CN104021728A - Novel material formula of high-strength adhesive and fragile paper label thereof - Google Patents
Novel material formula of high-strength adhesive and fragile paper label thereof Download PDFInfo
- Publication number
- CN104021728A CN104021728A CN201410283650.1A CN201410283650A CN104021728A CN 104021728 A CN104021728 A CN 104021728A CN 201410283650 A CN201410283650 A CN 201410283650A CN 104021728 A CN104021728 A CN 104021728A
- Authority
- CN
- China
- Prior art keywords
- fragile paper
- paper label
- layer
- strength
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention discloses a novel material formula of a high-strength adhesive. The novel material formula comprises the following raw materials by weight percent: 40-60% of acrylic resin, 15-25% of butanone, 15-25% of ethyl ester and 8-12% of cyclohexanone. The invention also provides a novel fragile paper label. The novel fragile paper label comprises a surface material layer, a mucilage glue layer and a release layer, which are sequentially laminated, wherein the mucilage glue layer is prepared by the novel material formula of the high-strength adhesive. The bonding strength is greater than the breaking strength of the surface material layer. Starting from the source, the adhesive formula of the fragile paper is improved, so that the adhesive force of the mucilage glue layer of the fragile paper label is increased, the mucilage glue layer can be better adhered to an article, and the quality of the fragile paper label is improved.
Description
Technical field
The present invention relates to the fragile paper label of a kind of high-strength structureal adhesives and formation thereof.
Background technology
Fragile paper adhesive label is important a kind of in adhesive label, and its fabric fracture strength is far below tackifier adhesive power, and it can not completely be peeled off after having stickup, not recycling feature.Fragile paper adhesive sticker plane materiel, after the operation processing such as printing, cross cutting, is made frangible label or frangible subsides, also claims the frangible quality guarantee of commodity to paste, and it is mainly used in and with some, by regular quality guarantee means, is difficult to the unconventional commodity sign method of accurate quality guarantee.Because its tensile strength is very low, very easily broken, there is shrinkability and there are to certain requirement temperature, humidity and storage life, substantially can not standing storage, so product is all to produce in time and sell in time conventionally.But according to investigations, due to each side reason, adding very sometimes industry and commerce (being used for false proof businessman at surface printing picture and text), be all to cause a lot of materials to be scrapped because of the problem on the time and in processing, cause waste, therefore, how to improve the quality of fragile paper label so that add the problem that use in man-hour becomes those skilled in the art's primary study.
Summary of the invention
In order to solve the problems of the prior art, the present invention, from source, provides a kind of fragile paper glue formula that can improve production fragile paper label quality.
To achieve these goals, the technical solution used in the present invention is as follows:
A kind of high-strength structureal adhesives new material formula, carries out proportioning by following mass percent:
As preferably, this high-strength structureal adhesives new material formula carries out proportioning by following mass percent:
Further, the present invention also provides a kind of fragile paper label, comprises and stacks gradually surface material layer, adhesive-layer and the release layer being composited, wherein, described adhesive-layer is made by above-mentioned high-strength structureal adhesives new material formula, and its bond strength is greater than the fracture strength of surface material layer.
As preferably, described surface material layer is made by easy crisp film.
As preferably, described release layer is made by copper-nickel alloy paper.
Further, this fragile paper label is composited by hot melt adhesive compounding machine.
Compared with prior art, the present invention has following beneficial effect:
The present invention is from source, by the improvement to fragile paper adhesive formula, increased the bounding force of fragile paper label adhesive-layer, can be bonded at better on object, improved the quality of fragile paper label, and after testing without noxious material, there is outstanding substantive distinguishing features and significant progressive, and the present invention is simple in structure, with low cost, easy to use safe and reliable, there is market application foreground widely, be applicable to applying.
Embodiment
Below in conjunction with embodiment, the invention will be further described, and embodiments of the present invention include but not limited to the following example.
Embodiment 1
This high-strength structureal adhesives new material formula, carries out proportioning by following mass percent:
The novel fragile paper label being formed by above-mentioned high-strength structureal adhesives new material formula, comprise and stack gradually surface material layer, adhesive-layer and the release layer being composited, wherein, described adhesive-layer is made by the sticky platform agent new material formula of above-mentioned high strength, and its bond strength is greater than the fracture strength of surface material layer.It is to be composited by hot melt adhesive compounding machine.
