CN104004286A - High-light-transmittance and high-impact-resistant polystyrene sheet and manufacturing method thereof - Google Patents
High-light-transmittance and high-impact-resistant polystyrene sheet and manufacturing method thereof Download PDFInfo
- Publication number
- CN104004286A CN104004286A CN201410256823.0A CN201410256823A CN104004286A CN 104004286 A CN104004286 A CN 104004286A CN 201410256823 A CN201410256823 A CN 201410256823A CN 104004286 A CN104004286 A CN 104004286A
- Authority
- CN
- China
- Prior art keywords
- sheet
- impact polystyrene
- light transmittance
- sheet material
- impact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/30—Extrusion nozzles or dies
- B29C48/305—Extrusion nozzles or dies having a wide opening, e.g. for forming sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
- B29C2948/92114—Dimensions
- B29C2948/92152—Thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92904—Die; Nozzle zone
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses a high-light-transmittance and high-impact-resistant polystyrene sheet and a manufacturing method thereof. The sheet comprises the following components by weight percent: 70% of general polystyrene and 30% of high-impact-resistant polystyrene. The manufacturing method comprises the following steps: mixing 70% of general polystyrene with 30% of high-impact-resistant polystyrene; performing melt extrusion on a mixture through an extruder at 180 DEG C to -250 DEG C; feeding a melt into a die head for casting the melt into a thick sheet at 200-250 DEG C; longitudinally and transversely drawing and shaping the thick sheet successively to obtain a thin sheet; and trimming the thin sheet, measuring the thickness, coating one/double surfaces with silicone oil, winding, performing aging treatment, and slicing. According to the method, the impact-resistant strength of the sheet is improved; the sheet is thin and uniform by reasonably controlling the melting temperature, the die head temperature and the longitudinal drawing speed of the extruder; the sheet has the advantages of high light transmittance and easy stacking and can be widely applied to packages of products such as foods, drugs, electronics, clothes and toys.
Description
Technical field
The present invention relates to technical field of polymer materials, relate in particular to a kind of high light transmittance, high-impact polystyrene sheet material and manufacture method thereof.
Background technology
Polystyrene film is a kind of novel green wrapping material that development in recent years is got up, the polyethylene, the polyvinyl chloride film etc. that use compared with tradition, it has that intensity is high, rigidity is large, nontoxicity, easily degraded, easy coloring, have good glossiness and transparency, the advantage such as easy to process, be widely used in all kinds of article if artwork, daily necessities, metal products are particularly in the packaging of food.Developed countries at present, as the biaxially oriented polystyrene film consumption of the U.S., Canada, Japan etc., oneself accounts for the more than 60% of all film classes.
But, there are many weak points in common polystyrene material, as low in fragility, shock strength, be prone to cracking, fire-retardant fireproof is poor, weathering resistance is bad, heat-drawn wire is low etc., and because the current control temperature generally adopting in process of production makes the polystyrene film thickness produced excessive, can not meet the day by day wide application demand of client, these shortcomings have all limited the range of application of polystyrene greatly.
Thereby, need not reduce under the prerequisite of polystyrene material physical properties at present, need badly to material produce technique improve to obtain that thinness controllability is strong, good toughness, polystyrene sheet material that transmittance is high, meet the current market requirement.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of high light transmittance, high-impact polystyrene sheet material and manufacture method thereof, improves its resistance to impact shock and light transmission.
For solving the problems of the technologies described above, the object of the invention is to be achieved through the following technical solutions.
A kind of high light transmittance, high-impact polystyrene sheet material, its composition is (%) by weight ratio:
General Purpose Polystyrenre 70%;
High-impact polystyrene 30%.
