CN104056412A - Serpentine mesh gel foam mud fire prevention and extinguishing agent - Google Patents
Serpentine mesh gel foam mud fire prevention and extinguishing agent Download PDFInfo
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- CN104056412A CN104056412A CN201410279419.5A CN201410279419A CN104056412A CN 104056412 A CN104056412 A CN 104056412A CN 201410279419 A CN201410279419 A CN 201410279419A CN 104056412 A CN104056412 A CN 104056412A
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- serpentine
- concave
- powder
- gel foam
- batching
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- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 title claims abstract description 82
- 239000006260 foam Substances 0.000 title claims abstract description 64
- 230000002265 prevention Effects 0.000 title abstract description 11
- 239000004927 clay Substances 0.000 claims abstract description 56
- 239000000843 powder Substances 0.000 claims abstract description 49
- 239000003063 flame retardant Substances 0.000 claims abstract description 47
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- 229920000742 Cotton Polymers 0.000 claims abstract description 27
- 238000002156 mixing Methods 0.000 claims abstract description 14
- 238000005507 spraying Methods 0.000 claims abstract description 10
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000661 sodium alginate Substances 0.000 claims abstract description 7
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 7
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 7
- 229960000892 attapulgite Drugs 0.000 claims abstract description 5
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 41
- 238000004519 manufacturing process Methods 0.000 claims description 26
- 238000003756 stirring Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 22
- 235000013312 flour Nutrition 0.000 claims description 21
- 241000270295 Serpentes Species 0.000 claims description 18
- 239000004575 stone Substances 0.000 claims description 18
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 16
- 238000004887 air purification Methods 0.000 claims description 16
- 235000013339 cereals Nutrition 0.000 claims description 15
- 239000007921 spray Substances 0.000 claims description 15
- 239000010451 perlite Substances 0.000 claims description 9
- 235000019362 perlite Nutrition 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 230000008961 swelling Effects 0.000 claims description 8
- 238000010298 pulverizing process Methods 0.000 claims description 7
- 239000000428 dust Substances 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- 238000005065 mining Methods 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 229940008099 dimethicone Drugs 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 239000011265 semifinished product Substances 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 230000000274 adsorptive effect Effects 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 230000032683 aging Effects 0.000 claims description 2
- 239000004568 cement Substances 0.000 claims description 2
- 238000001514 detection method Methods 0.000 claims description 2
- 238000004033 diameter control Methods 0.000 claims description 2
- 238000000855 fermentation Methods 0.000 claims description 2
- 230000004151 fermentation Effects 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 238000003672 processing method Methods 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 238000012360 testing method Methods 0.000 claims description 2
- 239000003245 coal Substances 0.000 abstract description 26
- 238000000034 method Methods 0.000 abstract description 13
- 230000008569 process Effects 0.000 abstract description 8
- 239000004615 ingredient Substances 0.000 abstract description 3
- 239000012784 inorganic fiber Substances 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 238000009775 high-speed stirring Methods 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000005187 foaming Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 231100000252 nontoxic Toxicity 0.000 description 4
- 230000003000 nontoxic effect Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 206010000269 abscess Diseases 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The invention discloses a serpentine mesh gel foam mud fire prevention and extinguishing agent. The key point of the technical scheme adopted by the invention lies in that the serpentine mesh gel foam mud fire prevention and extinguishing agent is composed of a serpentine composite flame retardant foaming agent, attapulgite pottery clay powder with an air purifying function, inorganic fiber spray coating cotton, serpentine powder, coal gangue powder, expanded perlite powder, sodium alginate and water. The ingredients of the serpentine mesh gel foam mud fire prevention and extinguishing agent are input into a rake type mixing machine to undergo high-speed stirring, thus obtaining the serpentine mesh gel foam mud fire prevention and extinguishing agent. The mesh gel foam mud is sprayed to a burning coal layer by an inorganic fiber spray coating machine, thus facilitating generating an integral mesh gel foam mud film in a fire prevention and extinguishing process. The film can always cover and adhere to an ore bed surface to rapidly isolate the burning coal layer from air, prevent coal mine from keeping burning and avoid reburning of the coal layer, thus reaching the purposes of flame retardance and fire prevention and extinguishing. The serpentine mesh gel foam mud fire prevention and extinguishing agent is suitable for fire prevention and extinguishing of coal mines, mine operation areas and forests.
