CN108485041A - Far infrared material for shoes preparation method based on graphene technology - Google Patents
Far infrared material for shoes preparation method based on graphene technology Download PDFInfo
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- CN108485041A CN108485041A CN201710850619.5A CN201710850619A CN108485041A CN 108485041 A CN108485041 A CN 108485041A CN 201710850619 A CN201710850619 A CN 201710850619A CN 108485041 A CN108485041 A CN 108485041A
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- Prior art keywords
- graphene
- far infrared
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- talcum powder
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0853—Ethene vinyl acetate copolymers
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention relates to a kind of far infrared material for shoes based on graphene technology, the parts by weight of constitutive material are：Ethylene-vinyl acetate 50 80,Ethylene octene copolymer 20 50,Ethylene propylene diene rubber 3 10,Graphene powder 0.5 5,Talcum powder 3 15,Stearic acid 0.3 1,Zinc stearate 0.5 1.5,Zinc oxide 13,Crosslinking agent 0.5 1.5,Foaming agent 15,Pass through the basic principle of following assembly apparatus,To realize that the sole generates heat and plays the process characteristic of far-infrared functional,With the fever process of graphene film piece,Far infrared heat energy can be transmitted to human body,The warm of generation distributes from inside to outside,This action intensity,In addition to playing warming basic function,Telangiectasis can also be made,It promotes blood circulation,Strengthen the metabolism between each tissue,Increase the power of regeneration of tissue,Improve the immunocompetence of body,Adjust autonomic nerve,To play the role of health care.
Description
Technical field
The invention belongs to footwear material technical field, the far infrared material for shoes system based on graphene technology is concretely related to
Preparation Method.
Background technology
Shoes are one of indispensable requisites in people's daily life.With the improvement of living standards with science and technology into
Step, higher requirements are also raised for comfort and functionality of the people to shoes.But existing footwear material is normally only by weaving
The homogenous materials such as object, rubber or leather are constituted, and do not have healthcare function.
103570999 A of Chinese patent application CN disclose a kind of far infrared footwear material, and far-infared ceramic powder is added in rubber
As footwear material, far-infared ceramic powder can reflect the far infrared that the wavelength that human body needs most is 4-14 μm, while use one
After the section time, the problems such as far-infared ceramic powder function and effect unobvious, causes, and the sole practicability is not strong, and graphene is relatively remote
Performance of the infrared ceramic powder with more transmitting far infrared.
Invention content
It is an object of the present invention to overcome the above-mentioned drawbacks of the prior art and provide with far-infrared functional
Footwear material and preparation method thereof, the far infrared material for shoes preparation method of graphene technology can continue to send out using graphene technology
Far infrared is penetrated, keeps health-care efficacy more lasting.
To achieve the above object, a kind of far infrared material for shoes based on graphene technology of the invention, constitutive material
Parts by weight be：Ethylene-vinyl acetate 50-80, ethylene octene copolymer 20-50, ethylene propylene diene rubber 3-10, Graphene powder
Body 0.5-5, talcum powder 3-15, stearic acid 0.3-1, zinc stearate 0.5-1.5, zinc oxide 1-3, crosslinking agent 0.5-1.5, foaming agent
1-5。
As a preferred embodiment of the above technical solution, the VA contents of the ethylene-vinyl acetate are 18%-40%.
As a preferred embodiment of the above technical solution, graphene powder number of plies Wei≤10 layer.
As a preferred embodiment of the above technical solution, the talcum powder mesh number is 3500 mesh.
The preparation method of the far infrared material for shoes based on graphene technology of the present invention, which is characterized in that including following
Step：
(1) it carries out being stirred into graphene talcum powder composite after graphene powder and talcum powder being weighed according to parts by weight
Material, graphene powder and talcum powder ratio are 1:4；Temperature is no more than 90 DEG C in whipping process, is subsequently cooled to 32-40 DEG C.
(2) by ethylene-vinyl acetate, ethylene octene copolymer, ethylene propylene diene rubber, graphene talcum powder composite
Material, stearic acid, zinc stearate, zinc oxide are poured into mixer and are kneaded, mixing time 7min-9min, temperature 105
℃。
(3) after being kneaded to step (2) in material, crosslinking agent is added and foaming agent is kneaded, time 3min- 5min, temperature
115 DEG C -120 DEG C of degree pours into granulation or Luntai slice inside comminutor, and then moulded from foam, is molded under the conditions of 180 DEG C
Foaming or moulded from foam, you can the far infrared material for shoes based on graphene technology of system.
