizer;
1.2, make elementary mixing wastewater with air liquid enter secondary mixing in impeller pump, form the mixing wastewater with air liquid of 0.35-0.65MPa pressure;
1.3, make the mixed mixing wastewater with air liquid of secondary by high precision electro automatic backwash filter and shower nozzle type controller spout, make secondary mixing wastewater with air liquid form the motion of high speed ordered linear, and collide with each other and obtain third time mixing wastewater with air liquid;
1.4, make mixed mixing wastewater with air liquid for the third time flow through from micromolecular water preparing device, perpendicular cuts magnetic line of force, is crushed to 0.5-1.5 nanometers by water molecules bundle, obtains micromolecular water;
1.5, micromolecular water is transported to recoil and swashs bubble reliever, produced the micro-nano bubble of bubble diameter 200 nanometer to 4 micron by the sharp bubble reliever that recoils, form the bubble liquid containing micro-nano hydrogen;
1.6, the bubble liquid of micro-nano hydrogen is sent into bottom storage vessel, the hydrogen in micro-nano bubble is dissolved in micromolecular water and prepares the rich hydrogen water of small molecules;
Described recoil swashs bubble reliever (12), comprise body (54), be arranged at the deflection cone (55) be sealed and matched with body (54) in body (54) and the reverse deflection cone (57) be fixedly connected with deflection cone (55), described deflection cone (55) has acceleration mouth (56), described reverse deflection cone (57) has an excitation cavity (59), the bottom of described excitation cavity (59) is V-arrangement, top smooth contraction transition forms the less opening of a cross-sectional area, and the cross-sectional area of this opening is greater than the acceleration mouth (56) of deflection cone (55); The opening part of described reverse deflection cone (57) has the guide face of the first spination projection along body (54) formation one that extends radially outwardly, the upper end face relative with guide face of described deflection cone (55) is provided with the second spination protruding, described first spination is protruding and the second spination is protruding forms zig-zag shearing passage (58), and described first spination is protruding to be crisscross arranged with the second spination projection.
2. the preparation method of the rich hydrogen water of a kind of small molecules according to claim 1, it is characterized in that, by oxygen and tap water in mass ratio 3-8% carry out preliminary balanced mixing forming primary oxygen and water mixed liquid afterwards, then what a process for preparing is small molecules heavy-oxygen-enriched water.
3. the Preparation equipment of the rich hydrogen water of small molecules, it is characterized in that, comprise drinking water container (1), hydrogen gas tank (15) and air water hybrid equalizer (5), drinking water container (1) outlet is connected with mixing wastewater with air equalizer (5), and hydrogen gas tank (15) is connected with mixing wastewater with air equalizer (5) by hydrogen reducing valve (14); Mixing wastewater with air equalizer (5) outlet is connected with impeller pump (6), impeller pump (6) outlet enters shower nozzle type controller (8) by high precision electro automatic backwash filter (7) and is connected with high-density air water mixing tank (9) entrance, high-density air water mixing tank (9) outlet is provided with micromolecular water transfer lime (11), and micromolecular water transfer lime (11) surrounding is provided with micromolecular water preparing device (10); Micromolecular water transfer lime (11) outlet is connected with storage vessel (13), is provided with recoil and swashs bubble reliever (12) in small molecules rich hydrogen water stainless steel storage vessel (13) lower entrances;
Described recoil swashs bubble reliever (12), comprise body (54), be arranged at the deflection cone (55) be sealed and matched with body (54) in body (54) and the reverse deflection cone (57) be fixedly connected with deflection cone (55), described deflection cone (55) has acceleration mouth (56), described reverse deflection cone (57) has an excitation cavity (59), the bottom of described excitation cavity (59) is V-arrangement, top smooth contraction transition forms the less opening of a cross-sectional area, and the cross-sectional area of this opening is greater than the acceleration mouth (56) of deflection cone (55); The opening part of described reverse deflection cone (57) has the guide face of the first spination projection along body (54) formation one that extends radially outwardly, the upper end face relative with guide face of described deflection cone (55) is provided with the second spination protruding, described first spination is protruding and the second spination is protruding forms zig-zag shearing passage (58), and described first spination is protruding to be crisscross arranged with the second spination projection.
