CN104003843B - Adopt the processing method of three-tower differential pressure rectifying ethanol - Google Patents
Adopt the processing method of three-tower differential pressure rectifying ethanol Download PDFInfo
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- CN104003843B CN104003843B CN201410256466.8A CN201410256466A CN104003843B CN 104003843 B CN104003843 B CN 104003843B CN 201410256466 A CN201410256466 A CN 201410256466A CN 104003843 B CN104003843 B CN 104003843B
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
- C07C29/82—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by azeotropic distillation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
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Abstract
The present invention relates to a kind of processing method adopting three-tower differential pressure rectifying ethanol, mainly solve the high problem of prior art energy consumption.The present invention is by adopting a kind of processing method adopting three-tower differential pressure rectifying ethanol, mainly comprise the following steps: the part that (1) comprises the stock liquid of ethanol enters rectifying tower I, obtain thick wine logistics I at the tower top of rectifying tower I, tower reactor obtains useless mash I; (2) part comprising the stock liquid of ethanol enters rectifying tower II, obtains thick wine logistics II at the tower top of rectifying tower II, and tower reactor obtains useless mash II; (3) thick wine logistics I and thick wine logistics II enter rectifying tower III after converging, and obtain azeotropic ethanol logistics at the tower top of rectifying tower III, the technical scheme that tower reactor obtains smart tower bottoms solves the problems referred to above preferably, can be used in the rectifying of ethanol.
Description
Technical field
The present invention relates to a kind of processing method adopting three-tower differential pressure rectifying ethanol.
Background technology
Along with the problem such as worsening shortages, environmental pollution, Greenhouse effect day by day serious of petroleum resources, alcohol fuel is little as a kind of environmental pollution, and the energy of alternative oil is paid close attention to widely.Alcohol fuel is as a kind of alternative fuel of gasoline, the energy that burning is released is certain, the energy consumption of producing alcohol fuel must be far smaller than the energy of burning releasing, otherwise promoting the use of of alcohol fuel will be restricted, therefore, the production power saving of alcohol fuel is more and more outstanding, and the energy consumption of producing alcohol fuel mainly concentrates on distillation dehydration workshop section, and the energy consumption reducing distillation dehydration workshop section is crucial.Although had significant improvement from the production method of fermenting-ripening mash production alcohol fuel at present, still there is the shortcoming that energy consumption is high.
CN101157890A provides a kind of fuel ethanol production equipment and method, is the topping still of two-tower process and rectifying tower are split as two topping stills and two rectifying tower respectively, forms and produces alcohol fuel by wine with dregs tower, rectifying tower, recovery tower three tower process.Although only there is recovery tower one tower to use live steam heating in this flow process, the thick capacity for liquor of recovery tower process is too large, and the live steam amount causing recovery tower to use is excessive; In addition, the heat of dehydrated alcohol steam after adsorption tower dehydration is not utilized, so whole system do not reach optimization, energy consumption is still very high.
CN102126921B provides a kind of three tower heating means of azeotropic ethanol processed: adopt topping still, low-pressure distillation tower, high-pressure rectification tower three tower process to produce alcohol fuel.In this flow process, the thick wine of topping still tower top enters low-pressure distillation tower bottom, and low-pressure distillation top of tower extraction azeotropic ethanol, bottoms material enter high-pressure rectification tower, and a high-pressure rectification top of tower discharging part is as backflow, and another part enters low-pressure distillation top of tower.The higher live steam of pressure is as an effect steam to the heating of high-pressure rectification tower, and high-pressure rectification column overhead gas heats to low-pressure distillation tower, and topping still heat is provided by the dehydrated alcohol gas of Molecular sieve dehydration units and low-pressure distillation tower overhead gas.Only external heat amount on smart tower in technique, the energy consumption of topping still needs subsequent technique to provide, therefore the large young pathbreaker of total energy consumption is directly limited to the energy consumption of topping still, and feed composition is very large for the energy consumption of topping still.This processing method, when ethanol input concentration is 8 ~ 12 % by weight, can obtain comparatively less energy-consumption, and general biofuel alcohol concn is lower, and be 3 ~ 6 % by weight, energy consumption will rise greatly at this concentration.
The present invention solves this problem targetedly.
Summary of the invention
Technical problem to be solved by this invention is the problem that prior art energy consumption is high, provides a kind of processing method of employing three-tower differential pressure rectifying ethanol newly.The method is used for, in the rectifying of ethanol, having the advantage that energy consumption is low.
