CN104017306B - Antifatigue PVC cable material - Google Patents
Antifatigue PVC cable material Download PDFInfo
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- CN104017306B CN104017306B CN201410241225.6A CN201410241225A CN104017306B CN 104017306 B CN104017306 B CN 104017306B CN 201410241225 A CN201410241225 A CN 201410241225A CN 104017306 B CN104017306 B CN 104017306B
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- CN
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- Prior art keywords
- antifatigue
- cable material
- pvc cable
- termite
- pvc
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- 239000000463 material Substances 0.000 title claims abstract description 18
- 230000002929 anti-fatigue Effects 0.000 title claims abstract description 14
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 21
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 21
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 10
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000008116 calcium stearate Substances 0.000 claims abstract description 4
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 4
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims abstract description 4
- XJQPQKLURWNAAH-UHFFFAOYSA-N dihydrocapsaicin Chemical compound COC1=CC(CNC(=O)CCCCCCC(C)C)=CC=C1O XJQPQKLURWNAAH-UHFFFAOYSA-N 0.000 claims description 8
- NFHFNBFYZIJLKZ-UHFFFAOYSA-N Asarinin Natural products CC1(OCC2C1COC2c3ccc4OCOc4c3)c5ccc6OCOc6c5 NFHFNBFYZIJLKZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- RBCYRZPENADQGZ-UHFFFAOYSA-N dihydrocapsaicin Natural products COC1=CC(COC(=O)CCCCCCC(C)C)=CC=C1O RBCYRZPENADQGZ-UHFFFAOYSA-N 0.000 claims description 7
- PEYUIKBAABKQKQ-UHFFFAOYSA-N epiasarinin Natural products C1=C2OCOC2=CC(C2OCC3C2COC3C2=CC=C3OCOC3=C2)=C1 PEYUIKBAABKQKQ-UHFFFAOYSA-N 0.000 claims description 7
- PEYUIKBAABKQKQ-AFHBHXEDSA-N (+)-sesamin Chemical compound C1=C2OCOC2=CC([C@H]2OC[C@H]3[C@@H]2CO[C@@H]3C2=CC=C3OCOC3=C2)=C1 PEYUIKBAABKQKQ-AFHBHXEDSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 4
- PEYUIKBAABKQKQ-WZBLMQSHSA-N 5-[(3r,3ar,6s,6ar)-3-(1,3-benzodioxol-5-yl)-1,3,3a,4,6,6a-hexahydrofuro[3,4-c]furan-6-yl]-1,3-benzodioxole Chemical compound C1=C2OCOC2=CC([C@@H]2OC[C@H]3[C@@H]2CO[C@@H]3C2=CC=C3OCOC3=C2)=C1 PEYUIKBAABKQKQ-WZBLMQSHSA-N 0.000 description 7
- 241000256602 Isoptera Species 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009661 fatigue test Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
Abstract
The invention discloses a kind of antifatigue PVC cable material, comprise following weight parts raw material: polyvinyl chloride resin 100 parts, dioctyl phthalate (DOP) 50-70 part, erucicamide 0.2-0.8 part, calcium stearate 2-6 part, Zinic stearas 2-4 part, water-ground limestone 40-60 part.Antifatigue PVC cable material of the present invention, expressing technique excellent performance, fatigue performance is strong.
Description
Technical field
The present invention relates to a kind of PVC cable material, particularly relate to a kind of antifatigue PVC cable material.
Background technology
Polyvinyl chloride cable material is resin based on polyvinyl chloride, add stablizer, dioctyl phthalate (DOP), Di Iso Decyl Phthalate, the inorganic fillers such as the softening agent such as dioctyl terephthalate, trioctyl trimellitate and calcium carbonate, the additive such as auxiliary agent and lubricant, mediates through mixture and extrudes and the particle prepared.
But existing PVC cable material, fatigue performance is poor.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of antifatigue PVC cable material.
Technical problem to be solved by this invention is achieved by the following technical solution:
A kind of antifatigue PVC cable material, comprises following weight parts raw material: polyvinyl chloride resin 100 parts, dioctyl phthalate (DOP) 50-70 part, erucicamide 0.2-0.8 part, calcium stearate 2-6 part, Zinic stearas 2-4 part, water-ground limestone 40-60 part.