Description
Technical field
The present invention relates to fire-prevention extinguishing agent, be specifically related to a kind of serpentine network gel foam mud fire-prevention extinguishing agent.
Background technology
The advantages such as that mining exploitation has is highly efficient and productive, low consumption, generally apply in a lot of coal productions of China base.But because the mining rate of this coal-mining method is large, goaf leaves over that residual coal is many, and height is large, leak out serious, often there will be the series of problems, particularly fire such as insoluble fire, gas, dust.
Fire foam is divided into chemical foam, air foam, fluoroprotein foam, AFFF and water-resistant foam etc.
China Patent Publication No. CN 102614615A, open day: on 08 01st, 2012, name is called " a kind of for the complex fire foam under coal mine ", " a kind of for the complex fire foam under coal mine; to it is characterized in that: by following raw materials according, made: major ingredient is that concentration is 40%～60% carbonic hydroammonium or sodium bicarbonate aqueous solution and the concentrated sulfuric acid; to press solute mass ratio 2:1～3:1 and mix; auxiliary material is stabilizing agent and blowing agent, and described supplementary product consumption is major ingredient gross weight 0.1%～2% " disclosed.
The weak point of above-mentioned patent is: although this extinguishing chemical coefficient of foaming can reach 20～200 times, foam stabilization time >=2.5h, but can only make at short notice " noble gas carbon dioxide foaming spreads and be full of its space in flame range; oxygen concentration in flame range is declined rapidly; flame range is suffocated because of anoxic ", can not really accomplish contacting of isolated burning coal layer and air, prevention colliery burns away, avoid coal seam resume combustion, reach the object of fire-retardant and anti-fire extinguishing.Take carbonic hydroammonium as the main raw material of extinguishing chemical, in fire extinguishing procedure, can discharge a large amount of ammonias, polluted the air of down-hole, be unfavorable for operating personnel's health.
Gangue is thrown aside, takies tract, and sulfide in gangue is overflowed or leached can atmosphere pollution, farmland and water body, and hillock also can spontaneous combustion breaking out of fire, or in avalanche in rainy season, silts river up and cause disaster.
Summary of the invention
The object of the invention is to overcome weak point in prior art, a kind of serpentine network gel foam mud fire-prevention extinguishing agent is provided.
Serpentine network gel foam mud fire-prevention extinguishing agent is comprised of compound flame-retardant expanded dose of serpentine, the concave convex rod potter's clay powder with air purification function, inorfil spraying cotton, snake stone flour, colliery powder, swelling perlite powder, sodium alginate and water.
The production method of serpentine network gel foam mud fire-prevention extinguishing agent: by the batching input plough type batch mixer of serpentine network gel foam mud fire-prevention extinguishing agent, high-speed stirred is serpentine network gel foam mud fire-prevention extinguishing agent.
That serpentine has is heat-resisting, anticorrosive, wear-resisting, heat insulation, sound insulation and operational characteristic preferably, and block or fibrous serpentine all can have gloss, block as wax, fibrous as thread.
The concave convex rod potter's clay powder with air purification function is comprised of the sticky Concave-convex clay rod of height, attapulite constant humidity amendment, natural-minerals adsorptive filter medium, cacumen biotae, aluminium silicate fiber peacekeeping polyacrylamide; There is good caking property, plasticity, thixotropy, fire resistance and heat endurance; The effective harmful substance such as formaldehyde, ammonia and benzene in absorbed air, protection of the environment and promote the healthy of people.
High sticky Concave-convex clay rod is the Concave-convex clay rod that adopts the processing technology production that improves viscosity of attapulgite clay, Concave-convex clay rod is after batching stirs, in input grinding machine, carry out abrasive dust for high sticky Concave-convex clay rod powder, grain fineness≤0.074 millimeter.