For solving the problem, the technical solution used in the present invention is as follows: a kind of processing method adopting three-tower differential pressure rectifying ethanol, mainly comprise the following steps: the part that (1) comprises the stock liquid of ethanol enters rectifying tower I, obtain thick wine logistics I at the tower top of rectifying tower I, tower reactor obtains useless mash I; (2) part comprising the stock liquid of ethanol enters rectifying tower II, obtains thick wine logistics II at the tower top of rectifying tower II, and tower reactor obtains useless mash II; (3) thick wine logistics I and thick wine logistics II enter rectifying tower III after converging, and obtain azeotropic ethanol logistics at the tower top of rectifying tower III, tower reactor obtains smart tower bottoms; Wherein, rectifying tower I tower reactor first reboiler is heated by dehydrated alcohol gas, rectifying tower I tower reactor second reboiler is heated by the thick wine logistics II from rectifying tower II tower top, rectifying tower II tower reactor reboiler is heated by a part of azeotropic ethanol logistics from rectifying tower III tower top, and rectifying tower III tower reactor reboiler is by steam heating; The working pressure of rectifying tower I is 20 ~ 90kPa, and the working pressure of rectifying tower II is 120 ~ 180kPa, and the working pressure of rectifying tower III is 400 ~ 600kPa.
In technique scheme, preferably, described in comprise ethanol stock liquid after preheater preheats, enter rectifying tower I and rectifying tower II respectively, described preheater is heated by the thick wine logistics I from rectifying tower I tower top; The azeotropic ethanol logistics part that rectifying tower III tower top obtains is back to rectifying tower III after entering the heat exchange of rectifying tower II tower reactor reboiler.
In technique scheme, preferably, the described dehydrated alcohol gas for heating rectifying tower I tower reactor first reboiler is from Molecular sieve dehydration units.
In technique scheme, preferably, the operational condition of described rectifying tower I: stage number is 20 ~ 30, tower top temperature is 60 ~ 80 DEG C, bottom temperature is 80 ~ 100 DEG C, and working pressure is 30 ~ 70kPa, feed plate position from top to bottom numerical digit in 2nd ~ 6 pieces of column plate places; The operational condition of rectifying tower II: stage number is 20 ~ 30, tower top temperature is 90 ~ 110 DEG C, and bottom temperature is 100 ~ 120 DEG C, and working pressure is 130 ~ 170kPa, feed plate position from top to bottom numerical digit in 2nd ~ 6 pieces of column plate places; The operational condition of rectifying tower III: stage number is 40 ~ 70, tower top temperature is 110 ~ 130 DEG C, and bottom temperature is 140 ~ 160 DEG C, and working pressure is 450 ~ 550kPa, feed plate position from top to bottom numerical digit in 35th ~ 65 pieces of column plate places.
In technique scheme, more preferably, the operational condition of described rectifying tower I: stage number is 23 ~ 27, tower top temperature is 65 ~ 78 DEG C, and bottom temperature is 85 ~ 98 DEG C; The operational condition of rectifying tower II: stage number is 23 ~ 27, tower top temperature is 95 ~ 108 DEG C, and bottom temperature is 105 ~ 118 DEG C; The operational condition of rectifying tower III: stage number is 50 ~ 60, tower top temperature is 115 ~ 128 DEG C, and bottom temperature is 145 ~ 158 DEG C.
In technique scheme, preferably, comprise the stock liquid of ethanol by weight, 40 ~ 50% enter rectifying tower I; 50 ~ 60% enter rectifying tower II; By weight, 60 ~ 80% for heating rectifying tower II tower reactor reboiler in the azeotropic ethanol logistics of described rectifying tower III tower top.
In technique scheme, preferably, described thick wine logistics I converges with the thick wine logistics II from rectifying tower I tower reactor second reboiler after preheater and described raw material heat exchange, enters rectifying tower III.
In technique scheme, preferably, in described stock liquid, alcohol concn is 1 ~ 8% by weight, more preferably, is 3 ~ 6%.
In this patent, adopt three rectifying tower, and three pressure towers increase progressively successively, rectifying tower I operates under negative pressure, and rectifying tower II operates near normal pressure, and rectifying tower III operates under higher pressure, thus realizes progressive solution.In addition, rectifying tower I tower reactor first reboiler is heated by dehydrated alcohol gas, rectifying tower I tower reactor second reboiler is heated by the thick wine logistics II from rectifying tower II tower top, rectifying tower II tower reactor reboiler is heated by a part of azeotropic ethanol logistics from rectifying tower III tower top, and rectifying tower III tower reactor reboiler is by steam heating.Therefore, only rectifying tower III tower reactor needs steam, and the triple effect achieving live steam utilizes, and effectively saves energy consumption.Compared with prior art, the energy consumption up to about 24% can be saved, achieve good technique effect.
