CN104054986A - Purifying device - Google Patents
Purifying device Download PDFInfo
- Publication number
- CN104054986A CN104054986A CN201310290185.XA CN201310290185A CN104054986A CN 104054986 A CN104054986 A CN 104054986A CN 201310290185 A CN201310290185 A CN 201310290185A CN 104054986 A CN104054986 A CN 104054986A
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- Prior art keywords
- electrode
- titanium alloy
- platinum
- europium
- gadolinium
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 71
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 54
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 49
- 229910001069 Ti alloy Inorganic materials 0.000 claims abstract description 36
- 239000003054 catalyst Substances 0.000 claims abstract description 34
- 239000010931 gold Substances 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 27
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 27
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 25
- 229910052693 Europium Inorganic materials 0.000 claims abstract description 25
- 229910052688 Gadolinium Inorganic materials 0.000 claims abstract description 25
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 25
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 25
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims abstract description 25
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims abstract description 25
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052737 gold Inorganic materials 0.000 claims abstract description 25
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 25
- 239000002131 composite material Substances 0.000 claims abstract description 23
- 238000004140 cleaning Methods 0.000 claims abstract description 16
- 238000005245 sintering Methods 0.000 claims abstract description 14
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 12
- 239000010936 titanium Substances 0.000 claims abstract description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000012535 impurity Substances 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 5
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract 9
- 238000009413 insulation Methods 0.000 claims description 7
- 125000006850 spacer group Chemical group 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 description 16
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 16
- 239000002245 particle Substances 0.000 description 16
- 235000013305 food Nutrition 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 230000001954 sterilising effect Effects 0.000 description 10
- 238000002156 mixing Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- -1 hydroxyl radical free radical Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 230000008878 coupling Effects 0.000 description 4
- 238000010168 coupling process Methods 0.000 description 4
- 238000005859 coupling reaction Methods 0.000 description 4
- 229920000128 polypyrrole Polymers 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 102000010637 Aquaporins Human genes 0.000 description 3
- 108010063290 Aquaporins Proteins 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000001784 detoxification Methods 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 235000021393 food security Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000002322 conducting polymer Substances 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000005911 diet Nutrition 0.000 description 2
- 230000037213 diet Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 238000007726 management method Methods 0.000 description 2
- 230000000873 masking effect Effects 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N Carbazole Natural products C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 206010016952 Food poisoning Diseases 0.000 description 1
- 208000019331 Foodborne disease Diseases 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002262 Schiff base Substances 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- CWRYPZZKDGJXCA-UHFFFAOYSA-N acenaphthene Chemical compound C1=CC(CC2)=C3C2=CC=CC3=C1 CWRYPZZKDGJXCA-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 235000018927 edible plant Nutrition 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 210000000867 larynx Anatomy 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- RGSODMOUXWISAG-UHFFFAOYSA-N n-prop-2-ynylprop-2-yn-1-amine Chemical compound C#CCNCC#C RGSODMOUXWISAG-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920001088 polycarbazole Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 230000002463 transducing effect Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/30—Physical treatment, e.g. electrical or magnetic means, wave energy or irradiation
- A23L5/32—Physical treatment, e.g. electrical or magnetic means, wave energy or irradiation using phonon wave energy, e.g. sound or ultrasonic waves
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
- B08B3/12—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/10—Apparatus features
- A61L2202/17—Combination with washing or cleaning means
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Nutrition Science (AREA)
- Hydrology & Water Resources (AREA)
- Organic Chemistry (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Electrochemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Catalysts (AREA)
Abstract
The invention provides a purifying device. The device comprises a water catalyst generating device, a cleaning sink, an ultrasonic transducer and a water pump, and is characterized in that an electrode of the water catalyst generating device is a titanium alloy electrode coated with a composite layer, wherein the composite layer having the thickness of 1-2 microns is prepared by drying a material composed of nickel, platinum, cerium, gadolinium, europium, gold and antimony and having nanoscale particle size at the temperature of 100-120 DEG C and sintering at the temperature of 400-680 DEG C; and an electrode substrate is a titanium alloy containing the components in parts by mass: 6.6-6.8 parts of Al, 1.2-1.4 parts of Sn, 1.2-1.4 parts of Cr, 1.2-1.4 parts of Mo, 1.2-1.4 parts of Zr, 0.6-0.26 part of Fe, 0.16-0.17 part of C, 0.11-0.25 part of O, 0.004-0.1 part of N, 0.0015-0.025 part of H, 0.1-0.25 part of Si, and the balance titanium and inevitable impurities.
