CN104035201A - Low-ghosting cylindrical lens type 3D (three-dimensional) optic sheet and preparation method thereof - Google Patents
Low-ghosting cylindrical lens type 3D (three-dimensional) optic sheet and preparation method thereof Download PDFInfo
- Publication number
- CN104035201A CN104035201A CN201410159479.3A CN201410159479A CN104035201A CN 104035201 A CN104035201 A CN 104035201A CN 201410159479 A CN201410159479 A CN 201410159479A CN 104035201 A CN104035201 A CN 104035201A
- Authority
- CN
- China
- Prior art keywords
- lens type
- ghost image
- graphene
- post lens
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 40
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 36
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 32
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002105 nanoparticle Substances 0.000 claims abstract description 20
- 239000011787 zinc oxide Substances 0.000 claims abstract description 20
- 239000011248 coating agent Substances 0.000 claims abstract description 18
- 238000000576 coating method Methods 0.000 claims abstract description 18
- 239000000178 monomer Substances 0.000 claims abstract description 16
- 239000000758 substrate Substances 0.000 claims abstract description 8
- 230000003287 optical effect Effects 0.000 claims description 38
- 125000003118 aryl group Chemical group 0.000 claims description 25
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 15
- 229920003232 aliphatic polyester Polymers 0.000 claims description 15
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 13
- 239000003822 epoxy resin Substances 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 11
- 239000012752 auxiliary agent Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 9
- 238000005096 rolling process Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000013530 defoamer Substances 0.000 claims description 7
- -1 light trigger Substances 0.000 claims description 7
- 239000000080 wetting agent Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 238000007766 curtain coating Methods 0.000 claims description 3
- 238000004513 sizing Methods 0.000 claims description 3
- 238000003980 solgel method Methods 0.000 claims description 3
- 238000009966 trimming Methods 0.000 claims description 3
- 150000004703 alkoxides Chemical class 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 238000010532 solid phase synthesis reaction Methods 0.000 claims description 2
- 239000012808 vapor phase Substances 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 abstract description 11
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 abstract 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 8
- 239000010408 film Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 4
- 229910002012 Aerosil® Inorganic materials 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 229940106691 bisphenol a Drugs 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229940117969 neopentyl glycol Drugs 0.000 description 3
- 125000005375 organosiloxane group Chemical group 0.000 description 3
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical class C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 210000004276 hyalin Anatomy 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000004451 qualitative analysis Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses a low-ghosting cylindrical lens type 3D (three-dimensional) optic sheet. The low-ghosting cylindrical lens type 3D (three-dimensional) optic sheet comprises a transparent substrate and a coating coated onto the substrate, wherein the coating is of a micro cylindrical lens array structure and is obtained through ultraviolet curing of a polymeric matrix, which comprises acrylate oligomer, acrylic monomer, graphene and zinc oxide nano-particles. The invention also relates to a preparation method of the low-ghosting cylindrical lens type 3D (three-dimensional) optic sheet. The low-ghosting cylindrical lens type 3D (three-dimensional) optic sheet has the advantages of being high in light transmittance and low in ghosting degree.
Description
Technical field
The present invention relates to field, a kind of information display technology field, post lens type 3D optical stereo diaphragm of a kind of low ghost image degree of specific design and preparation method thereof.
Background technology
In recent years, 3D film is subject to more and more spectators' favor with its visual experience true to nature, but very inconvenient but wearing spectacles is watched.Under this background, bore hole 3D technology is arisen at the historic moment.At present, at bore hole 3D, showing that in film, post lens type 3D technology can ensure picture brightness well, is that following 3D demonstration is expected to universal solution most.
So-called post lens type 3D optical stereo diaphragm is by ultraviolet ray, on the optical thin films such as PET, acryl resin be solidified into microtrabeculae array structure thereof and make.The major function of microtrabeculae array structure thereof is to realize the sub-pixel of different directions projection diaphragm below, the different videos of separated right and left eyes, thus when eyes are watched display screen, just can see different sub-pixels.For post lens type 3D optical stereo diaphragm existing a lot of patent documentations in bore hole formula 3D display technique, deliver at present Chinese patent that for example application number is 201110271474.6 etc.But how to improve post lens type 3D optical stereo diaphragm ghost image degree, improve its 3D display effect, be still one of core technology point of the most critical in its production run.