4. the Preparation equipment of the rich hydrogen water of a kind of small molecules according to claim 3, it is characterized in that, described mixing wastewater with air equalizer (5), there is a tube of pressure-stabilizing (22), tube of pressure-stabilizing upper cover (26) above tube of pressure-stabilizing (22), tube of pressure-stabilizing upper cover (26) and tube of pressure-stabilizing (5) are connected with joint flange and seal, water-in (18) is provided with in the lower right of tube of pressure-stabilizing (22), water-in (18) stretches into centre upwards 90 degree of connections charging tube (23) of tube of pressure-stabilizing (22), porous web plate (25) is had at the upper and lower ends of charging tube (23), charging tube (23) is built with porous ceramics material (24), open a pipeline on the top of water-in (18) to be connected with the negative pressure Self inhaling device (20) be provided with outside tube of pressure-stabilizing (22), high-pressure water inlet (19) is communicated with at the right-hand member of negative pressure Self inhaling device (20), gas inlet (21) is had in the top of negative pressure Self inhaling device (20), mixing wastewater with air liquid (27) is had in tube of pressure-stabilizing (22), mixing wastewater with air liquid outlet (28) is provided with in the lower left of tube of pressure-stabilizing (22).
5. the Preparation equipment of the rich hydrogen water of a kind of small molecules according to claim 3, it is characterized in that, described high precision electro automatic backwash filter (7) comprises lower cover (29), filter cylinder (30), filter vat (31), cartridge type hairbrush (32), filter inlet (35), shaft coupling sleeve (37), electric motor (38), speed reduction unit (39), upper cover inlet segment (41) and water outlet (44), joint flange (43) is had at the two ends of filter cylinder (30), bottom connects lower cover (29), top connects upper cover inlet segment (41), filter vat (31) and cartridge type hairbrush (32) are equipped with in inside, the upper and lower ends of cartridge type hairbrush (32) inserts in the groove of upper cover inlet segment (41) and lower cover (29) respectively, seal with O-ring seal (36), the hairbrush external diameter of cartridge type hairbrush (32) is greater than the internal diameter 3 to 5 millimeters of filter vat (31), self-align tubular hairbrush (32) is in the internal diameter of filter vat (31) and pressing force is scrubbed in formation, electric motor (38) and speed reduction unit (39) are housed on the top of upper cover inlet segment (41), electric motor (38) and speed reduction unit (39) pass to cartridge type hairbrush (32) by shaft coupling sleeve (37) and universal coupling pivot pin (34) rotary torque, filter inlet (35) place of filter cylinder (30) is provided with inlet pressure sensor (40), and water outlet (44) place of filter cylinder (30) is provided with outlet pressure sensor (45).
6. the Preparation equipment of the rich hydrogen water of a kind of small molecules according to claim 3, it is characterized in that, described high-density air water mixing tank (9), comprise the upright closed cylinder (46) arranged, the bottom of closed cylinder (46) is provided with mixed solution water outlet (48), is provided with the inlet pipe (50) of water inlet pipe (53) and the feeds air under pressure inserting into the inner portion's transfer pressure water on the top of described closed cylinder (46); The water side of described water inlet pipe (53) is fixedly connected with outlet shower nozzle type controller spout (51) upwards, and the outlet side of described inlet pipe (50) is communicated with water inlet pipe (53); In described closed cylinder (46), the top of shower nozzle type controller spout (51) is provided with the cover body (52) of arc surfaced, the water that described shower nozzle type controller spout (51) sprays falls in closed cylinder (46) after clashing into cover body (52), closed cylinder (46) is provided with liquidometer (49).
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