Description
Technical field
The present invention relates to a kind of purifier, specifically relate to a kind of purifier that can be used for fresh food, water, tableware, clothing.
Background technology
Food security is related to broad masses of the people's healthy and life security, is related to economic sound development and social stability, and food security has become weighs the importance that people's living standard, social management level and state legal system are built.China's security status of food pessimistic at present, the microbial contaminations such as the bacterium, virus, parasite existing for a long time, the chemical pollutants such as agricultural chemicals, hormone, antibiotic have brought huge potential safety hazard to food, and food origin disease is still the maximum Health Killer of facing mankind.Simultaneously, with the antiseptic hygiene problem of the closely-related tableware of diet be also larger potential safety hazard, at present because the self-disciplining of the enterprise of partly sterilizing is poor, sterilization process is simple, undesirable, cause the antihygienic situation of sterilizing dinnerware to happen occasionally, cause tableware surface to become the hotbed of bacteria breed, bring threat to consumer's healthy life.
Because food pollution link is numerous, watershed management difficulty is larger, only rely on strong government regulation and functional department to detect, can't thoroughly solve at short notice the pollution problem of food, therefore, food purifying sterilizing becomes and alleviates food security pressure, reduces the necessary means of food poisoning risk, guarantee people safe diet.At present, also there is no a kind of purifying and sterilizing device safe and efficient, easy to use, can process fresh food, water, tableware and clothing, mostly existing technology is to utilize ozone or chloride chemical reagent to process, its defect is that ozone dissolved degree is lower, in use procedure, can be diffused in a large number in air, and nose and larynx mucous membrane and eyes are had to spread effect, also can cause that lung capacity reduces, and damages human body; Contain the residual of carcinogenicity product and adopt chloride chemical reagent to cause.
No. 200320121904 utility model patent discloses a kind of water supply installation, and this device comprises a feed pipe, an electrolysis unit being connected on described feed pipe.Described electrolysis unit comprises that one has the diaphragm electrolytic cell of cathode chamber and anode chamber, described electrolytic cell has and is connected in the cathode chamber of electrolytic cell, the first row aquaporin that leads to washing tube top, described electrolytic cell has the second row aquaporin that is connected in anode chamber, and described second row aquaporin is connected on the discharge pipe line of washing tube.
200810147230.5 patent application specification discloses a kind of food purification apparatus, this device comprises cleaning sink and water pump, water catalyst generating means, described water catalyst generating means, cleaning sink and water pump are all provided with water inlet and delivery port, and water catalyst generating means, cleaning sink and water pump connect into closed loop by pipeline.
201110271764.0 number application for a patent for invention description discloses a kind of water catalyst sterilizing detoxification device, this device comprises water catalyst generator (1) and the dc source of powering for water catalyst generator (1), described water catalyst generator (1) comprises two electrodes that are used in combination, and two described electrodes are anode electrode and the cathode electrode joining with the positive-negative output end of described dc source respectively; Described anode electrode and described cathode electrode are titanium electrode, and are evenly coated with one deck composite coating on the outer surface of described anode electrode; Described composite coating is that the composite masking liquid on described anode electrode outer surface carries out the coating obtaining after drying and processing and sintering processes to brushing, composite masking liquid is that six kinds of described pulvis are respectively the compound powder of compound powder, niobium powder or niobium and the compound powder of tantalum powder or tantalum of compound powder, ruthenium powder or the ruthenium of compound powder, yttrium powder or the yttrium of compound powder, iridium powder or the iridium of platinum powder or platinum by six kinds of pulvis and absolute ethyl alcohol evenly mixes and mass concentration is 2.5%～4% mixed liquor.