Summary of the invention
For solving the problems of the technologies described above, the invention provides a kind of post lens type 3D optical stereo diaphragm with low ghost image degree.
In addition, the present invention also provides the preparation method of the post lens type 3D optical stereo diaphragm of above-mentioned low ghost image degree.
For first technical matters, technical scheme of the present invention is: a kind of 3D optical stereo diaphragm of low ghost image degree, and it comprises a transparency carrier and is coated on the coating on this substrate; This coating has microtrabeculae array structure thereof, by the polymeric matrices ultraviolet light polymerization that includes acrylate oligomer, acrylate monomer, Graphene and Zinc oxide nanoparticle, is obtained.
Preferably, described polymeric matrices comprises following component:
24～42 parts of aromatic epoxy resin acrylate oligomers,
4～7 parts of polyester-type aromatic urethane acrylate oligomers,
8～14 parts of aliphatic polyester acrylic acid oligomers,
28～45 parts of acrylate monomers,
1～2 part of Zinc oxide nanoparticle,
0.001～0.1 part of Graphene,
1～5 part of light trigger,
1～5 part of auxiliary agent.
Best described Graphene is graphene oxide.
Described Zinc oxide nanoparticle is of a size of 1～100nm.
Described auxiliary agent is one or more in levelling agent, wetting agent, defoamer.
Described acrylic monomers is isobornyl acrylate and neopentylglycol diacrylate by weight (1.5～3): 1 compound.
The thickness of described coating is 20 μ m～600 μ m.
For second technical matters, technical scheme of the present invention is a kind of preparation method of post lens type 3D optical stereo diaphragm of above-mentioned low ghost image degree, and it comprises the following steps:
One of s1, employing mechanical crushing method, sol-gel process, alkoxide hydrolysis, the precipitation method, hydro-thermal method, solid phase method, vapor phase method are prepared Zinc oxide nanoparticle;
S2, aromatic epoxy resin acrylate oligomer, polyester-type aromatic urethane acrylate oligomer, aliphatic polyester acrylic acid oligomer, acrylate monomer, Zinc oxide nanoparticle, Graphene, light trigger, auxiliary agent are mixed according to certain ratio, be made into polymeric matrices;
S3, polymeric matrices curtain coating is coated on transparency carrier, a pair of pressure roller rolling and forming on sizing material being comprised of nick version applicator roll and smooth roll, is formed with rule, evenly distributed microtrabeculae array structure thereof;
Polymeric matrices after s4, rolling forms curing coating with ultraviolet light polymerization, obtains post lens type 3D optical stereo diaphragm;
S5, optical protection layer is fitted in respectively to the surface of substrate and the surface of coating, finished product is through trimming, itemize, rolling again.
Preferably, the diameter of described nick version applicator roll is 20～50mm.
Preferably, described polymeric matrices comprises following component:
24～42 parts of aromatic epoxy resin acrylate oligomers,
4～7 parts of polyester-type aromatic urethane acrylate oligomers,
8～14 parts of aliphatic polyester acrylic acid oligomers,
28～45 parts of acrylate monomers,
1～2 part of Zinc oxide nanoparticle,
0.001～0.1 part of Graphene,
1～5 part of light trigger,
1～5 part of auxiliary agent;
Wherein, described Graphene is graphene oxide; Described Zinc oxide nanoparticle is of a size of 1～100nm; Described auxiliary agent is one or more in levelling agent, wetting agent, defoamer; Described acrylic monomers is isobornyl acrylate and neopentylglycol diacrylate by weight (1.5～3): 1 compound; The thickness of described coating is 20 μ m～600 μ m.
Advantage of the present invention and beneficial effect are:
1, the present invention adds zinc paste and Graphene in polymeric matrices, the unexpected printing opacity of finding to have improved blooming
Rate, has especially also reduced the ghost image degree that 3D shows.
