CN103987833A - Washing agent composition and washing method using same - Google Patents
Washing agent composition and washing method using same Download PDFInfo
- Publication number
- CN103987833A CN103987833A CN201280057925.9A CN201280057925A CN103987833A CN 103987833 A CN103987833 A CN 103987833A CN 201280057925 A CN201280057925 A CN 201280057925A CN 103987833 A CN103987833 A CN 103987833A
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- Prior art keywords
- water
- washing
- detergent composition
- capacity
- diethylene glycol
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- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 238000005406 washing Methods 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000003021 water soluble solvent Substances 0.000 claims abstract description 22
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 230000004907 flux Effects 0.000 claims abstract description 8
- 239000003599 detergent Substances 0.000 claims description 36
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- 229910000679 solder Inorganic materials 0.000 claims description 8
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 claims description 6
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 6
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N n-Butanol Substances CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 5
- CNJRPYFBORAQAU-UHFFFAOYSA-N 1-ethoxy-2-(2-methoxyethoxy)ethane Chemical compound CCOCCOCCOC CNJRPYFBORAQAU-UHFFFAOYSA-N 0.000 claims description 3
- 238000004821 distillation Methods 0.000 abstract description 4
- 238000003754 machining Methods 0.000 abstract 1
- 238000005191 phase separation Methods 0.000 abstract 1
- 239000012487 rinsing solution Substances 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 26
- 239000003921 oil Substances 0.000 description 21
- 238000001035 drying Methods 0.000 description 13
- 239000007788 liquid Substances 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 239000002904 solvent Substances 0.000 description 8
- 238000013329 compounding Methods 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- -1 glycol ethers Chemical class 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 239000003799 water insoluble solvent Substances 0.000 description 4
- 239000013543 active substance Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- LDMRLRNXHLPZJN-UHFFFAOYSA-N 3-propoxypropan-1-ol Chemical compound CCCOCCCO LDMRLRNXHLPZJN-UHFFFAOYSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Natural products OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- DJCYDDALXPHSHR-UHFFFAOYSA-N 2-(2-propoxyethoxy)ethanol Chemical compound CCCOCCOCCO DJCYDDALXPHSHR-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- JSGVZVOGOQILFM-UHFFFAOYSA-N 3-methoxy-1-butanol Chemical compound COC(C)CCO JSGVZVOGOQILFM-UHFFFAOYSA-N 0.000 description 1
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 description 1
- 102100036200 Bisphosphoglycerate mutase Human genes 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010018612 Gonorrhoea Diseases 0.000 description 1
- 101000594702 Homo sapiens Bisphosphoglycerate mutase Proteins 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000001089 [(2R)-oxolan-2-yl]methanol Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- OCUJLLGVOUDECM-UHFFFAOYSA-N dipivefrin Chemical compound CNCC(O)C1=CC=C(OC(=O)C(C)(C)C)C(OC(=O)C(C)(C)C)=C1 OCUJLLGVOUDECM-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- DQYBDCGIPTYXML-UHFFFAOYSA-N ethoxyethane;hydrate Chemical compound O.CCOCC DQYBDCGIPTYXML-UHFFFAOYSA-N 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 150000003903 lactic acid esters Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229940057867 methyl lactate Drugs 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- CIBMHJPPKCXONB-UHFFFAOYSA-N propane-2,2-diol Chemical compound CC(C)(O)O CIBMHJPPKCXONB-UHFFFAOYSA-N 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 238000010407 vacuum cleaning Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
-
- C11D2111/14—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
Abstract
The purpose of the present invention is to provide a non-flammable washing agent composition which has high washing performance against stains including a machining oil and a flux, does not require the use of any other rinsing solution such as pure water, enables an object washed with the washing agent composition to be dried directly, can be re-used repeatedly through the collection by distillation or the like, and does not undergo phase separation and therefore enables washing in a steady manner. A non-flammable washing agent composition characterized by comprising water, diethylene glycol diethyl ether and a water-soluble solvent and having a cloud point of 30 DEG C or higher and lower than 100 DEG C.
