CN104054987A - Purifying device - Google Patents
Purifying device Download PDFInfo
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- CN104054987A CN104054987A CN201310290289.0A CN201310290289A CN104054987A CN 104054987 A CN104054987 A CN 104054987A CN 201310290289 A CN201310290289 A CN 201310290289A CN 104054987 A CN104054987 A CN 104054987A
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
- A23L5/27—Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
- A23L5/276—Treatment with inorganic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
- B08B3/12—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
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- Hydrology & Water Resources (AREA)
- General Health & Medical Sciences (AREA)
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- Animal Behavior & Ethology (AREA)
- Environmental & Geological Engineering (AREA)
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- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
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Abstract
The invention provides a purifying device. The device comprises a water catalyst generating device, a cleaning sink, an ultrasonic transducer and a water pump, and is characterized in that an electrode of the water catalyst generating device is a titanium alloy electrode coated with a composite layer, wherein the composite layer having the thickness of 1-2 microns is prepared by drying a material composed of manganese, platinum, cerium, gadolinium, europium, gold, antimony, palladium and yttrium and having nanoscale particle size at the temperature of 100-120 DEG C and sintering at the temperature of 400-680 DEG C; and an electrode substrate is a titanium alloy containing the components in parts by mass: 3.1-4.0 parts of Al, 0.8-1.9 parts of Sn, 0.8-1.9 parts of Cr, 0.8-1.9 parts of Mo, 0.8-1.9 parts of Zr, 0.05-0.09 part of Fe, 0.08-0.15 part of C, 0.11-0.25 part of O, 0.004-0.1 part of N, 0.0015-0.025 part of H, 0.1-0.25 part of Si, and the balance titanium and inevitable impurities.
Description
Technical field
The present invention relates to a kind of purifier, specifically relate to a kind of purifier that can be used for fresh food, water, tableware, clothing.
Background technology
Food security is related to broad masses of the people's healthy and life security, is related to economic sound development and social stability, and food security has become weighs the importance that people's living standard, social management level and state legal system are built.China's security status of food pessimistic at present, the microbial contaminations such as the bacterium, virus, parasite existing for a long time, the chemical pollutants such as agricultural chemicals, hormone, antibiotic have brought huge potential safety hazard to food, and food origin disease is still the maximum Health Killer of facing mankind.Simultaneously, with the antiseptic hygiene problem of the closely-related tableware of diet be also larger potential safety hazard, at present because the self-disciplining of the enterprise of partly sterilizing is poor, sterilization process is simple, undesirable, cause the antihygienic situation of sterilizing dinnerware to happen occasionally, cause tableware surface to become the hotbed of bacteria breed, bring threat to consumer's healthy life.
Because food pollution link is numerous, watershed management difficulty is larger, only rely on strong government regulation and functional department to detect, can't thoroughly solve at short notice the pollution problem of food, therefore, food purifying sterilizing becomes and alleviates food security pressure, reduces the necessary means of food poisoning risk, guarantee people safe diet.
At present, also there is no a kind of purifying and sterilizing device safe and efficient, easy to use, can process fresh food, water, tableware and clothing, mostly existing technology is to utilize ozone or chloride chemical reagent to process, its defect is that ozone dissolved degree is lower, in use procedure, can be diffused in a large number in air, and nose and larynx mucous membrane and eyes are had to spread effect, also can cause that lung capacity reduces, and damages human body; Contain the residual of carcinogenicity product and adopt chloride chemical reagent to cause.
No. 200320121904 utility model patent discloses a kind of water supply installation, and this device comprises a feed pipe, an electrolysis unit being connected on described feed pipe.Described electrolysis unit comprises that one has the diaphragm electrolytic cell of cathode chamber and anode chamber, described electrolytic cell has and is connected in the cathode chamber of electrolytic cell, the first row aquaporin that leads to washing tube top, described electrolytic cell has the second row aquaporin that is connected in anode chamber, and described second row aquaporin is connected on the discharge pipe line of washing tube.
200810147230.5 patent application specification discloses a kind of food purification apparatus, this device comprises cleaning sink and water pump, water catalyst generating means, described water catalyst generating means, cleaning sink and water pump are all provided with water inlet and delivery port, and water catalyst generating means, cleaning sink and water pump connect into closed loop by pipeline.
