CN104051557A - Adhesive tape and solar module and product made of same - Google Patents
Adhesive tape and solar module and product made of same Download PDFInfo
- Publication number
- CN104051557A CN104051557A CN201410250754.2A CN201410250754A CN104051557A CN 104051557 A CN104051557 A CN 104051557A CN 201410250754 A CN201410250754 A CN 201410250754A CN 104051557 A CN104051557 A CN 104051557A
- Authority
- CN
- China
- Prior art keywords
- glue
- rimless
- luminous energy
- line
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002390 adhesive tape Substances 0.000 title claims abstract description 133
- 239000003292 glue Substances 0.000 claims abstract description 85
- 239000000463 material Substances 0.000 claims abstract description 64
- 230000037452 priming Effects 0.000 claims abstract description 56
- 230000032683 aging Effects 0.000 claims abstract description 32
- 239000010410 layer Substances 0.000 claims description 158
- 239000000758 substrate Substances 0.000 claims description 70
- 239000004800 polyvinyl chloride Substances 0.000 claims description 58
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 58
- 239000004698 Polyethylene Substances 0.000 claims description 51
- 238000000576 coating method Methods 0.000 claims description 51
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 43
- 239000011248 coating agent Substances 0.000 claims description 37
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 26
- 239000005030 aluminium foil Substances 0.000 claims description 26
- 239000011241 protective layer Substances 0.000 claims description 26
- 230000001070 adhesive effect Effects 0.000 claims description 20
- 239000000853 adhesive Substances 0.000 claims description 19
- 229920001971 elastomer Polymers 0.000 claims description 15
- -1 polyethylene Polymers 0.000 claims description 15
- 239000005060 rubber Substances 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 239000004814 polyurethane Substances 0.000 claims description 14
- 239000004411 aluminium Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 238000007789 sealing Methods 0.000 claims description 10
- 230000033228 biological regulation Effects 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 238000007654 immersion Methods 0.000 claims description 5
- 229920000554 ionomer Polymers 0.000 claims description 5
- 230000005855 radiation Effects 0.000 claims description 5
- 239000010409 thin film Substances 0.000 claims description 5
- 241000628997 Flos Species 0.000 claims description 4
- 229920002367 Polyisobutene Polymers 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 238000004078 waterproofing Methods 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 229920002943 EPDM rubber Polymers 0.000 claims description 2
- 239000003522 acrylic cement Substances 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000004677 Nylon Substances 0.000 claims 2
- 229920001778 nylon Polymers 0.000 claims 2
- 230000003287 optical effect Effects 0.000 abstract description 5
- 230000003139 buffering effect Effects 0.000 abstract 1
- 239000010408 film Substances 0.000 description 131
- 239000011265 semifinished product Substances 0.000 description 64
- 239000000047 product Substances 0.000 description 30
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 27
- 238000010586 diagram Methods 0.000 description 24
- 238000010030 laminating Methods 0.000 description 24
- 238000002360 preparation method Methods 0.000 description 23
- 239000013500 performance material Substances 0.000 description 22
- 239000002344 surface layer Substances 0.000 description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 16
- 229920002799 BoPET Polymers 0.000 description 15
- 238000004026 adhesive bonding Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 7
- 229910001051 Magnalium Inorganic materials 0.000 description 5
- 239000002033 PVDF binder Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
- 239000004926 polymethyl methacrylate Substances 0.000 description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- 229920009638 Tetrafluoroethylene-Hexafluoropropylene-Vinylidenefluoride Copolymer Polymers 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000005065 mining Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002620 polyvinyl fluoride Polymers 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000013084 building-integrated photovoltaic technology Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000005622 photoelectricity Effects 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 150000003141 primary amines Chemical group 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 229920001780 ECTFE Polymers 0.000 description 1
- 229920003298 Nucrel® Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920003182 Surlyn® Polymers 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- KTSFMFGEAAANTF-UHFFFAOYSA-N [Cu].[Se].[Se].[In] Chemical compound [Cu].[Se].[Se].[In] KTSFMFGEAAANTF-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000013036 cure process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229920003031 santoprene Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920006342 thermoplastic vulcanizate Polymers 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/35—Heat-activated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/383—Natural or synthetic rubber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S80/00—Details, accessories or component parts of solar heat collectors not provided for in groups F24S10/00-F24S70/00
- F24S80/40—Casings
- F24S80/45—Casings characterised by the material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S80/00—Details, accessories or component parts of solar heat collectors not provided for in groups F24S10/00-F24S70/00
- F24S80/70—Sealing means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Adhesive Tapes (AREA)
- Mechanical Engineering (AREA)
- Electromagnetism (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
Provided is a frameless optical energy module. The frameless optical energy module comprises an optical energy converter, the edge of the optical energy converter is sealed by adhesive tape, the adhesive tape comprises a bonding layer with the bonding and buffering function and an ageing resisting protection layer, the bonding layer is used for being in contact with the edge of an article, the bonding layer comprises a base material layer, a freely-selected first glue layer and a freely-selected second glue layer, the first glue layer and the second glue layer are freely selected and are oppositely located on the two sides of the base material layer, and the first glue layer is in contact with the article. The protection layer is arranged on the bonding layer and comprises a freely-selected priming coat on the bonding layer and a film layer on the priming coat or the second glue layer or the base material layer. The invention further provides the adhesive tape and a product made of the module.
Description
The application is to be dividing an application of on February 18th, 2011, the denomination of invention Chinese patent application No.201110042671.0 that is " adhesive tape and the solar components of being made by it and goods " the applying date.
Technical field
The present invention relates to solar components and manufacture field, relate in particular to a kind of solar components edge seal protective tapes and the solar components of being made by it and goods.
Background technology
Existing solar energy lamination assembly is mainly by installing and protect with the edge frame made of aluminum profiles of silica gel or the continuous adhesive tape fixing seal of Double-side foam.Existing solar components is to be formed by sandwich construction lamination; and most with aluminum alloy frame and silica gel or the continuous adhesive tape of Double-side foam, the edge of assembly sealed and protect to guarantee under the weather of variation, unaffected and maintain normal work in the situation such as sleety weather.But in the use of solar components, existing assembly is not all to need aluminum alloy frame, as at photoelectric curtain wall, roof photoelectricity, in the application such as photoelectricity street lamp.In some applications, aluminum alloy frame has increased weight and the cost of solar components, and fitting operation more complicated.
Therefore, need to provide a kind of product that can replace frame to seal the edge of solar components, for example adhesive tape.
