CN104017156A - Tourmaline sponge and preparation method thereof - Google Patents
Tourmaline sponge and preparation method thereof Download PDFInfo
- Publication number
- CN104017156A CN104017156A CN201410266867.1A CN201410266867A CN104017156A CN 104017156 A CN104017156 A CN 104017156A CN 201410266867 A CN201410266867 A CN 201410266867A CN 104017156 A CN104017156 A CN 104017156A
- Authority
- CN
- China
- Prior art keywords
- parts
- tourmaline
- sponge
- catalyzer
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses tourmaline sponge which comprises the following raw materials by weight parts: 50-80 parts of polyether polyol, 10-30 parts of polymer polyol, 30-60 parts of isocyanate, 0.2-0.5 part of catalyst, 3-8 parts of tourmaline powder and 2-4 parts of foamer water. A preparation method of the tourmaline sponge comprises the following steps of adding the catalyst into polyether polyol and polymer polyol according to the ratio, adding isocyanate for stirring, adding the tourmaline powder for stirring, uniformly mixing the raw materials, conveying a mixture into a foaming box at the speed of 150-300kg/min, and foaming at 35-50 DEG C for 2-4 minutes. The sponge has the characteristics of low heating speed and high heat dissipation speed, an effect of promoting blood circulation of a human body and a certain health effect.
Description
technical field:
The invention belongs to and relate to a kind of sponge, be specifically related to a kind of Tourmaline sponge with health-care effect, also relate to the preparation method of Tourmaline sponge.
background technology:
Along with improving constantly of people's living standard, people are also more and more higher to the requirement of sponge product.People, in the time selecting sponge, not only consider its sense of touch and elasticity, are more prone to select to have functional good sponge product.Quick heating after at present mostly sponge exists the sun to shine, the problem of weak heat-dissipating, the high temperature of common sponge easily makes people suffer from a series of disease, never causes uncomfortablely, and common sponge does not possess nourishing function yet.
Tourmaline claims again tourmalinite, it is the ring texture silicate minerals of aluminium taking boracic as feature, sodium, iron, magnesium, lithium, its maximum advantage is exactly to produce the permanent weak current of 0.06 milliampere, with current capacity by human nerve seemingly, can stimulate circulation smooth and easy.People have begun one's study Tourmaline have been applied in sponge production.Chinese patent CN101172611A discloses a kind of Verdelite sponge and preparation method thereof, tourmalinite or tourmaline composite are joined in common sponge, sponge is had and heat up slowly, rapid heat dissipation, the functions such as anion releasing, its shortcoming is: add tourmalinite in injection molding shaping operation, tourmalinite is skewness in cavernous body, affects its health-care effect.
summary of the invention:
The object of the invention is to for deficiency of the prior art, a kind of heat up slow, rapid heat dissipation are provided, promote the Tourmaline sponge of blood circulation of human body.
For solving the problems of the technologies described above, the technical solution used in the present invention is: according to the weight proportion in preparation process, comprise following material: 50～80 parts of polyether glycols, 10～30 parts of polymer polyatomic alcohols, 30～60 parts of isocyanic ester, 0.2～0.5 part of catalyzer, 3～8 parts of Tourmaline powders, 2～4 parts, whipping agent water.
Further, according to the weight proportion in preparation process, comprise following material: 60～70 parts of polyether glycols, 15～25 parts of polymer polyatomic alcohols, 45～50 parts of isocyanic ester, 0.3～0.4 part of catalyzer, 5～6 parts of Tourmaline powders, 2.5～3 parts, whipping agent water.
Further, the particle diameter of described Tourmaline powder is 650～750 orders.
Further, the particle diameter of described Tourmaline powder is 700 orders.
Further, described catalyzer is triethylene diamine.
The present invention also provides the preparation method of a kind of Tourmaline sponge, make through batching, foaming, moulding and cutting step: in proportion catalyzer is added in polyether glycol and polymer polyatomic alcohol, then add isocyanic ester to stir, add again Tourmaline powder to stir, after mixing, raw material is delivered in foam box with the flow of 150～300 kg/minute, under 35～50 DEG C of conditions, foam, the time is 2～4 minutes.
