CN104017300A - Flame-retardant insulation polyvinyl chloride cable material - Google Patents
Flame-retardant insulation polyvinyl chloride cable material Download PDFInfo
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- CN104017300A CN104017300A CN201410239948.2A CN201410239948A CN104017300A CN 104017300 A CN104017300 A CN 104017300A CN 201410239948 A CN201410239948 A CN 201410239948A CN 104017300 A CN104017300 A CN 104017300A
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- polyvinyl chloride
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- chloride cable
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Abstract
A flame-retardant insulation polyvinyl chloride cable material is disclosed. The cable material comprises following raw materials by weight: 100 parts of PVC resin, 20-30 parts of pentaerythritol oleate, 5-15 parts of trioctyl trimellitate, 2-10 parts of chlorinated paraffin, 2-6 parts of calcium stearate, 2-6 parts of zinc stearate, 1-3 parts of a lubricant, 0.2-0.8 part of an anti-oxidant, 3-9 parts of calcium carbonate and 3-7 parts of antimony oxide. The cable material has good flame retardant and insulating properties and has good shaping and processing properties.
Description
Technical field
The present invention relates to a kind of polyvinyl chloride cable material, relate in particular to a kind of fire retardant insulating grade polyvinyl chloride CABLE MATERIALS.
Background technology
Polyvinyl chloride cable material is taking polyvinyl chloride as base resin, add stablizer, dioctyl phthalate (DOP), Di Iso Decyl Phthalate, the inorganic fillers such as the softening agent such as dioctyl terephthalate, trioctyl trimellitate and calcium carbonate, the additive such as auxiliary agent and lubricant, mediates the particle of extruding and prepare through mixture.
Conventional P VC wire cable material is because having become the important factor of restriction electric wire in applications such as electric installation, Infrastructure, fundamental construction containing objectionable impuritiess such as a certain amount of heavy metal elements.For reducing exploitation that threat to social environment and pollution realize the Sustainable development environment-friendly PVC CABLE MATERIALS of enterprise, to protect mankind health maintenance ecotope becomes the theme of current cable material exploitation.
Enter 21 century, along with the raising of mankind's environmental consciousness and the people concern to self health, environmental problem becomes the focus that human society is paid close attention to, and the use of objectionable impurities is limited in many countries, area and organize and formulated one after another strict standard and regulation.Particularly European Union specifies that the product that later enters European Union member countries on July 1st, 2006 must meet environmental protection ROHS regulation, otherwise product cannot enter European Union member countries at all.Tradition material, because of containing objectionable impuritiess such as a certain amount of heavy metal elements, has become the important factor of restriction in applications such as electric installation, Infrastructure, fundamental construction.For to protect mankind health, safeguard ecotope, reduce threat and pollution to social environment, realize Sustainable development, the exploitation of environment-friendly cable material has become the theme of current cable material exploitation.
And, polyvinyl chloride cable material of the prior art, flame retardant effect is unsatisfactory.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of fire retardant insulating grade polyvinyl chloride CABLE MATERIALS.
Technical problem to be solved by this invention is achieved by the following technical solution:
A kind of fire retardant insulating grade polyvinyl chloride CABLE MATERIALS, comprise following weight parts raw material: 100 parts of polyvinyl chloride resins, PETO 20-30 part, trioctyl trimellitate 5-15 part, clorafin 2-10 part, calcium stearate 2-6 part, Zinic stearas 2-6 part, lubricant 1-3 part, oxidation inhibitor 0.2-0.8 part, calcium carbonate 3-9 part, antimonous oxide 3-7 part.
The preferred PVC-SG3 resin of polyvinyl chloride resin.
The Main Function of softening agent is melt temperature and the melt viscosity that reduces polymkeric substance, and then reduces the processing temperature of polymkeric substance; Give polymer product with flexibility and resistance to low temperature.In the present invention, select PETO, clorafin and the composite plasticizer combinations of trioctyl trimellitate, its comprehensive plasticizing efficiency is high, volatility is very little, transport property is little.
PETO, English name: Pentaerythritol Oleate, is called for short PETO, No. CAS: 19321-40-5.Clorafin, No. CAS: 63449-39-8.Trioctyl trimellitate, No. CAS: 3319-33-1.
The present invention is as the formulating of recipe of environment protection PVC insulation material; its stablizer should be containing the heavy metal element such as plumbous Pb, cadmium Cd, mercury Hg, sexavalent chrome Cr6 that human body is had to harm; the present invention selects calcium stearate and its thermostability of Zinic stearas one package stabilizer to approach or exceedes some barium/cadmium stabilizer, Pb stabilizer and can substitute poisonous stablizer, and good weatherability is nontoxic has the good transparency is of value to HUMAN HEALTH and environment protection.
Adding of weighting agent calcium carbonate, is mainly the consumption that reduces product cost minimizing resin, can also improve the electrical property of plastics simultaneously.
Lubricant, preferably polyethylene wax.
Adding of oxidation inhibitor, can effectively suppress ageing of plastics, in the present invention, can select the oxidation inhibitor that the industry is general, as antioxidant 1010, antioxidant 1076, irgasfos 168, DSTDP, DLTDP, BHT, CA oxidation inhibitor etc.