Summary of the invention
For addressing this problem, the present inventor has designed a kind of adhesive tape, it can replace frame to seal the edge of solar components, greatly alleviated the weight of solar components, without solidifying to have reduced, ETCD estimated time of commencing discharging, use instrument or equipment Continuous pressing device for stereo-pattern are easy to operate, and have reduced manufacturing cost.
According to a first aspect of the invention, provide a kind of Rimless luminous energy assembly, it comprises light energy converter, and the edge of described light energy converter is by rubber belt sealing, and described adhesive tape comprises a kind of for sealing the adhesive tape at article edge, and it comprises:
Play the tack coat of bonding and cushioning effect, its for described article EDGE CONTACT, wherein said tack coat comprises:
Substrate layer;
Optional, be located opposite from the first glue-line and second glue-line of substrate layer both sides, wherein the first glue-line contacts with described article; With
Ageing-resistant protective layer, it is positioned on described tack coat, and described protective layer comprises:
Optional priming coat, it is positioned on described tack coat; With
Rete, it is positioned at:
On described priming coat, if there is priming coat; Or
On described substrate layer, prerequisite is not have priming coat, the first glue-line and the second glue-line; Or
On described the second glue-line, prerequisite is have the second glue-line and there is no priming coat.
According to a second aspect of the invention, provide a kind of solar product, it has the solar components as above-mentioned first aspect.
According to a third aspect of the present invention, provide a kind of for sealing the adhesive tape at article edge, it comprises:
Play the tack coat of bonding and cushioning effect, its for described article EDGE CONTACT, wherein said tack coat comprises:
Substrate layer;
Optional, be located opposite from the first glue-line and second glue-line of substrate layer both sides, wherein the first glue-line contacts with described article; With
Ageing-resistant protective layer, it is positioned on described tack coat, and described protective layer comprises:
Optional priming coat, it is positioned on described tack coat; With
Rete, it is positioned at:
On described priming coat, if there is priming coat; Or
On described substrate layer, prerequisite is not have priming coat, the first glue-line and the second glue-line; Or
On described the second glue-line, prerequisite is have the second glue-line and there is no priming coat.
Use adhesive tape of the present invention can greatly alleviate the weight of solar components, during sealing, without solidifying, thereby reduced, ETCD estimated time of commencing discharging, can use easily instrument or equipment Continuous pressing device for stereo-pattern, and reduce manufacturing cost.As required, the protective layer material of adhesive tape of the present invention can have various functions, such as mar proof, weatherability, resistance to soiling or ornamental etc.In addition, as required, adhesive tape of the present invention also can provide good antidetonation shock-absorbing capacity.
Accompanying drawing explanation
Fig. 1 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 1;
Fig. 2 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 2;
Fig. 3 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 3;
Fig. 4 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 4;
Fig. 5 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 5;
Fig. 6 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 6;
Fig. 7 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 7;
Fig. 8 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 8;
Fig. 9 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 9;
Figure 10 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 10;
Figure 11 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 11;
Figure 12 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 12;
Figure 13 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 13;
Figure 14 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 14;
Figure 15 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 15;
Figure 16 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 16;
Figure 17 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 17;
Figure 18 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 18;
Figure 19 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 19;
Figure 20 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 20;
Figure 21 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 21;
Figure 22 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 22; With
Figure 23 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 23.
Figure 24 is the cross section structure schematic diagram according to the adhesive tape of the embodiment of the present invention 24.
Reference marker in figure represents respectively:
1: substrate layer;
2: the first glue-lines;
3: the second glue-lines;
4: rete;
5: priming coat;
6: release film;
7: top layer;
8: intermediate layer;
9: the three glue-lines
Embodiment
Unless specialized, in the present invention, following term has following definition:
Term " photo-thermal or photovoltaic module " (being referred to as " luminous energy assembly " herein) refers to and can utilize luminous energy as the panel type assembly of solar power generation or heating, include but not limited to crystal silicon solar assembly, amorphous silicon thin-film solar assembly, CIGS[CuInxGa (1-x) Se2, be thin film solar Copper Indium Gallium Selenide] etc. other thin film solar assemblies, and flat type solar heat collector.
Term " solar product " refers to the product that contains above-mentioned solar components, includes but not limited to the solar energy vehicles, solar water heater, solar street light, solar energy curtain wall etc.
Term " nonwoven fabrics " refers to the material consisting of orientation or random macromolecular fibre.
Term " acrylic glue " refers to the pressure sensitive adhesive of esters of acrylic acid.
Term " PUR " refers to as polyolefin block copolymer (SBS, SIS), ethylene-vinyl acetate copolymer (EVA) etc. is at room temperature solid-state, can become liquid at heating and melting, and after being coated on adherend, in seconds complete bonding adhesive through pressing is cooling.
Term " structure glue " refers to as epoxy resin, and polyurethane equal strength is high, can bear larger load, and ageing-resistant, endurance, corrosion-resistant, and stable performance in life expectancy is applicable to bear the bonding adhesive of powerful structural member.
Term " bubble is continuous " and " expanded material " have identical meanings in the present invention, refer to as polyethylene, and polyurethane, acrylic acid etc. have constrictive material after foaming.
Term " steeps continuous glue " and refers to usings above-mentioned " bubble is continuous " or " expanded material " as base material, for " bubble is continuous " or the one or both sides of " expanded material ", give the adhesive phase with bond properties, form the composite bonding material with compressibility and specific adhesive function.
Term " article " refer to the article that adhesive tape that utilization is invented seals, as light energy converter, solar components.
First aspect of the present invention provides a kind of Rimless luminous energy assembly, and it comprises light energy converter, and the edge of described light energy converter is by rubber belt sealing, and described adhesive tape comprises:
Play the tack coat of bonding and cushioning effect, its for described article EDGE CONTACT, wherein said tack coat comprises:
Substrate layer; With
Optional, be located opposite from the first glue-line and second glue-line of substrate layer both sides, wherein the first glue-line contacts with described article; With
Ageing-resistant protective layer, it is positioned on described tack coat, and described protective layer comprises:
Optional priming coat, it is positioned on described tack coat; With
Rete, it is positioned at:
On described priming coat, if there is priming coat; Or
On described substrate layer, prerequisite is not have priming coat, the first glue-line and the second glue-line; Or
On described the second glue-line, prerequisite is have the second glue-line and there is no priming coat.
Luminous energy assembly of the present invention can be photovoltaic or photo-thermal assembly, includes but not limited to photovoltaic panel, thin film photovoltaic panel, photo-thermal plate etc.