201110271764.0 number application for a patent for invention description discloses a kind of water catalyst sterilizing detoxification device, this device comprises water catalyst generator (1) and the dc source of powering for water catalyst generator (1), described water catalyst generator (1) comprises two electrodes that are used in combination, and two described electrodes are anode electrode and the cathode electrode joining with the positive-negative output end of described dc source respectively; Described anode electrode and described cathode electrode are titanium electrode, and are evenly coated with one deck composite coating on the outer surface of described anode electrode; Described composite coating is that the composite masking liquid on described anode electrode outer surface carries out the coating obtaining after drying and processing and sintering processes to brushing, composite masking liquid is that six kinds of described pulvis are respectively the compound powder of compound powder, niobium powder or niobium and the compound powder of tantalum powder or tantalum of compound powder, ruthenium powder or the ruthenium of compound powder, yttrium powder or the yttrium of compound powder, iridium powder or the iridium of platinum powder or platinum by six kinds of pulvis and absolute ethyl alcohol evenly mixes and mass concentration is 2.5%～4% mixed liquor.
The inventor has studied, has analyzed the report in above-mentioned prior art for a long period of time, also carefully analyze, conscientiously studied and recorded in patent documentation: the device of " a kind of simple in structure, reasonable in design, use the effective water catalyst sterilizing detoxification device of purified treatment easy and simple to handle ", " described electrolysis unit comprises that one has the diaphragm electrolytic cell of cathode chamber and anode chamber ", this device " can realize in the time of washing, catch for alkaline water to washing tube; And in the time of rinsing, provide acid water to washing tube; It further can, providing alkaline water simultaneously, provide the upgrading liquid that improves clean result "; " how the purification of hydroxyl radical free radical, sterilization, sterilizing function are applied to food field of purification; overcome prior art water consumption large, purify not thoroughly, the technological deficiency of not energy-conserving and environment-protective, realize food and purify convenient, laborsaving, efficient, water saving, clean, thorough ".The inventor finds on the basis of the above, existing have data, patent documentation to have no its concrete treatment effect, the object of " purifying convenient, laborsaving, efficient, water saving, clean, thorough " that these statement of facts water catalyst sterilizing detoxification device are expected with a certain distance from people also has, still exist some improved defects of still needing, can be become a kind of safe and reliable disinfecting detoxifying device.
Summary of the invention
The present invention is exactly a kind of safety and stability, the clean-up effect excellence proposing for above-mentioned defect, the better purifier of energy-saving and water-saving.
For realizing goal of the invention of the present invention, in purifier provided by the invention, described device comprises water catalyst generating means, cleaning sink, ultrasonic transducer and water pump, its improvements are that the electrode of described water catalyst generating means is titanium alloy electrode, the composite bed of 1～2 micron thick that at the drying at 100-120 DEG C of the manganese of coated with nano level particle diameter on it, platinum, cerium, gadolinium, europium, gold, antimony, palladium and yttrium composition, 400～680 DEG C prepared by sintering; Described electrode base material is titanium alloy, by mass parts, containing Al:3.1～4.0; Sn:0.8～1.9; Cr:0.8～1.9; Mo:0.8～1.9; Zr:0.8～1.9; Fe:0.05～0.09; C:0.08～0.15; O:0.11～0.25; N:0.004～0.1; H:0.0015～0.025; Si:0.1～0.25, all the other are titanium and inevitable impurity.
In preferred purifier provided by the invention, in described composite bed: manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～6:5～15:9～17:2～8:3～12:1～7:2～10:10～23:15～27, particle diameter is 5～30nm; Described titanium alloy is containing Al:3.1～3.9; Sn:0.8～1.7; Cr:0.8～1.7.
In the provided by the invention the 3rd preferred purifier, in described composite bed: manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～5:6～15:9～16:2～7:3～11:1～6:2～9:10～21:15～25, particle diameter is 5～30nm; Described titanium alloy is containing Mo:0.9～1.8; Zr:0.9～1.7; Fe:0.06～0.09.
In the provided by the invention the 4th preferred purifier, in described composite bed: manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～5:7～15:10～16:3～7:4～11:2～6:3～9:12～21:17～25, particle diameter is 5～30nm; Described titanium alloy is containing C:0.09～0.12; O:0.14～0.22; N:0.04～0.1.
In the provided by the invention the 5th preferred purifier, sintering temperature is 400～450 DEG C, in described composite bed: manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～5:7～13:10～15:3～6:4～10:2～5:3～8:12～19:17～22, particle diameter is 5～30nm; Described titanium alloy is containing H:0.018～0.025; Si:0.13～0.22.