High sticky Concave-convex clay rod soil property is fine and smooth, has oily soapy, and light weight, property are crisp, fracture is conchoidal or irregular shape, and water imbibition is strong, tool viscosity and plasticity when wet, viscosity >=the 2200mPas of high sticky Concave-convex clay rod powder, adhesive force is good, is conducive to the bonding between raw material.
Hydrogen peroxide is commonly called as hydrogen peroxide, and outward appearance is colourless transparent liquid, is a kind of strong oxidizer, and the present invention selects mass fraction >=35% of industrial hydrogen peroxide.After mixing with snake stone flour and the batchings such as concave convex rod potter's clay powder with air purification function, can generate a large amount of bubbles.
Aluminium hydroxide can not only be fire-retardant as fire retardant, and can prevent from being fuming, do not produce droppings, do not produce toxic gas.
Sodium sulfate of polyethenoxy ether of fatty alcohol is soluble in water, has good decontamination, emulsification, foam performance and anti-performance of hard water, is a kind of anion surfactant.
Micronized polyethylene alcohol powder is a kind of white, powdery, stable, nontoxic high molecular weight water soluble polymer, can be dissolved in fast in normal-temperature water, forms stable colloid, and water is the solvent that polyvinyl alcohol is good.Polyvinyl alcohol has the good film of making, the film forming has excellent adhesion, solvent resistance, rub resistance, tensile strength and oxygen barrier performance, can improve the viscosity of foam, there is certain steady bubble effect, and can improve the product bulk strength that adopts the compound flame-retardant expanded dose of production of serpentine.
Dimethicone surface tension is little, water insoluble, chemical stability is good, nontoxic, be a kind of defoamer and remover, the invalid bubble generating for eliminating foaming process, improve the make rate of abscess, also help cast quick demoulding and prevent from the mould that collapses from carrying out flame-retarding fire-extinguishing for fire-extinguishing location during foamed material, can not add dimethicone.
Inorfil spraying cotton is that to utilize industrial waste slag (blast-furnace cinder or Copper Slag, aluminium ore slag etc.) be primary raw material, the staple shape inorfil of making through techniques such as fusing, employing supercentrifugal process or blowing processes.It has light weight, thermal conductivity factor little, do not burn, the feature such as mothproof, inexpensive, corrosion-resistant, chemical stability is good and sound absorbing capabilities is good.
Gangue is the solid waste discharging in coal mining process and coal washing process, the present invention uses gangue can increase the content of serpentine network gel foam mud fire-prevention extinguishing agent aluminium oxide, improve the surface strength of network gel foam mud film, the present invention selects the colliery powder after pulverizing, grain fineness≤0.074 millimeter of colliery powder.
Perlite becomes a kind of lightweight, multifunctional novel shaped material through calcining expansion.Have that apparent density is light, thermal conductivity factor is low, chemical stability is good, serviceability temperature scope is wide, wettability power is little, and the feature such as nontoxic, tasteless, fire prevention, sound-absorbing.The present invention selects the swelling perlite powder after pulverizing, grain fineness≤0.074 millimeter of swelling perlite powder.
Sodium alginate is white or light brown powder, and ratio is dissolved in water arbitrarily, forms the thickness aqueous solution of good fluidity, is conducive to the ability that serpentine network gel foam mud fire-prevention extinguishing agent forms fast gelinite and strengthens its film forming.
The present invention is achieved by following technical proposals:
1, the batching of serpentine network gel foam mud fire-prevention extinguishing agent is comprised of following component by weight percentage: compound flame-retardant expanded dose 5～55% of serpentine, inorfil spray cotton mixture 5～35% and water 20～90%.
The production method of serpentine network gel foam mud fire-prevention extinguishing agent: by the batching input plough type batch mixer of serpentine network gel foam mud fire-prevention extinguishing agent, high-speed stirred is serpentine network gel foam mud fire-prevention extinguishing agent, the speed of plough type batch mixer is controlled at 2400～2800 revs/min, and mixing time is controlled at 2～20 minutes.
2, the compound flame-retardant expanded dose of batching of serpentine is comprised of following component by weight percentage: the compound flame-retardant expanded dose of paste 5～75% of serpentine, hydrogen peroxide 1～35%, dimethicone 0～5% and water 1～85%.