The inventor has studied, has analyzed the report in above-mentioned prior art for a long period of time, also carefully analyze, conscientiously studied and recorded in patent documentation: the device of " a kind of simple in structure, reasonable in design, use the effective water catalyst sterilizing detoxification device of purified treatment easy and simple to handle ", " described electrolysis unit comprises that one has the diaphragm electrolytic cell of cathode chamber and anode chamber ", this device " can realize in the time of washing, catch for alkaline water to washing tube; And in the time of rinsing, provide acid water to washing tube; It further can, providing alkaline water simultaneously, provide the upgrading liquid that improves clean result "; " how the purification of hydroxyl radical free radical, sterilization, sterilizing function are applied to food field of purification; overcome prior art water consumption large, purify not thoroughly, the technological deficiency of not energy-conserving and environment-protective, realize food and purify convenient, laborsaving, efficient, water saving, clean, thorough ".The inventor finds on the basis of the above, existing have data, patent documentation to have no its concrete treatment effect, the object of " purifying convenient, laborsaving, efficient, water saving, clean, thorough " that these statement of facts water catalyst sterilizing detoxification device are expected with a certain distance from people also has, still exist some improved defects of still needing, can be become a kind of safe and reliable disinfecting detoxifying device.
Summary of the invention
The present invention is exactly a kind of safety and stability, the clean-up effect excellence proposing for above-mentioned defect, the better purifier of energy-saving and water-saving.
For realizing goal of the invention of the present invention, in purifier provided by the invention, described device comprises water catalyst generating means, cleaning sink, ultrasonic transducer and water pump, its improvements are that the electrode of described water catalyst generating means is titanium alloy electrode, the composite bed of 1～2 micron thick that at the drying at 100-120 DEG C of the nickel of coated with nano level particle diameter on it, platinum, cerium, gadolinium, europium, gold and antimony composition, 400～680 DEG C prepared by sintering; Described electrode base material is titanium alloy, by mass parts, containing Al:6.6～6.8; Sn:1.2～1.4; Cr:1.2～1.4; Mo:1.2～1.4; Zr:1.2～1.4; Fe:0.6～0.26; C:0.16～0.17; O:0.11～0.25; N:0.004～0.1; H:0.0015～0.025; Si:0.1～0.25; All the other are titanium and inevitable impurity.
In preferred purifier provided by the invention, in described composite bed: nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～9:5～15:9～17:2～8:3～12:1～7:2～10 of antimony; Particle diameter is 5～30nm; Described titanium alloy is containing Al:6.7; Sn:1.3; Cr:1.3.
In the provided by the invention the 3rd preferred purifier, in described composite bed: nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～7:5～13:9～15:2～6:3～10:1～6:2～9 of antimony; Particle diameter is 5～30nm; Described titanium alloy is containing Mo:1.3; Zr:1.3; Fe:0.9～0.21.
In the provided by the invention the 4th preferred purifier, in described composite bed: nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～6:5～10:9～14:2～6:3～10:1～5:2～7 of antimony; Particle diameter is 5～30nm; Described titanium alloy is containing C:0.17; O:0.18～0.21; N:0.008～0.06.
In the provided by the invention the 5th preferred purifier, sintering temperature is 400～450 DEG C, in described composite bed: nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～6:5～10:9～14:2～6:3～9:1～5:2～6 of antimony; Particle diameter is 5～30nm; Described titanium alloy is containing H:0.0018～0.021; Si:0.2～0.22.
In the provided by the invention the 6th preferred purifier, in described composite bed: nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～6:5～11:9～14:2～6:3～9:1～5:2～7 of antimony; Particle diameter is 5～30nm; Described titanium alloy is containing Al:6.6～6.8; Sn:1.2～1.4; Cr:1.2～1.4; Mo:1.2～1.4; Zr:1.2～1.4.
In the provided by the invention the 7th preferred purifier, in described composite bed: nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～5:4～9:10～15:3～6:4～9:1～5:3～8 of antimony; Particle diameter is 5～30nm; Described titanium alloy is containing Fe:0.8～0.21; C:0.17; O:0.17～0.21; N:0.008～0.06; H:0.0019～0.021; Si:0.2～0.22.
