CN103983663A - Tobacco combustion heat measurement apparatus - Google Patents

Tobacco combustion heat measurement apparatus Download PDF

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Publication number
CN103983663A
CN103983663A CN201410151064.1A CN201410151064A CN103983663A CN 103983663 A CN103983663 A CN 103983663A CN 201410151064 A CN201410151064 A CN 201410151064A CN 103983663 A CN103983663 A CN 103983663A
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China
Prior art keywords
combustion
heating furnace
communicated
tobacco
pipeline
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Pending
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CN201410151064.1A
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Chinese (zh)
Inventor
周顺
王孝峰
何庆
张亚平
徐迎波
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China Tobacco Anhui Industrial Co Ltd
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China Tobacco Anhui Industrial Co Ltd
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Publication date
Application filed by China Tobacco Anhui Industrial Co Ltd filed Critical China Tobacco Anhui Industrial Co Ltd
Priority to CN201410151064.1A priority Critical patent/CN103983663A/en
Publication of CN103983663A publication Critical patent/CN103983663A/en
Pending legal-status Critical Current

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Abstract

The present invention discloses a tobacco combustion heat measurement apparatus, which comprises a gas supply device, a combustion device, a filtration device and an analysis device, wherein the combustion device comprises an annular heating furnace and a controller, one quartz pipe end arranged inside the annular heating furnace is a heating end, the other end is a non-heating end, the end is provided with a sealing member, a quartz boat is arranged in the quartz pipe and is pushed by a step motor to move at a uniform speed, the sealing member is provided with two through holes for a gas supply pipeline channel and a step motor transmission channel, the filtration device comprises a high temperature resistance filter directly connected with the gas outlet end of the annular heating furnace, and a second-stage filter communicated with the analysis device, the two stages of the filters are connected through a cooling pipeline, the filtration device is used for filtering particle phase substances and water in the combustion product so as to avoid influence on the analysis device, and the analysis device comprises an oxygen analyser communicated with the second-stage filter through a pipeline. According to the present invention, the accurate measurement of the combustion heat of the tobacco under the stable poor-oxygen combustion state is achieved.