The production method that serpentine is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of serpentine, the speed of mixer is controlled at 1400～1800 revs/min, mixing time is controlled at 1～30 minute, after stirring, be compound flame-retardant expanded dose of serpentine, in compound flame-retardant expanded dose of serpentine, contain a large amount of stable intensive bubbles.
The compound flame-retardant expanded dose of paste batching of serpentine is comprised of following component by weight percentage: snake stone flour 5～55%, the concave convex rod potter's clay powder 5～45% with air purification function, aluminium hydroxide 1～35%, sodium sulfate of polyethenoxy ether of fatty alcohol 0.01～15%, micronized polyethylene alcohol powder 0.01～5% and water 5～55%.
The production method of the compound flame-retardant expanded dose of paste of serpentine: will stir in the compound flame-retardant expanded dose of paste batching of serpentine input low-speed mixer, the speed of mixer is controlled at 600～800 revs/min, mixing time is controlled at 1～20 minute, after stirring for the compound flame-retardant expanded dose of paste of serpentine, generating portion bubble in the compound flame-retardant expanded dose of paste of serpentine.
Compound flame-retardant expanded dose of serpentine is to adopt by the inventor in " compound flame-retardant expanded dose of the serpentine " of application on 06 12nd, 2013, Chinese patent publication No.: CN 103253979 A, date of publication: on 08 21st, 2013.
3, the batching that inorfil sprays cotton mixture is comprised of following component by weight percentage: inorfil spraying is cotton 5～45%, snake stone flour 5～45%, colliery powder 5～35%, swelling perlite powder 2～25% and sodium alginate 0.01～5%.
Inorfil sprays the production method of cotton mixture: inorfil is sprayed in the batching input plough type batch mixer of cotton mixture, stirring at low speed is that inorfil sprays cotton mixture, the speed of plough type batch mixer is controlled at 800～1000 revs/min, and mixing time is controlled at 2～20 minutes.
4, the production method of snake stone flour: 1. serpentine is inputted in pulverizer and pulverized, grain fineness≤5 millimeter; 2. will in the serpentine input flour mill after pulverizing, be processed as snake stone flour, grain fineness≤0.074 millimeter of snake stone flour.
5, the batching that has a concave convex rod potter's clay powder of air purification function is comprised of following component by weight percentage: high sticky Concave-convex clay rod 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, cacumen biotae 2～15%, alumina silicate fibre 1～5% and polyacrylamide 0.1～3%; The production method with the concave convex rod potter's clay powder of air purification function: pulverize in input pulverizer after (1) the batching with the concave convex rod potter's clay powder of air purification function being mixed, the compound particles fineness after pulverizing is less than 0.5 millimeter; (2) pulverulent mixture is added and soak water in old pond and soak the old semi-finished product that are treated to, soak the old time to be controlled at 7～30 days; (3) semi-finished product are inputted in vacuum-extruder and be squeezed into cylindrical strip thing, the diameter control of cylindrical strip thing is at 2～10 millimeters; (4) cylindrical strip thing is input to cement threshing ground and carries out airing, the cylindrical strip thing water content after airing is less than 15%; (5) by carrying out abrasive dust in the cylindrical strip thing input grinding machine after airing, be powder, the grain fineness of powder is less than 0.074 millimeter, and PCm is weight percentage.
The concave convex rod potter's clay powder with air purification function is to adopt by the inventor in " the concave convex rod potter's clay powder with air purification function " of application on February 25th, 2011, Chinese patent Granted publication number is: CN 102173743 B, Granted publication day: on July 25th, 2012.