Description
Technical field
The present invention relates to the detergent composition that contains water, diethylene glycol diethyl ether and water-soluble solvent and use its washing methods.
More specifically, the present invention relates to the washing force excellence of the dirt such as processing oils, solder flux class to being attached to parts that use in the various industrial circles such as automobile, machinery, precision instrument, electric, electronics etc. and there is the non-flammable cleaner agent composition of good drying property and use its washing methods.
Background technology
In various industrial circles, in order to remove the dirt that is attached to metal parts, electronic unit, semiconductor device etc., having used halogen series solvent, hydrocarbon system washing composition, glycol ethers is the various washing composition such as washing composition, aqueous cleaning, accurate aqueous cleaning.
But chlorine series solvent is high to the hazardness of human body, environment, be mostly subject to regulation limitations etc., there is unworkable problem.Hydrocarbon system washing composition, glycol ethers be owing to having inflammableness, so must carry out explosion-proof installation to washing plant, or needs the countermeasure on the equipment such as fire-protection device, and then as specified in fire service law, treatment capacity becomes needs management fully when extensive.Because aqueous cleaning, accurate aqueous cleaning do not have inflammableness, so without antiknock device, but due to compounding in these washing composition nonvolatile compositions such as tensio-active agent, so must carry out rinsing washing with pure water etc. after washing, these draining processing etc. need a large amount of expense, equipment.In addition, owing to cannot utilizing re-using of Distillation recovery etc., so the liquid management of washing composition and purificant, to exchange periodically the problem such as numerous and diverse many.
For these problems, a kind of chlorine-free is disclosed and not containing the non-flammable cleaner agent (for example, with reference to patent documentation 1～5) of tensio-active agent, but because they all lack the solvability of oil content, so washing force is insufficient, in addition, cannot all meet the desired performance such as drying property, recyclability.
Prior art document
Patent documentation
Patent documentation 1: Japanese kokai publication hei 8-283973 communique
Patent documentation 2: Japanese kokai publication hei 9-255995 communique
Patent documentation 3: Japanese kokai publication hei 11-19986 communique
Patent documentation 4: TOHKEMY 2004-238442 communique
Patent documentation 5: TOHKEMY 2004-107561 communique
Summary of the invention
the problem that invention will solve
The object of the present invention is to provide a kind of non-flammable cleaner agent composition, described non-flammable cleaner agent composition is high to the detergency of the dirt such as treated oil, solder flux, without other rinsing liquids such as pure water, after washing, can directly be dried, can repeatedly re-use by Distillation recovery etc., and be not separated, can stably wash.
for the scheme of dealing with problems
The inventor etc. are in order to solve foregoing problems, repeatedly carry out various research, result is surprised to find: even if certain solvent mixture is in order to disappear and compounding water inflammableness, oil content solvability reduces also few, even if be the moisture concentration of non-flammable solution, also the required oil content solvability of washing that can holding member etc., thus the present invention completed.
That is, detergent composition of the present invention is a kind of non-flammable cleaner agent composition, it is characterized in that, contains water, diethylene glycol diethyl ether and water-soluble solvent, more than cloud point is 30 DEG C and lower than 100 DEG C.
The present invention will be described in more detail below.
As long as the water in detergent composition of the present invention has the water of the effect of the flash-point disappearance that makes detergent composition, be not particularly limited, can preferably use that impurity is few, impact on parts, washing machine, the few water of impact on the precision work quality after washing etc., such as distilled water, ion exchanged water etc.
So-called non-flammable herein, refers to be judged as at a gram sharp Forlan to obtain in (Cleveland) open flashing test method (JIS K2265) and do not confirm inflammable situation.