As preferably, described surface material layer is made by easy crisp film.
As preferably, described release layer is made by copper-nickel alloy paper.
Embodiment 2
The difference of the present embodiment and embodiment 1 is, the proportioning of described formula is:
Embodiment 3
The difference of the present embodiment and embodiment 1 is, the proportioning of described formula is:
Embodiment 4
The difference of the present embodiment and embodiment 1 is, the proportioning of described formula is:
Embodiment 5
The difference of the present embodiment and embodiment 1 is, the proportioning of described formula is:
Embodiment 6
The difference of the present embodiment and embodiment 1 is, the proportioning of described formula is:
The novel fragile paper label sample warp let-off SGS (the general notary of Switzerland) that above-described embodiment 1～6 is made detects, by " RoHS instruction 2011/65/EU " test, test result unharmful substance.As shown in table 1 below:
Table 1
Remarks: (1) 1mg/kg=1ppm=0.001%, (2) MDL=detection limits, (3) ND=does not detect (< MDL), (4) "-"=do not stipulate.
The method of testing that above-mentioned test adopts is as follows:
(1), with reference to IEC62321-5:2013, with ICP-OES, measure the content of cadmium;
(2), with reference to IEC62321-5:2013, with ICP-OES, measure plumbous content;
(3), with reference to IEC62321-4:2013, with ICP-OES, measure the content of mercury;
(4) with reference to IEC62321:2008, with the chromic content of ultraviolet-visible spectrophotometer colorimetric method for determining;
(5), with reference to IEC62321:2008, with GC-MS, measure the content of PBBs (PBBs) and PBDEs (PBDEs).
In addition, the product of above-described embodiment 1～6 is peeled off to test, control group is commercially available common fragile paper label, after labeling 1 hour, with the speed of 50 inch per minute clocks, surveys 180.Peeling force, result is as shown in table 2 below:
Table 2
Visible, fragile paper label of the present invention has better cohesive, and quality is better.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
According to above-described embodiment, just can realize well the present invention.What deserves to be explained is; under prerequisite based on said structure design, for solving same technical matters, even if some that make in the present invention are without substantial change or polishing; the essence of the technical scheme adopting is still consistent with the present invention, also should be in protection scope of the present invention.
Claims (6)
1. a high-strength structureal adhesives new material formula, is characterized in that, by following mass percent, carries out proportioning:
2. a kind of high-strength structureal adhesives new material formula according to claim 1, is characterized in that, by following mass percent, carries out proportioning:
3. a fragile paper label, it is characterized in that, comprise and stack gradually surface material layer, adhesive-layer and the release layer being composited, wherein, described adhesive-layer is made by a kind of high-strength structureal adhesives new material formula described in claim 1 or 2, and its bond strength is greater than the fracture strength of surface material layer.
4. a kind of fragile paper label according to claim 3, is characterized in that, described surface material layer is made by easy crisp film.
5. a kind of fragile paper label according to claim 3, is characterized in that, described release layer is made by copper-nickel alloy paper.