Below by embodiment, the invention will be further elaborated, but be not limited only to the present embodiment.
Embodiment
[comparative example]
Adopt the flow process described in CN102126921B, the stock liquid comprising ethanol enters the top of topping still, and after slightly heating up in a steamer, tower top obtains thick wine, and tower reactor obtains useless mash.Thick wine enters low-pressure distillation tower bottom, and after rectifying, the azeotropic ethanol fume part that tower top obtains is after condensation, and be back to low pressure essence tower top, another part enters Molecular sieve dehydration units.The tower bottoms of low-pressure distillation tower enters the bottom of high-pressure rectification tower, and after rectifying, tower reactor obtains waste water, and the logistics that tower top obtains enters low-pressure distillation tower top through condensation rear portion, and a part is back to high-pressure rectification tower top.Topping still tower reactor first reboiler is by the heat supply of dehydrated alcohol fume, the azeotropic ethanol fume heating that topping still tower reactor second reboiler is obtained by low-pressure distillation column overhead, the logistics heating that low-pressure distillation tower tower reactor reboiler is obtained by high-pressure rectification column overhead, high-pressure rectification tower tower reactor reboiler is by out-of-bounds live steam heat supply.
Topping still stage number is 26, and feed entrance point is the 2nd piece of column plate place from top to bottom, and working pressure is 40kPa, and tower top temperature is 60 DEG C, and bottom temperature is 81 DEG C.Low-pressure distillation tower stage number is 50, and feed entrance point is the 48th piece of column plate place from top to bottom, and working pressure is 130kPa, and tower top temperature is 85 DEG C, and bottom temperature is 92 DEG C.High-pressure rectification tower stage number is 68, and feed entrance point is the 60th piece of column plate place from top to bottom, and working pressure is 500kPa, and tower top temperature is 125 DEG C, and bottom temperature is 153 DEG C.Energy consumption is accounted result and is shown: steam total flow is 2.6 tons of steam/ton azeotropic ethanol product.
[embodiment 1]
Ethanol content be 5 % by weight stock liquid after preheating, be divided into first, second part, the weight ratio of first, second part is 0.95:1, first part enters the top of rectifying tower I, after slightly heating up in a steamer, tower reactor obtains useless mash I, tower top obtains the thick wine logistics I that ethanol mass content is 40%, and thick wine logistics I is through preheater heat exchange condensation; Second section stock liquid enters the top of rectifying tower II, and after slightly heating up in a steamer, tower reactor obtains useless mash II, and tower top obtains the thick wine logistics II that ethanol mass content is 40%, and thick wine logistics II enters rectifying tower I tower reactor second reboiler heat exchange condensation.Rectifying tower III bottom is entered after condensed thick wine logistics I and thick wine logistics II converge, after rectifying, tower reactor obtains the smart tower bottoms that quality content is greater than 99.99%, tower top obtains azeotropic ethanol logistics, azeotropic ethanol logistics is divided into two portions, the weight ratio of first part and second section is 2.5:1, first part's azeotropic ethanol logistics is back to rectifying tower III tower top after entering rectifying tower II tower reactor reboiler heat exchange condensation, and the logistics of second section azeotropic ethanol enters Molecular sieve dehydration units as output streams.Rectifying tower I tower reactor first reboiler is heated by the dehydrated alcohol gas from Molecular sieve dehydration units.
Rectifying tower I stage number is 25, and feed entrance point is several 2nd piece of column plate place from top to bottom, and working pressure is 31kPa, and tower top temperature is 66 DEG C, and bottom temperature is 81 DEG C.Rectifying tower II stage number is 26, feed entrance point is the 2nd piece of column plate place from top to bottom, working pressure is 131kPa, tower top temperature is 101 DEG C, and bottom temperature is 110 DEG C, and rectifying tower III stage number is 60, feed entrance point is several 55th piece of column plate place from top to bottom, working pressure is 461kPa, and tower top temperature is 122 DEG C, and bottom temperature is 152 DEG C.Energy consumption is accounted result and is shown: steam consumption is 2.01 tons of steam/ton azeotropic ethanol product.
[embodiment 2]
According to the condition described in embodiment 1 and step, ethanol content be 5 % by weight stock liquid after preheating, be divided into first, second part, the weight ratio of first, second part is 1:1, the azeotropic ethanol logistics that rectifying tower III tower top obtains is divided into two portions, and the weight ratio of first part and second section is 2.6:1.