Diethylene glycol diethyl ether in detergent composition of the present invention is the solvent that hazardous property is low, drying property is excellent.While adding water wherein, at room temperature dissolve and form uniform solution, while heating, water is separated, and demonstrates cloud point according to the compounding amount of water when roughly lower than 30 DEG C.And then while adding water-soluble solvent, cloud point raises, and the increase of the solvability of oil content, demonstrate good detergency.It should be noted that, the addition of water-soluble solvent is many, and when cloud point reaches more than 100 DEG C, the solvability of oil content becomes insufficient, and detergency also worsens.While not adding water that flash-point is disappeared containing the solvent of diethylene glycol diethyl ether, there is detergency, wash the problems such as irregular.
Water-soluble solvent in detergent composition of the present invention as long as be water-soluble solvent, is not particularly limited, the also water-soluble solvent molten with water for roughly more than 30 DEG C time.Due to compounding than and can cause the deterioration of drying property etc., therefore, preferably boiling point is 210 DEG C of following water-soluble solvents, for example, can list the glycol ethers such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, Diethylene glycol monopropyl ether, propylene glycol monomethyl ether, dihydroxypropane single-ether, propylene glycol monopropyl ether, dipropylene glycol monomethyl ether, DPE; The glycolss such as ethylene glycol, Diethylene Glycol, propylene glycol, hexylene glycol, isoamyl glycol; The methoxybutanol classes such as 3-methoxyl group-n-butyl alcohol, 3-methyl-3-methoxyl group-n-butyl alcohol; The lactic acid ester such as methyl lactate, ethyl lactate; The cyclic ether such as tetrahydrofurfuryl alcohol, furfuryl alcohol alcohols; Gamma-butyrolactone etc.Above-mentioned solvent may be used singly or in combination of two or more.
In above-mentioned water-soluble solvent, particularly boiling point is that 170 DEG C of above and 210 DEG C of following, propylene glycol, diethylene glycol monoethyl ether, dipropylene glycol monomethyl ether, 3-methyl-3-methoxyl group-n-butyl alcohol, diethylene glycol methyl ethyl ether etc. are with low uncertainty with the composition of diethylene glycol diethyl ether, therefore preferably, particularly preferably be flash-point higher than diethylene glycol diethyl ether, propylene glycol, diethylene glycol monoethyl ether or dipropylene glycol monomethyl ether.
More than the cloud point of detergent composition of the present invention is 30 DEG C and lower than 100 DEG C, become higher viewpoint from the solvability of oil content, more than particularly preferably cloud point is 50 DEG C and below 90 DEG C.
It should be noted that, cloud point in the present invention refers to, transparent solution is because temperature variation produces the temperature of mist, refer to the tween aqueous solution in the phenomenon that produces while similarly making the temperature of solution raise, be separated into the phase using solvent as main component and the phase using water as main component, transparent solution starts to produce muddy temperature.
Water, diethylene glycol diethyl ether and the water-soluble solvent of detergent composition of the present invention is by the whole compositions of compounding, thereby bring into play first the excellent effect as target detergent composition, particularly form the composition of the washing use that is suitable for the dirt including processing wet goods oil content, solder flux etc.That is, formed the composition of non-flammable for only compounding water and diethylene glycol diethyl ether or water and water-soluble solvent, the solvability of oil content is low, cannot obtain sufficient detergency.In addition, only compounding the composition of diethylene glycol diethyl ether and water-soluble solvent form flammable solution.
For the ratio in detergent composition of the present invention, consider from the viewpoint of detergency and flammable consumption, more than water is preferably 5 capacity % and below 30 capacity %, more than being particularly preferably 10 capacity % and below 25 capacity %.Consider from the solvability of oil content and the viewpoint of non-flammable composition, more than diethylene glycol diethyl ether is preferably 40 capacity % and below 90 capacity %, more than being particularly preferably 50 capacity % and below 80 capacity %.Consider from the deliquescent viewpoint of cloud point, oil content, more than water-soluble solvent is preferably 1 capacity % and below 40 capacity %, more than being particularly preferably 5 capacity % and below 30 capacity %.