2, the present invention is passing through aromatic epoxy resin acrylate oligomer and aliphatic polyester acrylic acid widow
Polymers use add polyester-type aromatic urethane acrylate oligomer simultaneously, have further reduced
The ghost image degree of blooming has kept high transmission rate simultaneously.
3, aspect manufacturing technology, adopt nick version applicator roll, reduced intaglio plate applicator roll and be coated with connecing of substrate
Touch area, reduced to enter and leave the liquid bridge amount of applying area, improved the quality of transfer coated, also
Reduced the ghost image degree of blooming.
Accompanying drawing explanation
Fig. 1 is production technological process of the present invention.
Embodiment
Below in conjunction with drawings and Examples, the specific embodiment of the present invention is further described.Following examples are only for technical scheme of the present invention is more clearly described, and can not limit the scope of the invention with this.
Embodiment 1
First adopt sol-gel process to prepare Zinc oxide nanoparticle; Then aromatic epoxy resin acrylate oligomer, polyester-type aromatic urethane acrylate oligomer, aliphatic polyester acrylic acid oligomer, acrylate monomer, Zinc oxide nanoparticle, Graphene, light trigger, auxiliary agent are mixed according to certain ratio, be made into polymeric matrices; As shown in Figure 1, then polymeric matrices curtain coating is coated on PET transparency carrier, the a pair of pressure roller rolling and forming on sizing material being formed by nick version applicator roll and smooth roll, be formed with rule, evenly distributed microtrabeculae array structure thereof, the diameter of nick version applicator roll is 20～50mm, is coated with fabric width degree sets according to difference, while being 300nm such as coating wide cut, adopt the nick version applicator roll that diameter is 20mm, when coating wide cut is 1600mm, adopt the nick version applicator roll that diameter is 50mm; Polymeric matrices after rolling forms curing coating with ultraviolet light polymerization, and the thickness of coating is 100 μ m, thereby obtains post lens type 3D optical stereo diaphragm; Finally optical protection layer is fitted in respectively to the surface of substrate and the surface of hyaline membrane material layer with guard column lens type 3D optical stereo diaphragm, finished product is through trimming, itemize, rolling again.
The formula of polymeric matrices (parts by weight) is: 32 parts of bisphenol-a epoxy acrylates (trade mark 9104), 5 parts of polyester-type aromatic urethane acrylate oligomers (trade mark 6210F-80), 10 parts of aliphatic polyester acrylic acid oligomers (trade mark is 5320), 20 parts of isobornyl acrylate, 10 parts of neopentylglycol diacrylates, 1.5 parts of Zinc oxide nanoparticles (1～100nm), 0.01 part of Graphene, 2 parts of 1-hydroxy cyclohexyl phenylketones (light trigger 184), 1 part of levelling agent (aerosil), defoamer (organosiloxane, trade mark EFKA2040) 0.5 part, wetting agent (fluorine-carbon modified acrylate, trade mark EFKA3277) 0.5 part.Table 1
| ? | Refractive index | Shrinkage factor | Transmittance | Ghost image degree |
| Do not add zinc paste and Graphene | 1.53 | 0.5% | 83% | 37% |
| Only add zinc paste | 1.53 | 0.1% | 86% | 27% |
| Only add Graphene | 1.53 | 0.3% | 87% | 30% |
| Add zinc paste and Graphene | 1.53 | 0.06% | 90% | 21% |
Table 1 be in one or more and the polymeric matrices being added with in polymeric matrices in embodiment 1 in zinc paste, Graphene, do not add post lens type 3D optical stereo diaphragm prepared by zinc paste, Graphene refractive index, shrinkage factor, transmittance and ghost image degree Performance Ratio.
As can be seen from Table 1, add zinc paste in polymeric matrices, the ghost image degree of the blooming obtaining is in a slight decrease, but far away from zinc paste and Graphene being used in conjunction with to the ghost image degree fall of generation, and the transmittance of the blooming obtaining is also improved.
