CN100525874C - Six-column differential-pressure distillation device for extra edible alcohol and process therefor - Google Patents
Six-column differential-pressure distillation device for extra edible alcohol and process therefor Download PDFInfo
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- CN100525874C CN100525874C CNB2006100353460A CN200610035346A CN100525874C CN 100525874 C CN100525874 C CN 100525874C CN B2006100353460 A CNB2006100353460 A CN B2006100353460A CN 200610035346 A CN200610035346 A CN 200610035346A CN 100525874 C CN100525874 C CN 100525874C
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- 238000004821 distillation Methods 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims description 55
- 230000008569 process Effects 0.000 title claims description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 144
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 75
- 238000005516 engineering process Methods 0.000 claims abstract description 14
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims description 76
- 241000282326 Felis catus Species 0.000 claims description 36
- 239000012535 impurity Substances 0.000 claims description 29
- 238000011084 recovery Methods 0.000 claims description 28
- 238000010992 reflux Methods 0.000 claims description 19
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 14
- 239000001760 fusel oil Substances 0.000 claims description 12
- 238000000855 fermentation Methods 0.000 claims description 10
- 230000004151 fermentation Effects 0.000 claims description 10
- 239000000284 extract Substances 0.000 claims description 8
- 238000007701 flash-distillation Methods 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 238000000605 extraction Methods 0.000 claims description 4
- 239000011265 semifinished product Substances 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 3
- 230000035622 drinking Effects 0.000 claims description 2
- 239000008236 heating water Substances 0.000 claims description 2
- 230000001112 coagulating effect Effects 0.000 claims 1
- 238000004064 recycling Methods 0.000 abstract description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 abstract 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 235000007164 Oryza sativa Nutrition 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000010612 desalination reaction Methods 0.000 abstract 1
- 239000013067 intermediate product Substances 0.000 abstract 1
- 229940041616 menthol Drugs 0.000 abstract 1
- 235000009566 rice Nutrition 0.000 abstract 1
- 239000000047 product Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002351 wastewater Substances 0.000 description 5
- 238000005265 energy consumption Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000003809 water extraction Methods 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
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- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
The invention discloses a six-tower distilling device and technology of superfine edible spirit, which comprises the following parts: crude distillation column, vacuum aldehydo-removing column, water scrubber, fractionating tower, methanol column and recycling tower, wherein the mature ferment fermented glutinour rice is preheat in the ferment procedure, which enters into the top of crude distillation column; the crude distillation column is negative pressure, whose top wine gas enters in the vacuum aldehydo-removing column through separator after cooling sequently; the aldehydo-removing wine on the bottom is sent into feeder layer of water scrubber after preheating, which flows desalination wine after extracted by micro-negative pressure water in the fractionating tower to proceed positive pressure distillation; the spirit intermediate product is led into the methanol column from top wine hole of fractionating tower to remove menthol, which obtains superfine edible spirit; the steam condensate of fractionating tower reboiler is recycled in the autoclave of recycling tower after flash-boiling disposal, which flows through methanol column reboiler, water scrubber and crude distillation column to proceed secondary condensing by reboiler.
Description
Technical field
The present invention relates to a kind of biomass to alcohol conversion process and device thereof, especially relate to six-column differential-pressure distil process and device thereof that a kind of superfine edible alcohol is produced.
Technical background
Alcohol Production differential distillation technology is the distillation technique that grows up of alcohol industry in recent years, the differential distillation technology of existing main flow, in " alcohol and Spirit technology " (Zhang Kechang chief editor China Light Industry Press in September, 2002), in " newly organized alcohol technology " documents such as (in July, 2004, published Beijing Chemical Industry Press university teaching publishing centre) detailed argumentation is arranged all.Domestic existing how tame Alcohol Plant adopts five tower differential distillation flow processs.Superfine edible alcohol product standard is carried out GB [GB10343-2002], is the high quality wine elaboration kind of an alcohol product of China, is similar to external neutral alcohol, and some index surpasses outer neutral alcohol.But for five tower differential distillation flow processs of the prior art, generally can only produce high grade edible spirit, the impurity in the alcohol can't further be got rid of, and therefore can not be used to produce superfine edible alcohol.