High sticky Concave-convex clay rod is the Concave-convex clay rod that adopts the processing technology production that improves viscosity of attapulgite clay, it is characterized in that, and from the Concave-convex clay rod of mining area exploitation, need to be through the weathering of 30～120 days; Modification processing method is: calculate by weight percentage, get the Concave-convex clay rod 94～98% after weathering, evenly add 2～6% sodium carbonate, jointly input in fermentation vat, add clear water to soak ageing, soak time is 72～120 hours; Get the Concave-convex clay rod after immersion, in input mixer, stir, and by the Concave-convex clay rod after stirring, through extruder, be extruded into thin slice, its THICKNESS CONTROL is at 0.5～2 millimeter, by Concave-convex clay rod thin slice, carry out airing, the Concave-convex clay rod thin slice after airing, its water content≤15%; Batching is calculated by weight percentage: the Concave-convex clay rod 94～98% after airing, high hydroscopic resin 0.5～5% and cellulose 0.5～3%, above-mentioned batching is stirred, after stirring, input and in grinding machine, carry out abrasive dust, grain fineness≤0.074 millimeter, PCm is weight percentage.
Above-mentioned production technology is to adopt " the improving the processing technology of viscosity of attapulgite clay " of being applied on June 20th, 2005 by the inventor, and Chinese patent Granted publication number is: CN 1317067C, Granted publication day: on May 23rd, 2007.
The detection method of high sticky Concave-convex clay rod: get 28.0g Concave-convex clay rod powder sample, add in the suspension cup of homogenizer, add again 372g water, suspension cup is placed on homogenizer, under the rotating speed of 11000 revs/min, stir 20 minutes, to pour in the beaker of 250mL through high-speed stirred sample suspension, use NDJ-1 type rotation viscometer to carry out the viscosity of test suspension liquid, tested viscosity value >=2200 mPas is high sticky Concave-convex clay rod.
The present invention selects mass fraction >=35% of industrial hydrogen peroxide, takes production scene to add the batching percentage that water is adjusted industrial hydrogen peroxide, is conducive to reduce freight and production cost, improves the foaming quality of product.
First inorfil is sprayed in the batching input plough type batch mixer of cotton mixture, stirring at low speed is that inorfil sprays cotton mixture, be conducive to by inorfil spraying cotton with snake stone flour, colliery powder, swelling perlite powder and the uniform shredding of sodium alginate, fragmentation, be uniformly mixed and be integrated.
Although compound flame-retardant expanded dose of serpentine adds after water high-speed stirred at flame-retarding fire-extinguishing scene, can discharge fast a large amount of gas, form cavernous foam mud, can be for flame-retarding fire-extinguishing, but use merely compound flame-retardant expanded dose of serpentine, can only be applicable to general fire-retardant and anti-fire extinguishing on ground, and for the material of anti-fire extinguishing in colliery, there is its particularity, require fire-prevention extinguishing agent to there is good mobility, permeability, thixotropy and adhesion property, not only can in colliery, put out a fire, also to there is rapidly contacting of isolated burning coal layer and air, stop colliery to burn away, avoid the function of coal seam resume combustion.
The present invention has formed a kind of novel serpentine network gel foam mud fire-prevention extinguishing agent after spraying cotton design of mixture by serpentine compound flame-retardant expanded dose and inorfil, can form fast a kind of network gel foam mud of sticky porous.
Network gel foam mud is ejected into the coal seam of burning by inorfil flush coater, be conducive to generate a kind of network gel foam mud film of globality in anti-fire extinguishing procedure, this network gel foam mud film is a kind of flexible film, can change along with the displacement of ore bed the shape of film, filling is between float coal and the rock crevice of inbreak, the obstruction passage that leaks out, minimizing is leaked out.
Network gel foam mud film covers the surface that sticks to ore bed all the time, rapidly isolated burning coal layer contacts with air, stop colliery to burn away, avoid coal seam resume combustion, reach the object of fire-retardant and anti-fire extinguishing, and can reduce the pollution of pernicious gas, the surface that network gel foam mud film covers ore bed can not produce a large amount of water vapours, the danger that does not exist water-gas blast and water vapour to hurt sb.'s feelings.
In the process of anti-fire extinguishing, network gel foam mud film at high temperature slow dehydration produces steam, absorbs large calorimetric, thereby can effectively reduce the temperature of inside, coal seam, and network gel foam mud film can keep certain wettability for a long time, prevents coal seam resume combustion; After the slow dehydration of network gel foam mud film, spray water was sprayed on network gel foam mud film surface in the past, in network gel foam mud film, high hydroscopic resin and cellulose water suction continue to expand, the anti-fire extinguishing effect of recovering and strengthen network gel foam mud film, the effect of anti-fire extinguishing will be over more than 24 hours.
