CN104013094B - A kind of raising CO2The additive of expanded cut tobacco quality and the application in cigarette thereof - Google Patents
A kind of raising CO2The additive of expanded cut tobacco quality and the application in cigarette thereof Download PDFInfo
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Abstract
The invention belongs to Cigarette processing field, it relates to a kind of raising CO2The additive of expanded cut tobacco quality and the application in cigarette thereof. Specifically, described additive-package is containing propylene glycol and/or glycerine, sodium alginate, mailland reaction product. The present invention also relates to described additive in the purposes prepared in tobacco product such as cigarette. The spray of this additive is added on pipe tobacco, then pipe tobacco is carried out CO2Expand, it is possible to effectively reduce CO2The loss of pipe tobacco flavour ingredient and relevant composition in expansion process, thus improve organoleptic quality and the physics humid keeping performance of expanded cut tobacco. It is broken that the additive of the present invention can also effectively reduce making of pipe tobacco in expansion process, reduces filament broken rate, it is to increase whole cut rate and Filling power, has higher production application and is worth.
Description
Technical field
The invention belongs to Cigarette processing field, it relates to a kind of raising CO2The additive of expanded cut tobacco quality and the application in cigarette thereof.
Background technology
Current CO2Pipe tobacco expansion technique is one of important means of domestic tobacco industry lowering harm and decreasing coking, reduction cigarette consumption. CO2Pipe tobacco expansion technique principle is exactly the carbon dioxide liquid under pipe tobacco certain temperature, pressure soaked, after making carbonic acid gas fully infiltrate pipe tobacco inside, fast decompression, making the liquid carbon dioxide in pipe tobacco be solidified as solid carbon dioxide, recycling high temperature gas flow rapid heating pipe tobacco, makes carbon dioxide sublimes, volume rapid expansion, the pipe tobacco cell walls of atrophy is opened in support, thus makes pipe tobacco volume become big, thus increases the filling properties of pipe tobacco.
But, the pipe tobacco after expansion not only has fragrance deficiency, the sense organ defect that assorted gas is obviously, stimulation change is big, the simultaneously decline of pipe tobacco snappiness, and resist processing ability reduces, the decline of physics humid keeping performance. It is not limited to theoretical restriction, owing to some compositions in tobacco are had certain extraction by carbonic acid gas in expansion process, total reducing sugar in the pipe tobacco after expansion, total nitrogen and total alkaloid content will be caused all to have reduction in various degree; Proline(Pro), Serine, L-glutamic acid, glycine, Histidine and Isoleucine etc. are totally on a declining curve; The component contents such as isovaleric acid in part flavour ingredient, lauric acid, oleic acid and nutmeg acid all decline.
In order to address these problems, tobacco industry has carried out correlative study. Cigarette in Shandong (investigation and application [J] of novel fragrance in tobacco shred bulking technique. the tobacco chemistry group annual meeting in 2004 of Chinese tobacco association, 2004:30-39), Agricultural University Of He'nan (improve carbon dioxide expanded cut tobacco processing quality and Usability Study [C]. Agricultural University Of He'nan's Master's thesis, 2008:1-10), in Hubei, the unit such as cigarette (CN103305342A) develops the flavoring essence for expanded cut tobacco respectively, expanded cut tobacco can carry out compensating aroma by these flavoring essences, it is to increase the organoleptic quality of expanded cut tobacco.
But above-mentioned research exists more deficiency, such as:
1) employ much natural or synthetic perfume due to these essence, there is certain volatility, can bring in carbonic acid gas in expansion process, it is possible to the expanded cut tobacco of next batch can be brought impact;
2) effect of these expanded cut tobacco essence mainly flavouring, does not have dependent interaction for the physics humectation effect improving expanded cut tobacco.
Therefore, need exploitation badly a kind of for improving CO2The additive of expanded cut tobacco organoleptic quality and physics humid keeping performance.
