CN104002532A - Transparent colored protective film and preparation method thereof - Google Patents
Transparent colored protective film and preparation method thereof Download PDFInfo
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- CN104002532A CN104002532A CN201410252812.5A CN201410252812A CN104002532A CN 104002532 A CN104002532 A CN 104002532A CN 201410252812 A CN201410252812 A CN 201410252812A CN 104002532 A CN104002532 A CN 104002532A
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Abstract
The invention provides a transparent colored protective film. The transparent colored protective film comprises a composite substrate layer, an adhesive layer and a release layer, wherein the composite substrate layer comprises a surface PET (polyethylene terephthalate) layer, a polyacrylic acid resin layer and an inner PET layer; the surface PET layer comprises two side surfaces, namely a corona surface and a non-corona surface; both the two side surfaces of the inner PET layer are corona surfaces; the corona surface of the surface PET layer is adhered to the corona surface of the inner PET layer through the polyacrylic acid resin layer; the adhesive layer coats the surface of the other corona surface of the inner PET layer; the release layer is adhered to the surface of the other side of the adhesive layer, colored ink is printed on the corona surface of the surface PET layer, and colored ink is printed on the corona of the corona surface of the inner PET layer. The invention also discloses a method for preparing the transparent colored protective film; the adhesion of the substrate layer is improved by the corona processing of the surface PET layer and the inner PET layer; colored components are added in a printing way so that the adhesion performance of the substrate layer is not influenced.
Description
Technical field
The present invention relates to membrane structure field, particularly a kind of diaphragm.
Background technology
At present, diaphragm is common in electronic applications, prevents by hard thing scratch with protection product by diaphragm being attached to electronic product surface.Diaphragm is generally plastic foil, according to the difference of purposes, also adopts one deck, two-layer or multi-layer film structure.Existing diaphragm generally includes substrate layer, adhesion coating and release layer, described substrate layer adopts Merlon (PC) conventionally, polyethylene (PE), PETG (PET), the materials such as orientation stretching polypropylene (OPP) or aromatic polyester, substrate layer is the primary structure layer of diaphragm, adhesion coating is attached at described substrate layer one side, conventionally adopt the polymer or the acrylate copolymer etc. that contain alkoxy silane, described adhesion coating is in order to be pasted on substrate layer protected product surface, release layer makes it keep viscosity for the protection of the adhesion coating before not using, when use, described release layer is first peeled off from adhesion coating one side, form layer protecting film by described adhesion coating one side being attached to product surface.Existing diaphragm mostly is transparent, colorless films, in use easily has the problem such as tear of leaking; Coloured diaphragm substrate layer be prone to sticking nature poor, use the phenomenons such as layering for a long time.
Based on the above, a kind ofly improve sticking nature and avoid the exploitation of transparent coloured diaphragm of substrate layer layering by necessary property.
Summary of the invention
For the problems referred to above; the invention provides a kind of transparent coloured diaphragm sticking nature and that avoid substrate layer layering that improves; this diaphragm makes described diaphragm present certain color by the specially treated of substrate layer; and ensured the sticking nature of substrate layer, after long-time use, described substrate layer is not stratified simultaneously.
The invention provides a kind of transparent coloured diaphragm, comprise, composite base material layer, comprise pet sheet layer, polyacrylic resin layer and PET internal layer, described pet sheet layer comprises corona surface and two sides of non-corona surface, described PET internal layer two sides are corona surface, and described pet sheet layer corona surface and described PET internal layer one corona surface close by one deck polyacrylic resin laminating; Adhesion coating, described adhesion coating is coated on another corona surface surface of described PET internal layer; Release layer, described release layer adheres to described adhesion coating surface; Wherein, described pet sheet layer corona surface is printed with color ink, and described PET internal layer corona surface corona is printed with color ink.
Preferably, described transparent coloured diaphragm, wherein, described pet sheet layer thickness is 15-25 μ m.
Preferably, described transparent coloured diaphragm, wherein, described PET internal layer thickness is 18-28 μ m.
Preferably, described transparent coloured diaphragm, wherein, described polyacrylic resin layer thickness is 5-15 μ m.
Preferably, described transparent coloured diaphragm, wherein, described adhesion coating adopts high temperature resistant glue, and described high temperature resistant glue principal component is acrylic resin.
