CN104045895B - A kind of protection against rodents PE expects - Google Patents
A kind of protection against rodents PE expects Download PDFInfo
- Publication number
- CN104045895B CN104045895B CN201410247123.5A CN201410247123A CN104045895B CN 104045895 B CN104045895 B CN 104045895B CN 201410247123 A CN201410247123 A CN 201410247123A CN 104045895 B CN104045895 B CN 104045895B
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- China
- Prior art keywords
- protection against
- against rodents
- expects
- mouse
- pelargonic amide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a kind of protection against rodents PE and expects and its preparation method, and its component includes PE base mateiral and drives mouse material, it is characterised in that, driving n-Vanillyl pelargonic amide content in mouse material is that protection against rodents PE expects the 0.31%��0.89% of gross weight. The protection against rodents PE of the present invention expects to control effectively driving the minimum amount scope of mouse by n-Vanillyl pelargonic amide content, and controls rational production cost, it is possible to being widely used in the production of all kinds of electric wire, a large amount of penetration and promotion mouse bite preventing electric wire becomes possibility.
Description
Technical field
The present invention relates to a kind of mouse bite preventing PE plastic material and its preparation method, more specifically, about a kind of electric wire, cable mouse bite preventing PE plastic material.
Background technology
According to incompletely statistics, the fire of all kinds of not clear reason have 25% be owing to mouse cable plastics sheath of breaking by the teeth causes, at home and abroad just being paid attention to by the non-product of the protection against rodents of electric wire, cable the sixties, particularly capsaicine (alkali) is added in all types of plastic as the research of mouse expelling agent also certain history. But, traditional purification capsaicine (alkali) (chemical name: vanillylnonanamides) per kilogram reaches 20,000 yuans, it is used as mouse expelling agent to add, makes that the cost of plastics is too high can not be promoted, therefore just stop in the research stage. The now price per kilogram only less than 1600 yuans of synthetic capsaicin (alkali) (chemical name: n-Vanillyl pelargonic amide) commercially, the production making capsaicine (alkali) be used for plastics as mouse expelling agent becomes possibility. Having before much about by the case of capsaicine (alkali) as mouse expelling agent, but substantially all do not mentioning natural biological and purify or chemosynthesis capsaicine (alkali), the purity of capsaicine (alkali) be not provided. In mouse expelling agent, the content of n-Vanillyl pelargonic amide will cause the content of n-Vanillyl pelargonic amide in PE material, and the content of n-Vanillyl pelargonic amide in PE expects is too low will not reach protection against rodents effect; N-Vanillyl pelargonic amide too high levels will significantly improve production cost, cause unnecessary waste.
Through the retrieval of prior art is found, it is vanillylnonanamides disclosed in China's patent 99113759.0 and 03136904.9, purity is not provided.
China's number of patent application 200710045549.2 discloses ant and mouse proofing agent and comprises n-Vanillyl pelargonic amide, but its content unexposed.
China number of patent application 20090051833.X discloses capsaicine, but does not mention natural biological and purify or chemosynthesis capsaicine, does not indicate the purity of capsaicine, does not mention the content of n-Vanillyl pelargonic amide.
Summary of the invention
The main purpose of the present invention is to provide a kind of mouse bite preventing PE plastic material and its preparation method, pass through the technical program, for the existing technological deficiency being added on the application of PE plastic material by mouse expelling agent of capsaicine (alkali), to overcome and to make up the deficiency of technique scheme, there is provided application different purity capsaicine (alkali) actual can reach mouse bite preventing function as Ratproof agent, and the formula of conservative control production cost and preparation method.
In order to achieve the above object, the technical scheme of the present invention is achieved in that
Its component includes PE base mateiral and drives mouse material, it is base material and anti-antiaging agent that described PE base mateiral at least includes PE, described driving contains synthetic capsaicin (alkali) (chemical name: n-Vanillyl pelargonic amide) in mouse material, n-Vanillyl pelargonic amide content is that protection against rodents PE expects the 0.31%��0.89% of gross weight.
Described drive n-Vanillyl pelargonic amide content in mouse material be protection against rodents PE expect gross weight 0.35%��0.49%.
Described drive n-Vanillyl pelargonic amide content in mouse material be protection against rodents PE expect gross weight 0.4%��0.45%.
Described when to drive mouse material be high purity synthetic capsaicin (alkali) that n-Vanillyl pelargonic amide content accounts for its weight 90%��99.8%, n-Vanillyl pelargonic amide content is that protection against rodents PE expects the 0.31%��0.89% of gross weight.
