CN104031416A - Modified calcium carbonate serving as sound absorbing filler and preparation method thereof - Google Patents
Modified calcium carbonate serving as sound absorbing filler and preparation method thereof Download PDFInfo
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- CN104031416A CN104031416A CN201410214640.2A CN201410214640A CN104031416A CN 104031416 A CN104031416 A CN 104031416A CN 201410214640 A CN201410214640 A CN 201410214640A CN 104031416 A CN104031416 A CN 104031416A
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Abstract
The invention discloses modified calcium carbonate serving as a sound absorbing filler. The modified calcium carbonate is characterized by being prepared from the following raw materials in parts by weight: 90-95 parts of calcium carbonate, 4-6 parts of nanometer hollow microspheres, 3-5 parts of aluminum silicate fiber cotton, 3-4 parts of zizania aquatica straw powder, 2-4 parts of expanded perlite, 3-4 parts of activated aluminum oxide, 2-3 parts of ammonium carbonate, 6-8 parts of polycarbonate, 5-6 parts of natural latex, 1-2 parts of alpha-vinyl sodium sulfonate and 3-4 parts of modified titanium dioxide. The modified calcium carbonate disclosed by the invention has excellent sound absorption performance due to addition of the nanometer hollow microspheres and the aluminum silicate fiber cotton, has a large specific surface area as well as sound absorption and adsorption effects due to addition of plant fibers and natural substances, and has increased dispersion performance due to addition of the modified titanium dioxide, so the modified calcium carbonate is applicable to production of additives including sound absorbing bricks, sound absorbing plates, coatings and the like.
Description
Technical field
The present invention relates to industrial filler field, particularly a kind of can be as modified calcium carbonate of sound-absorbing filler and preparation method thereof.
Background technology
Calcium carbonate is a kind of very important functional inorganic filling, is widely used in the industrial circles such as plastics, rubber, coating and papermaking.In the Application Areas of calcium carbonate, large multi-product belongs to the category of polymkeric substance, such as plastics, rubber, tackiness agent, coating etc., and occupy the important market share.Vital role has been played in performance and the application of properties-correcting agent to nano-calcium carbonate.For example, dispersion agent add the reunion that can reduce nano particle, improve dispersed; Adding of surface-modifying agent can improve the consistency of nano-calcium carbonate in polymeric system.As can be seen here, dispersion agent and surface-modifying agent are vital for the application of nano-calcium carbonate.But, adding of dispersion agent and surface-modifying agent, makes nano-calcium carbonate temperature use window greatly to diminish, and reason is that conventional dispersion agent and coupling agent is at high temperature easy to decompose, cause bubble, cracking, defect, distortion etc., thereby affect outward appearance, resistance toheat and the mechanical property of material.Changing the performance of traditional calcium carbonate product, improve its application performance to meet the needs of novel material, development of new techniques, is calcium carbonate industry urgent problem.
Summary of the invention
The object of this invention is to provide a kind of can be as modified calcium carbonate of sound-absorbing filler and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
Can, as a modified calcium carbonate for sound-absorbing filler, be made by the raw material of following weight part: calcium carbonate 90-95, nano-hollow microballon 4-6, aluminosilicate fiber cotton 3-5, wild rice stem straw powder 3-4, pearlstone 2-4, activated alumina 3-4, volatile salt 2-3, polycarbonate 6-8, natural rubber latex 5-6, α-sodium olefin sulfonate 1-2, modifying titanium dioxide 3-4;
Described modifying titanium dioxide is made up of the raw material of following weight part: aluminium hydroxide 2-4, nano titanium oxide 50-60, silicon carbide 4-6, methyl methacrylate 5-7, antimonous oxide 3-4, terephthalic acid 3-4, dioctyl maleate 3-5, ethylene glycol 5-6, water 50-60; First preparation method adds methyl methacrylate, nano titanium oxide, aluminium hydroxide, ethylene glycol, water to stir, form suspension, at 45-50 DEG C, dry to water content 2-3%, then add immediately terephthalic acid, dioctyl maleate mix and blend 25-35 minute, then add all the other remaining components, under 1200-1500 rev/min of condition, stir, at 50-60 DEG C, dry, be ground into ultrafine powder and get final product.
A kind of can, as the modified calcium carbonate of sound-absorbing filler, being made by following concrete steps of the present invention:
(1) calcium carbonate, nano-hollow microballon, pearlstone, activated alumina, volatile salt, polycarbonate are added in high-speed kneading machine, be warming up between 70-80 DEG C, insulated and stirred half an hour, continue to add natural rubber latex, continue to be warming up to 110-130 DEG C, be incubated and pour out after 15-20 minute;
(2) by adding appropriate deionized water and aluminosilicate fiber cotton, wild rice stem straw powder, α-sodium olefin sulfonate by pouring out material while hot, stir and grind 2-3 hour, form suspension stand-by;
(3) suspension is mixed with modifying titanium dioxide, stir 10-15 minute under 800-1000 rev/min, dry, be ground into ultrafine powder and get final product.