Preferably, described transparent coloured diaphragm, wherein, described release layer adopts mould release membrance, and described mould release membrance principal component is polyester film and silicone oil.
A kind of transparent coloured diaphragm preparation method, it makes by following steps,
1) prepare pet sheet layer: the PET film to 15-25 μ m carries out one-sided sided corona treatment, and the single side surface after corona is printed with color ink, makes pet sheet layer;
2) prepare PET internal layer: the PET film to 18-28 μ m carries out bilateral sided corona treatment, on the side after corona, be printed with color ink, make PET internal layer;
3) prepare composite base material layer: in pet sheet layer blue sides, apply 5-15 μ m polyacrylic resin, described PET internal layer blue sides and described polyacrylic resin laminating close, and make composite base material layer;
4) prepare coloured diaphragm: described composite base material layer PET internal layer one side applies adhesion coating, described adhesion coating opposite side laminating release layer, slaking 72h, punching molding.
The beneficial effect of transparent coloured diaphragm disclosed by the invention and preparation method thereof: 1) by adopting coloured substrate layer to make diaphragm with color; 2) improve the sticking nature of substrate layer by the sided corona treatment of pet sheet layer and PET internal layer, effectively prevented substrate layer layering after long-term use; 3) in described substrate layer, colored component adds by mode of printing, does not affect ectonexine PET adhesive property.
Brief description of the drawings
Fig. 1 is transparent coloured diaphragm structural representation of the present invention;
Fig. 2 is substrate layer structural representation in transparent coloured diaphragm of the present invention.
Detailed description of the invention
Below in conjunction with accompanying drawing, the present invention is described in further detail, to make those skilled in the art can implement according to this with reference to description word.
Embodiment 1
As shown in Figures 1 and 2, the invention provides a kind of transparent coloured diaphragm, comprise composite base material layer 1, adhesion coating 2 and release layer 3, wherein, described composite base material layer 1 comprises pet sheet layer 4, polyacrylic resin layer 5 and PET internal layer 6, described pet sheet layer 4 comprises corona surface and two sides of non-corona surface, and described PET internal layer 6 two sides are corona surface, and described pet sheet layer 4 corona surface and described PET internal layer 6 one corona surfaces are fitted by one deck polyacrylic resin layer 5; Described adhesion coating 2 is coated on described PET internal layer 6 another corona surface surfaces; Described release layer 3 adheres to described adhesion coating 2 surfaces; Wherein, described pet sheet layer 4 corona surface printing blue color ink, described PET internal layer 6 corona surface corona printing blue color inks.Described pet sheet layer 4 thickness are 20 μ m.Described PET internal layer 6 thickness are 23 μ m.Described polyacrylic resin layer 5 thickness are 10 μ m.Described adhesion coating 2 adopts high temperature resistant glue, and described high temperature resistant glue principal component is acrylic resin.Described release layer 3 adopts mould release membrance, and described mould release membrance principal component is polyester film and silicone oil.
Embodiment 2
The invention provides a kind of transparent coloured diaphragm preparation method, it makes by following steps,
1) prepare pet sheet layer 4: the PET film to 20 μ m carries out one-sided sided corona treatment, the single side surface printing blue color ink after corona, makes pet sheet layer 4;
2) prepare PET internal layer 6: the PET film to 23 μ m carries out bilateral sided corona treatment, printing blue color ink on the side after corona, makes PET internal layer 6;
3) prepare composite base material layer 1: in pet sheet layer 4 blue sides, apply 10 μ m polyacrylic resins, described PET internal layer 6 blue sides and described polyacrylic resin layer 5 are fitted, and make composite base material layer 1;
4) prepare coloured diaphragm: described composite base material layer 1PET internal layer 6 one sides apply adhesion coating 2, described adhesion coating 2 opposite side laminating release layers 3, slaking 72h, punching molding.
Although embodiment of the present invention are open as above, but it is not restricted to listed utilization in description and embodiment, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details and illustrates here and the legend of describing.
Claims (7)
1. a transparent coloured diaphragm, is characterized in that, comprises
Composite base material layer, comprise pet sheet layer, polyacrylic resin layer and PET internal layer, described pet sheet layer comprises corona surface and two sides of non-corona surface, described PET internal layer two sides are corona surface, and described pet sheet layer corona surface and described PET internal layer one corona surface close by one deck polyacrylic resin laminating;
Adhesion coating, described adhesion coating is coated on another corona surface surface of described PET internal layer;
Release layer, described release layer adheres to described adhesion coating surface;
Wherein, described pet sheet layer corona surface is printed with color ink, and described PET internal layer corona surface corona is printed with color ink.