According to a second aspect of the invention, provide a kind of solar product, it has the solar components as above-mentioned first aspect.It includes but not limited to the goods such as the solar energy vehicles, solar water heater, solar street light or solar energy curtain wall.
According to a third aspect of the present invention, provide a kind of for sealing the adhesive tape at article edge, it comprises:
Play the tack coat of bonding and cushioning effect, its for described article EDGE CONTACT, wherein said tack coat comprises:
Substrate layer;
Optional, be located opposite from the first glue-line and second glue-line of substrate layer both sides, wherein the first glue-line contacts with described article; With
Ageing-resistant protective layer, it is positioned on described tack coat, and described protective layer comprises:
Optional priming coat, it is positioned on described tack coat; With
Rete, it is positioned at:
On described priming coat, if there is priming coat; Or
On described substrate layer, prerequisite is not have priming coat, the first glue-line and the second glue-line; Or
On described the second glue-line, prerequisite is have the second glue-line and there is no priming coat.
Tack coat is preferably made by the tack coat adhesive with good bonding performance and sealing property.
According to some preferred embodiment, for adhesive tape of the present invention, also comprise the waterproof intermediate layer between described protective layer and tack coat.Between waterproof intermediate layer and protective layer, can use adhesive.Can adopt above-named those adhesives.
According to some preferred embodiment, for tack coat described in adhesive tape of the present invention, comprise:
Substrate layer;
The first glue-line and the second glue-line that are located opposite from substrate layer both sides, wherein the first glue-line contacts with described article;
Waterproof intermediate layer, it is between described the second glue-line and described protective layer;
Wherein said protective layer comprises:
Priming coat, it is positioned on described tack coat; With
Rete, it is positioned on described priming coat.
The protective layer of the adhesive tape in luminous energy assembly of the present invention has ageing-resistant performance, meets outdoor aging test condition and accelerated ageing test condition, preferably meets following condition:
According to the outdoor exposure condition of IEC60721-2-1 regulation, total radiation is 60kWh/m
2;
According to IEC61215, stipulate :-40 ℃ of-+85 ℃ of high low-temperature circulatings, 200 times;-40 ℃ of moist freeze cycle of-+85 ℃/85%RH, 10 times; Hot and humid aging 1000 hours of+85 ℃/85%RH etc.
Through above-mentioned typical aging condition, protective layer is without breakage, and cracking such as tears at the open defect, provides thus solar components outward appearance complete stable, and keeps assembly original function characteristic.
Ageing-resistant and protection layer adopts the ageing-resistant and good film of pliability or metal foil material to make, and preferably has good water vapor rejection and weather resistance.For example, according to some preferred embodiment, the rete in protective layer is preferably by being selected from the not PTFE of stabilisation, PVDF, and PVF, ETFE, ECTFE, THV, and the material of silicon rubber is made.Other rete with ultraviolet and degraded protection package comprises: PVDF/PMMA blend, block (for example Kuraray Kurarity polymer) or random PMMA/ acrylate copolymer, PMMA, shock resistance PMMA, polyethylene-methacrylic acid ionomer (for example Dupont Surlyn), polyethylene-acrylic acid ionomer (for example Dupont Nucrel), crosslinked polyisobutene, aliphatic polyurethane, hydrogenated styrene based block copolymer, Thermoplastic Vulcanizate (as ExxonMobil Santoprene), cross-linked ethylene propylene terpolymers, plasticising or unplasticizied polyvinyl chloride, thermoplastic polyurethane rubber, polyimides, polyethylene, polypropylene, ionomer, or the material of its mixture is made.According to other embodiment, rete also can be made as aluminium foil, Copper Foil by metal forming.Wherein more preferably polyvinyl chloride, polypropylene rete, they can provide required function by the use of formulation additives, as uvioresistant performance, fire resistance, shock resistance.Rete also can contain top layer, and it can provide required function, such as mar proof, weatherability, water proofing property, resistance to soiling or ornamental etc.Top layer is a kind of surperficial cure process layer, can be by obtaining to membrane surface polymer-coated.The example of coating can comprise that spraying, roller coat, intaglio plate coating and contact intaglio plate are oppositely coated with (direct reverse gravure coating), are optionally equipped with ultraviolet photo-curing technology for example UV or electron beam.According to some further preferred embodiment, described top layer is selected from mar proof coating, weather resistant coatings, water proofing property coating, resistance to soiling coating or decorative coating.The resistance to ag(e)ing that forms the material of described rete typically can be passed through IEC61215 burn-in test or externally use over 25 years.Described protective layer preferably has according to the outdoor exposure condition of IEC60721-2-1 regulation, and total radiation is 60kWh/m
2, and meet the weather resistance that IEC61215 stipulates :-40 ℃ of-+85 ℃ of high low-temperature circulatings, 200 times;-40 ℃ of moist freeze cycle of-+85 ℃/85%RH, 10 times; Hot and humid aging 1000 hours of+85 ℃/85%RH etc.
According to some preferred embodiment, described in adhesive tape of the present invention, priming coat is made by the material that is selected from silane coupler, polyolefin, polyvinyl, polyamide, isocyanates, halogenated rubber or metallic film.According to some preferred embodiment, priming coat described in adhesive tape of the present invention also contains the 3rd glue-line.According to some further preferred embodiment, described the 3rd glue-line is made by the adhesive that is selected from acrylic glue, PUR, structure glue, silica-based glue or its combination.The 3rd glue-line is for bonding rete and substrate layer or intermediate layer.The effect of priming coat can be for strengthening the interlayer adhesion of rete and the 3rd glue-line.More preferably, priming coat is generally formed by the mixed solution coating of the high molecular polymer with functional group's (as carboxyl, amide groups, hydroxyl, tertiary amine groups, ester group primary amine groups, primary amine groups).According to some preferred embodiment, priming coat applied thickness is less than 0.05 millimeter.Described priming coat can by silane coupling agent for example POLYMENT NK-350 (purchased from Nippon Shokubai Kogyo Co., the resin of the aminomethyl modification of Ltd.) coating form, described rete can be by black PVC, for example NAN YA0.10mm black PVC is made.