In order to produce the superfine alcohol that uses, six-column differential-pressure distillation flow process has appearred at present, a kind of wine with dregs tower, slightly auxilliary tower, water extraction tower, rectifying column, eparating methanol tower and contain the six-column differential-pressure distillation device of assorted fraction treating column of comprising arranged, can be used for producing superfine edible alcohol, but the steam consumption of its ton wine is more than 2.7～2.8t/t wine steam, need to extract a large amount of industrial alcohol simultaneously, extract (the production of general top grade alcohol more than 15% approximately, getting industrial alcohol is being normal below 3%), and produce unstable; Also have a kind of six-column differential-pressure distillation device that comprises wine with dregs tower, water extraction tower, rectifying column, eparating methanol tower, fusel oil tower and industrial alcohol tower, though can produce superfine edible alcohol, steam consumption is often up to 3.3～3.4 tons more than the steam, and energy resource consumption is higher.
Summary of the invention
The purpose of this invention is to provide a kind of six-column differential-pressure distillation device and technology thereof of producing superfine edible alcohol, the superfine edible alcohol of the production that it can be stable can be saved steam energy again.
For achieving the above object, superfine edible alcohol six-column differential-pressure distillation device of the present invention, comprise topping still, the vacuum dealdehyder tower, water scrubber, rectifying column, methanol column and recovery tower, rectifying tower top communicates with the 5th vapour liquid separator by methanol column reboiler shell-side through pipeline, the 5th vapour liquid separator top communicates with the 6th vapour liquid separator by water scrubber reboiler shell-side through pipeline, the 6th vapour liquid separator top communicates with the 3rd vapour liquid separator by the topping still second reboiler shell-side through pipeline, the top emptying after pipeline goes condensation of the 3rd vapour liquid separator, the 5th vapour liquid separator, the 6th vapour liquid separator, communicate with rectifying column reflux pump arrival end respectively at the bottom of the 3rd vapour liquid separator; The topping still top communicates with first vapour liquid separator by the first mash preheater shell-side, topping still condenser tube side successively through pipeline, the first vapour liquid separator top vacuumizes, the bottom is through pipeline and vacuum dealdehyder tower feeding inlet, communicate with thick wine pump intake end at the bottom of the vacuum dealdehyder tower, through aldehyde wine preheater tube side and water scrubber feeding inlet, vacuum dealdehyder tower middle part is provided with impurities removal wine mouth to thick wine pump discharge end by pipeline; The rectifying column reboiler shell-side port of export communicates with flash tank, and the flash distillation tank deck communicates with recovery Tata still through pipeline; Rectifying Tata still communicates with the surplus pump entrance end that heats up in a steamer by light wine preheater shell-side through pipeline, and the surplus exit of pump that heats up in a steamer is respectively through pipeline and water scrubber top, and is communicated with extraneous waste water processing station by aldehyde wine preheater shell-side; The wine fetch port at rectifying column top communicates with extraneous finished product basin by finished wine cooler tube side through pipeline at the bottom of the methanol column through pipeline and methanol column middle part feeding inlet.
Compared to existing technology, device of the present invention has increased the vacuum dealdehyder tower, under negative pressure condition, make accumulation of impurities in the wine liquid at tower middle part, the top, be convenient to extract, get rid of, alleviated follow-up each tower impurities removal load, make produce stable; The wine vapour of rectifying column helps despumation through multistage fractional condensation, and operating mode is controlled easily, improves wine liquid quality, and the vapour that the rectifying column reboiler uses coagulates steam that water produces and directly enters the recovery tower still and use after flash distillation, reclaimed heat energy, has saved steam; The surplus repeatedly corresponding material of preheating of water that heats up in a steamer at the bottom of the rectifying column, and, both reclaimed heat by making extraction water in the flow adding water scrubber, reduce the energy consumption of water scrubber again.
Flash tank of the present invention bottom communicates with vapour condensate pump inlet through pipeline, the outlet of vapour condensate pump communicates with the external world by the second mash preheater shell-side through pipeline, but the reuse of back boiler boiler, topping still top charging aperture communicates with the ripe mash pump of extraneous fermentation procedure by the second mash preheater tube side, the first mash preheater tube side successively through pipeline.Reclaim the heat that vapour coagulates in the water to be contained, thereby reduced energy consumption.
Washing cat head of the present invention communicates with the 4th vapour liquid separator by topping still the 3rd reboiler shell-side through pipeline, the methyl alcohol cat head communicates with second vapour liquid separator by the topping still first reboiler shell-side through pipeline, and the topping still first reboiler pipe side outlet communicates with the topping still second reboiler pipe side entrance through pipeline.Because of topping still is a negative-pressure operation, its operating pressure induces one corresponding each column overhead wine vapour to heat use in the topping still reboiler less than water scrubber, rectifying column and methanol column, can reclaim heat, reduces energy consumption.