In the provided by the invention the 8th preferred purifier, ultrasonic transducer comprises emitting head, insulation spacer, piezoelectric sheet, quality sheet and electrode; Said emitting head, insulation spacer, piezoelectric sheet and quality sheet are successively set on same axis; Described electrode is the electrode of being prepared by metal Pd; Described piezoelectric sheet is the thick polyyne of 10 μ m; In described composite bed: nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=4～6:6～13:12～15:3～6:4～9:2～6:3～8 of antimony; Particle diameter is 5～30nm; Described titanium alloy is containing Al:6.7; Cr:1.3; Zr:1.3; O:0.17～0.21; N:0.008～0.07; Si:0.1～0.23.
In the provided by the invention the 9th preferred purifier, the number that insulation spacer lays respectively at described emitting head and quality sheet the inner is the insulating trip of two, its inner be provided with left or the axial sections of 10～90 degree of turning right be concave character type and its left and right protuberance be positioned at respectively between described piezoelectric sheet, its bottom is greater than the first electrode slice of the radius of described insulating trip to the radius in the center of circle; The inner shafts that is positioned at described concave character type electrode slice is to the second electrode slice and the patch of piezoelectric material that set gradually patch of piezoelectric material, diameter and be greater than described patch of piezoelectric material.
Compared with the prior art, beneficial effect of the present invention is:
Vegetables or fruit pesticide volume before A (mg/kg)=washing; B=mg/kg (vegetables after washing or fruit pesticide volume), this measures all lower than vegetables, fruit residues of pesticides new standard after testing.
Brief description of the drawings
Fig. 1 is the structural representation of the embodiment of the present invention.
Fig. 2 is the rearview of Fig. 1.
Fig. 3 is the structural representation of top cover after starting in Fig. 1.
Fig. 4 is Fig. 3 side view.
Fig. 5 is the top view after Fig. 1 middle shell and base decompose.
Fig. 6 is the upward view after Fig. 1 middle shell and base decompose.
Fig. 7 is the upward view after base removal in Fig. 1.
Fig. 8 is the top view after Fig. 1 middle shell and top cover are removed.
Fig. 9 cleans to use ultrasonic transducer structure schematic diagram.
Detailed description of the invention
Below in conjunction with accompanying drawing, the specific embodiment of the present invention is described in further detail.
Please refer to Fig. 1, Fig. 2, Fig. 3, Fig. 4, Fig. 5, Fig. 6, Fig. 7, Fig. 8, the present invention is a kind of purifier, comprise housing 1 and base 2, in housing 1, be provided with cleaning sink 3, water catalyst generating means 4 and water pump 5 are installed on base 2, be provided with water inlet 6 and delivery port 7 in the bottom of cleaning sink 3, the below of water inlet 6 is provided with minitype nozzle 8, the below of delivery port 7 arranges tee pipe coupling 9, tee pipe coupling 9 is leaded up to magnetic valve 10 and is connected with drainpipe 14, the pipeline 11 of separately leading up to of tee pipe coupling 9 is communicated with the water inlet of water catalyst generating means 4, the delivery port of water catalyst generating means 4 is communicated with the water inlet of water pump 5 by No. two pipelines 12, the delivery port of water pump 5 is communicated with minitype nozzle 8 by No. three pipelines 13, minitype nozzle 8 is communicated with water inlet 6.