Tack coat in adhesive tape of the present invention can provide good adhesive property and sealing property.Tack coat can, higher than 1N/cm, can keep the functional characteristic of solar components effectively from the 90 degree peel strengths on solar components surface (glass, THV back veneer material, PVDF back veneer material, PVF back veneer material etc.).One or two surface of solar components can be coated with suitable silane coupling agent to promote bonding.Typically, the wet leakage tests that tack coat can be stipulated by IEC61215-10-15.According to some preferred embodiment, described in adhesive tape of the present invention, the first glue-line is made by the adhesive that is selected from acrylic glue, PUR, structure glue or its combination.According to some preferred embodiment, the second glue-line described in adhesive tape of the present invention is made by the adhesive that is selected from acrylic glue, silica-based glue, rubber based adhesives, PUR, structure glue or its combination.According to these schemes, tack coat performance should meet following outdoor aging test condition and accelerated ageing test condition simultaneously, concrete as: according to the outdoor exposure condition of IEC60721-2-1 regulation, total radiation is 60kWh/m
2.According to IEC61215, stipulate :-40 ℃ of-+85 ℃ of high low-temperature circulatings, 200 times;-40 ℃ of moist freeze cycle of-+85 ℃/85%RH, 10 times; Hot and humid aging 1000 hours of+85 ℃/85%RH etc.
Through above-mentioned typical aging condition, tack coat is from solar components surface (glass, THV back veneer material, PVDF back veneer material, PVF back veneer material etc.) 90 degree peel strengths can be greater than 1N/cm, provide thus solar components complete stable sealing effectiveness, the functional characteristic after simultaneously keeping solar components aging.The typical wet leakage tests of for example stipulating by IEC61215-10-15.
According to some preferred version, the second glue-line of tack coat is made by the adhesive that is selected from acrylic glue, rubber based adhesives or its combination.The second glue-line and by priming coat, formed layer between peeling force be greater than 1N/cm.
The adhesion strength of described tack coat and article to be sealed, in 90 degree peel strengths, is preferably greater than 1N/cm.It is continuous that the substrate layer of described tack coat is preferably acrylic bubble, and glue-line is preferably made by acrylic glue.For example, can adopt 3M4941VHB as tack coat.
According to some preferred embodiment, described in adhesive tape of the present invention, substrate layer is comprised of the material that is selected from expanded material, acrylic resin, polyurethane, polyethylene rubber, non-woven material or its mixture.For example, can adopt there is certain cushioning effect material as thering are viscoplasticity and constrictive glue, bubble silk floss, rubber, nonwoven fabrics etc. as substrate layer.Also can adopt the material with high-adhesion energy as substrate layer, for example, can adopt 3M2081 acrylic acid to steep continuous adhesive tape.
In order to strengthen the water resistance of adhesive tape, in product, also can add intermediate layer.For example add moisture permeability at 60g/m
2material layer below/24hr (37.8 ℃) is if PET (PETG) layer, polyisobutene layer and the polypropylene layer etc. of metal level, butyl rubber layer, surface modification are as aqueous vapor barrier layer.According to some preferred embodiment, described intermediate layer is made by the material that is selected from metal, rubber and polyurethane.According to some preferred embodiment, described metal is selected from aluminium, copper or its combination.According to some preferred embodiment, described rubber is selected from ethylene propylene diene rubber, fluoroelastomer, polyisobutene or its mixture.According to preferred embodiment, the wet leakage tests of immersion that waterproof intermediate layer can be stipulated by IEC61215 :-40 ℃ of moist freeze cycle of-+85 ℃/85%RH, 10 times; Hot and humid aging 1000 hours of+85 ℃/85%RH.Described waterproof intermediate layer can by metal forming for example aluminium foil make, its thickness is preferably 10-100 μ m.For example by Alcoa Inc's 8011 aluminium foils, made, its thickness is 47 μ m.
The thickness of each material layer is not particularly limited, and can adjust to realize according to the different demands of specific product the function of above-mentioned material layer simultaneously.For example, thickness is generally 0.01～100mm.
According to some particularly preferred embodiment, 90 degree peel strengths of the adhesive tape adopting in assembly of the present invention and sealed article are greater than 1N/cm, have following weather resistance: according to the outdoor exposure condition of IEC60721-2-1 regulation, total radiation is 60kWh/m
2and stipulate according to IEC61215 :-40 ℃ of-+85 ℃ of high low-temperature circulatings, 200 times;-40 ℃ of moist freeze cycle of-+85 ℃/85%RH, 10 times; Hot and humid aging 1000 hours of+85 ℃/85%RH.The wet leakage tests of immersion that its water resistance of aging front and back is all stipulated by IEC61215.Wherein, described substrate layer is preferably made by acrylic bubble silk floss, thickness is 0.2～2.0mm, and described the first and second glue-lines are comprised of acrylic adhesive, and thickness is 10～100 μ m, described waterproof intermediate layer is made by Alcoa Inc's 8011 aluminium foils, thickness is 47 μ m, and described priming coat is comprised of " POLYMENT3M NK-350 " silane coupling agent, and thickness is 0.005～0.05mm, described rete is made by Nan Ya black PVC, and thickness is 0.10～2mm.
Adhesive tape of the present invention can be applied to BIPV (BIPV) and roof photovoltaic, and optical road lamp etc. do not need in photovoltaic module that aluminium frame fixes.For example, adhesive tape of the present invention can be affixed on four edges of solar components, forms the structure of a bound edge.Tack coat steeps continuous adhesive and has certain shock-absorbing capacity, and protective layer material has good abrasion resistance properties, and can effectively stop water vapor permeable.The application of adhesive tape of the present invention has alleviated the weight of solar components greatly, thereby ETCD estimated time of commencing discharging without solidifying to have shortened, easy to operate during Continuous pressing device for stereo-pattern, and has reduced manufacturing cost.
Example 1
The structure of the adhesive tape of example 1 as shown in Figure 1.Rete 4 and release film 6 lay respectively at the both sides of substrate layer 1.The material of each layer is respectively:
Rete 4:Huasu0.06mm black PVC (polyvinyl chloride) film
Substrate layer 1: Minnesota Mining and Manufacturing Company's 2081 acrylic acid steep continuous glue
Release film 6: the 0.075mm PE of Mitsubishi KCC release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue and is coated on the 0.075mm PE of Mitsubishi chemical Co., Ltd (polyethylene) release film and formed substrate layer by solvent-free coating process.Complete after coating, substrate layer and the laminating of Huasu0.06mm black PVC film inner surface, obtain finished products of adhesive tapes.