Six-column differential-pressure distillation device of the present invention is provided with automatic control system, comprise sensors such as being located at on-the-spot temperature, pressure, liquid level and be provided with the active station of PLC system, each sensor can be handled signal and be input to the PLC system, and carries out communication by MPI port and PLC; Active station also is provided with respective display unit, print unit and form unit.
Production technology of the present invention is: the maturing fermentation wine with dregs that fermentation procedure comes after the first mash preheater on topping still top is with the wine vapour preheating of topping still top, enters thick top of tower charging layer; Topping still is a negative pressure, its top wine vapour is successively through after the first mash preheater and the cooling of topping still top condenser, the thick wine that comes out through the isolated thick wine of first vapour liquid separator and first mash preheater bottom, enter the full gear of vacuum dealdehyder tower together, vacuum dealdehyder tower middle part is extracted the wine liquid that contains fusel oil and is discharged by impurities removal wine mouth, full gear wine at the bottom of the tower is sent to water scrubber charging layer after by the preheating of aldehyde wine preheater, after little negative pressure water extract and separate, the light wine that comes out at the bottom of the water scrubber enters the distillation of rectifying column malleation after heating through the light wine pump and by the light wine preheater, the alcohol semi-finished product draw to methanol column charging layer from the rectifying tower top wine fetch port, superfine edible alcohol after methyl alcohol is sloughed in the distillation of methanol column malleation is drawn at the bottom of tower, sends to storage tank after the cooling;
The indirect steam of the steam condensate (SC) of rectifying column reboiler after flash distillation uses directly into the recovery tower still, the wine vapour of rectifying tower top enters methanol column reboiler, water scrubber reboiler, the topping still second reboiler condensation in proper order, not condensing emptying, condensate liquid is mainly made smart tower and is refluxed, and control is extracted in right amount and reclaimed for industrial alcohol; The surplus water that heats up in a steamer divides two-way to use earlier through coming weak liquor at the bottom of the light wine preheater heating water scrubber then at the bottom of the rectifying column, and the one road surplus water that heats up in a steamer enters water scrubber by traffic requirement and makes extraction water and use, and another road effluxes after drinking through aldehyde wine preheater heating aldehyde.
In the technology of the present invention, the extraneous ripe mash that comes coagulates through the vapour of the second mash preheater at the bottom of with flash tank after through the heating of the first mash preheater again and enters the topping still top after water heats, topping still tower still come out draff liquid one tunnel enter topping still the 3rd reboiler and wash cat head wine vapour heating with water, another road is introduced into topping still first reboiler with the heating of methyl alcohol cat head wine vapour, enters the rectifying tower top of coming with the 6th vapour liquid separator top in topping still second reboiler then and does not coagulate the heating of wine vapour.Produce indirect steam and loop back thick tower still, to thick tower heat supply.
Each tower operating pressure of control, temperature are in the technology of the present invention:
Topping still 0.35kg/cm
2, (absolute pressure), 65-69 ℃ of cat head temperature, end temperature 80-84 ℃;
Vacuum dealdehyder tower 0.35kg/cm
2, (absolute pressure), 52-56 ℃ of cat head temperature, end temperature 63-67 ℃;
Water scrubber 0.85kg/cm
2, (absolute pressure), 93-97 ℃ of cat head temperature, end temperature 93-97 ℃;
Rectifying column 2.50kg/cm
2, (absolute pressure), 103-107 ℃ of cat head temperature, end temperature 131-135 ℃;
Methanol column 1.6kg/cm
2, (absolute pressure), 90-94 ℃ of cat head temperature, end temperature 93-97 ℃;
Recovery tower 1.03kg/cm
2, (absolute pressure), 76-80 ℃ of cat head temperature, end temperature 106-110 ℃.
As the optimum operating pressure of each tower in the technology of the present invention, temperature be:
Topping still 0.35kg/cm
2, (absolute pressure), 67 ℃ of cat head temperature, 82 ℃ of end temperature;
Vacuum dealdehyder tower 0.35kg/cm
2, (absolute pressure), 54 ℃ of cat head temperature, 65 ℃ of end temperature;
Water scrubber 0.85kg/cm
2, (absolute pressure), 95 ℃ of cat head temperature, 95 ℃ of end temperature;
Rectifying column 2.50kg/cm
2, (absolute pressure), 105 ℃ of cat head temperature, 133.0 ℃ of end temperature;
Methanol column 1.6kg/cm
2, (absolute pressure), 92 ℃ of cat head temperature, 95 ℃ of end temperature;
Recovery tower 1.03kg/cm
2, (absolute pressure), 78 ℃ of cat head temperature, 108 ℃ of end temperature.