In graphene EVA composite material soles, by the basic principle of following assembly apparatus, to realize that the sole generates heat
And play the process characteristic of far-infrared functional：The sole made of the far infrared material for shoes based on graphene technology（1）Before
Graphene film far infrared heating piece is arranged in metacarpus position（2）, in sole（1）The setting of intermediate position sunken cord and slot and place electric wire
（3）, in sole（1）Heel region be arranged battery case（4）And placing battery, in sole（1）Tail portion be arranged USB charging sockets
（5）.
The graphene heating film of the present invention can be rapidly reached warming effect within 10 seconds, simultaneously because graphene adds
What hotting mask was sent out is to have good medical treatment, the Far-infrared spoke ejected wave of physiotherapy function, former using the infiltration and resonance of far infrared
Reason, acts on cell, achievees the effect that activating cell, realizes analgesic, detumescence and the effect for improving blood circulation.
In conclusion patented product of the present invention by the preparation, molding and assembly apparatus of the material, it can be achieved that graphene
Film heating sheets heating effect, according to the material property, and the far infrared of the inside graphene powder of sole distributes, right
Far infrared heat energy can be also transmitted to human body by the warming function that human foot plays, and the warm of generation distributes from inside to outside, this
Kind action intensity can also make telangiectasis, promote blood circulation in addition to playing warming basic function, strengthen each tissue
Between metabolism, increase the power of regeneration of tissue, improve the immunocompetence of body, adjust autonomic nerve, to play doctor
Treat the effect of health care.
Description of the drawings
Fig. 1 is a kind of structural schematic diagram of the far infrared shoes based on graphene technology of the present invention.
Specific implementation mode
The present invention is described in detail with specific embodiment below in conjunction with the accompanying drawings.
As shown in Fig. 1, the sole made of the far infrared material for shoes based on graphene technology（1）Half sole position set
Set graphene film far infrared heating piece（2）, in sole（1）The setting of intermediate position sunken cord and slot and place electric wire（3）, in sole
（1）Heel region be arranged battery case（4）And placing battery, in sole（1）Tail portion be arranged USB charging sockets（5）.
A kind of far infrared material for shoes based on graphene technology, the parts by weight of constitutive material are：Ethylene-vinyl acetate
Vinegar 50-80, ethylene octene copolymer 20-50, ethylene propylene diene rubber 3-10, graphene powder 0.5-5, talcum powder 3-15, tristearin
Sour 0.3-1, zinc stearate 0.5-1.5, zinc oxide 1-3, crosslinking agent 0.5-1.5, foaming agent 1-5.
As a preferred embodiment of the above technical solution, the VA contents of the ethylene-vinyl acetate are 18%-40%.
As a preferred embodiment of the above technical solution, graphene powder number of plies Wei≤10 layer.
As a preferred embodiment of the above technical solution, the talcum powder mesh number is 3500 mesh.
The preparation method of the far infrared material for shoes based on graphene technology of the present invention, which is characterized in that including following
Step：
(1) it carries out being stirred into graphene talcum powder composite after graphene powder and talcum powder being weighed according to parts by weight
Material, graphene powder and talcum powder ratio are 1:4；Temperature is no more than 90 DEG C in whipping process, is subsequently cooled to 32-40 DEG C.
(2) by ethylene-vinyl acetate, ethylene octene copolymer, ethylene propylene diene rubber, graphene talcum powder composite
Material, stearic acid, zinc stearate, zinc oxide are poured into mixer and are kneaded, mixing time 7min-9min, temperature 105
℃。
(3) after being kneaded to step (2) in material, crosslinking agent is added and foaming agent is kneaded, time 3min- 5min, temperature
115 DEG C -120 DEG C of degree pours into granulation or Luntai slice inside comminutor, and then moulded from foam, is molded under the conditions of 180 DEG C
Foaming or moulded from foam, you can the far infrared material for shoes based on graphene technology of system.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (5)
1. a kind of far infrared material for shoes based on graphene technology, it is characterised in that：The parts by weight of its constitutive material are：Ethylene
Vinyl acetate 50-80, ethylene octene copolymer 20-50, ethylene propylene diene rubber 3-10, graphene powder 0.5-5, talcum powder 3-
15, stearic acid 0.3-1, zinc stearate 0.5-1.5, zinc oxide 1-3, crosslinking agent 0.5-1.5, foaming agent 1-5.