Example 2
The structure of the adhesive tape of example 2 as shown in Figure 2.The two sides of substrate layer 1 arranges respectively priming coat 5 and release film 6, is provided with rete 4 above priming coat 5.The material of each layer is respectively:
Rete 4:Huasu0.10mm black PVC film
Priming coat 5:POLYMENT NK-350
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: the 0.075mm PP of Mitsubishi chemical Co., Ltd (polypropylene) release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue and is coated on the 0.075mm PE of Mitsubishi chemical Co., Ltd release film and formed substrate layer by solvent-free coating process.On the tack coat of Huasu0.10mm black PVC film, carry out the coating of priming coat.Complete after coating, substrate layer and the priming coat laminating being positioned on Huasu0.10mm black PVC film, complete product.
Example 3
The structure of the adhesive tape of example 3 as shown in Figure 3.The two sides of substrate layer 1 arranges respectively rete 4 and release film 6, is provided with top layer 7 above rete 4.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:Huasu0.10mm black PVC film
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue and is coated on tonneau 0.150mm PE release film and formed substrate layer by solvent-free coating process.Huasu0.10mm black PVC film outer surface layer carry out the coating of basal surface hardened layer MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 ".Complete after coating, the inner surface laminating of substrate layer and Huasu0.10mm black PVC film, completes product.
Example 4
The structure of the adhesive tape of example 4 as shown in Figure 4.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:Huasu0.10mm black PVC film
Priming coat 5:3M " ADHESION PROMOTER N-200 " silane coupling agent
Substrate layer 1: the 3M of Minnesota Mining and Manufacturing Company " SOLAR ACRYLIC FOAM TAPE FB80 " acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The 3M FB80 acrylic acid of Minnesota Mining and Manufacturing Company steeps continuous glue and coats tonneau 0.150mm PE release film formation substrate layer by solvent-free coating process, is coated with the cured layer of MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " at the outer surface layer of Huasu0.10mm black PVC film.Then at the inner surface coating 3M " ADHESION PROMOTER N-200 " of Huasu0.10mm black PVC film silane coupling agent.Complete after coating, substrate layer and the laminating of Huasu0.10mm black PVC film, complete product.
Example 5
The structure of the adhesive tape of example 5 as shown in Figure 5.The material of each layer is respectively:
Rete 4:Renolit0.10mm black PVC film
The 3rd glue-line 9:3M CSA3050 acrylate glue
Intermediate layer 8: magnalium 8011 aluminium foils
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue to be coated on tonneau 0.150mm PE release film and is formed substrate layer by solvent-free coating process, another side U.S. aluminium 8011 aluminium foils of fitting, after completing as semi-finished product I; At the interior surface layers coating 3M of Huasu0.10mm black PVC film CSA3050 glue, as semi-finished product II; Laminating by semi-finished product I and semi-finished product II, completes product.
Example 6
The structure of the adhesive tape of example 6 as shown in Figure 6.The material of each layer is respectively:
Rete 4:Renolit0.10mm black PVC film
The 3rd glue-line 9:3M CSA3050 acrylate glue
The beautiful 0.05mm transparent PET of intermediate layer 8: Yi Huadong film
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue to be coated on tonneau 0.150mm PE release film and is formed substrate layer by solvent-free coating process, the beautiful 0.05mm transparent PET film in another side laminating instrumentization east, after completing as semi-finished product I; At the interior surface layers coating 3M of Huasu0.10mm black PVC film CSA3050 glue, as semi-finished product II; By semi-finished product I and semi-finished product II laminating, complete product.
Example 7
The structure of the adhesive tape of example 7 as shown in Figure 7.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:NAN YA0.10mm black PVC film
The 3rd glue-line 9:3M CSA3050 acrylate glue
Intermediate layer 8: magnalium 8011 aluminium foils
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue and coats tonneau 0.150mm PE release film by solvent-free coating process, another side laminating magnalium 8011 aluminium foils, after completing as semi-finished product I; At the outer surface coating MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " of NAN YA0.10mm black PVC film hardening coat, interior surface layers coating 3M CSA3050 glue, as semi-finished product II; By semi-finished product I and semi-finished product II laminating, complete product.
Example 8
The structure of the adhesive tape of example 8 as shown in Figure 8.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:NAN YA0.10mm black PVC film
The 3rd glue-line 9:3M CSA3050 acrylate glue
The beautiful 0.05mm transparent PET of intermediate layer 8: Yi Huadong film
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue to be coated on tonneau 0.150mm PE release film and is formed substrate layer by solvent-free coating process, the beautiful 0.05mm transparent PET film in another side laminating instrumentization east, after completing as semi-finished product I; At the outer surface coating MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " of NAN YA0.10mm black PVC film hardening coat, interior surface layers coating 3M CSA3050 glue, as semi-finished product II; By semi-finished product I and semi-finished product II laminating, complete product.
Example 9
The structure of the adhesive tape of example 9 as shown in Figure 9.The material of each layer is respectively:
Rete 4:NAN YA0.10mm black PVC film
Priming coat 5:3M " ADHENSION PROMOTER N-200 " silane coupling agent
The 3rd glue-line 9:3M CSA3050 acrylate glue
Intermediate layer 8: U.S. aluminium 8011 aluminium foils
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue to be coated on tonneau 0.150mm PE release film and is formed substrate layer by solvent-free coating process, another side U.S. aluminium 8011 aluminium foils of fitting, after completing as semi-finished product I; Interior surface layers at NAN YA0.10mm black PVC film is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, then is coated with 3M CSA3050 glue, as semi-finished product II; By semi-finished product I and with semi-finished product II, fit, complete product.
Example 10
The structure of the adhesive tape of example 10 as shown in figure 10.The material of each layer is respectively:
Rete 4:NAN YA0.10mm black PVC film
Priming coat 5:3M " ADHENSION PROMOTER N-200 " silane coupling agent
The 3rd glue-line 9:3M CSA3050 acrylate glue
The beautiful 0.05mm transparent PET of intermediate layer 8: Yi Huadong film
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue to be coated tonneau 0.150mm PE release film by solvent-free coating process and forms substrate layer, the beautiful 0.05mm transparent PET film in another side laminating instrumentization east, after completing as semi-finished product I; Interior surface layers coating at NAN YA0.10mm black PVC film is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, then is coated with 3M CSA3050 glue, as semi-finished product II; By semi-finished product I and semi-finished product II laminating, complete product.
Example 11
The structure of the adhesive tape of example 11 as shown in figure 11.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:NAN YA0.10mm black PVC film
Priming coat 5:3M " ADHENSION PROMOTER N-200 " silane coupling agent
The 3rd glue-line 9:3M CSA3050 acrylate glue
Intermediate layer 8: magnalium 8011 aluminium foils
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue to be coated on tonneau 0.150mm PE release film and is formed substrate layer by solvent-free coating process, and another side is fitted with magnalium 8011 aluminium foils, after completing as semi-finished product I; At the outer surface coating MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " of NAN YA0.10mm black PVC film hardening coat, interior surface layers is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, be coated with again 3M CSA3050 glue, as semi-finished product II; By semi-finished product I and semi-finished product II laminating, complete product.