Six-column differential-pressure distillation device of the present invention and technology have been strengthened the removal of impurities effect to wine liquid, the superfine edible alcohol of production that can be stable, its steam consumption index is 2.2～2.3t/t wine, and energy-saving effect saves nearly 15%～21% than the prior art steam consumption 2.7～2.8t/t wine advanced person.
Description of drawings
Accompanying drawing 1 is a technological process schematic diagram of the present invention;
1, topping still, 101, first vapour liquid separator, 102, second vapour liquid separator, 103, the 3rd vapour liquid separator, 104, the 4th vapour liquid separator, 105, the 5th vapour liquid separator, 106, the 6th vapour liquid separator, 107, the 7th vapour liquid separator, 108, the 8th vapour liquid separator, 109, the 9th vapour liquid separator, 110, the water scrubber reflux pump, 111, thick wine pump, 112, the light wine pump, 113, the dealdehyder tower reflux pump, 114, the recovery tower reflux pump, 115, waste water pump, 116, the vapour condensate pump, 117, the surplus water pump that heats up in a steamer, 118, the rectifying column reflux pump, 119, the methanol column reflux pump, 2, the vacuum dealdehyder tower, 3, water scrubber, 4, rectifying column, 5, methanol column, 6, recovery tower, 700, the rectifying column reboiler, 701, the methanol column reboiler, 702, the water scrubber reboiler, 703, topping still first reboiler, 704, topping still second reboiler, 705, topping still the 3rd reboiler, 706, the dealdehyder tower reboiler, 8, flash tank, 901, the first mash preheater, 902, the second mash preheater, 903, the topping still condenser, 904, dealdehyder tower first condenser, 905, dealdehyder tower second condenser, 906, aldehyde wine preheater, 907, the light wine preheater, 908, last condenser stage, 909, the finished wine cooler, e, assorted wine liquid inlet, e1, impurities removal wine mouth, e2, impurities removal wine mouth, e3, impurities removal wine mouth, e4, impurities removal wine mouth, e5, impurities removal wine mouth, e6, impurities removal wine mouth, g, row's fusel oil wine mouth.
The specific embodiment
Embodiment: as shown in Figure 1, superfine edible alcohol six-column differential-pressure distillation device, comprise topping still 1, vacuum dealdehyder tower 2, water scrubber 3, rectifying column 4, methanol column 5 and recovery tower 6, rectifying column 1 top communicates with the 5th vapour liquid separator 105 by methanol column reboiler 701 shell-sides through pipeline, the 5th vapour liquid separator 105 tops communicate with the 6th vapour liquid separator 106 by water scrubber reboiler 702 shell-sides through pipeline, the 6th vapour liquid separator 106 tops communicate with the 3rd vapour liquid separator 103 by topping still second reboiler 704 shell-sides through pipeline, emptying is gone, the 5th vapour liquid separator 105 by pipeline through last condenser stage 908 pipe sides in the 3rd vapour liquid separator 103 tops, the 6th vapour liquid separator 106,103 ends of the 3rd vapour liquid separator, communicate with rectifying column reflux pump 118 arrival ends respectively.And suitably extract partly industrial alcohol at 103 ends of the 3rd vapour liquid separator.
Topping still 1 top communicates with first vapour liquid separator 101 by the first mash preheater, 901 shell-sides, topping still condenser 903 pipe sides successively through pipeline, first vapour liquid separator, 101 tops vacuumize, the bottom is through pipeline and vacuum dealdehyder tower 2 feeding inlet, and this pipeline is provided with impurities removal wine mouth e4; Topping still first reboiler 703 pipe side outlets communicate with topping still second reboiler 704 pipe side entrances through pipeline; The useless mash at 1 end of topping still is sent to extraneous useless mash system.
2 ends of vacuum dealdehyder tower, communicate with thick wine pump 111 arrival ends, and through aldehyde wine preheater 906 pipe side and water scrubber 3 feeding inlet, vacuum dealdehyder tower 2 middle parts are provided with impurities removal wine mouth e6 to thick wine pump 111 ports of export by pipeline; Vacuum dealdehyder tower 2 tops connect dealdehyder tower first condenser 904 pipe side and the 8th vapour liquid separators 108 successively by pipeline, the 8th vapour liquid separator 108 bottoms communicate with dealdehyder tower reflux pump 113 inlets through pipeline, its top communicates with the 9th vapour liquid separator 109 by dealdehyder tower second condenser 905 pipe sides, the 9th vapour liquid separator 109 tops vacuumize, and the bottom connects gets rid of extraneous industrial wine liquid systems.