In the scope of performance that does not hinder this composition, in detergent composition of the present invention, also can further comprise other polyol derivatives, ester class, ethers etc.In addition, can also further comprise anticorrosive agent, the rust-preventive agent such as antioxidant, alkamine, alkyl amine, benzotriazole category, benzothiazoles etc., iron, copper, zinc such as 2,6-di-t-butyl-p-cresol (BHT), thymol, pyrocatechol.
Detergent composition of the present invention comprises water, diethylene glycol diethyl ether and water-soluble solvent, more than their total content is preferably 80 capacity %, more than 95 capacity %, can be more preferably also 100 capacity %.
Detergent composition of the present invention does not contain the material of the non-volatilities such as tensio-active agent, owing to being made up of the composition that is easy to volatilization, so without other rinsing liquids, can directly be dried.Washings after washing can implement that warm braw is dry, suction dried, Rotary drying, vacuum-drying etc. are for the drying means of existing washing composition.
More than the drying temperature of the washings after washing is preferably 50 DEG C and below 120 DEG C, more than being preferably 10 seconds time of drying and below 1 hour, more than more preferably 30 seconds and below 0.5 hour.
In addition, the low boiling point solvents such as the rear water of washing, Virahol carry out after rinsing washing, also can be dried.Detergent composition of the present invention is water-soluble, so even for the washings of complicated shape also can carry out rinsing for water, can reduce the washing composition discharging to atmosphere when dry.In addition, the washing composition that is dissolved in these rinsing liquids can reclaim and use once again by distilling, being separated.
For detergent composition of the present invention, can utilize and can not cause the deteriorated intermittent type of composition variations, scourability etc. or the distilling machinery of continous way, separate dirt composition and by contaminated liquids recovery in the washing of processing wet goods dirt etc., and Reusability.It should be noted that, the distilling machinery using is not particularly limited, conventionally preferred vacuum (decompression) distilling machinery.
In addition, for detergent composition of the present invention, can add the poor solvent to dirt such as water, by washing, the dirt dissolving is separated, can be by the removals such as oil-water separator for dirt after separation.Oily water separation can suitably be used following method according to the separation accuracy of oil content: the existing oily water separation method of utilizing difference in specific gravity to separate; The oily water separation method effectively separating by coalescer (coalescer); The methods that separate by strainer, ultra-filtration membrane etc. etc., the liquid after separation can be by distilling, being separated washing composition is reclaimed.
Detergent composition of the present invention, except the dirt such as treated oil, solder flux, can also be applicable to remove ink, solder resist, moccasin (buff) etc.
The washing methods that uses detergent composition of the present invention to be attached with the washing of the parts of any person in treated oil, solder flux etc. is not particularly limited, for example can use ultrasonic washing, jet flow washing, dipping washing, shake washing, rotation washing, spray washing, spray washing, vacuum cleaning mode etc., consider desired degree of cleaning, needed time etc., can use separately or combine multiple mode and use.
The temperature that uses detergent composition of the present invention to be attached with the washing of the parts etc. of any person in treated oil, solder flux be preferably 0 DEG C above and below 90 DEG C, more preferably 10 DEG C above and below 70 DEG C.In addition, more than washing time is preferably 1 second and below 1 hour, more than more preferably 10 seconds and below 0.5 hour.
the effect of invention
About detergent composition of the present invention, to being attached to the washing force excellence of processing wet goods of parts that use in the various industrial circles such as automobile, machinery, precision instrument, electric, electronics etc., without other rinsing liquids, after washing, can directly be dried, can repeatedly re-use by Distillation recovery etc., and be non-flammable, can wash safely.
Embodiment
Embodiment
Illustrate in greater detail the present invention according to embodiment below, but the present invention is not limited to this.