Example 12
The structure of the adhesive tape of example 12 as shown in figure 12.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:NAN YA0.10mm black PVC film
Priming coat 5:3M " ADHENSION PROMOTER N-200 " silane coupling agent
The 3rd glue-line 9:3M CSA3050 acrylate glue
The beautiful 0.05mm transparent PET of intermediate layer 8: Yi Huadong film
Substrate layer 1:3M2081 acrylic acid steeps continuous glue
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
3M2081 acrylic acid steeps continuous glue to be coated on tonneau 0.150mm PE release film and is formed substrate layer by solvent-free coating process, the beautiful 0.05mm transparent PET film in another side laminating instrumentization east, after completing as semi-finished product I; At the outer surface coating MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " of NAN YA0.10mm black PVC film hardening coat, interior surface layers is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, be coated with again 3M CSA3050 glue, as semi-finished product II; By semi-finished product I and semi-finished product II laminating, complete product.
Example 13
The structure of the adhesive tape of example 13 as shown in figure 13.The material of each layer is respectively:
Rete 4:NAN YA0.10mm black PVC film
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, and the second glue-line and the laminating of NAN YA0.10mm black PVC film, complete product.
Example 14
The structure of the adhesive tape of example 14 as shown in figure 14.The material of each layer is respectively:
Rete 4:NAN YA0.10mm black PVC film
Priming coat 5:3M " ADHENSION PROMOTER N-200 " silane coupling agent
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, interior surface layers at NAN YA0.10mm black PVC film is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, then fit with the second glue-line of 4941VHB, complete product.
Example 15
The structure of the adhesive tape of example 15 as shown in figure 15.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:Renolit0.10mm black PVC film
Priming coat 5:3M " ADHENSION PROMOTER N-200 " silane coupling agent
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, at the outer surface coating MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " of NAN YA0.10mm black PVC film hardening coat, interior surface layers is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, then fit with the second glue-line of 4941VHB, complete product.
Example 16
The structure of the adhesive tape of example 16 as shown in figure 16.The material of each layer is respectively:
Rete 4:Renolit0.10mm black PVC film
The 3rd glue-line 9:3M CSA3060 acrylate glue
Intermediate layer 8: U.S. aluminium 8011 aluminium foils
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, and the second glue-line fits to a surface of U.S. aluminium 8011 aluminium foils, after completing as semi-finished product I; At the interior surface layers coating 3M of NAN YA0.10mm black PVC film CSA3060 glue, as semi-finished product II; Semi-finished product I is positioned to another surface of aluminium foil and that surface laminating of semi-finished product II gluing, completes product.
Example 17
The structure of the adhesive tape of example 17 as shown in figure 17.The material of each layer is respectively:
Rete 4:Renolit0.10mm black PVC film
The 3rd glue-line 9:3M CSA3060 acrylate glue
Intermediate layer 8: large magnificent 0.05mm transparent PET film
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, and the second glue-line fits to a surface of large magnificent 0.05mm transparent PET film, after completing as semi-finished product I; At the interior surface layers coating 3M of NAN YA0.10mm black PVC film CSA3060 glue, as semi-finished product II; Fitting with that surface of semi-finished product II gluing in another surface that semi-finished product I is positioned on PET film, completes product.
Example 18
The structure of the adhesive tape of example 18 as shown in figure 18.The material of each layer is respectively:
Rete 4:Renolit0.10mm black PVC film
Priming coat 5:3M " ADHENSION PROMOTER N-200 " silane coupling agent
The 3rd glue-line 9:3M CSA3060 acrylate glue
Intermediate layer 8: Alcoa Inc's 8011 aluminium foils
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, and the second glue-line fits to a surface of U.S. aluminium 8011 aluminium foils, after completing as semi-finished product I; Interior surface layers at NAN YA0.10mm black PVC film is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, then is coated with 3M CSA3060 glue, as semi-finished product II; Semi-finished product I is positioned to another surface of aluminium foil and that surface laminating of semi-finished product II gluing, completes product.
Example 19
The structure of the adhesive tape of example 19 as shown in figure 19.The material of each layer is respectively:
Rete 4:Renolit0.10mm black PVC film
Priming coat 5:POLYMENT NK-350 silane coupling agent
The 3rd glue-line 9:3M CSA3060 acrylate glue
Intermediate layer 8: large magnificent 0.05mm transparent PET film
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, and the second glue-line fits to a surface of large magnificent 0.05mm transparent PET film, after completing as semi-finished product I; Interior surface layers at NAN YA0.10mm black PVC film is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, then is coated with 3M CSA3060 glue, as semi-finished product II; Semi-finished product I is positioned to another surface of PET film and that surface laminating of semi-finished product II gluing, completes product.
Example 20
The structure of the adhesive tape of example 20 as shown in figure 20.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:Renolit0.10mm black PVC film
The 3rd glue-line 9:3M CSA3060 acrylate glue
Intermediate layer 8: U.S. aluminium 8011 aluminium foils
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, and the second glue-line fits to a surface of U.S. aluminium 8011 aluminium foils, after completing as semi-finished product I; At the outer surface coating MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " of NAN YA0.10mm black PVC film hardening coat, interior surface layers coating 3M CSA3060 glue, as semi-finished product II; Semi-finished product I is positioned to another surface of aluminium foil and that surface laminating of semi-finished product II gluing, completes product.
Example 21
The structure of the adhesive tape of example 21 as shown in figure 21.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:NAN YA0.10mm black PVC film
The 3rd glue-line 9:3M CSA3060 acrylate glue
Intermediate layer 8: large magnificent 0.05mm transparent PET film
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, and the second glue-line fits to a surface of large magnificent 0.05mm transparent PET film, after completing as semi-finished product I; At the outer surface coating MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " of NAN YA0.10mm black PVC film hardening coat, interior surface layers coating 3M CSA3060 glue, as semi-finished product II; Semi-finished product I is positioned to another surface of PET film and that surface laminating of semi-finished product II gluing, completes product.