Antimonous oxide, a kind of effectively fire-retardant for plastic.
Preferably, a kind of fire retardant insulating grade polyvinyl chloride CABLE MATERIALS, also comprises following weight parts raw material: anti-termite agent 1-3 part.
Described anti-termite agent is a kind of or its mixture in Avrmectin, Asarinin and Dihydrocapsaicin.
Preferably, described anti-termite agent, is made up of by weight following component: Avrmectin 70-90 part, Asarinin 5-15 part and Dihydrocapsaicin 5-15 part.
Avrmectin, No. CAS: 71751-41-2; Asarinin, No. CAS: 133-05-1; Dihydrocapsaicin, No. CAS: 19408-84-5.
Fire retardant insulating grade polyvinyl chloride CABLE MATERIALS of the present invention, can adopt this area universal method to be prepared from, for example adopt following preparation technology: each starting material are mixed to 6-10min on mixing machine, be to plastify granulation on two rank screw extrusion press of 130-160 DEG C at extrusion temperature, can make fire retardant insulating grade polyvinyl chloride CABLE MATERIALS of the present invention.
Fire retardant insulating grade polyvinyl chloride CABLE MATERIALS of the present invention, fire-retardant and insulating property are better, and there is good moulding processability.
Embodiment
Embodiment 1-5
Take each raw material according to corresponding embodiment 1-5 data in table 1.Each starting material are mixed to 8min on high-speed mixer, are to plastify granulation on two rank screw extrusion press of 150 DEG C at extrusion temperature, can make fire retardant insulating grade polyvinyl chloride CABLE MATERIALS of the present invention.
Again this fire retardant insulating grade polyvinyl chloride CABLE MATERIALS mold pressing 15min on 170 DEG C of presses is made to test piece, for experiment.
Table 1: fire retardant insulating grade polyvinyl chloride CABLE MATERIALS formula table unit: kilogram
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| PVC-SG3 resin 100 | 100 | 100 | 100 | 100 |
| PETO 25 | 25 | 25 | 25 | 25 |
| Trioctyl trimellitate 10 | 10 | 10 | 10 | 10 |
| Clorafin 6 | 6 | 6 | 6 | 6 |
| Calcium stearate 4 | 4 | 4 | 4 | 4 |
| Zinic stearas 4 | 4 | 4 | 4 | 4 |
| Polyethylene wax 2 | 2 | 2 | 2 | 2 |
| Antioxidant 1010 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| Calcium carbonate 6 | 6 | 6 | 6 | 6 |
| Antimonous oxide 5 | 5 | 5 | 5 | 5 |
| Avrmectin/ | 1.6 | 1.6 | 1.6 | / |
| Asarinin | / | 0.2 | 0.4 | / | 1 |
| Dihydrocapsaicin | / | 0.2 | / | 0.4 | 1 |
Test case 1
Table 2: CABLE MATERIALS performance test table
| Test event | Embodiment 1 | Embodiment 2 | Blank example |
| Oxygen index, % | 36.2 | 36.0 | 33.5 |
| 200 DEG C of heat-stable times, min | 188 | 185 | 125 |
Blank example and embodiment 1 fill a prescription basic identical, and difference is only: blank example is not added fire retardant antimonous oxide.
Test case 2:
Adopt GB/T2951.38-1986 electric wire termite test method, knock down method test.Test piece: 50mm × 50mm × 1mm.
Table 3: anti-ant performance test table
| ? | Termite is knocked down time KT50, min |
| Embodiment 1 | Termite is without knocking down, invalid |
| Embodiment 2 | 123 |
| Embodiment 3 | 155 |
| Embodiment 4 | 137 |
| Embodiment 5 | 424 |
Avrmectin has stronger toxic action to termite; Asarinin and Dihydrocapsaicin belong to biological anti-termite agent, and the toxicity of raw material own is less, but anti-ant effect is all obviously poor than Avrmectin.The present invention is after Avrmectin, Asarinin and three kinds of composite uses of anti-termite agent of Dihydrocapsaicin, synergy, and the termite time of knocking down obviously reduces, and anti-ant performance is good.
Claims (5)
1. fire retardant insulating grade polyvinyl chloride CABLE MATERIALS, it is characterized in that, comprise following weight parts raw material: 100 parts of polyvinyl chloride resins, PETO 20-30 part, trioctyl trimellitate 5-15 part, clorafin 2-10 part, calcium stearate 2-6 part, Zinic stearas 2-6 part, lubricant 1-3 part, oxidation inhibitor 0.2-0.8 part, calcium carbonate 3-9 part, antimonous oxide 3-7 part.
2. fire retardant insulating grade polyvinyl chloride CABLE MATERIALS as claimed in claim 1, is characterized in that, also comprises following weight parts raw material: anti-termite agent 1-3 part.
3. fire retardant insulating grade polyvinyl chloride CABLE MATERIALS as claimed in claim 2, is characterized in that, described anti-termite agent is made up of by weight following component: Avrmectin 70-90 part, Asarinin 5-15 part and Dihydrocapsaicin 5-15 part.