Table 2
| Zinc paste | Graphene | Transmittance | Ghost image degree |
| 1 | 0.001 | 87% | 19% |
| 1.3 | 0.05 | 88% | 23% |
| 1.5 | 0.01 | 90% | 21% |
| 2 | 0.2 | 89% | 22% |
Table 2 is to change the transmittance of post lens type 3D optical stereo diaphragm that in embodiment 1 prepared by hyaline membrane material layer zinc paste, Graphene content and the Performance Ratio of ghost image degree.
Table 3
Table 3 be in embodiment 1 acrylate oligomer be the compound of aromatic epoxy resin acrylate oligomer, aliphatic polyester acrylic acid oligomer and polyester-type aromatic urethane acrylate oligomer and acrylate oligomer for the Performance Ratio of refractive index, shrinkage factor, transmittance and the ghost image degree of one or both post lens type 3D optical stereo diaphragms of preparing wherein.
As can be seen from Table 3, acrylate oligomer is simple aromatic epoxy resin acrylate, and post lens type 3D optical stereo film has the shortcoming of high ghost image degree; Acrylate oligomer is simple aliphatic polyester acrylic acid oligomer, and post lens type 3D optical stereo film has low-refraction, is not inconsistent the refractive index requirement of zygostyle lens type 3D optical stereo film; Acrylate oligomer is the potpourri of aromatic epoxy resin acrylate and aliphatic polyester acrylic acid oligomer, and post lens type 3D optical stereo film transmittance is low.And acrylate oligomer adopts the compound of aromatic epoxy resin acrylate oligomer, aliphatic polyester acrylic acid oligomer and polyester-type aromatic urethane acrylate oligomer, when reducing ghost image degree, also do not affect transmittance.Table 4
| ? | Ghost image degree | Solvent resistance |
| Isobornyl acrylate | 20% | Poor |
| Neopentylglycol diacrylate | 23% | Excellent |
| Both compounds | 21% | Excellent |
Table 4 be in embodiment 1 acrylate monomer be the compound of isobornyl acrylate and neopentylglycol diacrylate and acrylate monomer be the post lens type 3D optical stereo diaphragm prepared of isobornyl acrylate or neopentylglycol diacrylate ghost image degree Performance Ratio.Wherein solvent resistance is the qualitative analysis for esters solvent.
As can be seen from Table 4, adopt the compound of isobornyl acrylate and neopentylglycol diacrylate can reduce post lens type 3D optical stereo diaphragm ghost image degree, improve solvent resistance.
Table 5
| ? | Transmittance | Ghost image degree |
| Pure Graphene | 90% | 21% |
| Graphene oxide | 91% | 21% |
Table 5 be in embodiment 1 in polymeric matrices Graphene be the transmittance of post lens type 3D optical stereo diaphragm prepared of pure Graphene and graphene oxide and the Performance Ratio of ghost image degree.Visible, graphene oxide contributes to improve the light transmission of post lens type 3D optical stereo diaphragm, and its reason may be its improved dispersiveness.
Embodiment 2
The difference of the present embodiment and embodiment 1 has been to change the formula of polymeric matrices.In the present embodiment, the formula of polymeric matrices (parts by weight) is: 42 parts of bisphenol-a epoxy acrylates (trade mark 9104), 7 parts of polyester-type aromatic urethane acrylate oligomers (trade mark 6210F-80), 8 parts of aliphatic polyester acrylic acid oligomers (trade mark is 5320), 27 parts of isobornyl acrylate, 18 parts of neopentylglycol diacrylates, 2 parts of Zinc oxide nanoparticles (1～100nm), 0.001 part of Graphene, 5 parts of 1-hydroxy cyclohexyl phenylketones (light trigger 184), 1.5 parts of levelling agents (aerosil), defoamer (organosiloxane, trade mark EFKA2040) 2.5 parts, wetting agent (fluorine-carbon modified acrylate, trade mark EFKA3277) 1 part.