2. transparent coloured diaphragm according to claim 1, is characterized in that, described pet sheet layer thickness is 15-25 μ m.
3. transparent coloured diaphragm according to claim 1, is characterized in that, described PET internal layer thickness is 18-28 μ m.
4. transparent coloured diaphragm according to claim 1, is characterized in that, described polyacrylic resin layer thickness is 5-15 μ m.
5. transparent coloured diaphragm according to claim 1, is characterized in that, described adhesion coating adopts high temperature resistant glue, and described high temperature resistant glue principal component is acrylic resin.
6. transparent coloured diaphragm according to claim 1, is characterized in that, described release layer adopts mould release membrance, and described mould release membrance principal component is polyester film and silicone oil.
7. a transparent coloured diaphragm preparation method, is characterized in that, make by following steps,
1) prepare pet sheet layer: the PET film to 15-25 μ m carries out one-sided sided corona treatment, and the single side surface after corona is printed with color ink, makes pet sheet layer;
2) prepare PET internal layer: the PET film to 18-28 μ m carries out bilateral sided corona treatment, on the side after corona, be printed with color ink, make PET internal layer;
3) prepare composite base material layer: in pet sheet layer blue sides, apply 5-15 μ m polyacrylic resin, described PET internal layer colored ink side and described polyacrylic resin laminating close, and make composite base material layer;
4) prepare coloured diaphragm: described composite base material layer PET internal layer one side applies adhesion coating, described adhesion coating opposite side laminating release layer, slaking 72h, punching molding.
Priority Applications (1)
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CN201410252812.5A CN104002532B (en) | 2014-06-09 | 2014-06-09 | A kind of transparent coloured protecting film and preparation method thereof |
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CN201410252812.5A CN104002532B (en) | 2014-06-09 | 2014-06-09 | A kind of transparent coloured protecting film and preparation method thereof |
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CN104002532A true CN104002532A (en) | 2014-08-27 |
CN104002532B CN104002532B (en) | 2016-06-15 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107335864A (en) * | 2017-06-29 | 2017-11-10 | 深圳市精品诚电子科技有限公司 | A kind of viscose plastic structure and its processing method |
CN110757902A (en) * | 2018-07-26 | 2020-02-07 | 苏州恒悦新材料有限公司 | Protective film for liquid crystal display and preparation process thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN202448521U (en) * | 2012-02-14 | 2012-09-26 | 扬州三星塑胶有限公司 | Corona sheet |
JP2013063566A (en) * | 2011-09-16 | 2013-04-11 | Riso Kagaku Corp | Thermal stencil paper |
CN103625066A (en) * | 2012-08-28 | 2014-03-12 | 昆山雅森电子材料科技有限公司 | Colored protective film, and cover film, composite film and stiffening plate containing the colored protective film |
-
2014
- 2014-06-09 CN CN201410252812.5A patent/CN104002532B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013063566A (en) * | 2011-09-16 | 2013-04-11 | Riso Kagaku Corp | Thermal stencil paper |
CN202448521U (en) * | 2012-02-14 | 2012-09-26 | 扬州三星塑胶有限公司 | Corona sheet |
CN103625066A (en) * | 2012-08-28 | 2014-03-12 | 昆山雅森电子材料科技有限公司 | Colored protective film, and cover film, composite film and stiffening plate containing the colored protective film |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107335864A (en) * | 2017-06-29 | 2017-11-10 | 深圳市精品诚电子科技有限公司 | A kind of viscose plastic structure and its processing method |
CN110757902A (en) * | 2018-07-26 | 2020-02-07 | 苏州恒悦新材料有限公司 | Protective film for liquid crystal display and preparation process thereof |
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Publication number | Publication date |
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CN104002532B (en) | 2016-06-15 |
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Address after: 223900 Sihong Province Economic Development Zone, West Ocean Road, No. 6, No. Patentee after: Jiangsu Stick new materials Polytron Technologies Inc Address before: 215400 Taicang Economic Development Zone, Jiangsu, Qingdao West Road, No. 11, No. Patentee before: Suzhou Sidike New Material Science & Technology Co., Ltd. |
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