Described when to drive mouse material be synthetic capsaicin (alkali) that n-Vanillyl pelargonic amide content accounts for its weight 50%��85%, n-Vanillyl pelargonic amide content is that protection against rodents PE expects the 0.35%��0.75% of gross weight.
The described mouse material that drives is that n-Vanillyl pelargonic amide content accounts for when driving mouse microcapsule of its weight 15%��35%, and n-Vanillyl pelargonic amide content is that protection against rodents PE expects the 0.4%��0.45% of gross weight.
Described when to drive mouse material be the protection against rodents masterbatch that n-Vanillyl pelargonic amide content accounts for its weight 5%��15%, n-Vanillyl pelargonic amide content is that protection against rodents PE expects the 0.4%��0.7% of gross weight.
The preparation method that described a kind of protection against rodents PE expects comprises the following steps: that synthetic capsaicin (alkali) is first pulverized powdered or particulate state through pulverizer by (1), or synthetic capsaicin (alkali) is warmed to 40 DEG C-100 DEG C slowly melts as liquid; (2) synthetic capsaicin (alkali) after pulverizing or thawing and PE base mateiral are mixed; (3) blended good protection against rodents PE raw material is finally sent into the obtained protection against rodents PE of extruding machine to expect.
Described a kind of protection against rodents PE expect preparation method comprise the following steps: (1) first will drive mouse microcapsule and PE matrix resin evenly blended; (2) again other group part such as antiaging agent is dropped into to drive the PE matrix resin continuation that mouse microcapsule mix evenly blended; (3) the protection against rodents PE raw material mixed finally is sent into the obtained protection against rodents PE of extruding machine to expect.
The preparation method that described a kind of protection against rodents PE expects comprises the following steps: that protection against rodents masterbatch and PE matrix resin, anti-antiaging agent etc. are first organized part and dropped into evenly blended by (1); (2) the protection against rodents PE raw material mixed finally is sent into the obtained protection against rodents PE of extruding machine to expect.
The invention has the beneficial effects as follows: the protection against rodents PE that the present invention's application different purity capsaicine (alkali) prepares as Ratproof agent expects, through (machinery industry standard JB/T10696.10-XXXX electric wire machinery and physicochemical property test method) test, all can reach the remarkable level mouse bite preventing function that protection ratio is greater than 90%, and conservative control production cost.
Embodiment
Specific embodiments of the invention will be described in further detail below.
Embodiment 1
Group part of the present embodiment is as follows:
The preparation method that above-mentioned protection against rodents PE expects is as follows:
(1) first the high purity capsaicine (alkali) of n-Vanillyl pelargonic amide content 95% is pulverized powdered or particulate state through pulverizer, or synthetic capsaicin (alkali) is warmed to 40 DEG C-100 DEG C slowly melts as liquid;
(2) high purity synthetic capsaicin (alkali) and PE matrix resin, antioxidant 1010, rheological agent, the PE wax of the n-Vanillyl pelargonic amide content 95% pulverized or after thawing are mixed together evenly;
(4) blended good protection against rodents PE raw material is finally sent into the obtained protection against rodents PE of extruding machine to expect.
Embodiment 2
Group part of the present embodiment is as follows:
The preparation method that above-mentioned protection against rodents PE expects is with embodiment 1
Embodiment 3
Group part of the present embodiment is as follows:
The preparation method that above-mentioned protection against rodents PE expects is as follows:
(1) first by n-Vanillyl pelargonic amide content 20% drive mouse microcapsule and PE matrix resin evenly blended;
(2) again by antioxidant 1010, rheological agent, PE wax and drive the PE matrix resin that mouse microcapsule mix and continue evenly blended;
(3) the protection against rodents PE raw material mixed finally is sent into the obtained protection against rodents PE of extruding machine to expect.
Embodiment 4
Group part of the present embodiment is as follows:
The preparation method that above-mentioned protection against rodents PE expects is as follows:
(1) first by n-Vanillyl pelargonic amide content 10% drive mouse masterbatch and PE matrix resin, antioxidant 1010, rheological agent, PE wax drop into evenly blended;
(2) the protection against rodents PE raw material mixed finally is sent into the obtained protection against rodents PE of extruding machine to expect.
Claims (2)
1. a protection against rodents PE expects, it is characterised in that, it is made up of the component of following weight part number:
PE matrix resin 100;
Antioxidant 1010 1.5;
Rheological agent 2;
PE wax 2.5;
The high purity capsaicine 0.5 of n-Vanillyl pelargonic amide content 95%.