Beneficial effect of the present invention:
1, sponge of the present invention has the feature of slow, the rapid heat dissipation of heating up and promotes the effect of blood circulation of human body, has certain health-care effect;
2, the present invention by adding Tourmaline powder in sponge material, and together foaming is made Tourmaline sponge, can not reduce the soft comfort level of sponge;
3, by method of the present invention, Tourmaline powder be uniformly distributed with sponge in, the good hand touch of sponge, the magnetic physiotherapeutic effect of Tourmaline is better brought into play.
embodiment:
Below in conjunction with specific embodiment, technical scheme of the present invention is elaborated.
Embodiment 1
A kind of Tourmaline sponge, is made up of the component of following weight part: 50 parts of polyether glycols, 10 parts of polymer polyatomic alcohols, 30 parts of isocyanic ester, 0.2 part of catalyzer, 3 parts of Tourmaline powders, 2 parts, whipping agent water.
In proportion catalyzer is added in polyether glycol and polymer polyatomic alcohol, then sneak into isocyanic ester and stir, then add Tourmaline powder to stir, after raw material mixes, be delivered in foam box with the flow of 150～300 kg/minute, under 35～50 DEG C of conditions, foam, the time is 2～4 minutes.
Embodiment 2
A kind of Tourmaline sponge, is made up of the component of following weight part: 65 parts of polyether glycols, 20 parts of polymer polyatomic alcohols, 50 parts of isocyanic ester, 0.3 part of catalyzer, 5 parts of Tourmaline powders, 2.5 parts, whipping agent water.
Embodiment 3
A kind of Tourmaline sponge, is made up of the component of following weight part: 80 parts of polyether glycols, 30 parts of polymer polyatomic alcohols, 60 parts of isocyanic ester, 0.5 part of catalyzer, 8 parts of Tourmaline powders, 4 parts, whipping agent water.
Adopt simple type negative ion tester to detect sponge.
The performance test results of Tourmaline sponge of the present invention is as following table.
| ? | Anion releasing | Far infrared wave (um) | Bioelectric current (mA) |
| Embodiment 1 | Have | 2-8 | 0.04 |
| Embodiment 2 | Have | 3-8 | 0.04 |
| Embodiment 3 | Have | 4-10 | 0.05 |
Claims (6)
1. a Tourmaline sponge, it is characterized in that: according to the weight proportion in preparation process, comprise following material: 50～80 parts of polyether glycols, 10～30 parts of polymer polyatomic alcohols, 30～60 parts of isocyanic ester, 0.2～0.5 part of catalyzer, 3～8 parts of Tourmaline powders, 2～4 parts, whipping agent water.
2. a kind of Tourmaline sponge according to claim 1, it is characterized in that: according to the weight proportion in preparation process, comprise following material: 60～70 parts of polyether glycols, 15～25 parts of polymer polyatomic alcohols, 45～50 parts of isocyanic ester, 0.3～0.4 part of catalyzer, 5～6 parts of Tourmaline powders, 2.5～3 parts, whipping agent water.
3. a kind of Tourmaline sponge according to claim 1, is characterized in that: the particle diameter of described Tourmaline powder is 650～750 orders.
4. a kind of Tourmaline sponge according to claim 1, is characterized in that: the particle diameter of described Tourmaline powder is 700 orders.
5. a kind of Tourmaline sponge according to claim 1, is characterized in that: described catalyzer is triethylene diamine.