In the provided by the invention the 6th preferred purifier, in described composite bed: manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～5:8～13:11～15:4～6:6～10:3～5:5～8:13～19:19～22, particle diameter is 5～30nm; Described titanium alloy is containing Al:3.3～4.0; Sn:0.9～1.8; Cr:0.9～1.8; Mo:0.9～1.8; Zr:0.9～1.8.
In the provided by the invention the 7th preferred purifier, in described composite bed: manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～4:9～13:12～15:4～5:6～9:3～4:5～7:14～19:19～21, particle diameter is 5～30nm; Described titanium alloy is containing Fe:0.06～0.08; C:0.09～0.13; O:0.16～0.22; N:0.007～0.1; H:0.013～0.022; Si:0.13～0.22.
In the provided by the invention the 8th preferred purifier, ultrasonic transducer comprises emitting head, insulation spacer, piezoelectric sheet, quality sheet and electrode; Said emitting head, insulation spacer, piezoelectric sheet and quality sheet are successively set on same axis; Described electrode is the electrode of being prepared by metal Ga; Described piezoelectric sheet is the end acetylene schiff bases that 10 μ m are thick; In described composite bed: manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=4:11:13:5:8:4:7:16:20, particle diameter is 5～30nm; Described titanium alloy is containing Al:3.2～4.0; Sn:1.0～1.7; Mo:1.0～1.7; Fe:0.07～0.09; C:0.09～0.13; O:0.15～0.22; N:0.007～0.1; Si:0.13～0.22.
In the provided by the invention the 9th preferred purifier, the number that insulation spacer lays respectively at described emitting head and quality sheet the inner is the insulating trip of two, its inner be provided with left or the axial sections of 10～90 degree of turning right be concave character type and its left and right protuberance be positioned at respectively between described piezoelectric sheet, its bottom is greater than the first electrode slice of the radius of described insulating trip to the radius in the center of circle; The inner shafts that is positioned at described concave character type electrode slice is to the second electrode slice and the patch of piezoelectric material that set gradually patch of piezoelectric material, diameter and be greater than described patch of piezoelectric material.
Compared with the prior art, beneficial effect of the present invention is:
Vegetables or fruit pesticide volume before A (mg/kg)=washing; B=mg/kg (vegetables after washing or fruit pesticide volume), this measures all lower than vegetables, fruit residues of pesticides new standard after testing.
Brief description of the drawings
Fig. 1 is the structural representation of the embodiment of the present invention.
Fig. 2 is the rearview of Fig. 1.
Fig. 3 is the structural representation of top cover after starting in Fig. 1.
Fig. 4 is Fig. 3 side view.
Fig. 5 is the top view after Fig. 1 middle shell and base decompose.
Fig. 6 is the upward view after Fig. 1 middle shell and base decompose.
Fig. 7 is the upward view after base removal in Fig. 1.
Fig. 8 is the top view after Fig. 1 middle shell and top cover are removed.
Fig. 9 cleans to use ultrasonic transducer structure schematic diagram.
Detailed description of the invention
Below in conjunction with accompanying drawing, the specific embodiment of the present invention is described in further detail.
Please refer to Fig. 1, Fig. 2, Fig. 3, Fig. 4, Fig. 5, Fig. 6, Fig. 7, Fig. 8, the present invention is a kind of purifier, comprise housing 1 and base 2, in housing 1, be provided with cleaning sink 3, water catalyst generating means 4 and water pump 5 are installed on base 2, be provided with water inlet 6 and delivery port 7 in the bottom of cleaning sink 3, the below of water inlet 6 is provided with minitype nozzle 8, the below of delivery port 7 arranges tee pipe coupling 9, tee pipe coupling 9 is leaded up to magnetic valve 10 and is connected with drainpipe 14, the pipeline 11 of separately leading up to of tee pipe coupling 9 is communicated with the water inlet of water catalyst generating means 4, the delivery port of water catalyst generating means 4 is communicated with the water inlet of water pump 5 by No. two pipelines 12, the delivery port of water pump 5 is communicated with minitype nozzle 8 by No. three pipelines 13, minitype nozzle 8 is communicated with water inlet 6.