Embodiment 3
The difference of the present embodiment and embodiment 1 has been to change the formula of polymeric matrices.In the present embodiment, the formula of polymeric matrices (parts by weight) is: 24 parts of bisphenol-a epoxy acrylates (trade mark 9104), 4 parts of polyester-type aromatic urethane acrylate oligomers (trade mark 6210F-80), 47 parts of aliphatic polyester acrylic acid oligomers (trade mark is 5320), 21 parts of isobornyl acrylate, 7 parts of neopentylglycol diacrylates, 1 part of Zinc oxide nanoparticle (1～100nm), 0.1 part of Graphene, 1 part of 1-hydroxy cyclohexyl phenylketone (light trigger 184), 0.4 part of levelling agent (aerosil), defoamer (organosiloxane, trade mark EFKA2040) 0.4 part, wetting agent (fluorine-carbon modified acrylate, trade mark EFKA3277) 0.2 part.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, do not departing under the prerequisite of the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1. a post lens type 3D optical stereo diaphragm for low ghost image degree, is characterized in that, comprises a transparency carrier and is coated on the coating on this substrate; This coating has microtrabeculae array structure thereof, by the polymeric matrices ultraviolet light polymerization that includes acrylate oligomer, acrylate monomer, Graphene and Zinc oxide nanoparticle, is obtained.
2. the post lens type 3D optical stereo diaphragm of low ghost image degree as claimed in claim 1, is characterized in that, described polymeric matrices comprises following component:
24 ~ 42 parts of aromatic epoxy resin acrylate oligomers,
4 ~ 7 parts of polyester-type aromatic urethane acrylate oligomers,
8 ~ 14 parts of aliphatic polyester acrylic acid oligomers,
28 ~ 45 parts of acrylate monomers,
1～2 part of Zinc oxide nanoparticle,
0.001～0.1 part of Graphene,
1 ~ 5 part of light trigger,
1 ~ 5 part of auxiliary agent.
3. the post lens type 3D optical stereo diaphragm of low ghost image degree as claimed in claim 2, is characterized in that, described Graphene is graphene oxide.
4. the post lens type 3D optical stereo diaphragm of low ghost image degree as claimed in claim 2, is characterized in that: described Zinc oxide nanoparticle is of a size of 1～100nm.
5. the post lens type 3D optical stereo diaphragm of low ghost image degree as claimed in claim 2, is characterized in that: described auxiliary agent is one or more in levelling agent, wetting agent, defoamer.
6. the post lens type 3D optical stereo diaphragm of the low ghost image degree as described in claim 2 to 5 any one, is characterized in that: described acrylic monomers is isobornyl acrylate and neopentylglycol diacrylate by weight (1.5 ~ 3): 1 compound.
7. the post lens type 3D optical stereo diaphragm of low ghost image degree as claimed in claim 1, is characterized in that: the thickness of described coating is 20 μ m～600 μ m.
8. the preparation method of the post lens type 3D optical stereo diaphragm of low ghost image degree as claimed in claim 1, is characterized in that, comprises the following steps:
One of s1, employing mechanical crushing method, sol-gel process, alkoxide hydrolysis, the precipitation method, hydro-thermal method, solid phase method, vapor phase method are prepared Zinc oxide nanoparticle;
S2, the polymeric matrices that comprises aromatic epoxy resin acrylate oligomer, polyester-type aromatic urethane acrylate oligomer, aliphatic polyester acrylic acid oligomer, acrylate monomer, Zinc oxide nanoparticle, Graphene, light trigger, auxiliary agent is mixed according to certain ratio, be made into polymeric matrices;
S3, polymeric matrices curtain coating is coated on transparency carrier, a pair of pressure roller rolling and forming on sizing material being comprised of nick version applicator roll and smooth roll, is formed with rule, evenly distributed microtrabeculae array structure thereof;
Polymeric matrices after s4, rolling forms curing coating with ultraviolet light polymerization, obtains post lens type 3D optical stereo diaphragm;
S5, optical protection layer is fitted in respectively to the surface of substrate and the surface of coating, finished product is through trimming, itemize, rolling again.