The bottom center of cleaning sink 3 is provided with ultrasonic transducer 15.The top of cleaning sink 3 is provided with cover plate 16, so that pick and place food and add clear water.On the backboard of base 2, be provided with power switch 17 and supply socket 18.On base 2, be provided with circuit board 19.On circuit board 19, be integrated with microcomputer controller.Microcomputer controller is controlled automatically to water catalyst generating means 4, water pump 5, ultrasonic transducer 15.Under the draft effect of water pump 5, water in cleaning sink 3 is discharged by delivery port 7, through tee pipe coupling 9, arrive the water inlet of water catalyst generating means 4 along pipeline 11, from the delivery port of water catalyst generating means 4 is discharged, become the high energy oxidize water that contains water catalyst functional group, high energy oxidize water arrives the water inlet of water pump 5 along No. two pipelines 12, after water pump 5 pressurizations, discharge from the delivery port of water pump 5, again through No. three pipelines 13, minitype nozzle 8, arrive the water inlet 6 of cleaning sink 3, turn back in cleaning sink 3, formation circulates, be provided with the guidance panel 20 of microcomputer controller at the end face of housing 1, can be to water pump 5 by guidance panel 20, the working time of water catalyst generating means 4 and ultrasonic transducer 15 is carried out timing controlled.When use, can, according to the difference that is cleaned object kind, select different timings, to reach best cleaning, purification, Disinfection Effect.After cleaning, microcomputer controller switches off the pump 5, water catalyst generating means 4 and ultrasonic transducer 15, opens solenoid valve 10, and the sewage in cleaning sink 3 is discharged by drainpipe 14.
1. water catalyst generating means:
Described in water catalyst generating means of the present invention, the electrode of water catalyst generating means is titanium alloy electrode, the composite bed of 1～2 micron thick that at the drying at 100-120 DEG C of the nickel of coated with nano level particle diameter on it, platinum, cerium, gadolinium, europium, gold and antimony composition, 400～680 DEG C prepared by sintering; Described electrode base material is titanium alloy.
In the present invention ratio and content all by mass parts, the electrode of water catalyst generating means is that on titanium alloy electrode, to apply particle diameter can be the nickel of 5nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony=2:5:9:2:3:1:2, the composite bed of 1 micron thick of dry at 100 DEG C, preparing by sintering at 400 DEG C; Electrode base material is that titanium alloy contains Al:6.7; Sn:1.3; Cr:1.3; Mo:1.3; Zr:1.3; Fe:0.6; C:0.16; O:0.11; N:0.004; H:0.0015; Si:0.1, all the other are titanium and inevitable impurity.
In the present invention ratio and content all by mass parts, the electrode of water catalyst generating means is that on titanium alloy electrode, to apply particle diameter can also be the nickel of 10nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony=3:6:10:3:4:2:3, the composite bed of 1 micron thick of dry at 105 DEG C, preparing by sintering at 420 DEG C; Electrode base material is that titanium alloy contains Al:6.6; Sn:1.2; Cr:1.2; Mo:1.3; Zr:1.3; Fe:0.9; C:0.16; O:0.12; N:0.005; H:0.002; Si:0.14, all the other are titanium and inevitable impurity.
In the present invention ratio and content all by mass parts, the electrode of water catalyst generating means is that on titanium alloy electrode, to apply particle diameter can also be the nickel of 15nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony=3:6:11:2:4:2:4, the composite bed of 1 micron thick of dry at 110 DEG C, preparing by sintering at 430 DEG C; Electrode base material is that titanium alloy contains Al:6.7; Sn:1.3; Cr:1.3; Mo:1.3; Zr:1.3; Fe:0.14; C:0.17; O:0.18; N:0.02; H:0.002; Si:0.15, all the other are titanium and inevitable impurity.
In the present invention ratio and content all by mass parts, the electrode of water catalyst generating means is that on titanium alloy electrode, to apply particle diameter can also be the nickel of 20nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony=3:6:10:3:4:3:4, the composite bed of 1 micron thick of dry at 115 DEG C, preparing by sintering at 440 DEG C; Electrode base material is that titanium alloy contains Al:6.7; Sn:1.3; Cr:1.3; Mo:1.3; Zr:1.3; Fe:0.12; C:0.16; O:0.16; N:0.01; H:0.0019; Si:0.2, all the other are titanium and inevitable impurity.