The preferred PVC-SG3 resin of polyvinyl chloride resin.
Preferably, a kind of antifatigue PVC cable material, also comprises following weight parts raw material: anti-termite agent 1-3 part.
Described anti-termite agent is one in Avrmectin, Asarinin and Dihydrocapsaicin or its mixture.
Preferably, described anti-termite agent, is made up of by weight following component: Avrmectin 70-90 part, Asarinin 5-15 part and Dihydrocapsaicin 5-15 part.
Avrmectin, No. CAS: 71751-41-2; Asarinin, No. CAS: 133-05-1; Dihydrocapsaicin, No. CAS: 19408-84-5.
Obviously, according to actual needs, oxidation inhibitor, tinting material etc. can also be added in the present invention.
Antifatigue PVC cable material of the present invention, this area universal method can be adopted to be prepared from, such as adopt following preparation technology: each starting material are mixed 6-10min on mixing machine, be that the screw extrusion press of 160-180 DEG C plastifies granulation at extrusion temperature, antifatigue PVC cable material of the present invention can be obtained.
Antifatigue PVC cable material of the present invention, expressing technique excellent performance, fatigue performance is strong.
Embodiment
Embodiment 1-5
Each raw material is taken according to embodiment 1-5 data corresponding in table 1.Each starting material are mixed 8min on mixing machine, is that the screw extrusion press of 170 DEG C plastifies granulation at extrusion temperature, antifatigue PVC cable material of the present invention can be obtained.
Table 1: antifatigue PVC cable material formula table unit: kilogram
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| PVC-SG3 resin | 100 | 100 | 100 | 100 | 100 |
| Dioctyl phthalate (DOP) | 60 | 60 | 60 | 60 | 60 |
| Erucicamide | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| Calcium stearate | 4 | 4 | 4 | 4 | 4 |
| Zinic stearas | 3 | 3 | 3 | 3 | 3 |
| Water-ground limestone | 50 | 50 | 50 | 50 | 50 |
| Avrmectin | / | 1.6 | 1.6 | 1.6 | / |
| Asarinin | / | 0.2 | 0.4 | / | 1 |
| Dihydrocapsaicin | / | 0.2 | / | 0.4 | 1 |
Test case 1
The resistance to fatigue test of embodiment 2: can alternating bending 60,000 times.
Test case 2:
Adopt GB/T2951.38-1986 electric wire termite test method, carry out knocking down method test.Test piece: 50mm × 50mm × 1mm.
Table 2: anti-ant performance test table
| Termite knockdown time KT50, min | |
| Embodiment 1 | Termite is without knocking down, invalid |
| Embodiment 2 | 141 |
| Embodiment 3 | 182 |
| Embodiment 4 | 165 |
| Embodiment 5 | 495 |
Avrmectin has stronger toxic action to termite; Asarinin and Dihydrocapsaicin belong to biological anti-termite agent, and the toxicity of raw material own is less, but anti-ant effect is all obvious poorer than Avrmectin.The present invention is by after the three kinds of composite uses of anti-termite agent of Avrmectin, Asarinin and Dihydrocapsaicin, and synergy, termite knockdown time obviously reduces, and anti-ant performance is good.