Summary of the invention
The present inventor, through deep research and creative work, obtains a kind of additive. The present inventor finds in surprise, the spray of this additive is added on pipe tobacco, then pipe tobacco is carried out CO2Expand, it is possible to effectively reduce CO2The loss of pipe tobacco flavour ingredient and relevant composition in expansion process, it is to increase the organoleptic quality of expanded cut tobacco and physics humid keeping performance. In addition, can also effectively to reduce making of pipe tobacco in expansion process broken for this additive, it is to increase whole cut rate, has higher production application and be worth. Thus provide following invention:
An aspect of the present invention relates to a kind of additive, comprises following composition:
Propylene glycol and/or glycerine, sodium alginate, mailland reaction product;
Specifically, described additive is cigarette additive; More specifically, it is CO2Expanded cut tobacco additive; Further specifically, for for improving CO2The additive of expanded cut tobacco organoleptic quality and/or physics humid keeping performance. The additive of the present invention is also called composite additive.
The additive of the present invention used before pipe tobacco expands. Before pipe tobacco expands, spray is added on pipe tobacco, utilizes the action character of additive, decreases the loss of the compositions such as expansion process pipe tobacco flavour ingredient, thus play the effect of flavouring humectation.
Additive according to arbitrary item of the present invention, it is preferable that propylene glycol and glycerine use simultaneously. Specifically, calculating according to mass percent, propylene glycol is 10%-70% in the ratio of whole expanded cut tobacco specific complex additive, and glycerine is 5%-50%.
Additive according to arbitrary item of the present invention, sodium alginate is 0.1%-10% in the ratio of whole expanded cut tobacco specific complex humectant.
Being not limited to theoretical restriction, sodium alginate is the backbone material with larger molecular weight. Containing the different group such as hydroxyl, amino, carboxyl, salt in structure, these groups can form stronger interaction with dissimilar chemical composition in pipe tobacco, it is possible to decreases the loss of pipe tobacco chemical composition in expansion process. Sodium alginate also may form certain film at tobacco leaf surface, to repair pipe tobacco surface due to the breakage that causes of expanding, reduce the loss of the materials such as moisture, it is to increase pipe tobacco physics humid keeping performance. Sodium alginate structural formula is as follows:
The molecular formula of sodium alginate can represent for (C6H7NaO6) n. Preferably, the polymerization degree of sodium alginate or the scope of wherein n are 500-700.
Additive according to arbitrary item of the present invention, Maillard reaction products is 1%-50% in the ratio of whole expanded cut tobacco specific complex additive.
Additive according to arbitrary item of the present invention, this water is 10%-30% in the ratio of whole expanded cut tobacco specific complex additive.
Additive according to the arbitrary item of the present invention, calculates according to mass percent, and it comprises any a group in following (1)-(8) group:
(1)
(2)
(3)
(4)
(5)
(6)
(7)
With
(8)
Additive according to the arbitrary item of the present invention, it also comprises water;Specifically, calculate according to the mass percent after adding water, the content of water is >=10%, >=13%, 10%-50%, 10%-33%, 10%-30%, 13%-50%, 13%-33%, 13%-30%, 10%, 13%, 30%, 33% or 50%.
Water can be mixed together with propylene glycol and/or glycerine, sodium alginate, mailland reaction product. It is dissolved in water again after can also formerly obtaining the solid mixture comprising propylene glycol and/or glycerine, sodium alginate, mailland reaction product or dilutes.
Additive according to the arbitrary item of the present invention, wherein, described mailland reaction product obtains as follows:
Sugar and amino acid being mixed, add 10-50 distilled water dissolving doubly, obtain mixing solutions, solution is heated to 90 DEG C-95 DEG C, react after 2-8 hour, cooling obtains mailland reaction product;
Specifically,
Amino acid used be selected from proline(Pro), glycine and L-Ala any one or multiple,
Sugar used is glucose and/or fructose,
Amino acid used and sugar mol ratio be 1:(1-5), 1:(1-4), 1:(1-3), 1:(1-2), 1:5,1:4,1:3,1:2 or 1:1.