6. the preparation method of a Tourmaline sponge claimed in claim 1, make through batching, foaming, moulding and cutting step, it is characterized in that: in proportion catalyzer is added in polyether glycol and polymer polyatomic alcohol, then add isocyanic ester to stir, add again Tourmaline powder to stir, after raw material mixes, be delivered in foam box with the flow of 150～300 kg/minute, under 35～50 DEG C of conditions, foam, the time is 2～4 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410266867.1A CN104017156A (en) | 2014-06-16 | 2014-06-16 | Tourmaline sponge and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410266867.1A CN104017156A (en) | 2014-06-16 | 2014-06-16 | Tourmaline sponge and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104017156A true CN104017156A (en) | 2014-09-03 |
Family
ID=51434187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410266867.1A Pending CN104017156A (en) | 2014-06-16 | 2014-06-16 | Tourmaline sponge and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104017156A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111607063A (en) * | 2020-06-05 | 2020-09-01 | 浙江国顺富诗曼智能家居有限公司 | Negative oxygen ion sponge and composition and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457017A (en) * | 2007-12-13 | 2009-06-17 | 赵勐 | Polyurethane composite material releasing negative ion and preparation technique thereof |
| CN101463187A (en) * | 2007-12-19 | 2009-06-24 | 秦荣 | Tourmaline polyether type sponge material, and production method and use thereof |
| CN101709143A (en) * | 2009-12-31 | 2010-05-19 | 南通恒康海绵制品有限公司 | Novel ventilated slow-resilience sponge |
| CN102212265A (en) * | 2011-05-12 | 2011-10-12 | 中国科学院合肥物质科学研究院 | Preparation method for electroconductive polyurethane complex with anion releasing function |
| CN103739825A (en) * | 2013-12-20 | 2014-04-23 | 苏州市万泰真空炉研究所有限公司 | Preparation method of novel electromagnetic shielding rigid polyurethane foaming plastic |
-
2014
- 2014-06-16 CN CN201410266867.1A patent/CN104017156A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457017A (en) * | 2007-12-13 | 2009-06-17 | 赵勐 | Polyurethane composite material releasing negative ion and preparation technique thereof |
| CN101463187A (en) * | 2007-12-19 | 2009-06-24 | 秦荣 | Tourmaline polyether type sponge material, and production method and use thereof |
| CN101709143A (en) * | 2009-12-31 | 2010-05-19 | 南通恒康海绵制品有限公司 | Novel ventilated slow-resilience sponge |
| CN102212265A (en) * | 2011-05-12 | 2011-10-12 | 中国科学院合肥物质科学研究院 | Preparation method for electroconductive polyurethane complex with anion releasing function |
| CN103739825A (en) * | 2013-12-20 | 2014-04-23 | 苏州市万泰真空炉研究所有限公司 | Preparation method of novel electromagnetic shielding rigid polyurethane foaming plastic |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111607063A (en) * | 2020-06-05 | 2020-09-01 | 浙江国顺富诗曼智能家居有限公司 | Negative oxygen ion sponge and composition and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103601468B (en) | The health tile of anion and far infrared can be produced | |
| CN105013087A (en) | Ingredients, a preparation method and application of an organic material comprising magnet, far-infrared and negative ion materials | |
| CN104356352A (en) | Sponge and preparation method thereof | |
| CN104875320A (en) | Latex mattress production process | |
| MX2013006859A (en) | Improved nutritional composition, especially for infants, with particular fat particles. | |
| CN105254327A (en) | Environment-friendly autoclaved aerated concrete block and preparation method thereof | |
| CN105879240A (en) | Far-infrared negative ion health care pad | |
| CN104017156A (en) | Tourmaline sponge and preparation method thereof | |
| CN104816422B (en) | A kind of latex product production technology | |
| CN105949785A (en) | Preparation method of high-toughness antimicrobial dough kneading mat | |
| CN1961989A (en) | Far infrared magnetic patch for physical therapy and production method thereof | |
| CN103817946B (en) | Heat insulation pad for enveloping production technology and foaming die cutting die before in a kind of automobile | |
| CN104002605B (en) | A kind of processing technology of anti-scald pottery edge silverware ware | |
| CN106173960A (en) | A kind of konjak noodle | |
| CN104151812A (en) | Cassia seed-containing negative ion memory cotton and making method thereof | |
| CN104013517A (en) | High-energy health care plate composite material and preparation method thereof | |
| CN104446415A (en) | Radiation absorption material and preparation method thereof | |
| CN106009198A (en) | Polyethylene hose filling material and production technology thereof | |
| CN107174073A (en) | A kind of preparation method of sedative health-care straw mat | |
| CN108485041A (en) | Far infrared material for shoes preparation method based on graphene technology | |
| CN106177370A (en) | A kind of ointment treating chilblain | |
| CN106234998A (en) | A kind of Konja health-care noodles | |
| CN102524839A (en) | Processing method for soft-shelled turtle eggembryosin and finished product | |
| KR20160111219A (en) | Manufacturing method of bedding material for pen | |
| CN101172611A (en) | Verdelite sponge and method of manufacturing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140903 |