9. the preparation method of the post lens type 3D optical stereo diaphragm of low ghost image degree as claimed in claim 8, is characterized in that, the diameter of described nick version applicator roll is 20～50mm.
10. the preparation method of the post lens type 3D optical stereo diaphragm of low ghost image degree as claimed in claim 9, is characterized in that, described polymeric matrices comprises following component:
24 ~ 42 parts of aromatic epoxy resin acrylate oligomers,
4 ~ 7 parts of polyester-type aromatic urethane acrylate oligomers,
8 ~ 14 parts of aliphatic polyester acrylic acid oligomers,
28 ~ 45 parts of acrylate monomers,
1～2 part of Zinc oxide nanoparticle,
0.001～0.1 part of Graphene,
1 ~ 5 part of light trigger,
1 ~ 5 part of auxiliary agent;
Wherein, described Graphene is graphene oxide; Described Zinc oxide nanoparticle is of a size of 1～100nm; Described auxiliary agent is one or more in levelling agent, wetting agent, defoamer; Described acrylic monomers is isobornyl acrylate and neopentylglycol diacrylate by weight (1.5 ~ 3): 1 compound; The thickness of described coating is 20 μ m～600 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410159479.3A CN104035201B (en) | 2014-04-18 | 2014-04-18 | Post lens type 3D optical stereoscopic diaphragm of a kind of low ghost image degree and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410159479.3A CN104035201B (en) | 2014-04-18 | 2014-04-18 | Post lens type 3D optical stereoscopic diaphragm of a kind of low ghost image degree and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104035201A true CN104035201A (en) | 2014-09-10 |
| CN104035201B CN104035201B (en) | 2016-03-02 |
Family
ID=51466027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410159479.3A Active CN104035201B (en) | 2014-04-18 | 2014-04-18 | Post lens type 3D optical stereoscopic diaphragm of a kind of low ghost image degree and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104035201B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087187A (en) * | 2014-05-26 | 2014-10-08 | 东莞市纳利光学材料有限公司 | Optical protection film with 3D visual effect and preparation method thereof |
| CN106752739A (en) * | 2016-11-29 | 2017-05-31 | 燕园众欣纳米科技（北京）有限公司 | A kind of graphite oxide ene-type UV coating and preparation method thereof |
| CN109852276A (en) * | 2019-01-31 | 2019-06-07 | 深圳日高胶带新材料有限公司 | A kind of stereoptics adhesive tape |
| CN113956780A (en) * | 2021-07-19 | 2022-01-21 | 广州申威新材料科技有限公司 | 3D film grating layer coating and preparation method and application thereof |
| WO2022159039A1 (en) * | 2021-01-25 | 2022-07-28 | Nanyang Technological University | Curable compositions |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05111959A (en) * | 1991-10-23 | 1993-05-07 | Mitsubishi Rayon Co Ltd | Manufacture of sheet-shaped resin molded form |
| WO2008111579A1 (en) * | 2007-03-15 | 2008-09-18 | Michiyoshi Nagashima | Lenticular lens, image display method, image display device and lenticular lens manufacturing method |
| CN102933987A (en) * | 2010-06-07 | 2013-02-13 | 新日铁住金化学株式会社 | Method for producing lenticular lens, lenticular lens, optical element and three-dimensional display device |
| CN102991049A (en) * | 2012-11-08 | 2013-03-27 | 江阴通利光电科技有限公司 | Novel 3D (three dimensional) optical stereoscopic membrane and preparation method thereof |
| TW201319621A (en) * | 2011-09-30 | 2013-05-16 | Henkel Corp | Lenticular print three dimensional image display device and method of fabricating the same |
-
2014
- 2014-04-18 CN CN201410159479.3A patent/CN104035201B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05111959A (en) * | 1991-10-23 | 1993-05-07 | Mitsubishi Rayon Co Ltd | Manufacture of sheet-shaped resin molded form |
| WO2008111579A1 (en) * | 2007-03-15 | 2008-09-18 | Michiyoshi Nagashima | Lenticular lens, image display method, image display device and lenticular lens manufacturing method |