A manufacture method for high light transmittance described above, high-impact polystyrene sheet material, comprises step:
(1) 70% General Purpose Polystyrenre and 30% high-impact polystyrene are fully uniformly mixed resulting mixture by weight percentage;
(2) by described mixture by forcing machine through melt extruding, melt temperature is controlled between 180 DEG C to 250 DEG C;
(3) melts is sent into die head and extrude, cast sheet, in die head, temperature is controlled between 200 DEG C to 250 DEG C;
(4) sheet is first carried out to preheating on vertical drawing machine, carry out longitudinal stretching and sizing simultaneously; On horizontal drawing machine, carry out again preheating, carry out cross directional stretch and sizing simultaneously, obtain thin slice;
(5) described thin slice is carried out to deburring and thickness measuring, single-side/double-side is coated with silicone oil, after rolling, ageing treatment, cuts.
Preferably, between described step (1) and (2), also comprise step: described mixture is dropped into blower fan hopper, blow to moisture eliminator and carry out drying treatment through roots blower.
Preferably, in described step (3), by vacuum pump, mixture after treatment drying is drawn to the hopper of forcing machine.
Preferably, the preheating temperature of described vertical drawing machine is controlled between 50 DEG C to 150 DEG C.
Preferably, the preheating temperature of described horizontal drawing machine is controlled between 100 DEG C to 150 DEG C.
The present invention has following beneficial effect:
The present invention has improved the resistance to impact shock of sheet material by having increased HIPS; By the reasonable control of the melt temperature to forcing machine, die head temperature and longitudinal stretching speed, even thickness and the thinness of having guaranteed the polystyrene sheet material of producing are controlled, and sheet material transmittance provided by the invention is high, easily stacking, the packaging that can be widely used in the products such as food, medicine, electronics, clothes, toy, has met the market requirement greatly.
Brief description of the drawings
Fig. 1 is the high light transmittance that provides of the embodiment of the present invention, preparation method's schema of high-impact polystyrene sheet material.
Embodiment
High light transmittance provided by the invention, high-impact polystyrene sheet material, its composition is (%) by weight ratio: GPPS(General Purpose Polystyrenre) 70%; HIPS(high-impact polystyrene) 30%.
In the present invention, the complete processing of high light transmittance, high-impact polystyrene sheet material as shown in Figure 1, comprising:
1, first take by weight ratio GPPS and HIPS, mix; The raw material that mixes is dropped into hopper, blow to moisture eliminator and carry out drying treatment through roots blower;
2, from moisture eliminator, extract mixture by vacuum pump and send into the hopper of forcing machine;
3, said mixture on forcing machine through melting, extrude, melt temperature is controlled between 180 DEG C to 250 DEG C;
4, after filter filters out impurities, melts is sent into die head and extrude, cast sheet, in die head, temperature is controlled between 200 DEG C to 250 DEG C;
5, sheet is carried out to preheating on vertical drawing machine, preheating temperature is controlled between 50 DEG C to 150 DEG C, carries out longitudinal stretching and sizing simultaneously; The film obtaining is carried out on horizontal drawing machine to preheating, preheating temperature is controlled between 100 DEG C to 150 DEG C, carries out cross directional stretch and sizing simultaneously again;
6, thin slice is carried out to deburring and thickness measuring, single-side/double-side is coated with silicone oil, then carries out rolling, and the packing of product that was cut into required specification at parent roll through 48 hours after ageing treatment is dispatched from the factory.
For ease of the present invention is further understood, now describe the present invention in conjunction with specific embodiments:
In the present embodiment, polystyrene sheet material is mixed in container by weight GPPS 70%, HIPS 30%, drop into stub bar, dispel to moisture eliminator and carry out drying treatment through roots blower.Afterwards, the material mixing is joined in the hopper of twin screw extruder, after melt blending, send into T-shaped die head and extrude sheet; Wherein, forcing machine processing temperature is 180 DEG C-250 DEG C, and die head temperature is 200 DEG C-250 DEG C.Then, to sheet carry out longitudinal stretching, cross directional stretch obtains thin slice, the preheating temperature of longitudinal stretching is 50 DEG C, the preheating temperature of cross directional stretch is 100 DEG C.Deburring thickness measuring, single-side/double-side is coated with silicone oil, and rolling, cuts after ageing treatment and obtains a sample in order to performance test.