The invention has the beneficial effects as follows: the present invention is by adding nano-hollow microballon and aluminosilicate fiber cotton, there is good sound absorption qualities, add vegetable fibre and crude substance, there is large specific surface area, there is sound-absorbing adsorption, add modifying titanium dioxide, increased dispersing property, be applicable to produce the auxiliary agents such as acoustical tile, acoustic panel, coating.
Specific embodiments
Below by specific examples, the present invention is described in detail.
Can be as the modified calcium carbonate of sound-absorbing filler, by following weight part (kilogram) raw material make: calcium carbonate 90, nano-hollow microballon 4, aluminosilicate fiber cotton 3, wild rice stem straw powder 3, pearlstone 2, activated alumina 3, volatile salt 2, polycarbonate 6, natural rubber latex 5, α-sodium olefin sulfonate 1, modifying titanium dioxide 3;
Described modifying titanium dioxide by following weight part (kilogram) raw material make: aluminium hydroxide 2, nano titanium oxide 50, silicon carbide 4, methyl methacrylate 5, antimonous oxide 3, terephthalic acid 3, dioctyl maleate 3, ethylene glycol 5, water 50; First preparation method adds methyl methacrylate, nano titanium oxide, aluminium hydroxide, ethylene glycol, water to stir, form suspension, at 45-50 DEG C, dry to water content 2-3%, then add immediately terephthalic acid, dioctyl maleate mix and blend 25-35 minute, then add all the other remaining components, under 1200-1500 rev/min of condition, stir, at 50-60 DEG C, dry, be ground into ultrafine powder and get final product.
A kind of can, as the modified calcium carbonate of sound-absorbing filler, being made by following concrete steps of the present invention:
(1) calcium carbonate, nano-hollow microballon, pearlstone, activated alumina, volatile salt, polycarbonate are added in high-speed kneading machine, be warming up between 70-80 DEG C, insulated and stirred half an hour, continue to add natural rubber latex, continue to be warming up to 110-130 DEG C, be incubated and pour out after 15-20 minute;
(2) by adding appropriate deionized water and aluminosilicate fiber cotton, wild rice stem straw powder, α-sodium olefin sulfonate by pouring out material while hot, stir and grind 2-3 hour, form suspension stand-by;
(3) suspension is mixed with modifying titanium dioxide, stir 10-15 minute under 800-1000 rev/min, dry, be ground into ultrafine powder and get final product.
Performance Detection to modified calcium carbonate of the present invention and ordinary calcium carbonate is compared as follows:
First measure the tap density of the forward and backward calcium carbonate of modification, then calcium carbonate good modification and unmodified water-ground limestone are joined in polyvinyl chloride resin in 15% ratio respectively, make sample, test respectively both mechanical properties, comparing result sees the following form:
As can be seen from the above table, the loose bulk density of the calcium carbonate after modification diminishes, and illustrates that calcium carbonate split fully disperses, and it can also be seen that every mechanical property of calcium carbonate is all improved after modification.
Claims (2)
1. one kind can be used as the modified calcium carbonate of sound-absorbing filler, it is characterized in that, made by the raw material of following weight part: calcium carbonate 90-95, nano-hollow microballon 4-6, aluminosilicate fiber cotton 3-5, wild rice stem straw powder 3-4, pearlstone 2-4, activated alumina 3-4, volatile salt 2-3, polycarbonate 6-8, natural rubber latex 5-6, α-sodium olefin sulfonate 1-2, modifying titanium dioxide 3-4;
Described modifying titanium dioxide is made up of the raw material of following weight part: aluminium hydroxide 2-4, nano titanium oxide 50-60, silicon carbide 4-6, methyl methacrylate 5-7, antimonous oxide 3-4, terephthalic acid 3-4, dioctyl maleate 3-5, ethylene glycol 5-6, water 50-60; First preparation method adds methyl methacrylate, nano titanium oxide, aluminium hydroxide, ethylene glycol, water to stir, form suspension, at 45-50 DEG C, dry to water content 2-3%, then add immediately terephthalic acid, dioctyl maleate mix and blend 25-35 minute, then add all the other remaining components, under 1200-1500 rev/min of condition, stir, at 50-60 DEG C, dry, be ground into ultrafine powder and get final product.