In the present invention ratio and content all by mass parts, the electrode of water catalyst generating means is that on titanium alloy electrode, to apply particle diameter can also be the nickel of 25nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony=4:7:11:3:4:2:4, the composite bed of 2 micron thick of dry at 115 DEG C, preparing by sintering at 460 DEG C; Electrode base material is that titanium alloy contains Al:6.7; Sn:1.4; Cr:1.4; Mo:1.4; Zr:1.4; Fe:0.12; C:0.17; O:0.17; N:0.01; H:0.005; Si:0.11, all the other are titanium and inevitable impurity.
In the present invention ratio and content all by mass parts, the electrode of water catalyst generating means is that on titanium alloy electrode, to apply particle diameter can also be the nickel of 28nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony=5:9:12:5:6:3:5, the composite bed of 2 micron thick of dry at 120 DEG C, preparing by sintering at 470 DEG C; Electrode base material is that titanium alloy contains Al:6.6; Sn:1.3; Cr:1.3; Mo:1.2; Zr:1.2; Fe:0.14; C:0.17; O:0.17; N:0.02; H:0.13; Si:0.2, all the other are titanium and inevitable impurity.
In the present invention ratio and content all by mass parts, the electrode of water catalyst generating means is that on titanium alloy electrode, to apply particle diameter can also be the manganese of 30nm nanometer: the mixing coating material of platinum: cerium: gadolinium: europium: gold: antimony=5:12:14:5:8:5:7, the composite bed of 2 micron thick of dry at 120 DEG C, preparing by sintering at 680 DEG C; Electrode base material is that titanium alloy contains Al:6.7; Sn:1.3; Cr:1.3; Mo:1.3; Zr:1.3; Fe:0.15; C:0.17; O:0.21; N:0.07; H:0.02; Si:0.2, all the other are titanium and inevitable impurity.2. excusing from death ripple transducing converter
As shown in Figure 9, ultrasonic transducer of the present invention advantageously comprises a kind of polyethylene sheets for setting gradually emitting head, insulation spacer, Au electrode, polypyrrole piezoelectric patches, Au electrode, polypyrrole piezoelectric patches, Au electrode, polypyrrole piezoelectric patches and mass, piezoelectric sheet on axial, thickness is 5 μ m to 75 μ, typically be 9 μ m to 35 μ m thick, typically be 20 μ m to 25 μ m thick, typically be 25 μ m most thick.
In its best form, piezoelectric sheet is typically by Kynoar (" P VDF ") thin slice or is made up of the copolymer thin slice that comprises PVDF.This thin slice has two electrodes fixed thereon at least, is typically and on each of thin slice, has an electrode.These electrodes can be same material or different materials, are typically same material.The example of electrode material is such as metal A u, Pd, Pt, Ti, Zn, Al, Ag, Cu, Sn, Ga, In, Ni, conducting polymer, this polymer need to be filled with additive, additive is iodine, fluorine, alkali metal and salt thereof, metal carbonate and fontanel arsenic, this conducting polymer comprises: polyyne, polyyne copolymer, polypyrrole, polypropylene is fine, aromatic polymer, polyaniline, polythiophene, polycarbazole, poly-beta-diketon, poly-dipropargyl amine, poly-acenaphthene/N-vinyl heterocycle lewis acid, poly-(aromatic heterocycle 1, the sub-ethene of 2-), poly-phthalocyanine, with 1, the two polymer that replace sub-benzene chemically reactive of 9-, cluster phylloerythrin, heterocyclic ladder polymer, alternative aromatics and quinoid sequence, polyisothianaphthene and poly-(p-phenylene) thioether, do not need the polymer of doping, for example: poly-(the two o-nitriles of two ehter bonds), polyacetylene and the poly-diine with structure cell, poly-(the peri-position bitter edible plant), poly-(carbon diselenide), poly-(the benzo two thiol alkene) of transition metal, poly-(thiophene-sulfonic acid ester) and end acetylene schiff bases.
In described ultrasonic transducer, electrode is Pd, piezoelectric thickness of slab 10 μ m.
Finally should be noted that: above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit, although the present invention is had been described in detail with reference to above-described embodiment, those of ordinary skill in the field are to be understood that: still can modify or be equal to replacement the specific embodiment of the present invention, and do not depart from any amendment of spirit and scope of the invention or be equal to replacement, it all should be encompassed in the middle of claim scope of the present invention.