The raw materials such as the rice hulls of the concave convex rod potter's clay powder with air purification function after by the sticky Concave-convex clay rod of height, quick dissolved sodium silicate, zeolite powder, acidifying, the zeolite after acidifying, the Concave-convex clay rod after acidifying, the bentonite after acidifying, the diatomite after acidifying, volcanic rock, alumine, cacumen biotae, aluminium silicate fiber peacekeeping polyacrylamide form; There is good caking property, plasticity, thixotropy, fire resistance and heat endurance, harmful substance in the effective absorbed air of energy, protection of the environment and enhancement people's is healthy.
The gas that serpentine network gel foam mud fire-prevention extinguishing agent produces in foaming process is lighter than gel foam mud; have a certain amount of gas ionization on gel foam mud film upper strata; can the coal seam resume combustion below gel foam mud film not had a negative impact, and the oxygen containing in gas can contribute to protect, miner or fire fighter's is healthy.
Serpentine network gel foam mud fire-prevention extinguishing agent is a kind of fire-retardant fireproofing extinguishing materials of high-quality, in carrying out the process of anti-fire extinguishing, do not produce carburization zone and flue gas, inorfil spraying cotton fiber in network gel foam mud film and other batching interweave and are bonded as one, formation has the dimensional network structure of some strength and toughness, remain the integrality of network gel foam mud film, improve the efficiency of anti-fire extinguishing.
Utilize serpentine network gel foam mud fire-prevention extinguishing agent to carry out anti-fire extinguishing, technique is simple, equipment needed thereby is few, nontoxic, free from environmental pollution, there is good mobility, permeability, thixotropy and adhesion property, be conducive at freely burning fire and leak out the on-the-spot application of mine serious, not only effectively fire-retardant and anti-fire extinguishing, also have adsorption cleaning air, reduce the function of mine environment pollution, meet the requirement of coal mine underground coal bed control spontaneous combustion and fire, put out a fire fast and effectively in time and prevent coal seam resume combustion, guaranteeing mine safety.
Serpentine network gel foam mud fire-prevention extinguishing agent is applicable to the anti-fire extinguishing of colliery, other mine operation district and forest.
The specific embodiment
Below in conjunction with embodiment, the invention will be further described:
1, the batching of serpentine network gel foam mud fire-prevention extinguishing agent is comprised of following component by weight percentage: compound flame-retardant expanded dose 32% of serpentine, inorfil spray cotton mixture 24% and water 44%.
The production method of serpentine network gel foam mud fire-prevention extinguishing agent: by the batching input plough type batch mixer of serpentine network gel foam mud fire-prevention extinguishing agent, high-speed stirred is serpentine network gel foam mud fire-prevention extinguishing agent, the speed of plough type batch mixer is controlled at 2400～2800 revs/min, and mixing time is controlled at 14 minutes.
2, the compound flame-retardant expanded dose of batching of serpentine is comprised of following component by weight percentage: the compound flame-retardant expanded dose of paste 52% of serpentine, hydrogen peroxide 10%, dimethicone 0% and water 38%.
The production method that serpentine is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of serpentine, the speed of mixer is controlled at 1400～1800 revs/min, mixing time is controlled at 15 minutes, is compound flame-retardant expanded dose of serpentine after stirring.
The compound flame-retardant expanded dose of paste batching of serpentine is comprised of following component by weight percentage: snake stone flour 40%, the concave convex rod potter's clay powder 16% with air purification function, aluminium hydroxide 5%, sodium sulfate of polyethenoxy ether of fatty alcohol 2%, micronized polyethylene alcohol powder 0.5% and water 36.5%.
The production method of the compound flame-retardant expanded dose of paste of serpentine: will stir in the compound flame-retardant expanded dose of paste batching of serpentine input low-speed mixer, the speed of mixer is controlled at 600～800 revs/min, mixing time is controlled at 14 minutes, is the compound flame-retardant expanded dose of paste of serpentine after stirring.
3, the batching that inorfil sprays cotton mixture is comprised of following component by weight percentage: inorfil spraying is cotton 30%, snake stone flour 34%, colliery powder 28%, swelling perlite powder 7% and sodium alginate 1%.
Inorfil sprays the production method of cotton mixture: inorfil is sprayed in the batching input plough type batch mixer of cotton mixture, stirring at low speed is that inorfil sprays cotton mixture, the speed of plough type batch mixer is controlled at 800～1000 revs/min, and mixing time is controlled at 12 minutes.
4, the production method of snake stone flour: 1. serpentine is inputted in pulverizer and pulverized, grain fineness≤5 millimeter; 2. will in the serpentine input flour mill after pulverizing, be processed as snake stone flour, grain fineness≤0.074 millimeter of snake stone flour.
Claims (10)
1. a serpentine network gel foam mud fire-prevention extinguishing agent, it is characterized in that, the batching of serpentine network gel foam mud fire-prevention extinguishing agent is comprised of following component by weight percentage: compound flame-retardant expanded dose 5～55% of serpentine, inorfil spray cotton mixture 5～35% and water 20～90%.
2. the production method of serpentine network gel foam mud fire-prevention extinguishing agent according to claim 1, it is characterized in that, by in the batching input plough type batch mixer of serpentine network gel foam mud fire-prevention extinguishing agent, high-speed stirred is serpentine network gel foam mud fire-prevention extinguishing agent, the speed of plough type batch mixer is controlled at 2400～2800 revs/min, and mixing time is controlled at 2～20 minutes.
3. the compound flame-retardant expanded dose of batching of serpentine according to claim 1, it is characterized in that, by following component, formed by weight percentage: the compound flame-retardant expanded dose of paste 5～75% of serpentine, hydrogen peroxide 1～35%, dimethicone 0～5% and water 1～85%; The production method that serpentine is compound flame-retardant expanded dose: will stir in the compound flame-retardant expanded dose of batching input homogenizer of serpentine, the speed of mixer is controlled at 1400～1800 revs/min, mixing time is controlled at 1～30 minute, is compound flame-retardant expanded dose of serpentine after stirring.
4. the compound flame-retardant expanded dose of paste of serpentine prepared burden according to claim 3, it is characterized in that, by following component, formed by weight percentage: snake stone flour 5～55%, the concave convex rod potter's clay powder 5～45% with air purification function, aluminium hydroxide 1～35%, sodium sulfate of polyethenoxy ether of fatty alcohol 0.01～15%, micronized polyethylene alcohol powder 0.01～5% and water 5～55%; The production method of the compound flame-retardant expanded dose of paste of serpentine: will stir in the compound flame-retardant expanded dose of paste batching of serpentine input low-speed mixer, the speed of mixer is controlled at 600～800 revs/min, mixing time is controlled at 1～20 minute, is the compound flame-retardant expanded dose of paste of serpentine after stirring.
5. inorfil sprays the batching of cotton mixture according to claim 1, it is characterized in that, by following component, formed by weight percentage: inorfil spraying cotton 5～45%, snake stone flour 5～45%, colliery powder 5～35%, swelling perlite powder 2～25% and sodium alginate 0.01～5%; Inorfil sprays the production method of cotton mixture: inorfil is sprayed in the batching input plough type batch mixer of cotton mixture, stirring at low speed is that inorfil sprays cotton mixture, the speed of plough type batch mixer is controlled at 800～1000 revs/min, and mixing time is controlled at 2～20 minutes.
6. the production method of snake stone flour according to claim 5, is characterized in that, 1. serpentine is inputted in pulverizer and is pulverized, grain fineness≤5 millimeter; 2. will in the serpentine input flour mill after pulverizing, be processed as snake stone flour, grain fineness≤0.074 millimeter of snake stone flour.
7. the concave convex rod potter's clay powder according to claim 4 with air purification function, it is characterized in that, the batching with the concave convex rod potter's clay powder of air purification function is comprised of following component by weight percentage, high sticky Concave-convex clay rod 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, cacumen biotae 2～15%, alumina silicate fibre 1～5% and polyacrylamide 0.1～3%; The production method with the concave convex rod potter's clay powder of air purification function: pulverize in input pulverizer after (1) the batching with the concave convex rod potter's clay powder of air purification function being mixed, the compound particles fineness after pulverizing is less than 0.5 millimeter; (2) pulverulent mixture is added and soak water in old pond and soak the old semi-finished product that are treated to, soak the old time to be controlled at 7～30 days; (3) semi-finished product are inputted in vacuum-extruder and be squeezed into cylindrical strip thing, the diameter control of cylindrical strip thing is at 2～10 millimeters; (4) cylindrical strip thing is input to cement threshing ground and carries out airing, the cylindrical strip thing water content after airing is less than 15%; (5) by carrying out abrasive dust in the cylindrical strip thing input grinding machine after airing, be powder, the grain fineness of powder is less than 0.074 millimeter.
8. high sticky Concave-convex clay rod is the Concave-convex clay rod that adopts the processing technology production that improves viscosity of attapulgite clay according to claim 7, it is characterized in that, and from the Concave-convex clay rod of mining area exploitation, need to be through the weathering of 30～120 days; Modification processing method is: calculate by weight percentage, get the Concave-convex clay rod 94～98% after weathering, evenly add 2～6% sodium carbonate, jointly input in fermentation vat, add clear water to soak ageing, soak time is 72～120 hours; Get the Concave-convex clay rod after immersion, in input mixer, stir, and by the Concave-convex clay rod after stirring, through extruder, be extruded into thin slice, its THICKNESS CONTROL is at 0.5～2 millimeter, by Concave-convex clay rod thin slice, carry out airing, the Concave-convex clay rod thin slice after airing, its water content≤15%; Batching is calculated by weight percentage: the Concave-convex clay rod 94～98% after airing, high hydroscopic resin 0.5～5% and cellulose 0.5～3%, above-mentioned batching is stirred, and after stirring, input and in grinding machine, carry out abrasive dust, grain fineness≤0.074 millimeter.
9. the detection method of high sticky Concave-convex clay rod according to claim 7, it is characterized in that, get 28.0g Concave-convex clay rod powder sample, add in the suspension cup of homogenizer, add again 372g water, suspension cup is placed on homogenizer, under the rotating speed of 11000 revs/min, stir 20 minutes, to pour in the beaker of 250mL through high-speed stirred sample suspension again, use NDJ-1 type rotation viscometer to carry out the viscosity of test suspension liquid, tested viscosity value >=2200 mPas is high sticky Concave-convex clay rod.
10. inorfil sprays the batching of cotton mixture according to claim 5, it is characterized in that grain fineness≤0.074 millimeter of colliery powder, grain fineness≤0.074 millimeter of swelling perlite powder.
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| CN102114316A (en) * | 2010-12-22 | 2011-07-06 | 北京林丰源生态科技有限公司 | Fire proofing and extinguishing agent composite for mine and preparation and use method thereof |
| CN102614615A (en) * | 2012-03-14 | 2012-08-01 | 抚顺正工矿业科技发展有限公司 | Complex foam extinguishing agent for coal mine |
| CN103253979A (en) * | 2013-06-12 | 2013-08-21 | 许庆华 | Serpentine composite type flame-retardant foaming agent |
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2014
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Patent Citations (5)
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| JPH02121682A (en) * | 1988-10-31 | 1990-05-09 | Morita Pump Kk | Method for fire-fighting |
| CN1640511A (en) * | 2004-01-08 | 2005-07-20 | 马利华 | Thick liquid efficient fire extinguishing agent |
| CN102114316A (en) * | 2010-12-22 | 2011-07-06 | 北京林丰源生态科技有限公司 | Fire proofing and extinguishing agent composite for mine and preparation and use method thereof |
| CN102614615A (en) * | 2012-03-14 | 2012-08-01 | 抚顺正工矿业科技发展有限公司 | Complex foam extinguishing agent for coal mine |
| CN103253979A (en) * | 2013-06-12 | 2013-08-21 | 许庆华 | Serpentine composite type flame-retardant foaming agent |
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