Rectifying tower I stage number is 25, and feed entrance point is several 2nd piece of column plate place from top to bottom, and working pressure is 41kPa, and tower top temperature is 72 DEG C, and bottom temperature is 86.5 DEG C.Rectifying tower II stage number is 27, feed entrance point is the 2nd piece of column plate place from top to bottom, working pressure is 151kPa, tower top temperature is 105 DEG C, and bottom temperature is 115 DEG C, and rectifying tower III stage number is 65, feed entrance point is several 60th piece of column plate place from top to bottom, working pressure is 481kPa, and tower top temperature is 123.6 DEG C, and bottom temperature is 152.6 DEG C.Energy consumption is accounted result and is shown: steam consumption is 1.96 tons of steam/ton azeotropic ethanol product.
[embodiment 3]
According to the condition described in embodiment 1 and step, ethanol content be 5 % by weight stock liquid after preheating, be divided into first, second part, the weight ratio of first, second part is 0.9:1, the azeotropic ethanol logistics that rectifying tower III tower top obtains is divided into two portions, and the weight ratio of first part and second section is 2.4:1.
Rectifying tower I stage number is 26, and feed entrance point is several 2nd piece of column plate place from top to bottom, and working pressure is 51kPa, and tower top temperature is 77.2 DEG C, and bottom temperature is 89.7 DEG C.Rectifying tower II stage number is 27, feed entrance point is the 2nd piece of column plate place from top to bottom, working pressure is 170kPa, tower top temperature is 108.6 DEG C, and bottom temperature is 117.4 DEG C, and rectifying tower III stage number is 65, feed entrance point is several 60th piece of column plate place from top to bottom, working pressure is 501kPa, and tower top temperature is 125 DEG C, and bottom temperature is 155.2 DEG C.Energy consumption is accounted result and is shown: steam consumption is 2.203 tons of steam/ton azeotropic ethanol product.
[embodiment 4]
According to the condition described in embodiment 1 and step, ethanol content be 3 % by weight stock liquid after preheating, be divided into first, second part, the weight ratio of first, second part is 0.8:1, the azeotropic ethanol logistics that rectifying tower III tower top obtains is divided into two portions, and the weight ratio of first part and second section is 3:1.
Rectifying tower I stage number is 30, and feed entrance point is several 5th piece of column plate place from top to bottom, and working pressure is 31kPa, and tower top temperature is 67.3 DEG C, and bottom temperature is 82 DEG C.Rectifying tower II stage number is 30, feed entrance point is the 5th piece of column plate place from top to bottom, working pressure is 151kPa, tower top temperature is 106 DEG C, and bottom temperature is 114 DEG C, and rectifying tower III stage number is 70, feed entrance point is several 65th piece of column plate place from top to bottom, working pressure is 451kPa, and tower top temperature is 121.5 DEG C, and bottom temperature is 150 DEG C.Energy consumption is accounted result and is shown: steam consumption is 2.51 tons of steam/ton azeotropic ethanol product.
[embodiment 5]
According to the condition described in embodiment 1 and step, ethanol content be 6 % by weight stock liquid after preheating, be divided into first, second part, the weight ratio of first, second part is 0.7:1, the azeotropic ethanol logistics that rectifying tower III tower top obtains is divided into two portions, and the weight ratio of first part and second section is 2:1.
Rectifying tower I stage number is 22, and feed entrance point is several 2nd piece of column plate place from top to bottom, and working pressure is 61kPa, and tower top temperature is 80 DEG C, and bottom temperature is 94 DEG C.Rectifying tower II stage number is 25, feed entrance point is the 2nd piece of column plate place from top to bottom, working pressure is 165kPa, tower top temperature is 107 DEG C, and bottom temperature is 118 DEG C, and rectifying tower III stage number is 45, feed entrance point is several 40th piece of column plate place from top to bottom, working pressure is 471kPa, and tower top temperature is 123 DEG C, and bottom temperature is 153 DEG C.Energy consumption is accounted result and is shown: steam consumption is 1.85 tons of steam/ton azeotropic ethanol product.