Claims (1)
1. antifatigue PVC cable material, is characterized in that, comprises following weight parts raw material: polyvinyl chloride resin 100 parts, dioctyl phthalate (DOP) 50-70 part, erucicamide 0.2-0.8 part, calcium stearate 2-6 part, Zinic stearas 2-4 part, water-ground limestone 40-60 part, anti-termite agent 1-3 part;
Described anti-termite agent, is made up of by weight following component: Avrmectin 70-90 part, Asarinin 5-15 part and Dihydrocapsaicin 5-15 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410241225.6A CN104017306B (en) | 2014-06-01 | 2014-06-01 | Antifatigue PVC cable material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410241225.6A CN104017306B (en) | 2014-06-01 | 2014-06-01 | Antifatigue PVC cable material |
Publications (2)
| Publication Number | Publication Date |
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| CN104017306A CN104017306A (en) | 2014-09-03 |
| CN104017306B true CN104017306B (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410241225.6A Active CN104017306B (en) | 2014-06-01 | 2014-06-01 | Antifatigue PVC cable material |
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| Country | Link |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315579A (en) * | 2015-10-30 | 2016-02-10 | 安徽天星光纤通信设备有限公司 | Anti-fatigue cable material and preparation method thereof |
| CN105504583A (en) * | 2015-12-31 | 2016-04-20 | 东莞市祺龙电业有限公司 | Anti-termite PVC (Polyvinyl Chloride) modified material and preparation method thereof |
| CN105949666A (en) * | 2016-06-18 | 2016-09-21 | 苏州市吴通光电科技有限公司 | Preparation method of cable sheath capable of emitting special smell |
| CN107011644A (en) * | 2017-04-09 | 2017-08-04 | 福建华塑新材料有限公司 | A kind of polysiloxane polycarbonate copolymeric material and preparation method thereof |
| CN107418175A (en) * | 2017-04-25 | 2017-12-01 | 福建华塑新材料有限公司 | One kind is applied to remote control eyeglass with high infrared ray makrolon and its preparation technology thoroughly |
| CN107083039A (en) * | 2017-04-25 | 2017-08-22 | 福建华塑新材料有限公司 | A kind of control box shell polycarbonate compositions and its preparation technology |
| CN107266770A (en) * | 2017-07-26 | 2017-10-20 | 合肥尚强电气科技有限公司 | A kind of endurance fire-resistant cable material and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1226383A (en) * | 1998-12-31 | 1999-08-25 | 武汉市白蚁防治研究所 | Composite biological pesticide for killing termite and caterpillar |
| CN101798417B (en) * | 2010-03-26 | 2011-12-07 | 华南理工大学 | Anti-termite and coloring functional master batch for plastic and preparation method thereof |
| CN102446586B (en) * | 2011-08-30 | 2013-08-28 | 上海贝恩科电缆有限公司 | Rat-proof termite-proof low-smoke low-halogen leadless flame-retardant control cable for elevator shaft |
| JP2013129776A (en) * | 2011-12-22 | 2013-07-04 | Hitachi Cable Ltd | Vinyl chloride resin composition, and electric wire and cable using the same |
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| CN104017306A (en) | 2014-09-03 |
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Inventor after: Zhang Jianfeng Inventor before: Huang Yi |
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Effective date of registration: 20170330 Address after: 215000 Shaxi City, Jiangsu province Taicang Town, Hong Kong Village Patentee after: Taicang Meite plastic products factory Address before: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20170330 Address after: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 200137 room 1F79, building, No. 528, Yang Gao Bei Road, Shanghai, Pudong New Area Patentee before: SHANGHAI TAOHONG CHEMICAL TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20200728 Address after: 430000 705, 706a, building 1, Huigu spacetime, No.206, laowuhuang highway, Donghu New Technology Development Zone, Wuhan City, Hubei Province Patentee after: Wuhan Tuozhijia Information Technology Co.,Ltd. Address before: 215000 Shaxi City, Jiangsu province Taicang Town, Hong Kong Village Patentee before: Taicang Meite plastic products factory |
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Effective date of registration: 20201109 Address after: 241000 No.6, Erba Road, Wucheng Town, Wuwei City, Wuhu City, Anhui Province Patentee after: Du Lihong Address before: 430000 705, 706a, building 1, Huigu spacetime, No.206, laowuhuang highway, Donghu New Technology Development Zone, Wuhan City, Hubei Province Patentee before: Wuhan Tuozhijia Information Technology Co.,Ltd. |
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Effective date of registration: 20201201 Address after: 233000 Room 102 north, No.11, No.2 building, liukm Huayuan commercial building, Changqing Township, Yuhui District, Bengbu City, Anhui Province Patentee after: Anhui Licha Information Technology Co.,Ltd. Address before: 241000 No.6, Erba Road, Wucheng Town, Wuwei City, Wuhu City, Anhui Province Patentee before: Du Lihong |
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Effective date of registration: 20210324 Address after: 214401 area B-4, Second Industrial Road, industrial park, Qingyang Town, Jiangyin City, Wuxi City, Jiangsu Province Patentee after: Wuxi Huacheng Cable Co.,Ltd. Address before: 233000 Room 102 north, No.11, No.2 building, liukm Huayuan commercial building, Changqing Township, Yuhui District, Bengbu City, Anhui Province Patentee before: Anhui Licha Information Technology Co.,Ltd. |