2. the far infrared material for shoes based on graphene technology as described in claim 1, it is characterised in that：The ethylene vinyl acetate
The VA contents of ethylene vinegar are 18%-40%.
3. the far infrared material for shoes based on graphene technology as described in claim 1, it is characterised in that：The Graphene powder
Body number of plies Wei≤10 layer.
4. the far infrared material for shoes based on graphene technology as described in claim 1, it is characterised in that：The talcum powder mesh
Number is 3500 mesh.
5. the preparation method of the far infrared material for shoes according to any one of claims 1-4 based on graphene technology, special
Sign is, includes the following steps：
(1) it carries out being stirred into graphene talcum powder composite after graphene powder and talcum powder being weighed according to parts by weight
Material, graphene powder and talcum powder ratio are 1:4；Temperature is no more than 90 DEG C in whipping process, is subsequently cooled to 32-40 DEG C;
(2) by ethylene-vinyl acetate, ethylene octene copolymer, ethylene propylene diene rubber, graphene talcum powder blended compound material,
Stearic acid, zinc stearate, zinc oxide are poured into mixer and are kneaded, mixing time 7min-9min, 105 DEG C of temperature;
(3) after being kneaded to step (2) in material, crosslinking agent is added and foaming agent is kneaded, time 3min- 5min, temperature
115 DEG C -120 DEG C, granulation or Luntai slice inside comminutor are poured into, then moulded from foam, injection molding hair is carried out under the conditions of 180 DEG C
Bubble or moulded from foam, you can the far infrared material for shoes based on graphene technology of system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710850619.5A CN108485041A (en) | 2017-09-20 | 2017-09-20 | Far infrared material for shoes preparation method based on graphene technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710850619.5A CN108485041A (en) | 2017-09-20 | 2017-09-20 | Far infrared material for shoes preparation method based on graphene technology |
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| Publication Number | Publication Date |
|---|---|
| CN108485041A true CN108485041A (en) | 2018-09-04 |
Family
ID=63343897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710850619.5A Pending CN108485041A (en) | 2017-09-20 | 2017-09-20 | Far infrared material for shoes preparation method based on graphene technology |
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| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110016181A (en) * | 2019-05-08 | 2019-07-16 | 福建五持恒科技发展有限公司 | Graphene regeneration rubber-plastic foamed shoe-pad and preparation method thereof |
| CN112662019A (en) * | 2020-12-17 | 2021-04-16 | 福建五持恒科技发展有限公司 | Natural rubber far infrared insole containing graphene additives |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448521A (en) * | 2014-11-18 | 2015-03-25 | 安踏（中国）有限公司 | EVA composite foam material and preparation method thereof |
| CN104725713A (en) * | 2015-04-08 | 2015-06-24 | 广州维桢化工科技有限公司 | EVA (ethylene vinyl-acetate copolymer) sole material and preparation method thereof |
| CN105037902A (en) * | 2014-12-02 | 2015-11-11 | 东莞市国立科技有限公司 | A kind of high elastic wear-resistant EVA and its preparation method and application |
| CN206462507U (en) * | 2017-02-15 | 2017-09-05 | 青岛瑞利特新材料科技有限公司 | A kind of novel graphite alkene warming insole |
-
2017
- 2017-09-20 CN CN201710850619.5A patent/CN108485041A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104448521A (en) * | 2014-11-18 | 2015-03-25 | 安踏（中国）有限公司 | EVA composite foam material and preparation method thereof |
| CN105037902A (en) * | 2014-12-02 | 2015-11-11 | 东莞市国立科技有限公司 | A kind of high elastic wear-resistant EVA and its preparation method and application |
| CN104725713A (en) * | 2015-04-08 | 2015-06-24 | 广州维桢化工科技有限公司 | EVA (ethylene vinyl-acetate copolymer) sole material and preparation method thereof |
| CN206462507U (en) * | 2017-02-15 | 2017-09-05 | 青岛瑞利特新材料科技有限公司 | A kind of novel graphite alkene warming insole |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110016181A (en) * | 2019-05-08 | 2019-07-16 | 福建五持恒科技发展有限公司 | Graphene regeneration rubber-plastic foamed shoe-pad and preparation method thereof |
| CN112662019A (en) * | 2020-12-17 | 2021-04-16 | 福建五持恒科技发展有限公司 | Natural rubber far infrared insole containing graphene additives |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180904 |
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| RJ01 | Rejection of invention patent application after publication |