< cloud point is measured >
Experimental liquid is joined in Glass Containers, stir while heating lentamente.Approximately 1 DEG C of the every rising of temperature of experimental liquid, the outward appearance of observing liquid, using the temperature that gonorrhoea occurs as cloud point.
< detergency test >
The bottle (M8 × 20) that is attached with commercially available water insoluble cutting oil agent is immersed in the various detergent composition 100ml that are held in 35 DEG C of temperature, carry out after 3 minutes ultrasonic washings (frequency 38kHz, output 200W), at 70 DEG C, carry out 1 hour warm braw dry.After dry, measure the residual oil component of bottle, carry out the evaluation of detergency according to following metewand.
Metewand ◎: remaining oil content is less than 10 μ g
Zero: remaining oil content 10 μ g are above and be less than 50 μ g
△: remaining oil content 50 μ g are above and be less than 100 μ g
×: more than remaining oil content 100 μ g
< drying property test >
By aluminium sheet
be impregnated in the washing composition of 40 DEG C, mention and slowly hang 30 seconds, liquid is removed in control, afterwards, under the warm braw of 50 DEG C, is dried, and measures the dry time.The metewand of drying property is as described below.
Metewand: ◎: be less than 70 seconds, zero: 70 second above and be less than 80 seconds,
△: 80 seconds～be less than 100 seconds, ×: more than 100 seconds
< flashing test >
Based on JIS K2265, use a gram sharp Forlan to obtain open flash(point)tester and measure flash-point.
Metewand: zero: without flash-point ×: have flash-point
< comprehensive evaluation >
Carry out comprehensive evaluation according to following metewand.
Metewand ◎: what the evaluation of detergency, drying property was ◎, flash-point is evaluated as zero
Zero: the evaluation of detergency, drying property is not all ◎ or be not all ×, flash-point be evaluated as zero
×: detergency, drying property, flash-point be ×
It should be noted that, the implication of the symbol in table is as described below.
DEGDE: diethylene glycol diethyl ether
PG: propylene glycol
DEGE: diethylene glycol monoethyl ether
DPGM: dipropylene glycol monomethyl ether
MMB:3-methyl-3-methoxyl group-n-butyl alcohol
MMBA:3-methyl-3-methoxyl group-1-butylacetic acid ester (water-insoluble solvent)
DEGEM: diethylene glycol methyl ethyl ether
PNB: propylene glycol monobutyl ether (water-insoluble solvent)
DPGB: Dipropylene glycol mono-n-butyl Ether (water-insoluble solvent)
DPGP: dipropylene glycol list propyl ether (water-insoluble solvent)
PNP: propylene glycol monopropyl ether
Embodiment 1～14
The detergent composition that comprises water, diethylene glycol diethyl ether and water-soluble solvent of recording in preparation table 1, evaluates gained detergent composition.
Comparative example 1～12
The detergent composition of recording in preparation table 1, evaluates gained detergent composition.
Do not make water comparative example 2, do not use diethylene glycol diethyl ether comparative example 3～9,11,12, do not use the detergent composition of recording in the comparative example 1,10 of water-soluble solvent compared with the detergent composition of recording in embodiment, evaluation result is poor.
[table 1]
utilizability in industry
Detergent composition of the present invention can be for the washing to the processing wet goods that is attached to parts that use in the various industrial circles such as automobile, machinery, precision instrument, electric, electronics etc.
It should be noted that, the full content of specification sheets, claim and the summary of No. 2011-258050, the Japanese patent application of on November 25th, 2011 application is referred to herein, introduce as the disclosure of specification sheets of the present invention.
Claims (8)
1. a non-flammable cleaner agent composition, is characterized in that, contains water, diethylene glycol diethyl ether and water-soluble solvent, more than cloud point is 30 DEG C and lower than 100 DEG C.