Claims (9)
1. a purifier, described device comprises water catalyst generating means, cleaning sink, ultrasonic transducer and water pump, the electrode that it is characterized in that described water catalyst generating means is titanium alloy electrode, the composite bed of 1～2 micron thick that at the drying at 100-120 DEG C of the nickel of coated with nano level granularity on it, platinum, cerium, gadolinium, europium, gold and antimony composition, 400～680 DEG C prepared by sintering; Described electrode base material is titanium alloy, by mass parts, containing Al:6.6～6.8; Sn:1.2～1.4; Cr:1.2～1.4; Mo:1.2～1.4; Zr:1.2～1.4; Fe:0.6～0.26; C:0.16～0.17; O:0.11～0.25; N:0.004～0.1; H:0.0015～0.025; Si:0.1～0.25; All the other are titanium and inevitable impurity.
2. according to the purifier of claim 1, it is characterized in that described nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～9:5～15:9～17:2～8:3～12:1～7:2～10 of antimony; Granularity is 5～30nm; Described titanium alloy is containing Al:6.7; Sn:1.3; Cr:1.3.
3. according to the purifier of claim 1, it is characterized in that described nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～7:5～13:9～15:2～6:3～10:1～6:2～9 of antimony; Granularity is 5～30nm; Described titanium alloy is containing Mo:1.3; Zr:1.3; Fe:0.9～0.21.
4. according to the purifier of claim 1, it is characterized in that described nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～6:5～10:9～14:2～6:3～10:1～5:2～7 of antimony; Granularity is 5～30nm; Described titanium alloy is containing C:0.17; O:0.18～0.21; N:0.008～0.06.
5. according to the purifier of claim 1, it is characterized in that described sintering temperature is 400～450 DEG C, described nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～6:5～10:9～14:2～6:3～9:1～5:2～6 of antimony; Granularity is 5～30nm; Described titanium alloy is containing H:0.0018～0.021; Si:0.2～0.22.
6. according to the purifier of claim 1, it is characterized in that described nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～6:5～11:9～14:2～6:3～9:1～5:2～7 of antimony; Granularity is 5～30nm; Described titanium alloy is containing Al:6.6～6.8; Sn:1.2～1.4; Cr:1.2～1.4; Mo:1.2～1.4; Zr:1.2～1.4.
7. according to the purifier of claim 1, it is characterized in that described nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=2～5:4～9:10～15:3～6:4～9:1～5:3～8 of antimony; Granularity is 5～30nm; Described titanium alloy is containing Fe:0.8～0.21; C:0.17; O:0.17～0.21; N:0.008～0.06; H:0.0019～0.021; Si:0.2～0.22.
8. according to the purifier of claim 1, it is characterized in that described ultrasonic transducer comprises emitting head, insulation spacer, piezoelectric sheet, quality sheet and electrode; Said emitting head, insulation spacer, piezoelectric sheet and quality sheet are successively set on same axis; Described electrode is the electrode of being prepared by metal Pd; Described piezoelectric sheet is the thick polyyne of 10 μ m; Described nickel: platinum: cerium: gadolinium: europium: gold: mass ratio=4～6:6～13:12～15:3～6:4～9:2～6:3～8 of antimony; Granularity is 5～30nm; Described titanium alloy is containing Al:6.7; Cr:1.3; Zr:1.3; O:0.17～0.21; N:0.008～0.07; Si:0.1～0.23.
9. purifier according to Claim 8, it is characterized in that number that described insulation spacer lays respectively at described emitting head and quality sheet the inner is the insulating trip of two, its inner be provided with left or the axial sections of 10～90 degree of turning right be concave character type and its left and right protuberance be positioned at respectively between described piezoelectric sheet, its bottom is greater than the first electrode slice of the radius of described insulating trip to the radius in the center of circle; The inner shafts that is positioned at described concave character type electrode slice is to the second electrode slice and the patch of piezoelectric material that set gradually patch of piezoelectric material, diameter and be greater than described patch of piezoelectric material.
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