4. the fire retardant insulating grade polyvinyl chloride CABLE MATERIALS as described in any one in claim 1-3, is characterized in that, described polyvinyl chloride resin is PVC-SG3 resin.
5. the fire retardant insulating grade polyvinyl chloride CABLE MATERIALS as described in any one in claim 1-3, is characterized in that, described lubricant is polyethylene wax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410239948.2A CN104017300B (en) | 2014-06-01 | 2014-06-01 | Fire retardant insulating grade polyvinyl chloride CABLE MATERIALS |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410239948.2A CN104017300B (en) | 2014-06-01 | 2014-06-01 | Fire retardant insulating grade polyvinyl chloride CABLE MATERIALS |
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| CN104017300A true CN104017300A (en) | 2014-09-03 |
| CN104017300B CN104017300B (en) | 2016-04-20 |
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| CN201410239948.2A Expired - Fee Related CN104017300B (en) | 2014-06-01 | 2014-06-01 | Fire retardant insulating grade polyvinyl chloride CABLE MATERIALS |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104341676A (en) * | 2014-11-03 | 2015-02-11 | 安徽天元电缆有限公司 | Novel low-smoke zero halogen flame-retardant cable material |
| CN104974448A (en) * | 2015-07-08 | 2015-10-14 | 常州市诚天电子有限公司 | Cable material based on PVC material and preparation method thereof |
| CN104987617A (en) * | 2015-06-26 | 2015-10-21 | 佛山市粤佳信电线电缆有限公司 | Household appliance environmental protection cable material |
| CN106832687A (en) * | 2017-03-22 | 2017-06-13 | 安徽星鑫化工科技有限公司 | A kind of preparation method of the hollow inexpensive lightweight CABLE MATERIALS of calcium carbonate crosslinking |
| CN106977868A (en) * | 2017-03-22 | 2017-07-25 | 合肥浦尔菲电线科技有限公司 | The cable protective sleeve and its manufacture craft of a kind of rat-and-ant proof |
| CN107619551A (en) * | 2017-08-21 | 2018-01-23 | 无锡市苏南电缆有限公司 | A kind of improved fire-resistant cable material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1847304A (en) * | 2005-04-15 | 2006-10-18 | 江苏圣安电缆有限公司 | Environment friendly soft PVC plastic without heavy metal for electric wire and cable |
| CN101955618A (en) * | 2010-10-15 | 2011-01-26 | 镇江市华银仪表电器有限公司 | Novel environment-friendly polyvinyl chloride cable material |
| CN102446586A (en) * | 2011-08-30 | 2012-05-09 | 上海贝恩科电缆有限公司 | Rat-proof termite-proof low-smoke low-halogen leadless flame-retardant control cable for elevator shaft |
-
2014
- 2014-06-01 CN CN201410239948.2A patent/CN104017300B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1847304A (en) * | 2005-04-15 | 2006-10-18 | 江苏圣安电缆有限公司 | Environment friendly soft PVC plastic without heavy metal for electric wire and cable |
| CN101955618A (en) * | 2010-10-15 | 2011-01-26 | 镇江市华银仪表电器有限公司 | Novel environment-friendly polyvinyl chloride cable material |
| CN102446586A (en) * | 2011-08-30 | 2012-05-09 | 上海贝恩科电缆有限公司 | Rat-proof termite-proof low-smoke low-halogen leadless flame-retardant control cable for elevator shaft |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104341676A (en) * | 2014-11-03 | 2015-02-11 | 安徽天元电缆有限公司 | Novel low-smoke zero halogen flame-retardant cable material |
| CN104987617A (en) * | 2015-06-26 | 2015-10-21 | 佛山市粤佳信电线电缆有限公司 | Household appliance environmental protection cable material |
| CN104974448A (en) * | 2015-07-08 | 2015-10-14 | 常州市诚天电子有限公司 | Cable material based on PVC material and preparation method thereof |
| CN106832687A (en) * | 2017-03-22 | 2017-06-13 | 安徽星鑫化工科技有限公司 | A kind of preparation method of the hollow inexpensive lightweight CABLE MATERIALS of calcium carbonate crosslinking |
| CN106977868A (en) * | 2017-03-22 | 2017-07-25 | 合肥浦尔菲电线科技有限公司 | The cable protective sleeve and its manufacture craft of a kind of rat-and-ant proof |
| CN107619551A (en) * | 2017-08-21 | 2018-01-23 | 无锡市苏南电缆有限公司 | A kind of improved fire-resistant cable material |
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| CN104017300B (en) | 2016-04-20 |
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Inventor after: Cheng Jing Inventor before: Huang Yi |
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Effective date of registration: 20160620 Address after: 334100 Futian Road, Shangrao Economic Development Zone, Jiangxi, 8 Patentee after: Jiangxi Hanguang cable Limited by Share Ltd Address before: 200137 room 1F79, building, No. 528, Yang Gao Bei Road, Shanghai, Pudong New Area Patentee before: Shanghai Taohong Chemical Technology Co., Ltd. |
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