Rectifying column reboiler 700 shell-side steam (vapor) outlet ends communicate with flash tank 8, and flash tank 8 tops communicate with recovery tower 6 tower stills through pipeline; Communicate with surplus water pump 117 arrival ends that heat up in a steamer by light wine preheater 907 shell-sides through pipeline at the bottom of rectifying column 4 towers, the surplus water pump 117 that heats up in a steamer exports respectively through pipeline and water scrubber 3 tops, and communicates with extraneous waste water system by aldehyde wine preheater 906 shell-sides; The wine fetch port at rectifying column 14 tops communicates with methanol column 5 middle part charging layers through pipeline, and 5 ends of methanol column communicate with finished product alcohol storehouse by finished wine cooler 909 pipe sides through pipeline, and rectifying column 4 middle parts, top are provided with three impurities removal wine mouth e1, e2 and e3.
Flash tank 8 bottoms communicate with vapour condensate pump 116 inlets through pipeline, 116 outlets of vapour condensate pump communicate with extraneous vapour condensed water recovering system by the second mash preheater, 902 shell-sides through pipeline, and topping still 1 top charging aperture communicates with extraneous fermentation procedure by the second mash preheater, 902 pipe sides, the first mash preheater, 901 pipe sides successively through pipeline.
Water scrubber 3 tops communicate with the 4th vapour liquid separator 104 by topping still the 3rd reboiler 705 shell-sides through pipeline, the 4th vapour liquid separator 104 tops communicate with vacuum system, its bottom communicates with water scrubber reflux pump 110 inlets, 110 outlets of water scrubber reflux pump communicate with water scrubber 3 reflux layers, its outlet line is provided with impurities removal wine mouth e5, water scrubber 3 bottoms communicate with light wine pump 112 inlets through pipeline, and 112 outlets of light wine pump are communicated with rectifying column 4 charging layers by pipeline through light wine preheater 907 pipe sides.
Methanol column 5 tops communicate with second vapour liquid separator 102 by topping still first reboiler 703 shell-sides through pipeline, second vapour liquid separator, 102 tops are gone emptying by pipeline through last condenser stage 908 pipe sides, its bottom connects methanol column reflux pump 119 inlets by pipeline, 119 outlets of methanol column reflux pump connect methanol column 5 reflux layers through pipeline, and this pipeline is communicated with extraneous industrial wine liquid systems simultaneously.
Recovery tower 6 tops connect recovery tower reflux pump 114 inlets through pipeline by vacuum dealdehyder tower reboiler 706 shell-sides, and 114 outlets of recovery tower reflux pump connect recovery tower 6 reflux layers by pipeline one tunnel, and another road is communicated with extraneous industrial wine liquid systems; 6 ends of recovery tower, be communicated with extraneous waste water system by waste water pump 115; Recovery tower 6 tops are provided with row's fusel oil wine mouth g, discharge fusel oil wine, and impurity elimination alcohol oil eliminator is recycled; The assorted wine that each impurities removal wine mouth is got rid of adds by the charging aperture e on recovery tower 6 tops, with recycling fusel oil, alcohol and despumation wherein; The wine mouth is carried by pipeline connection water scrubber 3 top charging apertures in recovery tower 6 tops in addition, and extraction unit is divided industrial wine, and other sends to water scrubber, and recovered alcohol improves yield rate.
Six-column differential-pressure distillation device of the present invention is provided with automatic control system, comprise sensors such as being located at on-the-spot temperature, pressure, liquid level and be provided with the active station of PLC system, each sensor can be handled signal and be input to the PLC system, and carries out communication by MPI port and PLC; Active station also is provided with respective display unit, print unit and form unit.
The trend of material is: from the next maturing fermentation wine with dregs of fermentation procedure, earlier through the first mash preheater 901, coagulate the second mash preheater, 902 preheatings of water heating again through flash tank 8 vapour, enter topping still 1, the wine vapour on topping still 1 top is through the first mash preheater 901, topping still condenser 903 is condensed into thick wine, thick wine enters vacuum dealdehyder tower 2, full gear wine is sent to through thick wine pump 111 at the bottom of tower, enter the charging layer of water scrubber 3 through aldehyde wine preheater 906, behind water scrubber 3 little negative pressure water extracting operations, light wine comes out to remove light wine preheater 907 by light wine pump 112 pumps from tower bottom, enter rectifying column 4 charging layers after the preheating, after rectifying column 4 malleation rectifying, the alcohol semi-finished product draw to methanol column 5 from the wine fetch port of cat head, further get rid of methyl alcohol through the distillation of methanol column 5 malleations, draw superfine edible alcohol finished product from tower bottom and remove basin;
Regulate the negative pressure value of topping still 1, vacuum dealdehyder tower 2, water scrubber 3 by the pipeline control valve;
The poor liquid at 1 end of topping still is by topping still first reboiler 703, topping still second reboiler 704, topping still the 3rd reboiler 705, and being heated boils again realizes circulation.