The another aspect of the present invention relates to a tobacco articles, and it contains or is added with the additive according to any one of the present invention; Specifically, described tobacco product is cigarette, pipe tobacco or pipe tobacco formula; Specifically, it is CO2Expanded cut tobacco; Specifically, the content of described additive is the 0.01%-1% of tobacco quality; Preferably, it is 0.05%-1% or 0.05%-0.5%.
Another aspect of the invention relates to the additive according to any one of the present invention in the purposes preparing in tobacco product; Specifically, described tobacco product is cigarette, pipe tobacco or pipe tobacco formula; Specifically, it is CO2Expanded cut tobacco; Specifically, the consumption of described additive is the 0.01%-1% of tobacco quality; Preferably, it is 0.05%-1% or 0.05%-0.5%.
Another aspect of the invention relates to a kind of method preparing tobacco product, comprises the step using the additive according to any one of the present invention; Specifically, described tobacco product is cigarette, pipe tobacco or pipe tobacco formula; Specifically, described tobacco product is CO2Expanded cut tobacco.
Method according to the arbitrary item of the present invention, wherein, the consumption of described additive is the 0.01%-1% of tobacco quality; Preferably, it is 0.05%-1% or 0.05%-0.5%.
Method according to the arbitrary item of the present invention, it also comprises the steps:
Pipe tobacco after spraying additive is carried out carbonic maceration and high-temperature expansion.
Described carbonic maceration and high-temperature expansion can conveniently technology carry out.
Another aspect of the invention relate to according to any one of additive for improving CO2The purposes of expanded cut tobacco organoleptic quality and/or physics humid keeping performance.
Tobacco product according to arbitrary item of the present invention, purposes or method, wherein, calculate according to mass percent, the content of described additive or consumption or addition are 0.01%-1%, 0.05%-1%, 0.05%-0.1%, 0.05%-0.5%, 0.5%-1%, 0.01%, 0.02%, 0.03%, 0.04%, 0.05%, 0.06%, 0.07%, 0.08%, 0.09%, 0.1%, 0.15%, 0.2%, 0.25%, 0.3%, 0.35%, 0.4%, 0.45%, 0.5%, 0.55%, 0.6%, 0.65%, 0.7%, 0.75%, 0.8%, 0.85%, 0.9%, 0.95%, 1%, and the two numerical range formed as end points arbitrarily in these concrete numerical value.
The beneficial effect of the invention
Under the prerequisite keeping the normal rate of expansion of pipe tobacco, it is possible to reduce the loss of pipe tobacco flavour ingredient and other composition in expansion process, thus improve organoleptic quality and the physics humid keeping performance of expanded cut tobacco. It is broken that this additive can also effectively reduce making of pipe tobacco in expansion process, it is to increase whole cut rate, has higher production application and is worth.
Accompanying drawing explanation
Fig. 1: sample physics humid keeping performance test result. In figure, 1#, 2#, 3# expanded cut tobacco is that laboratory sample 1#, 2#, 3#, 0 are for blank sample.
Embodiment
Embodiment of the present invention being described in detail below in conjunction with embodiment, but it will be understood to those of skill in the art that, the following example is only for illustration of the present invention, and should not be considered as limiting the scope of the present invention. Unreceipted concrete condition person in embodiment, conveniently the condition of condition or manufacturers's suggestion carries out. Agents useful for same or the unreceipted production firm person of instrument, being can by the conventional products of commercial acquisition.
Preparation example 1: the preparation of mailland reaction product 1
Amino acid is: proline(Pro), glycine, L-Ala, and ratio is 1:1.5:1 (mol ratio).
Sugar is: glucose, fructose, and ratio is 1:3 (mol ratio).
The ratio of amino acid and sugar is 1:1 (mol ratio).
Preparation technology: sugar and amino acid are mixed, the distilled water adding 10 times dissolves, and obtains mixing solutions, solution is heated to 90 DEG C, react after 2 hours, and cooling obtains mailland reaction product 1.
For the following examples 1.
Preparation example 2: the preparation of mailland reaction product 2
Amino acid is: proline(Pro), glycine, and ratio is 1:2.5 (mol ratio).
Sugar is: glucose.
The ratio of amino acid and sugar is 1:5 (mol ratio).
Preparation technology: sugar and amino acid are mixed, the distilled water adding 30 times dissolves, and obtains mixing solutions, solution is heated to 95 DEG C, react after 8 hours, and cooling obtains mailland reaction product 2.
For the following examples 2.
Preparation example 3: the preparation of mailland reaction product 3
Amino acid is: proline(Pro), L-Ala, and ratio is 1:4 (mol ratio).
Sugar is: glucose, fructose, and ratio is 1:5 (mol ratio).
The ratio of amino acid and sugar is 1:3 (mol ratio).
Preparation technology: sugar and amino acid are mixed, the distilled water adding 50 times dissolves, and obtains mixing solutions, solution is heated to 93.5 DEG C, react after 5 hours, and cooling obtains mailland reaction product 3.
For the following examples 3.
The preparation of embodiment 1: additive samples A
Take propylene glycol, glycerine, sodium alginate, mailland reaction product 1 and water according to the mass ratio of 30:20:10:10:30, and by being uniformly mixed, make expanded cut tobacco additive A.
The preparation of embodiment 2: additive samples B
Take propylene glycol, glycerine, sodium alginate, mailland reaction product 2 and water according to the mass ratio of 10:5:0.1:5:10, and by being uniformly mixed, make expanded cut tobacco additive B.
The preparation of embodiment 3: additive samples C
Take propylene glycol, glycerine, sodium alginate, mailland reaction product 3 and water according to the mass ratio of 70:10:5:40:20, and by being uniformly mixed, make expanded cut tobacco addition of C.
Embodiment 1-3 above is only exemplary, it is also possible to propylene glycol, glycerine, sodium alginate and mailland reaction product are mixed to get additive, it may also be useful to the front water adding corresponding proportion.
Embodiment 4: the preparation of expanded cut tobacco sample 1#
Additive therefor is the obtained additive samples A of embodiment 1.
Doping sample A is sprayed in expanded cut tobacco leaf group according to tobacco quality 0.1%, after first flooding 20 minutes in carbonic maceration tank, sample enters sublimer when contacting with about 350 DEG C process gass (steam, carbonic acid gas, air), immerse solidified carbon dioxide in pipe tobacco cell and make pipe tobacco rapid spatial expansion, the carbon dioxide expanded cut tobacco laboratory sample 1# after being expanded.
Tobacco leaf formulation used and reference ratio are such as table 1 below.
Table 1: tobacco leaf formulation
Embodiment 5: the preparation of expanded cut tobacco sample 2#
Additive therefor is the obtained additive samples B of embodiment 2.
Doping sample B is sprayed in expanded cut tobacco leaf group according to tobacco quality 1%, after first flooding 30 minutes in carbonic maceration tank, sample enters sublimer when contacting with about 325 DEG C process gass (steam, carbonic acid gas, air), immerse solidified carbon dioxide in pipe tobacco cell and make pipe tobacco rapid spatial expansion, the carbon dioxide expanded cut tobacco laboratory sample 2# after being expanded.
Tobacco leaf formulation used is identical with embodiment 4.
Embodiment 6: the preparation of expanded cut tobacco sample 3#
Additive therefor is the obtained additive samples C of embodiment 3.
Doping sample C is sprayed in expanded cut tobacco leaf group according to tobacco quality 0.5%, after first flooding 25 minutes in carbonic maceration tank, sample enters sublimer when contacting with about 335 DEG C process gass (steam, carbonic acid gas, air), immerse solidified carbon dioxide in pipe tobacco cell and make pipe tobacco rapid spatial expansion, the carbon dioxide expanded cut tobacco laboratory sample 3# after being expanded.
Tobacco leaf formulation used is identical with embodiment 4.
Comparative example 1: the preparation of expanded cut tobacco sample 0# (blank sample)
According to the technique identical with embodiment 4 preparation, except not using additive, pipe tobacco leaf group used is also completely identical. Obtain blank sample 0#.
The physicochemical data analysis, the organoleptic quality that are used in the following examples 7-10 by expanded cut tobacco sample 1#-3# obtained for embodiment 4-6 and the obtained blank sample 0# of comparative example 1 smoke panel test, applicating evaluating in cigarette and humid keeping performance detection.
Embodiment 7: the physical structure contrast of expanded cut tobacco
1. laboratory sample
Expanded cut tobacco sample 1#, 2#, 3#, 0# prepared by embodiment 4-6 and comparative example 1.
2. experimental technique
Expanded cut tobacco laboratory sample and blank sample are carried out physical structure detection according to industry standard, measures the indexs such as long filament rate, whole cut rate, filament broken rate, Filling power. Expanded cut tobacco Filling power measures and measures expanded cut tobacco Filling power according to the method for YC/T152-2001; Expanded cut tobacco structure (long filament rate, whole cut rate, filament broken rate) measures and measures expanded cut tobacco structure according to the method for YC/T178-2003.
3. experimental result
As shown in Table 2 below.
Table 2: physical structure correlation data
| Long filament rate % | Whole cut rate % | Filament broken rate % | Filling power mm | |
| The blank sample of 0# | 43.4 | 69.7 | 2.8 | 21.63 |
| 1# tests sample | 50.8 | 74.1 | 2.1 | 24.63 |
| 2# tests sample | 50.1 | 73.2 | 2.3 | 24.03 |
| 3# tests sample | 50.6 | 72.5 | 2.5 | 23.56 |
From the experimental data of table 2 it can be seen that add the long filament rate of the expanded cut tobacco of additive, whole cut rate and Filling power and significantly improved, filament broken rate is then reduced to 2.1-2.5% by 2.8%. Meanwhile, experiment pipe tobacco is obviously more soft than blank sample, and elasticity is better, and there is moist feeling on surface, it is possible to improve the resist processing of expanded cut tobacco.
Embodiment 8: the flavour ingredient of expanded cut tobacco compares
1. laboratory sample and instrument
Expanded cut tobacco sample 1#, 2#, 3#, 0# prepared by embodiment 4-6 and comparative example 1.
Simultaneous distillation-extraction instrument (Zhengzhou tobacco research institute); ThermoFisherISQGC/MS combined instrument (match Mo Feishier Science and Technology Ltd. of Germany).
2. experimental technique
Adopt the method for Simultaneous distillation-extraction to extract expanded cut tobacco laboratory sample and blank sample, with GC/MS, the flavour ingredient of extract is analyzed.
Concrete steps are as follows:
In 1000mL round-bottomed flask, add 20g expanded cut tobacco sample and 350mL distilled water (add a few perpleexite in order to avoid quick-fried boil) simultaneously, in 100mL round-bottomed flask, add 60mLCH2C12. The flask filling cigarette sample is adopted electric mantle heating (temperature controls at 150 DEG C), to filling CH2C12Flask adopt heating in water bath (60 DEG C), simultaneously distillation extraction 2.5 hours. After extraction terminates, at CH2C12Extracting solution adds 6g anhydrous Na2SO4, it is placed on refrigerator overnight. Dried organic layer solution is transferred to concentrated bottle by elimination solid, adds 0.40272mg Phenylethyl ethanoate as interior mark, concentrates to about 1.5mL with Rotary Evaporators at the temperature of about 40 DEG C. Cross 0.45 ��m of organic phase filter membrane.
GC/MS analysis condition is as follows:
Chromatographic column: DB-5MS (30m �� 0.25mm �� 0.25 ��m) capillary chromatographic column; Carrier gas: He, 99.999%; Flow velocity: 1.0mL/min; Injector temperature: 290 DEG C; Sample size: 1 �� L; Enter sample pattern: split stream sampling; Splitting ratio: 10: 1;
Heating schedule:
45 DEG C keep 2 minutes; 200 DEG C are risen to the speed of 5 DEG C/min; 250 DEG C are risen to the speed of 3 DEG C/min; 300 DEG C are risen to the speed of 5 DEG C/min; Keep 10 minutes at 300 DEG C.
Ion source: electron bombardment (EI); Electron energy: 70eV; Ion source temperature: 250 DEG C, transmission line temperature: 300 DEG C; Analyzer: level Four bar mass analyzer; Scan pattern: full scan; Mass scan range: 40-500amu; Solvent delay: 4.5min.
3. experimental result
The quantitative result of flavour ingredient is as shown in Table 3 below.
Table 3: the quantitative result of flavour ingredient
From the experimental data of table 3 it may be seen that the flavour ingredient content of laboratory sample will far away higher than blank sample. The increase of ketone class, alcohol class, acid class, ester class, alkene class is obvious.
Embodiment 9: the sensory evaluation experiment of expanded cut tobacco in cigarette
1. laboratory sample
Expanded cut tobacco sample 1#, 2#, 3#, 0# prepared by embodiment 4-6 and comparative example 1.
2. experimental technique
Expanded cut tobacco laboratory sample and blank sample are added in test cigarette leaf group by same ratio, rolls into cigarette, adopt national standard method (GB5606.4-1996) that it is carried out sensory evaluation, aesthetic quality's difference of contrast two kinds of samples.
3. experimental result
As shown in Table 4 below.
Table 4: sensory evaluation result
| Project | Gloss | Fragrance | Harmony | Assorted gas | Pungency | Pleasant impression | Add up to |
| Full marks value | 5 | 32 | 6 | 12.0 | 20 | 25 | 100 |
| Blank sample 0# | 5 | 29 | 5 | 11.0 | 17.5 | 21.5 | 89 |
| Laboratory sample 1# | 5 | 29.5 | 5 | 11.0 | 17.5 | 22 | 90 |
| Laboratory sample 2# | 5 | 29 | 5 | 11.5 | 17.5 | 22 | 89.5 |
| Laboratory sample 3# | 5 | 29.5 | 5 | 11.0 | 18.0 | 22 | 90.5 |
By the experimental data of table 4 it can be seen that laboratory sample improves relatively obvious on fragrance and pleasant impression, can with leaf group harmony, the agglomerating row of flue gas and smooth and easy sense are improved, flue gas exquisiteness is soft, better rich, dried-up breath and oral cavity comfort level are better, and overall aesthetic quality improves 0.5-1.5 and divides.
Embodiment 10: physics humid keeping performance test experiments
1. laboratory sample
Expanded cut tobacco sample 1#, 2#, 3#, 0# prepared by embodiment 4-6 and comparative example 1.
2. experimental technique
Expanded cut tobacco laboratory sample and blank sample are carried out physics humid keeping performance evaluation, investigates the difference of its humid keeping performance fermentation.
Testing process is as follows:
(1) sample is after RH=60% (thermostatic constant wet chamber) balance (48 hours), detects its water ratio by national standard method (YC/T31-1996);
(2) weighing bottle used is numbered, and symmetrical measuring bottle is weighed, and is accurate to 0.0001g;
(3) taking sample with weighing bottle respectively, example weight is 6g �� 2mg;
(4) open balance measurement software, complete the calibration to balance;
(5) sample is placed on balance, starts to run balance measurement software after placing and start, example weight is carried out continuous weighting; Within every minute, measure an example weight; Gather 72 hours altogether or the longer time;
(6) to be tested reach the specified time after, stop test;
(7) take out test its water ratio of sample detection, make the lost data of moisture in cut tobacco;
(8) by moisture loss data importing humid keeping performance evaluation software, form fit equation and matched curve, calculate the indexs such as the average rate-of-loss of coolant of its arbitrary period, instant rate-of-loss of coolant.
Evaluation equation:
As t �� ��, the water ratio W �� a of tobacco, i.e. equilibrium moisture content; C is spread coefficient;
No matter under low wet (namely separating wet) condition or high (i.e. moisture absorption) condition that wets, b value is close to the difference of initial aqueous rate and equilibrium moisture content.
Judgement criteria:
Thermodynamic Criteria: under same environmental conditions, equilibrium moisture content is more high, and its humid keeping performance is more good;
Dynamics index: under same environmental conditions, rate-of-loss of coolant is more low, and its humid keeping performance is more good;
1. the spread coefficient C of fit equation, 2. immediately/average rate-of-loss of coolant 3. identical fluid loss, required time.
3. experimental result
As shown in accompanying drawing 1 and table 5 below.
Table 5: expanded cut tobacco humectation effect assessment data after reinforced
From test data it may be seen that the control sample that cannot not be better than reinforcedly of the humid keeping performance adding the expanded cut tobacco of punishment in advance. In addition, in 4 samples, the physics humid keeping performance of 3# is better, although it is slightly low to show as the initial water ratio of 3# sample, but its equilibrium moisture content under 30% humidity condition is the highest, reaches 6.82%, relatively contrasts sample 0# and want 6.52% to exceed 0.3%; Secondly, the average rate-of-loss of coolant of 3# sample in 0-12 hour, and the moment percentage of water loss of the 12nd hour is also minimum.
Although the specific embodiment of the present invention has obtained detailed description, it will be understood to those of skill in the art that. According to disclosed all instructions, it is possible to those details carry out various amendment and replacement, and these change all within protection scope of the present invention. Whole scopes of the present invention are provided by claims and the jljl such as any thereof.
Claims (28)
1. an additive, calculates according to mass percent, and described additive-package contains:
Described additive is CO2Expanded cut tobacco additive.
2. additive according to claim 1, calculates according to mass percent, and it comprises:
3. an additive, calculates according to mass percent, and described additive-package contains:
Described additive is CO2Expanded cut tobacco additive.
4. additive according to claim 1, calculates according to mass percent, and it comprises:
5. additive according to claim 1, calculates according to mass percent, and it comprises any a group in following (1)-(2) group:
(1)
(2)
6. an additive, calculates according to mass percent, and described additive-package contains:
Described additive is CO2Expanded cut tobacco additive.
7. additive according to claim 1, it also comprises water;Calculating according to the mass percent after adding water, the content of water is >=10%.
8. additive according to claim 7, calculates according to the mass percent after adding water, and the content of water is >=13%.
9. additive according to claim 7, calculates according to the mass percent after adding water, and the content of water is 10%-50%.
10. additive according to claim 7, calculates according to the mass percent after adding water, and the content of water is 10%-33%.
11. additives according to claim 7, calculate according to the mass percent after adding water, and the content of water is 10%-30%.
12. additives according to claim 7, calculate according to the mass percent after adding water, and the content of water is 13%-50%.
13. additives according to claim 7, calculate according to the mass percent after adding water, and the content of water is 13%-33%.
14. additives according to claim 7, calculate according to the mass percent after adding water, and the content of water is 13%-30%.
15. additives according to claim 7, calculate according to the mass percent after adding water, and the content of water is 10%, 13%, 30%, 33% or 50%.