Claims (5)
1. adopt a processing method for three-tower differential pressure rectifying ethanol, mainly comprise the following steps:
(1) part comprising the stock liquid of ethanol enters rectifying tower I, obtains thick wine logistics I at the tower top of rectifying tower I, and tower reactor obtains useless mash I;
(2) part comprising the stock liquid of ethanol enters rectifying tower II, obtains thick wine logistics II at the tower top of rectifying tower II, and tower reactor obtains useless mash II;
(3) thick wine logistics I and thick wine logistics II enter rectifying tower III after converging, and obtain azeotropic ethanol logistics at the tower top of rectifying tower III, tower reactor obtains smart tower bottoms;
Wherein, rectifying tower I tower reactor first reboiler is heated by dehydrated alcohol gas, rectifying tower I tower reactor second reboiler is heated by the thick wine logistics II from rectifying tower II tower top, rectifying tower II tower reactor reboiler is heated by a part of azeotropic ethanol logistics from rectifying tower III tower top, and rectifying tower III tower reactor reboiler is by steam heating; The working pressure of rectifying tower I is 20 ~ 90kPa, and the working pressure of rectifying tower II is 120 ~ 180kPa, and the working pressure of rectifying tower III is 400 ~ 600kPa; The described stock liquid comprising ethanol enters rectifying tower I and rectifying tower II respectively after preheater preheats, and described preheater is heated by the thick wine logistics I from rectifying tower I tower top; The azeotropic ethanol logistics part that rectifying tower III tower top obtains is back to rectifying tower III after entering the heat exchange of rectifying tower II tower reactor reboiler; The operational condition of described rectifying tower I: stage number is 20 ~ 30, tower top temperature is 60 ~ 80 DEG C, and bottom temperature is 80 ~ 100 DEG C, and working pressure is 30 ~ 70kPa, feed plate position from top to bottom numerical digit in 2nd ~ 6 pieces of column plate places; The operational condition of rectifying tower II: stage number is 20 ~ 30, tower top temperature is 90 ~ 110 DEG C, and bottom temperature is 100 ~ 120 DEG C, and working pressure is 130 ~ 170kPa, feed plate position from top to bottom numerical digit in 2nd ~ 6 pieces of column plate places; The operational condition of rectifying tower III: stage number is 40 ~ 70, tower top temperature is 110 ~ 130 DEG C, and bottom temperature is 140 ~ 160 DEG C, and working pressure is 450 ~ 550kPa, feed plate position from top to bottom numerical digit in 35th ~ 65 pieces of column plate places; Comprise the stock liquid of ethanol by weight, 40 ~ 50% enter rectifying tower I; 50 ~ 60% enter rectifying tower II; By weight, 60 ~ 80% for heating rectifying tower II tower reactor reboiler in the azeotropic ethanol logistics of described rectifying tower III tower top; In described stock liquid, alcohol concn is 1 ~ 8% by weight.
2. adopting the processing method of three-tower differential pressure rectifying ethanol according to claim 1, it is characterized in that described for heating the dehydrated alcohol gas of rectifying tower I tower reactor first reboiler from Molecular sieve dehydration units.
3. adopt the processing method of three-tower differential pressure rectifying ethanol according to claim 1, it is characterized in that described thick wine logistics I converges with the thick wine logistics II from rectifying tower I tower reactor second reboiler after preheater and described raw material heat exchange, enter rectifying tower III.
4. adopt the processing method of three-tower differential pressure rectifying ethanol according to claim 1, it is characterized in that the operational condition of described rectifying tower I: stage number is 23 ~ 27, tower top temperature is 65 ~ 78 DEG C, and bottom temperature is 85 ~ 98 DEG C; The operational condition of rectifying tower II: stage number is 23 ~ 27, tower top temperature is 95 ~ 108 DEG C, and bottom temperature is 105 ~ 118 DEG C; The operational condition of rectifying tower III: stage number is 50 ~ 60, tower top temperature is 115 ~ 128 DEG C, and bottom temperature is 145 ~ 158 DEG C.
5. adopt the processing method of three-tower differential pressure rectifying ethanol according to claim 1, it is characterized in that in described stock liquid, alcohol concn is 3 ~ 6% by weight.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101157890A (en) * | 2007-08-14 | 2008-04-09 | 天津大学 | Fuel ethanol production equipment and method |
| CN102126920A (en) * | 2010-01-13 | 2011-07-20 | 中国石油化工集团公司 | Method for preparing azeotropic ethanol through three-tower triple-effect differential pressure heat integration |
| CN102126921A (en) * | 2010-01-13 | 2011-07-20 | 中国石油化工集团公司 | Three-tower heating method for preparing azeotropic ethanol |
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| US8704012B2 (en) * | 2011-06-16 | 2014-04-22 | Celanese International Corporation | Distillation of crude alcohol product using entrainer |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101157890A (en) * | 2007-08-14 | 2008-04-09 | 天津大学 | Fuel ethanol production equipment and method |
| CN102126920A (en) * | 2010-01-13 | 2011-07-20 | 中国石油化工集团公司 | Method for preparing azeotropic ethanol through three-tower triple-effect differential pressure heat integration |
| CN102126921A (en) * | 2010-01-13 | 2011-07-20 | 中国石油化工集团公司 | Three-tower heating method for preparing azeotropic ethanol |
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