Example 22
The structure of the adhesive tape of example 22 as shown in figure 22.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:Renolit0.10mm black PVC film
Priming coat 5:POLYMENT NK-350 silane coupling agent
The 3rd glue-line 9:3M CSA3060 acrylate glue
Intermediate layer 8: U.S. aluminium 8011 aluminium foils
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, and the second glue-line fits to a surface of U.S. aluminium 8011 aluminium foils, after completing as semi-finished product I; At the outer surface coating MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " of NAN YA0.10mm black PVC film hardening coat, interior surface layers is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, then is coated with 3M CSA3060 glue as semi-finished product II; Semi-finished product I is positioned to another surface of aluminium foil and that surface laminating of semi-finished product II gluing, completes product.
Example 23
The structure of the adhesive tape of example 23 as shown in figure 23.The material of each layer is respectively:
Top layer 7:MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 "
Rete 4:Renolit0.10mm black PVC film
Priming coat 5:POLYMENT NK-350 silane coupling agent
The 3rd glue-line 9:3M CSA3060 acrylate glue
Intermediate layer 8: the 0.05mm PET of Mitsubishi film
First glue-line 2+ substrate layer 1+ the second glue-line 3:3M4941VHB adhesive tape
Release film 6: tonneau 0.150mm PE release film
The preparation process of this adhesive tape is as follows:
The first glue-line of 3M4941VHB adhesive tape is fitted to tonneau 0.150mm PE release film, and the second glue-line fits to a surface of large magnificent 0.05mm transparent PET film, after completing as semi-finished product I; At the outer surface coating MOMENTIVE PERFORMANCE MATERIALS " UVHC8558 " of NAN YA0.10mm black PVC film hardening coat, interior surface layers is first coated with 3M " ADHENSION PROMOTER N-200 " silane coupling agent, then is coated with 3M CSA3060 glue as semi-finished product II; Semi-finished product I is positioned to another surface of PET film and that surface laminating of semi-finished product II gluing, completes product.
Example 24
The structure of the adhesive tape of example 24 as shown in figure 24.In the present embodiment, adopted and be purchased 32mils (0.8mm) " 3M SEMITRANSPARENT MATERIAL RIVET TACKY TAPE SEAL4422B " (3M/ Sumitomo, Japan).
This adhesive tape forms by three layers:
Rete 4:6mils (0.15mm) is thick, ionomer/acrylic;
Substrate layer 1:24mils (0.6mm) is thick, the multipurpose acrylic that stickiness is strong;
Release film 6:2mils (0.05mm) thick polyester film.
By " 3M SILANE GLASS TREATMENT AP115 " (the 3M company of Minn. St.Paul) in the glass surface primary coat of luminous energy assembly, and the polyester back sheet surface of luminous energy assembly is coated with " 3M TAPE PRIMER94 " (3M company of Minn. St.Paul).
Test:
Test to protective layer and waterproof intermediate layer:
The following weather resistance that in embodiment 1-24, the material of protective layer has passed through IEC61215 regulation is respectively tested: at-40 ℃ of-+85 ℃ of high low temperature, be circulated to few 200 times; The moist freeze cycle of-40 ℃ of-+85 ℃/85%RH at least 10 times; Hot and humid aging at least 1000 hours of+85 ℃/85%RH.
In embodiment 1-24, the material of waterproof intermediate layer has passed through the wet leakage tests of following immersion of IEC61215 regulation respectively :-40 ℃ of moist freeze cycle of-+85 ℃/85%RH, 10 times; Under hot and humid aging 1000 hours conditions of+85 ℃/85%RH.
Test to adhesive tape:
The test of ageing-resistant performance is carried out according to the regulation of IEC61215.In embodiment above, according to IEC61215, carry out following every burn-in test each 1000 hours: 85% 85 ℃ of humidity are aging; UV irradiation 15Kwh/m
2aging; Thermal cycle 200 times; Moist freeze cycle 10 times.Result shows: aging front and back, and tape surface does not have season cracking or breakage, and 90 degree are peeled off adhesive strength and are not less than 1N/mm.
The test result of each embodiment adhesive tape is summarized in following table:
Listed test data in table, the sample of each embodiment has all passed through every test smoothly.
Claims (27)
1. a Rimless luminous energy assembly, it comprises light energy converter, and the edge of described light energy converter is by rubber belt sealing, and described adhesive tape comprises:
(1) play bonding and the tack coat of cushioning effect, its for article EDGE CONTACT, wherein said tack coat comprises:
Substrate layer; With
The first glue-line and the second glue-line that are located opposite from substrate layer both sides, wherein the first glue-line contacts with described article; With
(2) ageing-resistant protective layer, it is positioned on described tack coat, and described protective layer comprises rete, and it is positioned on described the second glue-line.
2. according to the Rimless luminous energy assembly of claim 1, wherein said protective layer also comprises priming coat, and it is positioned on described tack coat.
3. according to the Rimless luminous energy assembly of claim 2, wherein said rete is positioned on described priming coat.
4. according to the Rimless luminous energy assembly of claim 2, also comprise waterproof intermediate layer, it is between described the second glue-line and described protective layer.
5. according to the Rimless luminous energy assembly of claim 1, wherein said substrate layer is comprised of the material that is selected from expanded material, acrylic resin, polyurethane, polyethylene rubber, non-woven material or its mixture.
6. according to the Rimless luminous energy assembly of claim 1, wherein said the first glue-line is made by the adhesive that is selected from acrylic glue, PUR, structure glue or its combination.
7. according to the Rimless luminous energy assembly of claim 1, wherein said the second glue-line is made by the adhesive that is selected from acrylic glue, silica-based glue, rubber based adhesives, PUR, structure glue or its combination.
8. according to the Rimless luminous energy assembly of claim 4, wherein said intermediate layer is made by the material that is selected from metal, rubber, polyurethane or its combination.
9. Rimless luminous energy assembly according to Claim 8, wherein said metal is selected from aluminium, copper or its combination.
10. Rimless luminous energy assembly according to Claim 8, wherein said rubber is selected from ethylene propylene diene rubber, fluorubber, polyisobutene or its mixture.
11. according to the Rimless luminous energy assembly of claim 1, and wherein said rete is made by the material that is selected from polyvinyl chloride, polypropylene, polyethylene, polytetrafluoroethylene, nylon, ionomer or its mixture.
12. according to the Rimless luminous energy assembly of claim 2, and wherein said priming coat is made by the material that is selected from polyvinyl chloride, polypropylene, polyvinyl, polytetrafluoroethylene, nylon or metal forming.
13. according to the Rimless luminous energy assembly of claim 2, and wherein said priming coat also contains the 3rd glue-line, and the 3rd glue-line is positioned at that side of the close substrate layer of priming coat.