Material properties test data are in table 1:
Table 1
From above-mentioned the performance test results, apply raw material and the corresponding manufacture method of weight proportion of the present invention, the polystyrene of producing has that transmittance is high, even, thin thickness and the advantage such as even.
Above high light transmittance provided by the present invention, high-impact polystyrene sheet material and manufacture method thereof are described in detail, applied specific case herein principle of the present invention and embodiment are set forth, the explanation of above embodiment is just for helping to understand method of the present invention and core concept thereof; , for one of ordinary skill in the art, according to thought of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention meanwhile.
Claims (6)
1. high light transmittance, a high-impact polystyrene sheet material, is characterized in that, its composition is (%) by weight ratio:
General Purpose Polystyrenre 70%;
High-impact polystyrene 30%.
2. a manufacture method for high light transmittance, high-impact polystyrene sheet material as claimed in claim 1, is characterized in that, comprises step:
(1) 70% General Purpose Polystyrenre and 30% high-impact polystyrene are fully uniformly mixed resulting mixture by weight percentage;
(2) by described mixture by forcing machine through melt extruding, melt temperature is controlled between 180 DEG C to 250 DEG C;
(3) melts is sent into die head and extrude, cast sheet, in die head, temperature is controlled between 200 DEG C to 250 DEG C;
(4) sheet is first carried out to preheating on vertical drawing machine, carry out longitudinal stretching and sizing simultaneously; On horizontal drawing machine, carry out again preheating, carry out cross directional stretch and sizing simultaneously, obtain thin slice;
(5) described thin slice is carried out to deburring and thickness measuring, single-side/double-side is coated with silicone oil, after rolling, ageing treatment, cuts.
3. the manufacture method of high light transmittance as claimed in claim 2, high-impact polystyrene sheet material, it is characterized in that: between described step (1) and (2), also comprise step: described mixture is dropped into blower fan hopper, blow to moisture eliminator and carry out drying treatment through roots blower.
4. the manufacture method of high light transmittance as claimed in claim 3, high-impact polystyrene sheet material, is characterized in that: in described step (3), by vacuum pump, mixture after treatment drying is drawn to the hopper of forcing machine.
5. the manufacture method of high light transmittance as claimed in claim 2, high-impact polystyrene sheet material, is characterized in that: the preheating temperature of described vertical drawing machine is controlled between 50 DEG C to 150 DEG C.
6. the manufacture method of high light transmittance as claimed in claim 2, high-impact polystyrene sheet material, is characterized in that: the preheating temperature of described horizontal drawing machine is controlled between 100 DEG C to 150 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410256823.0A CN104004286A (en) | 2014-06-10 | 2014-06-10 | High-light-transmittance and high-impact-resistant polystyrene sheet and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410256823.0A CN104004286A (en) | 2014-06-10 | 2014-06-10 | High-light-transmittance and high-impact-resistant polystyrene sheet and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104004286A true CN104004286A (en) | 2014-08-27 |
Family
ID=51365202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410256823.0A Pending CN104004286A (en) | 2014-06-10 | 2014-06-10 | High-light-transmittance and high-impact-resistant polystyrene sheet and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104004286A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530581A (en) * | 2014-12-26 | 2015-04-22 | 深圳永合高分子材料有限公司 | Yellow polystyrene sheet and manufacturing method thereof |
| CN104829956A (en) * | 2015-04-21 | 2015-08-12 | 侨健新能源科技（苏州）有限公司 | Compound bidirectionally-stretched polystyrene and method for manufacturing same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102311589A (en) * | 2010-12-21 | 2012-01-11 | 深圳市科聚新材料有限公司 | Transparent K-resin/GPPS (general purpose polystyrene) alloy material and preparation method thereof |
| CN103030897A (en) * | 2012-12-14 | 2013-04-10 | 上海洛兴包装材料有限公司 | Anti-fog sheet and manufacturing method thereof |
-
2014
- 2014-06-10 CN CN201410256823.0A patent/CN104004286A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102311589A (en) * | 2010-12-21 | 2012-01-11 | 深圳市科聚新材料有限公司 | Transparent K-resin/GPPS (general purpose polystyrene) alloy material and preparation method thereof |
| CN103030897A (en) * | 2012-12-14 | 2013-04-10 | 上海洛兴包装材料有限公司 | Anti-fog sheet and manufacturing method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘鹰: "双向拉伸透明抗静电聚苯乙烯片材的研制", 《包装世界》 * |
| 杜强国等: "《塑料工业手册 苯乙烯系树脂》", 31 October 2004, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530581A (en) * | 2014-12-26 | 2015-04-22 | 深圳永合高分子材料有限公司 | Yellow polystyrene sheet and manufacturing method thereof |
| CN104829956A (en) * | 2015-04-21 | 2015-08-12 | 侨健新能源科技（苏州）有限公司 | Compound bidirectionally-stretched polystyrene and method for manufacturing same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104004283A (en) | Environment-friendly two-way stretching polystyrene sheet material for printing and manufacture method thereof | |
| CN104004284A (en) | High-toughness polystyrene sheet and manufacturing method thereof | |
| CN104031324A (en) | Antistatic biaxial oriented polystyrene sheet and manufacturing method thereof | |
| JP2013010931A5 (en) | ||
| CN109016768A (en) | A kind of biaxially oriented polyester film and preparation method thereof | |
| CN102922837B (en) | For making composite sheet and the processing method thereof of antistatic carrying belt | |
| CN103571163B (en) | Regenerative PET bottle sheet and regeneration LDPE alloy production multi-layer co-extruded film PP Pipe Compound and preparation method thereof | |
| CN104004286A (en) | High-light-transmittance and high-impact-resistant polystyrene sheet and manufacturing method thereof | |
| CN103009751B (en) | Biaxial stretching polypropylene high heat-seal film and manufacturing method thereof | |
| CN103408833A (en) | Preparation method of high-performance thermochromic material and suckers | |
| CN104527101A (en) | Production technology for R-PVC tangle film | |
| CN104558878A (en) | Polystyrene sheet capable of being uniformly contracted and applied to toy manufacturing, and manufacturing method of polystyrene sheet | |
| CN106550800B (en) | Polyolefin greenhouse film and preparation method thereof | |
| CN104530580A (en) | Brown polystyrene sheet and manufacturing method thereof | |
| CN104530581A (en) | Yellow polystyrene sheet and manufacturing method thereof | |
| CN102873950A (en) | High-surface-energy double-direction stretching polypropylene thin film and manufacturing method thereof | |
| CN104558876A (en) | Golden polystyrene plastic sheet and manufacturing method thereof | |
| CN103009757B (en) | High-gloss two-way stretched polypropylene heat-sealing film and preparation method thereof | |
| CN104558877A (en) | Blue anti-fogging polystyrene sheet and manufacturing method thereof | |
| CN104004285A (en) | High-antifogging polystyrene sheet suitable for special food packaging and manufacturing method thereof | |
| CN102848569B (en) | Production method of two-way stretched thin film made of 3-hydroxybutyrate-4-hydroxybutyrate copolymer | |
| CN104893132A (en) | Black composite biaxially-oriented polystyrene sheet | |
| CN104829956A (en) | Compound bidirectionally-stretched polystyrene and method for manufacturing same | |
| CN109747253A (en) | A kind of blow molding PE film and its production method | |
| CN106800779A (en) | A kind of preparation technology of the sheet material of polyphenylene sulfide reinforcing material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140827 |