2. detergent composition according to claim 1, wherein, water-soluble solvent be select in the group of free propylene glycol, diethylene glycol monoethyl ether, dipropylene glycol monomethyl ether, 3-methyl-3-methoxyl group-n-butyl alcohol and diethylene glycol methyl ethyl ether composition more than a kind.
3. detergent composition according to claim 1 and 2, wherein, water is that 5 capacity % are above and below 30 capacity %, diethylene glycol diethyl ether is more than 40 capacity %, water-soluble solvent is below 40 capacity %.
4. according to the detergent composition described in any one in claim 1～3, wherein, diethylene glycol diethyl ether is more than 50 capacity % and below 80 capacity %.
5. according to the detergent composition described in any one in claim 1～4, wherein, water-soluble solvent is more than 5 capacity % and below 30 capacity %.
6. according to the detergent composition described in any one in claim 1～5, wherein, cloud point be 50 DEG C above and below 90 DEG C.
7. according to the detergent composition described in any one in claim 1～6, wherein, water-soluble solvent is propylene glycol, diethylene glycol monoethyl ether or dipropylene glycol monomethyl ether.
8. a washing methods, is characterized in that, right to use requires the detergent composition described in any one in 1～7 to wash the parts that are attached with any person in treated oil, solder flux.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011-258050 | 2011-11-25 | ||
| JP2011258050 | 2011-11-25 | ||
| PCT/JP2012/080240 WO2013077383A1 (en) | 2011-11-25 | 2012-11-21 | Washing agent composition and washing method using same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103987833A true CN103987833A (en) | 2014-08-13 |
| CN103987833B CN103987833B (en) | 2018-11-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280057925.9A Active CN103987833B (en) | 2011-11-25 | 2012-11-21 | Detergent composition and use its washing methods |
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| Country | Link |
|---|---|
| JP (1) | JP6056345B2 (en) |
| CN (1) | CN103987833B (en) |
| TW (1) | TWI567187B (en) |
| WO (1) | WO2013077383A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109517677A (en) * | 2017-09-19 | 2019-03-26 | 荒川化学工业株式会社 | Detergent composition stoste and detergent composition comprising the detergent composition stoste |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6226144B2 (en) * | 2014-02-27 | 2017-11-08 | 荒川化学工業株式会社 | Detergent composition stock solution, detergent composition and cleaning method |
| JP6650100B2 (en) * | 2015-04-30 | 2020-02-19 | 荒川化学工業株式会社 | Article cleaning and rinsing method and article cleaning and rinsing apparatus |
| JP6733202B2 (en) * | 2016-02-15 | 2020-07-29 | 東ソー株式会社 | Aerosol type cleaner |
| JP7031412B2 (en) * | 2017-05-17 | 2022-03-08 | 東ソー株式会社 | Detergent composition and cleaning method using it |
| CN113491682A (en) * | 2020-04-01 | 2021-10-12 | 宁海德宝立新材料有限公司 | Gallstone dissolving agent |
| CN115747816A (en) * | 2022-12-05 | 2023-03-07 | 中国工程物理研究院材料研究所 | Application of glycol ether in cleaning of active metal, non-water-based cleaning agent and cleaning method of active metal |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6477426A (en) * | 1987-09-16 | 1989-03-23 | Mitsubishi Mining & Cement Co | Protective circuit for semiconductor circuit |
| JPH0679852A (en) * | 1992-07-13 | 1994-03-22 | Sanyo Chem Ind Ltd | Cleansing for screen printing board |