2. the preparation method that a kind of protection against rodents PE according to claim 1 expects, it is characterised in that comprise the following steps:
(1) first the high purity capsaicine of n-Vanillyl pelargonic amide content 95% is pulverized powdered or particulate state through pulverizer;
(2) high purity synthetic capsaicin and PE matrix resin, antioxidant 1010, rheological agent, the PE wax of the n-Vanillyl pelargonic amide content 95% after pulverizing are mixed together evenly;
(3) blended good protection against rodents PE raw material is finally sent into the obtained protection against rodents PE of extruding machine to expect.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410247123.5A CN104045895B (en) | 2014-06-06 | 2014-06-06 | A kind of protection against rodents PE expects |
| PCT/CN2015/077485 WO2015184937A1 (en) | 2014-06-06 | 2015-04-27 | Rodent-proof pe material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410247123.5A CN104045895B (en) | 2014-06-06 | 2014-06-06 | A kind of protection against rodents PE expects |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104045895A CN104045895A (en) | 2014-09-17 |
| CN104045895B true CN104045895B (en) | 2016-06-08 |
Family
ID=51499315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410247123.5A Active CN104045895B (en) | 2014-06-06 | 2014-06-06 | A kind of protection against rodents PE expects |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN104045895B (en) |
| WO (1) | WO2015184937A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104045895B (en) * | 2014-06-06 | 2016-06-08 | 桐庐雷泰生物科技有限公司 | A kind of protection against rodents PE expects |
| CN104045903B (en) * | 2014-06-06 | 2016-06-08 | 桐庐雷泰生物科技有限公司 | A kind of protection against rodents low-smoke halogen-free material |
| CN105062036B (en) * | 2015-07-31 | 2017-09-12 | 大禹节水（天津）有限公司 | A kind of mouse bite preventing drip irrigation tube mother material |
| CN106098169B (en) * | 2016-05-26 | 2017-11-24 | 杭州富通电线电缆有限公司 | Protection against rodents data cable |
| CN107593704A (en) * | 2017-09-15 | 2018-01-19 | 南通香佳纺织科技有限公司 | A kind of steamer cable capsaicine Ratproof agent and preparation method thereof |
| CN109181052B (en) * | 2018-07-18 | 2021-03-23 | 山东华能线缆有限公司 | Slow-release type rat-proof and termite-proof cable sheath material |
| TWI730546B (en) * | 2019-12-16 | 2021-06-11 | 宏泰電工股份有限公司 | Hybrid anti-rodent and anti-termite cable |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3469695B2 (en) * | 1995-12-01 | 2003-11-25 | 日本化薬株式会社 | Animal bite prevention masterbatch for polyolefin resin and method for producing the same |
| CN1141332C (en) * | 1999-06-01 | 2004-03-10 | 周宝茂 | Plastics for preventing cable from being eaten by ant and mouse |
| JP2000348542A (en) * | 1999-06-03 | 2000-12-15 | Yazaki Corp | Rat proof electrical cable |
| CN1197908C (en) * | 2003-05-24 | 2005-04-20 | 周宝茂 | Polyethylene plastic of electric cable for ant and mouse proofing |
| CN101161712A (en) * | 2007-09-03 | 2008-04-16 | 上海斯瑞聚合体科技有限公司 | Environment-friendly type ant-proof ratproof material for electric wire and cable |
| JP5182935B2 (en) * | 2008-07-29 | 2013-04-17 | 矢崎エナジーシステム株式会社 | Anti-mold resin composition and coated electric wire using the same |
| CN102321284A (en) * | 2011-07-13 | 2012-01-18 | 保定铭望机电科技有限公司 | Ratproof plastic drip irrigation tube/belt and preparation method thereof |
| CN102775674B (en) * | 2012-08-02 | 2014-09-17 | 深圳市沃尔核材股份有限公司 | Ant- and rat-resistant radiation-crosslinked flame-retardant pyrocondensation material and manufacturing method thereof |
| CN102775663B (en) * | 2012-08-02 | 2015-03-25 | 深圳市沃尔核材股份有限公司 | Ant- and rat-resistant radiation-crosslinked flame-retardant pyrocondensation material and manufacturing method thereof |
| CN104045895B (en) * | 2014-06-06 | 2016-06-08 | 桐庐雷泰生物科技有限公司 | A kind of protection against rodents PE expects |
| CN104045903B (en) * | 2014-06-06 | 2016-06-08 | 桐庐雷泰生物科技有限公司 | A kind of protection against rodents low-smoke halogen-free material |
-
2014
- 2014-06-06 CN CN201410247123.5A patent/CN104045895B/en active Active
-
2015
- 2015-04-27 WO PCT/CN2015/077485 patent/WO2015184937A1/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015184937A1 (en) | 2015-12-10 |
| CN104045895A (en) | 2014-09-17 |
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