Absolute pressure is 5kg/cm
2Primary steam, mainly supply with rectifying column reboiler 700 and use, the indirect steam of condensed water flash is for the use of recovery tower 6 tower stills, the net thermal water after the flash distillation removes behind the second mash preheater 902 just back boiler again.
To produce 60000 tons of superfine edible alcohols per year is example,
Control each column overhead operating pressure, temperature is:
Topping still 1 0.35kg/cm
2, (absolute pressure), 67 ℃ of cat head temperature, 82 ℃ of end temperature.
Vacuum dealdehyder tower 2 0.35kg/cm
2, (absolute pressure), 54 ℃ of cat head temperature, 65 ℃ of end temperature.
Water scrubber 3 0.85kg/cm
2, (absolute pressure), 95 ℃ of cat head temperature, 95 ℃ of end temperature.
Rectifying column 4 2.50kg/cm
2, (absolute pressure), 105 ℃ of cat head temperature, 133.0 ℃ of end temperature.
Methanol column 5 1.6kg/cm
2, (absolute pressure), 92 ℃ of cat head temperature, 95 ℃ of end temperature.
Recovery tower 6 1.03kg/cm
2, (absolute pressure), 78 ℃ of cat head temperature, 108 ℃ of end temperature.
108.5 tons of come from fermentation procedure 30 ℃ maturing fermentation wine with dregs that contain wine 11.5% (V/V)/time, earlier be preheating to 48 ℃ through the first mash preheater 901, the second mash preheater 902 that coagulates water heating through 8 end of flash tank vapour is preheating to 65 ℃ again, enters the charging layer of topping still 1.67 ℃ of the fume temperature on topping still 1 top, operating pressure is absolute pressure 0.35kg/cm
2Be condensed into thick wine through the first mash preheater 901, topping still condenser 903, get part and remove recovery tower 6 as assorted wine, all the other thick wine are sent to the charging layer of vacuum dealdehyder tower 2, after vacuum dealdehyder tower 2 negative-pressure operations separate, full gear wine comes out from tower bottom, go into water scrubber 3 charging layers through thick wine pump 111 by 906 heat exchange of aldehyde wine preheater are laggard, after micro-negative pressure operation water extract and separate, 95 ℃ light wine comes out from tower bottom, remove light wine preheater 907 by light wine pump 112 pumps, be preheating to 120 ℃ and enter rectifying column 4 charging layers.After rectifying column 4 malleation rectifying, alcohol semi-finished product 96.0% (V/V), 105 ℃, draw to methanol column 5 charging layers from the wine fetch port of cat head, methyl alcohol is further got rid of in the distillation of methanol column 5 malleations, draws superfine edible alcohol finished product 96.0% (V/V) from tower bottom, 95 ℃ are removed the smart cooler 909 of finished wine, 8.386 tons of normal temperature/time superfine edible alcohol finished product advance the alcohol basin.
For guaranteeing product quality, must get rid of impurity, be provided with a plurality of impurities removal points in this flow process, wherein negative pressure (vacuum) impurities removal point is 3, extracts 7 of industrial wine impurities removal points, extracts 6 of assorted wine impurities removal points, 1 of emptying impurities removal point, 1 of fusel oil impurities removal point is realized the multiple spot impurities removal.
The industrial alcohol that contains impurity is directly sent to the industrial alcohol basin.
The assorted wine that contains impurity enters recovery tower 6 after concentrating, and concentrates on recovery tower and gets hydraulic fluid port g and get the oily wine liquid that contains fusel oil, goes conventional fusel oil separator system further to separate fusel oil.