| JPH07109493A (en) * | 1993-10-15 | 1995-04-25 | Toagosei Co Ltd | Detergent composition |
| JPH07331287A (en) * | 1994-06-13 | 1995-12-19 | Dai Ichi Kogyo Seiyaku Co Ltd | Cleaning of rosin-type flux residue |
| JPH08224740A (en) * | 1995-02-22 | 1996-09-03 | Dai Ichi Kogyo Seiyaku Co Ltd | Washing agent for glass mold |
| JPH08269495A (en) * | 1995-04-03 | 1996-10-15 | Sanyo Chem Ind Ltd | Detergent for screen printing plate |
| JPH0949094A (en) * | 1995-08-07 | 1997-02-18 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent composition for hybrid integrated circuit |
| JPH1077426A (en) * | 1996-09-03 | 1998-03-24 | Toho Chem Ind Co Ltd | Detergent composition |
| JPH10287896A (en) * | 1997-04-10 | 1998-10-27 | Sanyo Chem Ind Ltd | Detergent for magnetic card |
| JP2006233029A (en) * | 2005-02-25 | 2006-09-07 | Sanyo Chem Ind Ltd | Alkaline detergent |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08245988A (en) * | 1995-03-10 | 1996-09-24 | Toho Chem Ind Co Ltd | Cleaning agent composition |
| JP2949425B2 (en) * | 1996-10-11 | 1999-09-13 | 花王株式会社 | Detergent composition |
| JP5609348B2 (en) * | 2009-08-25 | 2014-10-22 | 東ソー株式会社 | Cleaning composition and cleaning method using the same |
-
2012
- 2012-10-05 JP JP2012222849A patent/JP6056345B2/en active Active
- 2012-11-21 WO PCT/JP2012/080240 patent/WO2013077383A1/en active Application Filing
- 2012-11-21 CN CN201280057925.9A patent/CN103987833B/en active Active
- 2012-11-26 TW TW101144108A patent/TWI567187B/en active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6477426A (en) * | 1987-09-16 | 1989-03-23 | Mitsubishi Mining & Cement Co | Protective circuit for semiconductor circuit |
| JPH0679852A (en) * | 1992-07-13 | 1994-03-22 | Sanyo Chem Ind Ltd | Cleansing for screen printing board |
| JPH07109493A (en) * | 1993-10-15 | 1995-04-25 | Toagosei Co Ltd | Detergent composition |
| JPH07331287A (en) * | 1994-06-13 | 1995-12-19 | Dai Ichi Kogyo Seiyaku Co Ltd | Cleaning of rosin-type flux residue |
| JPH08224740A (en) * | 1995-02-22 | 1996-09-03 | Dai Ichi Kogyo Seiyaku Co Ltd | Washing agent for glass mold |
| JPH08269495A (en) * | 1995-04-03 | 1996-10-15 | Sanyo Chem Ind Ltd | Detergent for screen printing plate |
| JPH0949094A (en) * | 1995-08-07 | 1997-02-18 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent composition for hybrid integrated circuit |
| JPH1077426A (en) * | 1996-09-03 | 1998-03-24 | Toho Chem Ind Co Ltd | Detergent composition |
| JPH10287896A (en) * | 1997-04-10 | 1998-10-27 | Sanyo Chem Ind Ltd | Detergent for magnetic card |
| JP2006233029A (en) * | 2005-02-25 | 2006-09-07 | Sanyo Chem Ind Ltd | Alkaline detergent |
Non-Patent Citations (1)
| Title |
|---|
| 刘程等: "《表面活性剂应用手册 第3版》", 30 September 2004, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109517677A (en) * | 2017-09-19 | 2019-03-26 | 荒川化学工业株式会社 | Detergent composition stoste and detergent composition comprising the detergent composition stoste |
| CN109517677B (en) * | 2017-09-19 | 2021-05-18 | 荒川化学工业株式会社 | Detergent composition stock solution, and detergent composition containing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6056345B2 (en) | 2017-01-11 |
| WO2013077383A1 (en) | 2013-05-30 |
| TWI567187B (en) | 2017-01-21 |
| CN103987833B (en) | 2018-11-06 |
| TW201333185A (en) | 2013-08-16 |
| JP2013129815A (en) | 2013-07-04 |
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