6. a kind of fragile paper label according to claim 3, is characterized in that, this fragile paper label is composited by hot melt adhesive compounding machine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410283650.1A CN104021728A (en) | 2014-06-24 | 2014-06-24 | Novel material formula of high-strength adhesive and fragile paper label thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410283650.1A CN104021728A (en) | 2014-06-24 | 2014-06-24 | Novel material formula of high-strength adhesive and fragile paper label thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104021728A true CN104021728A (en) | 2014-09-03 |
Family
ID=51438456
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410283650.1A Pending CN104021728A (en) | 2014-06-24 | 2014-06-24 | Novel material formula of high-strength adhesive and fragile paper label thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104021728A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106023797A (en) * | 2016-08-03 | 2016-10-12 | 成都天星印务股份有限公司 | Fragile paper label |
| CN106835838A (en) * | 2017-02-13 | 2017-06-13 | 深圳市冠宝胶粘制品有限公司 | Shielding fragile paper high and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280165A (en) * | 2008-05-21 | 2008-10-08 | 山东福源聚氨酯工业有限公司 | Hot-transfer thermoprinting adhesive for electrical aluminum |
| CN101928492A (en) * | 2010-09-01 | 2010-12-29 | 浙江阳阳包装有限公司 | Specific coloring agent for electric aluminum coating and preparation method thereof |
| CN103305145A (en) * | 2012-03-09 | 2013-09-18 | 罗门哈斯公司 | Primerless removable adhesive systems |
-
2014
- 2014-06-24 CN CN201410283650.1A patent/CN104021728A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101280165A (en) * | 2008-05-21 | 2008-10-08 | 山东福源聚氨酯工业有限公司 | Hot-transfer thermoprinting adhesive for electrical aluminum |
| CN101928492A (en) * | 2010-09-01 | 2010-12-29 | 浙江阳阳包装有限公司 | Specific coloring agent for electric aluminum coating and preparation method thereof |
| CN103305145A (en) * | 2012-03-09 | 2013-09-18 | 罗门哈斯公司 | Primerless removable adhesive systems |
Non-Patent Citations (2)
| Title |
|---|
| 王清成: "无苯溶剂型丙烯酸酯压敏胶粘剂的合成", 《精细化工》, vol. 21, 31 October 2004 (2004-10-31) * |
| 金银河: "《特种印刷技术及其应用》", 31 January 2008 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106023797A (en) * | 2016-08-03 | 2016-10-12 | 成都天星印务股份有限公司 | Fragile paper label |
| CN106835838A (en) * | 2017-02-13 | 2017-06-13 | 深圳市冠宝胶粘制品有限公司 | Shielding fragile paper high and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102088171B1 (en) | Adhesive layer and adhesive film | |
| JP5295533B2 (en) | Surface protective film and optical film with surface protective film | |
| JP5715857B2 (en) | Adhesive sheet peeling method | |
| TW201639935A (en) | Optical film with pressure sensitive adhesive and image display device | |
| TWI532813B (en) | Double-sided adhesive tape having improved reworkability | |
| CN102051133A (en) | Optical-use pressure-sensitive adhesive sheet | |
| CN110079219A (en) | Double-sided adhesive sheet and image display device | |
| CN109897574B (en) | Pressure-sensitive adhesive and preparation method thereof, and adhesive label and preparation method thereof | |
| CN109810658A (en) | A kind of easy-to-draw removable adhesive tape of thermoplastic elastomer (TPE) substrate and its preparation and application | |
| CN103320067A (en) | Rapid bonding hot-melt pressure-sensitive adhesive for expressing waterproof bag and preparation method of rapid bonding hot-melt pressure-sensitive adhesive | |
| MX2017005074A (en) | Pressure sensitive adhesive compositions. | |
| CN104021728A (en) | Novel material formula of high-strength adhesive and fragile paper label thereof | |
| CN108913050A (en) | A kind of high viscosity optical double-sided adhesive tape band production method | |
| CN106459678A (en) | Adhesive tape and method for disassembling electronic devices and articles | |
| KR101240621B1 (en) | Dual cure type acrylic pressure sensitive adhesive composition | |
| CN106142787B (en) | Light guide plate online laminating protective film and preparation process thereof | |
| MX2012012098A (en) | Double-sidedly self-adhesive products with high optical quality. | |
| WO2017217749A1 (en) | Binder composition for bonding polymer thermoplastic resin material, method for preparing said composition, and product bonded by said composition | |
| CN103171226A (en) | PVC (Polyvinyl Chloride) low-viscosity self-adhesive static protective film | |
| JP5620050B2 (en) | (Meth) acrylic independent adhesive film | |
| CN203311746U (en) | Waterproof adhesive label | |
| CN107163871A (en) | Anti-counterfeit adhesive tape and its manufacture method | |
| JP2004315775A (en) | Re-peelable adhesive film | |
| CN207944050U (en) | A kind of cold lamination film | |
| CN209555126U (en) | Double faced adhesive tape |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: Shouan industrial zone of Pujiang County of Chengdu City, Sichuan province 611600 (Shouan Town Park Road No. 203) Applicant after: CHENGDU T-STAR PRINTING CO., LTD. Address before: Shouan Industrial Zone Pujiang County town of Chengdu City, Sichuan province 611600 Applicant before: TianXing, Chengdu YinWu Co., Ltd |
|
| COR | Change of bibliographic data | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140903 |