| CN102933987A (en) * | 2010-06-07 | 2013-02-13 | 新日铁住金化学株式会社 | Method for producing lenticular lens, lenticular lens, optical element and three-dimensional display device |
| TW201319621A (en) * | 2011-09-30 | 2013-05-16 | Henkel Corp | Lenticular print three dimensional image display device and method of fabricating the same |
| CN102991049A (en) * | 2012-11-08 | 2013-03-27 | 江阴通利光电科技有限公司 | Novel 3D (three dimensional) optical stereoscopic membrane and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087187A (en) * | 2014-05-26 | 2014-10-08 | 东莞市纳利光学材料有限公司 | Optical protection film with 3D visual effect and preparation method thereof |
| CN104087187B (en) * | 2014-05-26 | 2015-09-16 | 东莞市纳利光学材料有限公司 | A kind of have optical protection layer of 3D visual effect and preparation method thereof |
| CN106752739A (en) * | 2016-11-29 | 2017-05-31 | 燕园众欣纳米科技（北京）有限公司 | A kind of graphite oxide ene-type UV coating and preparation method thereof |
| CN109852276A (en) * | 2019-01-31 | 2019-06-07 | 深圳日高胶带新材料有限公司 | A kind of stereoptics adhesive tape |
| WO2022159039A1 (en) * | 2021-01-25 | 2022-07-28 | Nanyang Technological University | Curable compositions |
| CN113956780A (en) * | 2021-07-19 | 2022-01-21 | 广州申威新材料科技有限公司 | 3D film grating layer coating and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104035201B (en) | 2016-03-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104035201B (en) | Post lens type 3D optical stereoscopic diaphragm of a kind of low ghost image degree and preparation method thereof | |
| CN103308959B (en) | Blooming, polaroid, liquid crystal panel and image display device | |
| CN102859398B (en) | Optical multilayered product, polarizer, and display device | |
| CN104838292B (en) | Anisotropic optical film | |
| CN103926697B (en) | A kind of 3 d display device and preparation method thereof | |
| CN104854643B (en) | Display device | |
| CN104246543A (en) | Viewing angle limiting sheet and flat panel display | |
| KR101648119B1 (en) | Film for autostereoscopic display | |
| CN102262256B (en) | Patterned retarder film and method for manufacturing same | |
| CN109375301A (en) | Optical film and display device with touch panel | |
| CN106324846B (en) | Suspension imaging optical film | |
| CN109283730A (en) | Light is redirected film and its manufacturing method | |
| CN202727838U (en) | Raster glass stereograph | |
| KR102067163B1 (en) | Film for improving color sense and method for preparing the same | |
| CN102967962B (en) | Transparent polymer dispersed liquid crystal display device and manufacturing method and application thereof | |
| CN102243330A (en) | Production method for micro-retarder without alignment layer | |
| WO2015076409A1 (en) | Optical member and display device | |
| TWI600949B (en) | 2d/3d switching lens and display device thereof | |
| CN102193235A (en) | 3D optical barrier type liquid crystal display and manufacturing process thereof | |
| TWI490238B (en) | An acrylic resin composition, an alignment film formed, and a three-dimensional liquid Crystal display | |
| TW201128239A (en) | Optical laminate and manufacturing method thereof as well as polarizing plate and display device using the same | |
| CN102540307A (en) | Optical filter and liquid crystal display including the same | |
| CN113655554B (en) | Antiglare film and polarizing plate having the same | |
| JP2011107335A (en) | Optical laminate | |
| CN204331157U (en) | A kind of mobile phone 3D shows glass |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A low ghosting cylindrical lens type 3D optical stereoscopic film and its preparation method Effective date of registration: 20231012 Granted publication date: 20160302 Pledgee: Yunongshang Financial Leasing Co.,Ltd. Pledgor: JIANGYIN TONGLI OPTOELECTRONIC TECHNOLOGY Co.,Ltd. Registration number: Y2023980060795 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |