CN104005225B - A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency - Google Patents
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency Download PDFInfo
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Abstract
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency, step is as follows: (1) makes lyocell fiber immerse in a kind of solution containing cross-linking agent, catalyst and penetrating agent；(2) after this fiber being dried at 75 85 DEG C pretreatment 90 150s, at 125 135 DEG C, then bake 90 150s, make fiber solidifying crosslinking；(3) fiber after baking washs 37 times with the soft water of 50 DEG C, then washs 13 times with cold soft water: fiber is finally dried at 80 DEG C by (4), i.e. can get antigen fibrillation lyocell fiber cellulose fiber.The cross-linking agent that the present invention provides is easy to get, and is processed lyocell fiber cellulose fiber by specific method, thus obtains the lyocell fiber with anti-Fibrillation Properties.
Description
Technical field
The present invention relates to fibre modification processing technique field, in particular to one reduces lyocell fiber
The method of cellulose fiber fibrillation tendency.
Background technology
The appearance of chemical fibre greatly meet people to clothing, decoration and the demand of fabrics for industrial use, but
Along with the minimizing of world oil storage level, the exploitation of the synthetic fibers with oil as primary raw material also will be limited
System.The shortage of non-renewable textile raw material forces the focus that utilizes of people to turn to reproducible textile raw material, and
And along with people's concern to environmental conservation, with renewable natural resources for development of raw materials staple fibre increasingly
Come into one's own.
The production of the Lyocell fiber polyhydroxy with wood pulp as raw material, on this technology utilization NMMO and cellulose
Hydrogen bond can be produced and make the characteristic of cellulose dissolution, wood pulp, water and solvent NMMO be heated, by cellulose slurry
Dissolve (physical property dissolving), obtain the spinning liquid (viscosity up to thousand of pools about) of thickness, then with wet-dry change
Spinning process spinning forms.The NMMO separated out in spinning coagulation bath, rinse bath can reclaim, refine, molten
The agent response rate is up to more than 99%.Owing to eliminating viscose rayon production in the production process of Lyocell fiber
Middle a large amount of waste liquids, waste gas and the waste residue produced because adding the various chemical reagent such as Carbon bisulfide, with safety
Chemicals NMMO (toxicity is lower than ethanol) is solvent, and whole production system forms closed loop Recovery and recycle
System, does not has trash discharge, environmentally safe.
Owing to Lyocell fiber product is the cellulose of 100%, can within a short period of time complete biodegradable be
Inorganic matter CO2 and H2O, participates in the material circulation of natural ecosystems, again to environment without any pollution, quilt
It is described as " green fiber " of 21 century.Coming out of Lyocell fiber provides excellent former for producing textile
Material, authoritative institution of the world predicts, Lyocell fiber will become cotton of continuing, hair, silk, numb four big natural fibers it
After the fifth-largest fiber.
Lyocell fiber has skin-core structure, and its cortex is two-layer composite, and sandwich layer is by highly crystalline and takes
To tassel shape giant fibril and unformed area composition.Because cortex is the thinnest, Lyocell fiber almost all is sandwich layer
Structure.Height-oriented and the mutual lateral connection of Lyocell sandwich layer giant fibril is the weakest, unformed area quilt
Water or sodium hydroxide solution infiltration can occur acutely to expand later, weaken the contact between fibril further.This
Structures shape Lyocell fiber under conditions of the hygral expansion or alkali hygral expansion state and mechanical external force effect,
Easily produce fibrillation phenomenon.This characteristic utilizing Lyocell fiber can produce imitative peach-skin fabrics.
But, under many circumstances, fibrillation brings the most unnecessary fiber crops can to again production and processing person and consumer
Tired.
At present, solve lyocell fiber cellulose fiber to be prone to the approach of fibrillation and mainly fiber is cross-linked
Post processing realizes, or the fabric being made into fiber carries out cross-linking post processing and realizes.Wherein publication number
The patent report of CN1147281A with N-methoxyl group resin and zero formaldehyde resin as cross-linking agent, citric acid is for urging
Agent, with cellulose base fiber fabric haptoreaction, reduces the fibrillation tendency of fiber in fabric.Invention number
The patent report of the CN103306136A oligomeric polyprotic acid with molecular weight as 400-1000 and C2～C6 polyprotic acid
The cross-linking agent combined, reacts with cellulose fibre, and the anti-Fibrillation Properties of fiber is had obvious effect.
The patent of invention CN103046146A reports and dissolves cellulose fiber by the ionic liquid of zwitterion composition
Dimension, has obtained, by the spinning of dry-jet wet-spinning, the cellulose fibre that anti-Fibrillation Properties is excellent.But above-mentioned patent
Used in cross-linking agent synthesis loaded down with trivial details, complex process, commercial production difficulty is bigger.
Summary of the invention
The technical problem to be solved is to provide a kind of lyocell fiber cellulose fiber fibrillation that reduces and inclines
To method, it has screened the cross-linking agent being easy to get, and by specific method to lyocell fiber cellulose fiber
Process, thus eliminate defect in above-mentioned background technology.
For solving above-mentioned technical problem, the technical scheme is that
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency, step is as follows:
(1) lyocell fiber is made to immerse in a kind of aqueous solution containing cross-linking agent, catalyst and penetrating agent；
(2) pretreatment 90-150s, then roasting at 125-135 DEG C at 75-85 DEG C after this fiber being dried
Dry 90-150s, make fiber solidifying crosslinking；
(3) fiber after baking washs 3-7 time with the soft water of 50 DEG C, then with cold soft water washing 1-3
Secondary:
(4) finally fiber is dried at 80 DEG C, i.e. can get antigen fibrillation lyocell fiber cellulose fiber.
In the present invention, in step (1), lyocell fiber can be to pass through the dry state fibre of dried
Dimension, but the hygrometric state fiber of more preferably undried.This hygrometric state fiber not being dried itself has swelling
Property, cross-linking agent, catalyst etc. be more easy to enter fibrous inside, react is in hgher efficiency, and fiber surface
Swelling, the reaction with cross-linking agent is more abundant, and the cross-linked structure of formation is more, can substantially reduce its fibrillation and incline
To.If the most dried dry state fiber, to be then soaked in water a period of time before crosslinking Treatment, make
Fiber is the most swelling.
In the present invention, in step (1), described cross-linking agent is the carbochain twain-aldehyde compound cross-linking agent at C2-C6, excellent
Select Biformyl.Biformyl contains Liang Ge carbonyl group, under the effect of catalyst, it is believed that cellulose divides
Hydroxyl in son reacts with the carbonyl in Biformyl due to acetalation, and thus cellulosic molecule produces
Raw crosslinking, in described solution, every liter contains 60-90g, preferably contains the Biformyl of 70-90g.
In the present invention, in step (1), described catalyst is the one in magnesium chloride, aluminum sulfate or tartaric acid.
In the present invention, in step (1), described catalyst concentration in the solution be respectively magnesium chloride 6-8g/L,
Aluminum sulfate 0.7-0.8g/L, tartaric acid 4-5g/L.Inventor finds in long-term practice, catalyst dense
This technique is played vital effect by degree, and in treatment fluid, the concentration of catalyst is come according to the activity of catalyst
Determining, the concentration of highly active metal salt catalyst typically normally about can exist from the scope of 5-20g/L
The scope of 6-8g/L.Low activity catalyst, the such as concentration of amine salt catalyst can cause about 40g/L by height.Have
The concentration of machine acid catalyst is typically in the scope of 2-9g/L, and the preferable concentration of tartaric acid is the scope of 4-5g/L.
And inventor is through the three of the above catalyst of a large amount of experiment screenings repeatedly, play highly significant in the process
Catalytic action, agree with very much with this technique.
Described penetrating agent is a kind of surfactant, including nonionic surfactant and ion and ion-type
Surfactant.The γ cmc of nonionic surfactant is respectively less than 30mN/m, the γ of ionic surfactant
Cmc is at about 40mN/m.Nonionic 1～2 order of magnitude lower than the cmc of ionic surfactant, easily
Form micelle, beneficially emulsifying.Therefore selecting nonionic surfactant to make penetrating agent, inventor is through excessive
Amount test repeatedly proves: when employing penetrating agent is JFC, and concentration in the solution is 1-7g/L, preferably
When being 2-3g/L, the highest with the compatible degree of this technique, it is possible to greatly reduce lyocell fiber cellulose fiber fibril
Change tendency.
In lyocell fiber cellulose fiber of the present invention crosslinking post-processing approach, it is special that the time of dipping does not has
Requirement, is preferably immersed in 5-10min in cross-linking agent solution by lyocell fiber cellulose fiber.Within the range,
Cross-linking agent can be made the most sufficiently and uniformly to be impregnated in cellulose fibre while controlling time cost.
In lyocell fiber cellulose fiber of the present invention crosslinking post-processing approach, the temperature of dipping is the most crucial
Requirement, in order to preferably improve the anti-Fibrillation Properties of lyocell fiber cellulose fiber, control solution temperature is 60-90
DEG C scope, the scope of preferably 60-70 DEG C.At this temperature, solution system is more stable, and then permissible
Preferably protect the self structure of fiber, it is ensured that the physical property of fiber.
At lyocell fiber cellulose fiber of the present invention after crosslinking Treatment, cross-linking agent is at lyocell fiber element
In the range of fixed amount on fiber is the 0.1-3% (weight) of cellulose fibre weight, preferably fixed amount exists
In the range of 0.2-0.35%.Cross-linking agent fixed amount is controlled within the range, advantageously ensures that cross-linking effect, carry
The anti-Fibrillation Properties of high lyocell fiber cellulose fiber.
Owing to have employed technique scheme, the invention has the beneficial effects as follows:
The present invention can use on the industrial production line producing lyocell fiber cellulose fiber, and lyocell is fine
Cellulose fiber shapes through coagulating bath, wash, cut off after, directly the application present invention carries out cross-linking post processing, or
Person applies the present invention to the fibre bundle under extended state and carries out crosslinking Treatment, dries in washing, can
Obtain the lyocell fiber with anti-Fibrillation Properties.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect,
Below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency, step is as follows:
(1) lyocell fiber is made to immerse 5min in a kind of solution containing cross-linking agent, catalyst and penetrating agent,
Keeping temperature 60 C, wherein, cross-linking agent is Biformyl, and concentration is 70g/L in the solution, and catalyst is wine
Stone acid concentration in the solution is 4g/L, and penetrating agent is JFC, and concentration in the solution is 2g/L, it is ensured that cross-linking agent
Fixed amount on lyocell fiber cellulose fiber is the 0.2% of cellulose fibre weight,
(2) after this fiber being dried at 75 DEG C pretreatment 90s, then at 125 DEG C, bake 90s, make
Fiber solidifying crosslinking；
(3) fiber after baking washs 3 times with the soft water of 50 DEG C, then washs 1 time with cold soft water:
(4) finally fiber is dried at 80 DEG C, i.e. can get antigen fibrillation lyocell fiber cellulose fiber.
Embodiment 2
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency, step is as follows:
(1) lyocell fiber is made to immerse in a kind of aqueous solution containing cross-linking agent, catalyst and penetrating agent
10min, keeps temperature 70 C, and wherein, cross-linking agent is Biformyl, and concentration is 80g/L in the solution, catalysis
Agent is aluminum sulfate, and concentration is 0.8g/L in the solution, and penetrating agent is JFC, and concentration in the solution is 3g/L,
Ensure that cross-linking agent fixed amount on lyocell fiber cellulose fiber is the 0.35% of cellulose fibre weight；
(2) after this fiber being dried at 85 DEG C pretreatment 150s, then at 135 DEG C, bake 150s,
Make fiber solidifying crosslinking；
(3) fiber after baking washs 7 times with the soft water of 50 DEG C, then washs 3 times with cold soft water:
(4) finally fiber is dried at 80 DEG C, i.e. can get antigen fibrillation lyocell fiber cellulose fiber.
Embodiment 3
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency, step is as follows:
(1) lyocell fiber is made to immerse 7min in a kind of aqueous solution containing cross-linking agent, catalyst and penetrating agent,
Keeping temperature 65 DEG C, wherein, cross-linking agent is Biformyl, and concentration is 90g/L in the solution, and catalyst is chlorine
Changing magnesium, concentration is 7g/L in the solution, and penetrating agent is JFC, and concentration in the solution is 2.5g/L, it is ensured that hand over
Connection agent fixed amount on lyocell fiber cellulose fiber is the 0.3% of cellulose fibre weight；
(2) after this fiber being dried at 80 DEG C pretreatment 130s, then at 130 DEG C, bake 130s,
Make fiber solidifying crosslinking；
(3) fiber after baking washs 5 times with the soft water of 50 DEG C, then washs 2 times with cold soft water:
(4) finally fiber is dried at 80 DEG C, i.e. can get antigen fibrillation lyocell fiber cellulose fiber.
Analysis method (mensuration of original fiber degree)
The method of testing of wet friction value: experimental provision is the steel pole of wetted cotton cladding, is contained in one
Different rotating speeds can be set as required with on the motor of speed governing, and above fiber, increases flesh dripping device.
Under some tension, lyocell fiber and the friction roller moistening cotton with Surface coating are rubbed clockwise,
Mensuration friction roller starts rotational value lyocell fiber bundle and ruptures completely the required time, and is defined as wet
Friction valve.Each sample test 6 times, takes its meansigma methods seat wet friction value, and wet friction value is the biggest, shows
The anti-Fibrillation Properties of lyocell fiber is the strongest.
Embodiment 4
Under room temperature, Biformyl, magnesium chloride and penetrating agent JFC are configured to cross-linking agent solution, in this cross-linking agent solution
The content of Biformyl is 70g/L, the content of magnesium chloride be the content of 6g/L, JFC be 2g/L, will not do
Dry lyocell fiber cellulose fiber is immersed in the cross-linking agent solution that temperature is 60 DEG C, and dip time is respectively
5,10,15,20min, composite fibre is dried, then by the fiber that dries at 80 DEG C of pretreatment 90s,
Then at 120 DEG C, bake 120s, finally fiber wash is dried.Gained fiber wet friction value and mechanical property
Table 1 can be listed in.
Table 1
Dip time (min) wet friction value (min) fracture strength (cN/dtex) elongation at break (%)
——1.743.5214.50
| 5 | 8.16 | 3.41 | 14.10 |
| 10 | 8.21 | 3.38 | 13.86 |
| 15 | 8.23 | 3.31 | 14.05 |
| 20 | 8.27 | 3.35 | 13.98 |
From content in table 1, cross-linking agent is used to carry out lyocell fiber cellulose fiber cross-linking post processing,
Can effectively improve the anti-Fibrillation Properties of fiber.Along with the dip time in crosslinker solution of fiber extends,
Fiber wet friction value does not increase significantly, and the physical property impact on fiber is not very big, from the time
Becoming original to consider, fiber dip time in crosslinker solution controls at 5-10min.
Embodiment 5
Under room temperature, Biformyl, magnesium chloride and penetrating agent JFC are configured to cross-linking agent solution, in this cross-linking agent solution
The content of Biformyl is 70g/L, aluminum sulfate concentration be the content of 1.0g/L, JFC be 2g/L, will not do
Dry lyocell fiber cellulose fiber impregnates 5min in cross-linking agent solution, be immersed in temperature be respectively 60,70,
80,90 DEG C, by the fiber that dries at 80 DEG C of pretreatment 90s, then at 120 DEG C, 120s is baked, finally
Fiber wash is dried.Gained fiber wet friction value and mechanical property are listed in table 2.
Table 2
| Dipping temperature (DEG C) | Wet friction value (min) | Fracture strength (cN/dtex) | Elongation at break (%) |
| —— | 1.69 | 3.49 | 15.00 |
| 60 | 8.18 | 3.41 | 14.80 |
| 70 | 8.25 | 3.45 | 14.73 |
| 80 | 8.31 | 3.39 | 14.79 |
| 90 | 8.28 | 3.37 | 14.69 |
From content in table 2, cross-linking agent is used to carry out lyocell fiber cellulose fiber cross-linking post processing,
Can effectively improve the anti-Fibrillation Properties of fiber.Along with the raising of crosslinker solution temperature, the wet of fiber rubs
Wiping value does not significantly improve, but presents fluctuation status, affects the least, from saving on the physical property of fiber
From the point of view of energy aspect, the temperature of crosslinker solution controls in the range of 60-70 DEG C.
Embodiment 6
Under room temperature, Biformyl, magnesium chloride and penetrating agent JFC are configured to cross-linking agent solution, in this cross-linking agent solution
The content of Biformyl is 80g/L, the content of magnesium chloride be the content of 7g/L, JFC be 2g/L, will not do
Dry lyocell fiber cellulose fiber impregnates 5min in the cross-linking agent solution of 65 DEG C.Then by fiber preheating
Reason, pretreatment temperature is respectively 60,70,80,90 DEG C, then at 120 DEG C, fiber is baked 120s,
After fiber wash is dried.Gained fiber wet friction value and mechanical property are listed in table 3.
Table 3
| Preheating temperature (DEG C) | Preheating time (s) | Wet friction value (min) | Fracture strength (cN/dtex) | Elongation at break (%) |
| —— | —— | 1.70 | 3.51 | 15.20 |
| Do not preheat | 0 | 6.32 | 3.45 | 14.87 |
| 60 | 120 | 8.05 | 3.39 | 14.81 |
| 70 | 120 | 8.97 | 3.31 | 14.67 |
| 80 | 60 | 8.26 | 3.35 | 14.70 |
| 80 | 120 | 9.35 | 3.20 | 14.59 |
| 80 | 180 | 10.05 | 3.05 | 14.42 |
| 90 | 120 | 10.15 | 3.08 | 14.31 |
By table 3 it is found that after cross-linking in processing procedure, after increasing the pre-heat treatment step, fiber anti-
Fibrillation Properties is significantly improved.Preheating temperature is the highest, and the time is the longest, and fiber wet friction value is the biggest, antigen
Fibrillation performance is the best, but too high treatment temperature and long process time, and low-fiber physics all can drop
Performance.In the present invention, the pre-heat treatment temperature controls at 75-85 DEG C, and the time controls at 90-150s.
Embodiment 7
Under room temperature, Biformyl, magnesium chloride and penetrating agent JFC are configured to cross-linking agent solution, in this cross-linking agent solution
The content of Biformyl is 80g/L, the content of magnesium chloride be the content of 7g/L, JFC be 2g/L, will not do
Dry lyocell fiber cellulose fiber impregnates 5min in the cross-linking agent solution of 65 DEG C.Then by fiber 80
The pre-heat treatment 120s at DEG C, is baking certain time by fiber respectively at 120,130,140,150 DEG C,
Finally fiber wash is dried.Gained fiber wet friction value and mechanical property are listed in table 4.
Table 4
| Baking temperature (DEG C) | Bake the time (s) | Wet friction value (min) | Fracture strength (cN/dtex) | Elongation at break (%) |
| —— | —— | 1.72 | 3.53 | 15.17 |
| 120 | 120 | 9.31 | 3.28 | 14.89 |
| 130 | 60 | 7.51 | 3.25 | 14.73 |
| 130 | 120 | 9.87 | 3.15 | 14.27 |
| 130 | 180 | 10.25 | 2.97 | 13.37 |
| 130 | 240 | 10.97 | 2.78 | 12.94 |
| 140 | 120 | 10.81 | 2.74 | 13.21 |
| 150 | 120 | 12.13 | 2.56 | 11.87 |
From the content in table 4, lyocell fiber cellulose fiber is after crosslinking post processing, along with baking temperature
The rising spent and the prolongation baking the time, the wet friction value of fiber has significantly rising, and the antigen of fiber is fine
Change performance to be obviously improved, but the logistics performance of fiber has had serious decline, so the present invention is the warmest
Degree is for 125-135 DEG C, and the time is 90-150s.
Embodiment 8
Under room temperature, Biformyl, catalyst and penetrating agent JFC are configured to cross-linking agent solution, in this cross-linking agent solution
The content of Biformyl is 80g/L, and kind and the content of catalyst see table, and the content of JFC is 2g/L, will not
Once the lyocell fiber cellulose fiber being dried impregnates 5min in the cross-linking agent solution of 65 DEG C.Then fiber is existed
The pre-heat treatment 120s at 80 DEG C, is baking fiber the 120s time respectively at 130 DEG C, is finally being washed by fiber
Wash dry.Gained fiber wet friction value and mechanical property are listed in table 5.
Table 5
From the content of table 5, the addition of catalyst considerably increases the efficiency of aldolisation, crosslinking Treatment
The wet friction value of rear fiber has had significant increase, and the anti-Fibrillation Properties of fiber is significantly improved.Three kinds
Cross-linking efficiency is all significantly improved by catalyst, and in three, the catalytic capability of magnesium chloride is best.The present invention is excellent
Select magnesium chloride catalyst, concentration span of control 6-8g/L, if using aluminum sulfate as catalyst agent, preferred concentration control
Scope processed is 0.7-0.8g/L, if selecting tartaric acid catalyst, preferred concentration span of control is 4-5g/L.
Embodiment 9
Under room temperature, Biformyl, catalyst and penetrating agent JFC are configured to cross-linking agent solution, in this cross-linking agent solution
The content of Biformyl is 70～100g/L, the content of catalyst magnesium chloride be the content of 7g/L, JFC be 2g/L,
The lyocell fiber cellulose fiber not being dried is impregnated 5min in the cross-linking agent solution of 65 DEG C.Then by fibre
Dimension the pre-heat treatment 120s at 80 DEG C, is baking the 120s time, respectively finally by fibre at 130 DEG C by fiber
Dimension washing is dried.Gained fiber wet friction value and mechanical property are listed in table 6.
Table 6
Can be obtained by table 6, along with the raising of cross-linking agent Biformyl concentration, the fixed amount of cross-linking agent in fiber
Also being gradually increased, the wet friction value of fiber is the most also increasing, and the anti-Fibrillation Properties of fiber has and substantially carries
Rising, the logistics performance of fiber does not significantly decrease.But after the concentration of cross-linking agent is more than 80g/L, with dense
The anti-Fibrillation Properties increasing fiber of degree promotes and inconspicuous, so the concentration of cross-linking agent Biformyl is preferred
70-90g/L, now in cellulose fibre, cross-linking agent fixed amount scope is between 0.2-0.35%.
The present invention is not limited to above-mentioned detailed description of the invention, and all technology based on the present invention are conceived, done
Structure on improvement, each fall among protection scope of the present invention.
Claims (5)
1. the method reducing lyocell fiber cellulose fiber fibrillation tendency, it is characterised in that: step is as follows:
(1) lyocell fiber is made to immerse in a kind of solution containing cross-linking agent, catalyst and penetrating agent；Institute
Stating cross-linking agent is the carbochain twain-aldehyde compound cross-linking agent at C2-C6, and described catalyst is magnesium chloride, aluminum sulfate or wine
One in stone acid, described catalyst concentration in the solution is respectively magnesium chloride 6-8g/L, aluminum sulfate
0.7-0.8g/L, tartaric acid 4-5g/L；Described penetrating agent is JFC, and penetrating agent concentration in the solution is
2-3g/L；Lyocell fiber cellulose fiber is impregnated 5-10min in the solution, and holding solution temperature is
60-70℃；
(2) pretreatment 90-150s, then roasting at 125-135 DEG C at 75-85 DEG C after this fiber being dried
Dry 90-150s, make fiber solidifying crosslinking；
(3) fiber after baking washs 3-7 time with the soft water of 50 DEG C, then with cold soft water washing 1-3
Secondary；
(4) finally fiber is dried at 80 DEG C, i.e. can get antigen fibrillation lyocell fiber cellulose fiber.
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency the most as claimed in claim 1, it is special
Levying and be: in step (1), lyocell fiber is the hygrometric state fiber of undried.
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency the most as claimed in claim 1, it is special
Levying and be: in step (1), described cross-linking agent is Biformyl.
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency the most as claimed in claim 3, it is special
Levying and be: in step (1), described Biformyl concentration in the solution is 70-90g/L.
A kind of method reducing lyocell fiber cellulose fiber fibrillation tendency the most as claimed in claim 1, it is special
Levy and be: the lyocell fiber cellulose fiber of step (1) is after crosslinking Treatment, it is ensured that cross-linking agent exists
Fixed amount on lyocell fiber cellulose fiber is the 0.2-0.35% of cellulose fibre weight.
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| CN105926272A (en) * | 2016-05-12 | 2016-09-07 | 东华大学 | Preparation method of superfine-velvet Lyocell fiber fabric |
| CN109402774B (en) * | 2018-11-02 | 2021-10-15 | 恒天海龙（潍坊）新材料有限责任公司 | Anti-fibrillation cellulose fiber and preparation method thereof |
| CN110172754B (en) * | 2019-02-26 | 2021-10-08 | 东华大学 | Preparation method of anti-fibrillation cellulose fibers |
| KR102440861B1 (en) * | 2020-05-26 | 2022-09-05 | 오영세 | Method for manufacturing lyocell fiber and lyocell fiber therefrom |
| CN111893749B (en) * | 2020-08-14 | 2022-12-06 | 亚太森博（山东）浆纸有限公司 | Crosslinking agent and method for fibrillation-resistant treatment of lyocell fiber |
| CN115161989A (en) * | 2022-09-02 | 2022-10-11 | 青岛大学 | Scouring and bleaching process for Lyocell knitted fabric |
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| Lyocell针织物的整理;吴重亮等;《广西纺织科技》;20010930;第30卷(第3期);第19-22页 * |
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| CN104005225A (en) | 2014-08-27 |
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