Claims (8)
1, a kind of superfine edible alcohol six-column differential-pressure distillation device, comprise topping still (1), water scrubber (3), rectifying column (4), methanol column (5) and recovery tower (6), it is characterized in that: it also is provided with vacuum dealdehyder tower (2), wherein rectifying column (4) top communicates with the 5th vapour liquid separator (105) by methanol column reboiler (701) shell-side through pipeline, the 5th vapour liquid separator (105) top communicates with the 6th vapour liquid separator (106) by water scrubber reboiler (702) shell-side through pipeline, the 6th vapour liquid separator (106) top communicates with the 3rd vapour liquid separator (103) by topping still second reboiler (704) shell-side through pipeline, emptying is gone through pipeline, the 5th vapour liquid separator (105) in the 3rd vapour liquid separator (103) top, the 6th vapour liquid separator (106), the 3rd vapour liquid separator (103) end, communicate with rectifying column reflux pump (118) arrival end respectively; Topping still (1) top communicates with first vapour liquid separator (101) by first mash preheater (901) shell-side, topping still condenser (903) pipe side successively through pipeline, first vapour liquid separator (101) top vacuumizes, the bottom is through pipeline and vacuum dealdehyder tower (2) feeding inlet, vacuum dealdehyder tower (2) end, communicate with thick wine pump (111) arrival end, through aldehyde wine preheater (906) pipe side and water scrubber (3) feeding inlet, vacuum dealdehyder tower (2) middle part is provided with impurities removal wine mouth (e6) to thick wine pump (111) port of export by pipeline; Rectifying column reboiler (700) the shell-side port of export communicates with flash tank (8), and flash tank (8) top communicates with recovery tower (6) tower still through pipeline; Rectifying column (4) tower still communicates with surplus water pump (117) arrival end that heats up in a steamer by light wine preheater (907) shell-side through pipeline, and the surplus water pump (117) that heats up in a steamer exports respectively through pipeline and water scrubber (3) top, and communicates with the external world by aldehyde wine preheater (906) shell-side; The wine fetch port at rectifying column (4) top communicates with methanol column (5) middle part through pipeline, and methanol column (5) end communicates with the external world by finished wine cooler (909) pipe side through pipeline.
2, superfine edible alcohol six-column differential-pressure distillation device according to claim 1, it is characterized in that: described flash tank (8) bottom communicates with vapour condensate pump (116) inlet through pipeline, vapour condensate pump (116) outlet communicates with the external world by second mash preheater (901) shell-side through pipeline, and topping still (1) top charging aperture communicates with the external world by the second mash preheater (902) pipe side, the first mash preheater (901) pipe side successively through pipeline.
3, superfine edible alcohol six-column differential-pressure distillation device according to claim 1, it is characterized in that: water scrubber (3) top communicates with the 4th vapour liquid separator (104) by topping still the 3rd reboiler (705) shell-side through pipeline, methanol column (5) top communicates with second vapour liquid separator (102) by topping still first reboiler (703) shell-side through pipeline, and topping still first reboiler (703) pipe side outlet communicates with topping still second reboiler (704) pipe side entrance through pipeline.
4, superfine edible alcohol six-column differential-pressure distillation device according to claim 1, it is characterized in that: it also is provided with automatic control system, comprise the active station that is located at on-the-spot temperature, pressure, liquid level sensor and is provided with the PLC system, each sensor can be handled signal and be input to the PLC system, and carries out communication by MPI port and PLC; Active station also is provided with respective display unit, print unit and form unit.
5, a kind of usefulness superfine edible alcohol six-column differential-pressure distillation device as claimed in claim 1 technology of producing superfine edible alcohol, it is characterized in that: the maturing fermentation wine with dregs that fermentation procedure comes, after the first mash preheater (901) on topping still (1) top is used topping still (1) top wine vapour preheating, enter topping still (1) its top feed layer; Topping still (1) is a negative pressure, its top wine vapour is successively through after the first mash preheater (901) and topping still top condenser (903) cooling, enter vacuum dealdehyder tower (2) full gear through the isolated thick wine of first vapour liquid separator (101), fusel oil wine liquid is extracted at vacuum dealdehyder tower (2) middle part, discharge by row's fusel oil wine mouth (e6), full gear wine at the bottom of the tower is sent to water scrubber (3) charging layer after by aldehyde wine preheater (906) preheating, after little negative pressure water extract and separate, the light wine that comes out in water scrubber (3) end enters the distillation of rectifying column (4) malleation through light wine pump (112) and after by light wine preheater (907) heating, the alcohol semi-finished product draw to methanol column (5) charging layer from rectifying column (4) top wine fetch port, superfine edible alcohol after methyl alcohol is sloughed in the distillation of methanol column (5) malleation is drawn at the bottom of tower, sends to storage tank after the cooling; The indirect steam of steam condensate (SC) after flash distillation of rectifying column reboiler (700) uses directly into recovery tower (6) tower still, the wine vapour on rectifying column (4) top enters methanol column reboiler (701), water scrubber reboiler (702), topping still second reboiler (704) condensation in proper order, not condensing emptying, the condensate liquid major part refluxes as smart tower, suitably extracts partly and reclaims for industrial alcohol; The surplus water that heats up in a steamer is earlier through light wine preheater (907) heating water scrubber (3) end weak liquor at rectifying column (4) end, divide two-way to use then, the one road surplus water that heats up in a steamer enters water scrubber (3) by traffic requirement and makes extraction water and use, and another road effluxes after drinking through aldehyde wine preheater (906) heating aldehyde.