2. a kind of can, as the modified calcium carbonate of sound-absorbing filler, it is characterized in that according to claim 1, made by following concrete steps:
(1) calcium carbonate, nano-hollow microballon, pearlstone, activated alumina, volatile salt, polycarbonate are added in high-speed kneading machine, be warming up between 70-80 DEG C, insulated and stirred half an hour, continue to add natural rubber latex, continue to be warming up to 110-130 DEG C, be incubated and pour out after 15-20 minute;
(2) by adding appropriate deionized water and aluminosilicate fiber cotton, wild rice stem straw powder, α-sodium olefin sulfonate by pouring out material while hot, stir and grind 2-3 hour, form suspension stand-by;
(3) suspension is mixed with modifying titanium dioxide, stir 10-15 minute under 800-1000 rev/min, dry, be ground into ultrafine powder and get final product.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104277377A (en) * | 2014-10-31 | 2015-01-14 | 安徽省三乐门窗幕墙工程有限公司 | Heat-preservation plastic door and window filler and preparation method thereof |
CN104277376A (en) * | 2014-10-31 | 2015-01-14 | 安徽省三乐门窗幕墙工程有限公司 | Calcium carbonate filler for plastic doors and windows and preparation method of calcium carbonate filler |
CN104292704A (en) * | 2014-10-31 | 2015-01-21 | 安徽省三乐门窗幕墙工程有限公司 | Strengthening filler for plastic doors and windows and preparation method of strengthening filler |
CN104292705A (en) * | 2014-10-31 | 2015-01-21 | 安徽省三乐门窗幕墙工程有限公司 | Special calcium carbonate filler for PVC doors and windows, and preparation method thereof |
CN104292707A (en) * | 2014-10-31 | 2015-01-21 | 安徽省三乐门窗幕墙工程有限公司 | Oxidation resisting calcium carbonate filler and preparation method thereof |
CN105153853A (en) * | 2015-09-02 | 2015-12-16 | 太仓顺如成建筑材料有限公司 | Indoor coating with sound absorption function |
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US20030109617A1 (en) * | 2000-04-18 | 2003-06-12 | Mari Niinikoski | Method for pretreatment of filler, modified filler with a hydrophobic polymer and use of the hydrophobic polymer |
CN102965845A (en) * | 2012-11-22 | 2013-03-13 | 芜湖跃飞新型吸音材料股份有限公司 | PET (polyethylene glycol terephthalate) fiber/aluminum silicate fiber composite sound absorbing cotton and preparation method of PET fiber/aluminum silicate fiber composite sound absorbing cotton |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US20030109617A1 (en) * | 2000-04-18 | 2003-06-12 | Mari Niinikoski | Method for pretreatment of filler, modified filler with a hydrophobic polymer and use of the hydrophobic polymer |
CN102965845A (en) * | 2012-11-22 | 2013-03-13 | 芜湖跃飞新型吸音材料股份有限公司 | PET (polyethylene glycol terephthalate) fiber/aluminum silicate fiber composite sound absorbing cotton and preparation method of PET fiber/aluminum silicate fiber composite sound absorbing cotton |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104277377A (en) * | 2014-10-31 | 2015-01-14 | 安徽省三乐门窗幕墙工程有限公司 | Heat-preservation plastic door and window filler and preparation method thereof |
CN104277376A (en) * | 2014-10-31 | 2015-01-14 | 安徽省三乐门窗幕墙工程有限公司 | Calcium carbonate filler for plastic doors and windows and preparation method of calcium carbonate filler |
CN104292704A (en) * | 2014-10-31 | 2015-01-21 | 安徽省三乐门窗幕墙工程有限公司 | Strengthening filler for plastic doors and windows and preparation method of strengthening filler |
CN104292705A (en) * | 2014-10-31 | 2015-01-21 | 安徽省三乐门窗幕墙工程有限公司 | Special calcium carbonate filler for PVC doors and windows, and preparation method thereof |
CN104292707A (en) * | 2014-10-31 | 2015-01-21 | 安徽省三乐门窗幕墙工程有限公司 | Oxidation resisting calcium carbonate filler and preparation method thereof |
CN105153853A (en) * | 2015-09-02 | 2015-12-16 | 太仓顺如成建筑材料有限公司 | Indoor coating with sound absorption function |
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Effective date of registration: 20200521 Address after: 542808 laohu'ao (Cologne Industrial Park), Huangtian Town, Pinggui District, Hezhou City, Guangxi Zhuang Autonomous Region Patentee after: GUANGXI HEZHOU KELONG MICRO-POWDER Co.,Ltd. Address before: Gu Qiao Zhen Tong Ying community natural village of Fengtai County in Anhui province Huainan city 232100 Patentee before: FENGTAI JINGXING BIOLOGICAL TECHNOLOGY Co.,Ltd. |
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