The bottom center of cleaning sink 3 is provided with ultrasonic transducer 15.The top of cleaning sink 3 is provided with cover plate 16, so that pick and place food and add clear water.On the backboard of base 2, be provided with power switch 17 and supply socket 18.On base 2, be provided with circuit board 19.On circuit board 19, be integrated with microcomputer controller.Microcomputer controller is controlled automatically to water catalyst generating means 4, water pump 5, ultrasonic transducer 15.Under the draft effect of water pump 5, water in cleaning sink 3 is discharged by delivery port 7, through tee pipe coupling 9, arrive the water inlet of water catalyst generating means 4 along pipeline 11, from the delivery port of water catalyst generating means 4 is discharged, become the high energy oxidize water that contains water catalyst functional group, high energy oxidize water arrives the water inlet of water pump 5 along No. two pipelines 12, after water pump 5 pressurizations, discharge from the delivery port of water pump 5, again through No. three pipelines 13, minitype nozzle 8, arrive the water inlet 6 of cleaning sink 3, turn back in cleaning sink 3, formation circulates, be provided with the guidance panel 20 of microcomputer controller at the end face of housing 1, can be to water pump 5 by guidance panel 20, the working time of water catalyst generating means 4 and ultrasonic transducer 15 is carried out timing controlled.When use, can, according to the difference that is cleaned object kind, select different timings, to reach best cleaning, purification, Disinfection Effect.After cleaning, microcomputer controller switches off the pump 5, water catalyst generating means 4 and ultrasonic transducer 15, opens solenoid valve 10, and the sewage in cleaning sink 3 is discharged by drainpipe 14.
1. water catalyst generating means:
Described in water catalyst generating means of the present invention, the electrode of water catalyst generating means is titanium alloy electrode, the composite bed of 1～2 micron thick that at the drying at 100-120 DEG C of the manganese of coated with nano level particle diameter on it, platinum, cerium, gadolinium, europium, gold, antimony, palladium and yttrium composition, 400～680 DEG C prepared by sintering; Described electrode base material is titanium alloy.
1. except being otherwise noted, in the present invention, ratio and content are all by mass parts, the electrode of water catalyst generating means is on titanium alloy electrode, to apply the manganese that particle diameter is 5nm nanometer: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium=6:15:17:8:12:7:10:23:27, mixing coating material, the composite bed of 1 micron thick of dry at 100 DEG C, preparing by sintering at 400 DEG C; Electrode base material is that titanium alloy contains Al:4.1; Sn:0.8; Cr:0.8; Mo:0.9; Zr:0.9; Fe:0.05; C:0.08; O:0.11; N:0.004; H:0.0015; Si:0.1, all the other are titanium and inevitable impurity.
2. except being otherwise noted, in the present invention, ratio and content are all by mass parts, the electrode of water catalyst generating means is on titanium alloy electrode, to apply the manganese that particle diameter is 10nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium=3:6:9:2:3:1:2:10:15, the composite bed of 1 micron thick of dry at 105 DEG C, preparing by sintering at 420 DEG C; Electrode base material is that titanium alloy contains Al:3.3; Sn:1.0; Cr:1.0; Mo:0.9; Zr:1.0; Fe:0.06; C:0.15; O:0.12; N:0.005; H:0.002; Si:0.14, all the other are titanium and inevitable impurity.
3. except being otherwise noted, in the present invention, ratio and content are all by mass parts, the electrode of water catalyst generating means is on titanium alloy electrode, to apply the manganese that particle diameter is 15nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium=4:15:16:7:11:6:9:21:25, the composite bed of 1 micron thick of dry at 110 DEG C, preparing by sintering at 430 DEG C; Electrode base material is that titanium alloy contains Al:3.4; Sn:1.1; Cr:1.0; Mo:1.1; Zr:0.9; Fe:0.08; C:0.11; O:0.2; N:0.05; H:0.002; Si:0.15, all the other are titanium and inevitable impurity.
4. except being otherwise noted, in the present invention, ratio and content are all by mass parts, the electrode of water catalyst generating means is on titanium alloy electrode, to apply the manganese that particle diameter is 20nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium=5:7:10:3:4:2:3:12:17, the composite bed of 1 micron thick of dry at 115 DEG C, preparing by sintering at 440 DEG C; Electrode base material is that titanium alloy contains Al:3.5; Sn:1.3; Cr:0.8; Mo:1.2; Zr:0.9; Fe:0.07; C:0.12; O:0.16; N:0.01; H:0.02; Si:0.2, all the other are titanium and inevitable impurity.
5. except being otherwise noted, in the present invention, ratio and content are all by mass parts, the electrode of water catalyst generating means is on titanium alloy electrode, to apply the manganese that particle diameter is 25nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium=5:8:11:6:10:5:8:13:22, the composite bed of 2 micron thick of dry at 115 DEG C, preparing by sintering at 460 DEG C; Electrode base material is that titanium alloy contains Al:4.0; Sn:1.7; Cr:1.6; Mo:0.9; Zr:0.9; Fe:0.08; C:0.15; O:0.17; N:0.01; H:0.005; Si:0.12, all the other are titanium and inevitable impurity.
6. except being otherwise noted, in the present invention, ratio and content are all by mass parts, the electrode of water catalyst generating means is on titanium alloy electrode, to apply the manganese that particle diameter is 28nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium=3:10:14:4:7:3:6:15:21, the composite bed of 2 micron thick of dry at 120 DEG C, preparing by sintering at 470 DEG C; Electrode base material is that titanium alloy contains Al:3.7; Sn:0.9; Cr:1.1; Mo:1.3; Zr:1.5; Fe:0.06; C:0.13; O:0.18; N:0.09; H:0.009; Si:0.2, all the other are titanium and inevitable impurity.
7. except being otherwise noted, in the present invention, ratio and content are all by mass parts, the electrode of water catalyst generating means is on titanium alloy electrode, to apply the manganese that particle diameter is 30nm nanometer: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium=4:11:13:5:8:4:7:16:20 mixing coating material, the composite bed of 2 micron thick of dry at 120 DEG C, preparing by sintering at 680 DEG C; Electrode base material is that titanium alloy contains Al:3.3; Sn:1.7; Cr:1.5; Mo:1.2; Zr:1.6; Fe:0.07; C:0.12; O:0.2; N:0.08; H:0.02; Si:0.2, all the other are titanium and inevitable impurity.
2. excusing from death ripple transducing converter
As shown in Figure 9, ultrasonic transducer of the present invention advantageously comprises a kind of polyethylene sheets for setting gradually emitting head, insulation spacer, Au electrode, polypyrrole piezoelectric patches, Au electrode, polypyrrole piezoelectric patches, Au electrode, polypyrrole piezoelectric patches and mass, piezoelectric sheet on axial, thickness is 5 μ m to 75 μ, typically be 9 μ m to 35 μ m thick, typically be 20 μ m to 25 μ m thick, typically be 25 μ m most thick.
In its best form, piezoelectric sheet is typically by Kynoar (" P VDF ") thin slice or is made up of the copolymer thin slice that comprises PVDF.This thin slice has two electrodes fixed thereon at least, is typically and on each of thin slice, has an electrode.These electrodes can be same material or different materials, are typically same material.The example of electrode material is such as metal A u, Pd, Pt, Ti, Zn, Al, Ag, Cu, Sn, Ga, In, Ni, conducting polymer, this polymer need to be filled with additive, additive is iodine, fluorine, alkali metal and salt thereof, metal carbonate and fontanel arsenic, this conducting polymer comprises: polyyne, polyyne copolymer, polypyrrole, polypropylene is fine, aromatic polymer, polyaniline, polythiophene, polycarbazole, poly-beta-diketon, poly-dipropargyl amine, poly-acenaphthene/N-vinyl heterocycle lewis acid, poly-(aromatic heterocycle 1, the sub-ethene of 2-), poly-phthalocyanine, with 1, the two polymer that replace sub-benzene chemically reactive of 9-, cluster phylloerythrin, heterocyclic ladder polymer, alternative aromatics and quinoid sequence, polyisothianaphthene and poly-(p-phenylene) thioether, do not need the polymer of doping, for example: poly-(the two o-nitriles of two ehter bonds), polyacetylene and the poly-diine with structure cell, poly-(the peri-position bitter edible plant), poly-(carbon diselenide), poly-(the benzo two thiol alkene) of transition metal, poly-(thiophene-sulfonic acid ester) and end acetylene schiff bases.
In described ultrasonic transducer, electrode is Ga, piezoelectric thickness of slab 10 μ m.
Finally should be noted that: above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit, although the present invention is had been described in detail with reference to above-described embodiment, those of ordinary skill in the field are to be understood that: still can modify or be equal to replacement the specific embodiment of the present invention, and do not depart from any amendment of spirit and scope of the invention or be equal to replacement, it all should be encompassed in the middle of claim scope of the present invention.
Claims (9)
1. a purifier, described device comprises water catalyst generating means, cleaning sink, ultrasonic transducer and water pump, the electrode that it is characterized in that described water catalyst generating means is titanium alloy electrode, the composite bed of 1～2 micron thick that at the drying at 100-120 DEG C of the manganese of coated with nano level particle diameter on it, platinum, cerium, gadolinium, europium, gold, antimony, palladium and yttrium composition, 400～680 DEG C prepared by sintering; Described electrode base material is titanium alloy, by mass parts, containing Al:3.1～4.0; Sn:0.8～1.9; Cr:0.8～1.9; Mo:0.8～1.9; Zr:0.8～1.9; Fe:0.05～0.09; C:0.08～0.15; O:0.11～0.25; N:0.004～0.1; H:0.0015～0.025; Si:0.1～0.25, all the other are titanium and inevitable impurity.
2. according to the purifier of claim 1, it is characterized in that described manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～6:5～15:9～17:2～8:3～12:1～7:2～10:10～23:15～27, particle diameter is 5～30nm; Described titanium alloy is containing Al:3.1～3.9; Sn:0.8～1.7; Cr:0.8～1.7.
3. according to the purifier of claim 1, it is characterized in that described manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～5:6～15:9～16:2～7:3～11:1～6:2～9:10～21:15～25, particle diameter is 5～30nm; Described titanium alloy is containing Mo:0.9～1.8; Zr:0.9～1.7; Fe:0.06～0.09.
4. according to the purifier of claim 1, it is characterized in that described manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～5:7～15:10～16:3～7:4～11:2～6:3～9:12～21:17～25, particle diameter is 5～30nm; Described titanium alloy is containing C:0.09～0.12; O:0.14～0.22; N:0.04～0.1.
5. according to the purifier of claim 1, it is characterized in that described sintering temperature is 400～450 DEG C, described manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～5:7～13:10～15:3～6:4～10:2～5:3～8:12～19:17～22, particle diameter is 5～30nm; Described titanium alloy is containing H:0.018～0.025; Si:0.13～0.22.
6. according to the purifier of claim 1, it is characterized in that described manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～5:8～13:11～15:4～6:6～10:3～5:5～8:13～19:19～22, particle diameter is 5～30nm; Described titanium alloy is containing Al:3.3～4.0; Sn:0.9～1.8; Cr:0.9～1.8; Mo:0.9～1.8; Zr:0.9～1.8.
7. according to the purifier of claim 1, it is characterized in that described manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=3～4:9～13:12～15:4～5:6～9:3～4:5～7:14～19:19～21, particle diameter is 5～30nm; Described titanium alloy is containing Fe:0.06～0.08; C:0.09～0.13; O:0.16～0.22; N:0.007～0.1; H:0.013～0.022; Si:0.13～0.22.
8. according to the purifier of claim 1, it is characterized in that described ultrasonic transducer comprises emitting head, insulation spacer, piezoelectric sheet, quality sheet and electrode; Said emitting head, insulation spacer, piezoelectric sheet and quality sheet are successively set on same axis; Described electrode is the electrode of being prepared by metal Ga; Described piezoelectric sheet is the end acetylene schiff bases that 10 μ m are thick; Described manganese: platinum: cerium: gadolinium: europium: gold: antimony: palladium: yttrium mass ratio=4:11:13:5:8:4:7:16:20, particle diameter is 5～30nm; Described titanium alloy is containing Al:3.2～4.0; Sn:1.0～1.7; Mo:1.0～1.7; Fe:0.07～0.09; C:0.09～0.13; O:0.15～0.22; N:0.007～0.1; Si:0.13～0.22.
9. purifier according to Claim 8, it is characterized in that number that described insulation spacer lays respectively at described emitting head and quality sheet the inner is the insulating trip of two, its inner be provided with left or the axial sections of 10～90 degree of turning right be concave character type and its left and right protuberance be positioned at respectively between described piezoelectric sheet, its bottom is greater than the first electrode slice of the radius of described insulating trip to the radius in the center of circle; The inner shafts that is positioned at described concave character type electrode slice is to the second electrode slice and the patch of piezoelectric material that set gradually patch of piezoelectric material, diameter and be greater than described patch of piezoelectric material.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113458021A (en) * | 2021-05-21 | 2021-10-01 | 德州市纤维检验所 | Detection equipment for pesticide residues and heavy metals in cotton |
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Application publication date: 20140924 |