6, superfine edible alcohol six-column differential-pressure distilling producing process according to claim 5, it is characterized in that: after extraneous next ripe mash heats through the first mash preheater (901), enter topping still (1) top after coagulating the water heating through the second mash preheater (902) with the vapour at flash tank (8) end again, topping still (1) tower still come out wine lees liquor one tunnel enter topping still the 3rd reboiler (705) and wash the heating of tower (3) top wine vapour with water, another road is introduced into topping still first reboiler (703) with the wine vapour heating of methanol column (5) top, enters rectifying column (4) top of coming with the 6th vapour liquid separator (106) top in topping still second reboiler (704) then and does not coagulate the heating of wine vapour.
7, according to claim 5 or 6 described superfine edible alcohol six-column differential-pressure distilling producing process, it is characterized in that: control each tower operating pressure, temperature is:
Topping still (1) absolute pressure 0.35kg/cm
2, 65-69 ℃ of cat head temperature, end temperature 80-84 ℃;
Vacuum dealdehyder tower (2) absolute pressure 0.35kg/cm
2, 52-56 ℃ of cat head temperature, end temperature 63-67 ℃;
Water scrubber (3) absolute pressure 0.85kg/cm
2, 93-97 ℃ of cat head temperature, end temperature 93-97 ℃;
Rectifying column (4) absolute pressure 2.50kg/cm
2, 103-107 ℃ of cat head temperature, end temperature 131-135 ℃;
Methanol column (5) absolute pressure 1.6kg/cm
2, 90-94 ℃ of cat head temperature, end temperature 93-97 ℃;
Recovery tower (6) absolute pressure 1.03kg/cm
2, 76-80 ℃ of cat head temperature, end temperature 106-110 ℃.
8, superfine edible alcohol six-column differential-pressure distilling producing process according to claim 7 is characterized in that: control each tower operating pressure, temperature is:
Topping still (1) absolute pressure 0.35kg/cm
2, 67 ℃ of cat head temperature, 82 ℃ of end temperature;
Vacuum dealdehyder tower (2) absolute pressure 0.35kg/cm
2, 54 ℃ of cat head temperature, 65 ℃ of end temperature;
Water scrubber (3) absolute pressure 0.85kg/cm
2, 95 ℃ of cat head temperature, 95 ℃ of end temperature;
Rectifying column (4) absolute pressure 2.50kg/cm
2, 105 ℃ of cat head temperature, 133.0 ℃ of end temperature;
Methanol column (5) absolute pressure 1.6kg/cm
2, 92 ℃ of cat head temperature, 95 ℃ of end temperature;
Recovery tower (6) absolute pressure 1.03kg/cm
2, 78 ℃ of cat head temperature, 108 ℃ of end temperature.
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| CN101235391B (en) * | 2008-02-01 | 2011-08-17 | 清华大学 | Method and system for continuously separating ethanol and utilizing residual heat based on solid-state fermentation material |
| CN101748037B (en) * | 2009-11-23 | 2013-12-11 | 广东中科天元新能源科技有限公司 | Special grade edible alcohol six-tower difference pressure distilling device and process thereof |
| CN102040472B (en) * | 2010-11-17 | 2013-07-10 | 蓝仁水 | Energy-saving process for rectifying alcohol by adopting heat integration of three rectifying columns |
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| CN104232455B (en) * | 2014-09-26 | 2016-02-03 | 广东中科天元新能源科技有限公司 | General level and high grade edible spirit coproduction energy-saving distillation device and energy-saving technique thereof |
| CN105753651B (en) * | 2014-12-17 | 2018-05-08 | 中粮生化能源（肇东）有限公司 | A kind of method for producing edible alcohol |
| CN106422388B (en) * | 2016-10-26 | 2019-02-19 | 广东中科天元新能源科技有限公司 | The differential distillation energy saver and its production technology of double thick tower production top grade alcohol |
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| CN109876486A (en) * | 2019-04-03 | 2019-06-14 | 广东中科天元新能源科技有限公司 | A kind of eight column differential-pressure distillation device of superfine alcohol and energy-saving processing technique |
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