14. according to the Rimless luminous energy assembly of claim 13, and wherein said the 3rd glue-line is made by the adhesive that is selected from acrylic glue, PUR, structure glue, silica-based glue or its combination.
15. according to the Rimless luminous energy assembly of claim 1, and wherein said rete also contains top layer.
16. according to the Rimless luminous energy assembly of claim 15, and wherein said top layer is selected from mar proof coating, weather resistant coatings, water proofing property coating, resistance to soiling coating or decorative coating.
17. according to the Rimless luminous energy assembly of claim 1, and the adhesion strength of described tack coat and article to be sealed, by 90 degree peel strengths, is greater than 1N/cm.
18. according to the Rimless luminous energy assembly of claim 17, and the glue-line of described tack coat is acrylic glue-line, and the substrate layer of described tack coat is made by acrylic bubble silk floss.
19. according to the Rimless luminous energy assembly of claim 1, and described protective layer and described adhesive tape have following weather resistance :-40 ℃ of-+85 ℃ of high low temperature in IEC61215 regulation are circulated to few 200 times; The moist freeze cycle of-40 ℃ of-+85 ℃/85%RH at least 10 times; Hot and humid aging at least 1000 hours of+85 ℃/85%RH.
20. according to the Rimless luminous energy assembly of claim 19, and described protective layer comprises priming coat and rete, and wherein said rete is made by black pvc.
21. according to the Rimless luminous energy assembly of claim 4, the wet leakage tests of immersion under the following condition that described waterproof intermediate layer can be stipulated by IEC61215 :-40 ℃ of moist freeze cycle of-+85 ℃/85%RH, 10 times; Hot and humid aging 1000 hours of+85 ℃/85%RH.
22. according to the Rimless luminous energy assembly of claim 21, and described waterproof intermediate layer is made by aluminium foil.
23. according to the Rimless luminous energy assembly of claim 4, and wherein, described substrate layer is made by acrylic bubble silk floss, and thickness is 0.2～2.0mm; Described first, second glue-line is comprised of acrylic adhesive, and thickness is 10～100 μ m; Described waterproof intermediate layer is made by aluminium foil, and thickness is 10～100 μ m; Described priming coat is comprised of silane coupling agent, and thickness is 0.005～0.05mm; Described rete is made by black pvc, and thickness is 0.10～2mm,
Described assembly is greater than 1N/cm from 90 degree peel strengths of sealed article, and possesses following weather resistance:
According to the outdoor exposure condition of IEC60721-2-1 regulation, total radiation is 60kWh/m
2;
According to IEC61215, stipulate:
-40 ℃ of-+85 ℃ of high low-temperature circulatings, 200 times;
-40 ℃ of moist freeze cycle of-+85 ℃/85%RH, 10 times;
Hot and humid aging 1000 hours of+85 ℃/85%RH,
Aging front and back wherein, the wet leakage tests of immersion that the water resistance of described assembly is all stipulated by IEC61215.
24. according to the Rimless luminous energy assembly of claim 1, and wherein said substrate layer is made by steeping continuous glue.
25. according to the Rimless luminous energy assembly of claim 1, and it is the assembly that is selected from photovoltaic panel, thin film photovoltaic panel, photo-thermal plate.
26. 1 kinds of solar products, it has the luminous energy assembly as described in any one in claim 1-25.
27. according to the goods of claim 26, and it is the goods that are selected from the solar energy vehicles, solar water heater, solar street light or solar energy curtain wall.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410250754.2A CN104051557B (en) | 2011-02-18 | 2011-02-18 | Adhesive tape and the solar components and product being made from it |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410250754.2A CN104051557B (en) | 2011-02-18 | 2011-02-18 | Adhesive tape and the solar components and product being made from it |
| CN201110042671.0A CN102646740B (en) | 2011-02-18 | 2011-02-18 | Adhesive tape, solar assembly manufactured by adhesive tape and product |
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| CN201110042671.0A Division CN102646740B (en) | 2011-02-18 | 2011-02-18 | Adhesive tape, solar assembly manufactured by adhesive tape and product |
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| CN105153955A (en) * | 2015-09-10 | 2015-12-16 | 上海晶华胶粘新材料股份有限公司 | Photovoltaic module bonding adhesive product and preparation technique thereof |
| CN107325745A (en) * | 2017-08-08 | 2017-11-07 | 常州斯威克新材料科技有限公司 | A kind of high-performance compound inslation isolating bar and preparation method thereof |
| TWI607870B (en) * | 2015-10-23 | 2017-12-11 | 鼎基先進材料股份有限公司 | A separable carrier film device and manufacturing method |
| CN107725780A (en) * | 2017-11-09 | 2018-02-23 | 昆明纳太科技有限公司 | Pressure difference sealing structure and pressure difference encapsulating method |
| CN108676467A (en) * | 2018-05-31 | 2018-10-19 | 成都佳驰电子科技有限公司 | A kind of suction wave composition and flexible patch absorbing material |
| CN109504307A (en) * | 2017-09-13 | 2019-03-22 | 苏州赛伍应用技术股份有限公司 | It is a kind of to seal block water adhesive tape and its application |
| CN110481108A (en) * | 2019-07-01 | 2019-11-22 | 嘉兴紫昇变压器有限公司 | A kind of anti-puncture silicone band |
| CN111073594A (en) * | 2019-12-30 | 2020-04-28 | 苏州赛伍应用技术股份有限公司 | Hot-melt anti-corrosion adhesive, hot-melt anti-corrosion adhesive tape and preparation method thereof |
| CN111154417A (en) * | 2020-01-19 | 2020-05-15 | 惠州Tcl移动通信有限公司 | Protective film assembly |
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| CN111073594B (en) * | 2019-12-30 | 2021-07-30 | 苏州赛伍应用技术股份有限公司 | Hot-melt anti-corrosion adhesive, hot-melt anti-corrosion adhesive tape and preparation method thereof |
| CN111073594A (en) * | 2019-12-30 | 2020-04-28 | 苏州赛伍应用技术股份有限公司 | Hot-melt anti-corrosion adhesive, hot-melt anti-corrosion adhesive tape and preparation method thereof |
| CN111154417B (en) * | 2020-01-19 | 2021-09-03 | 惠州Tcl移动通信有限公司 | Protective film assembly |
| CN111154417A (en) * | 2020-01-19 | 2020-05-15 | 惠州Tcl移动通信有限公司 | Protective film assembly |
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| CN104051557B (en) | 2018-05-11 |
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