16. additives according to any one of claim 1 to 15, wherein, described mailland reaction product obtains as follows:
Sugar and amino acid being mixed, add 10-50 distilled water dissolving doubly, obtain mixing solutions, solution is heated to 90 DEG C-95 DEG C, react after 2-8 hour, cooling obtains mailland reaction product;
Amino acid used be selected from proline(Pro), glycine and L-Ala any one or multiple, sugar used is glucose and/or fructose, amino acid used and sugar mol ratio be 1:(1-5).
17. 1 tobacco articles, it contains or is added with the additive according to any one of claim 1 to 16; Described tobacco product is cigarette, CO2Expanded cut tobacco or CO2Expanded cut tobacco is filled a prescription; The content of described additive is the 0.01%-1% of tobacco quality.
18. tobacco products according to claim 17, wherein, the content of described additive is the 0.05%-1% of tobacco quality.
19. tobacco products according to claim 17, wherein, the content of described additive is the 0.05%-0.5% of tobacco quality.
Additive according to any one of 20. claims 1 to 16 is in the purposes prepared in tobacco product; Described tobacco product is cigarette, CO2Expanded cut tobacco or CO2Expanded cut tobacco is filled a prescription; The consumption of described additive is the 0.01%-1% of tobacco quality.
21. purposes according to claim 20, wherein, the consumption of described additive is the 0.05%-1% of tobacco quality.
22. purposes according to claim 20, wherein, the consumption of described additive is the 0.05%-0.5% of tobacco quality.
Prepare the method for tobacco product for 23. 1 kinds, comprise the step using the additive according to any one of claim 1 to 16; Described tobacco product is cigarette, CO2Expanded cut tobacco or CO2Expanded cut tobacco is filled a prescription.
24. methods according to claim 23, wherein, the consumption of described additive is the 0.01%-1% of tobacco quality.
25. methods according to claim 23, wherein, the consumption of described additive is the 0.05%-1% of tobacco quality.
26. methods according to claim 23, wherein, the consumption of described additive is the 0.05%-0.5% of tobacco quality.
27. methods according to claim 23, it also comprises the steps:
Pipe tobacco after spraying additive is carried out carbonic maceration and high-temperature expansion.
Additive according to any one of 28. claims 1 to 16 is for improving CO2The purposes of expanded cut tobacco organoleptic quality and/or physics humid keeping performance.
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| CN1375244A (en) * | 2002-03-29 | 2002-10-23 | 云南瑞升科技有限公司 | Tobacco-swelling biological additive and its prepn. and application |
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| CN103305342A (en) * | 2013-06-28 | 2013-09-18 | 湖北中烟工业有限责任公司 | Casing flavor for expanded cut tobacco |
| CN103409238A (en) * | 2013-09-03 | 2013-11-27 | 红塔烟草(集团)有限责任公司 | Cut stem fumet for tobacco as well as preparation method and application thereof |
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| CN1228945A (en) * | 1999-03-16 | 1999-09-22 | 南京大学 | Additive for reducing content of nitrosamine in cigarette smoke and cigarette containing the additive |
| CN1371638A (en) * | 2002-03-29 | 2002-10-02 | 云南瑞升科技有限公司 | Expansion tobacco chemical additives and preparation process and application thereof |
| CN1375244A (en) * | 2002-03-29 | 2002-10-23 | 云南瑞升科技有限公司 | Tobacco-swelling biological additive and its prepn. and application |
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| CN103146481A (en) * | 2013-03-11 | 2013-06-12 | 华宝食用香精香料（上海）有限公司 | Method for preparing tobacco maillard reaction spice |
| CN103305342A (en) * | 2013-06-28 | 2013-09-18 | 湖北中烟工业有限责任公司 | Casing flavor for expanded cut tobacco |
| CN103409238A (en) * | 2013-09-03 | 2013-11-27 | 红塔烟草(集团)有限责任公司 | Cut stem fumet for tobacco as well as preparation method and application thereof |
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