Description

A kind of result of combustion of tobacco thermal measurement device
Technical field:
The present invention relates to a kind of result of combustion of tobacco thermal measurement device, belong to calorimetry technical field.
Background technology:
Cigarette is a kind of special consumer goods that rely on burning to embody its quality.Result of combustion of tobacco heat is one of important parameter of result of combustion of tobacco characteristic, all closely related with flavor component formation and objectionable impurities release and cigarette ignition behavior etc. in tobacco aesthetic quality, flue gas.
At present, the measurement mechanism that can be used for material combustion heat mainly comprises tapered calorimeter and micro-combustion calorimeter.The design of taper calorimeter and micro-combustion calorimeter is all according to oxygen consumption principle, and while specifically referring to substance combustion, the oxygen of every consumption unit mass can produce substantially the same heat, and the oxygen consumption heating power of material is basic identical.Oxygen consumption principle is found in 1917 by Thornton.Huggett has carried out system-computed application oxygen consumption principle in 1980 to common combustible polymers and natural material, and the mean value that has obtained oxygen consumption heating power is 13.1kJ/g, and the E value deviation of storeroom is 5%.It should be noted that, heating power release characteristics and material burning situation of living in is closely related, and for tobacco, the measurement of its heating power only just has more and is worth and practical significance under the condition that approaches cigarette burning environment.Present stage, great many of experiments and numerical simulation result are verified, the glow state of cigarette burning environment in the rich hydrogen of oxygen deprivation.Tapered calorimeter is to discharge for testing ad hoc rules sample heat under violent combustion case in the unlimited system of oxygen abundance, due to the singularity of tobacco sample physical behavior, is difficult to realize its accurate measurement to result of combustion of tobacco heat.Micro-combustion calorimeter is in the time that the heating power of measuring material discharges, be by minute quantity (general 4-5 milligram) sample after the abundant cracking of pyrolysis furnace, cracked gas is placed in to combustion furnace burning, therefore its reflection is pyrolysis and the burning behavior of material under micro-scale again, and repeatability is poor.Clearly, tapered calorimeter and micro-combustion calorimeter all cannot be accomplished to simulate cigarette combustion with meagre oxygen environment, are not suitable for the measurement of result of combustion of tobacco heat.
Standard ISO 19700 proposed equivalence ratio ( ) concept, core is to control the generation speed (v of fuel fuel) with the delivery rate (v of air air) ratio, shown in formula specific as follows,
When when=1, >1, represent that respectively material is in air abundance, stable state combustion when stoichiometric ratio (theoretical value) and under oxygen deprivation condition.Wherein, physical meaning refer to the supply of air when each element in fuel fully burns.Therefore, based on oxygen consumption principle, utilize controlled equivalence ratio method just can Measurement accuracy tobacco heating power under simulation cigarette burning situation.
Summary of the invention:
For overcoming the defect of prior art, the object of the present invention is to provide a kind of result of combustion of tobacco thermal measurement device, realize tobacco at the Measurement accuracy of stablizing heating power under combustion with meagre oxygen state.
Technical solution problem of the present invention adopts following technical scheme:
A kind of result of combustion of tobacco thermal measurement device, it comprises:
Feeder, burner, filtration unit and analytical equipment;
Described burner comprises rotary heating furnace and annular-heating furnace controller, one end that quartz ampoule is located in described rotary heating furnace is fire end, the other end is non-fire end, be provided with seal at described non-fire end, quartz boat is located in described quartz ampoule and by outside stepper motor and is promoted in quartz ampoule, at the uniform velocity to move, on described seal, be provided with two through holes for supply air line path and stepper motor transmission path, described supply air line is communicated with described feeder;
The temperature range of described rotary heating furnace heating is in room temperature to 1200 DEG C, and its furnace chamber internal diameter is slightly larger than the external diameter of quartz ampoule, so that the gap between quartz ampoule and rotary heating furnace furnace chamber is as far as possible little;
Described filtration unit comprises the second level filtrator that is directly connected to the high-temperature resistant filter of described rotary heating furnace outlet side and is communicated with described analytical equipment, between described high-temperature resistant filter and described second level filtrator, is connected by cooling line;
Described filtration unit, for the granule phase substance of filtration combustion product, is avoided the impact on analytical equipment;
Described analytical equipment comprises by pipeline and the oxygen analyser that described second level filtrator is communicated with, is provided with first flow meter in described pipeline.
Described feeder comprises gas-holder and the second flowmeter, and described gas-holder is by described supply air line to described rotary heating furnace air feed, and described the second flowmeter is located on described supply air line.The source of the gas of feeder is pressurized air or synthesis of air (79% nitrogen+21% oxygen), if pressurized air requires it to enter the dedusting that will dehumidify before flowmeter, dehumidifying drying agent, as anhydrous calcium chloride etc., filter paper is used in dedusting, as quartz filter paper, glass fiber filter paper etc.; Described the second flow is counted single air flowmeter or nitrogen, oxygen flow meter combination, and this depends on source of the gas used;
Described oxygen analyser is paramagnetic oxygen analyzer, and analyst coverage is at least between 0-25%.
A kind of result of combustion of tobacco thermal measurement device, it comprises:
Feeder, burner, filtration unit and analytical equipment;
Described burner comprises rotary heating furnace and annular-heating furnace controller, one end that quartz ampoule is located in described rotary heating furnace is fire end, the other end is non-fire end, be provided with seal at described non-fire end, quartz boat is located in described quartz ampoule and by outside stepper motor and is promoted in quartz ampoule, at the uniform velocity to move, on described seal, be provided with two through holes for supply air line path and stepper motor transmission path, described supply air line is communicated with described feeder;
Described filtration unit comprises the second level filtrator that is directly connected to the high-temperature resistant filter of described rotary heating furnace outlet side and is communicated with described analytical equipment, between described high-temperature resistant filter and described second level filtrator, is connected by cooling line;
Described analytical equipment comprises the gas collection bag being communicated with described second level filtrator by the first pipeline and the oxygen analyser being communicated with described gas collection bag by the second pipeline; On described the first pipeline, be provided with the first operation valve, on described the second pipeline, be provided with the second operation valve and clarifier.
Described feeder comprises gas-holder and the second flowmeter, and described gas-holder is by described supply air line to described rotary heating furnace air feed, and described the second flowmeter is located on described supply air line.
Described oxygen analyser is paramagnetic oxygen analyzer, and analyst coverage is at least between 0-25%.
Described cooling line outside is provided with chilled water runner, and the flow direction of described chilled water flows to contrary with tobacco sample products of combustion.
Compared with the prior art, beneficial effect of the present invention is embodied in:
Compared to existing technology, the invention solves current combustion thermal measurement instrument and be difficult to simulate the problem of cigarette combustion with meagre oxygen environment, utilize controlled equivalence ratio method to realize tobacco at the oxygen deprivation stable state combustion close under cigarette burning environment, and can quantitatively calculate HRR and the hot burst size under each combustion with meagre oxygen state in conjunction with oxygen consumption principle, for the accurate measurement of result of combustion of tobacco heat provides a feasible scheme.
Brief description of the drawings:
Fig. 1 is the structure principle chart of apparatus of the present invention; Fig. 2 is the structural representation of on-line measurement device of the present invention; Fig. 3 is the structural representation of off-line measurement device of the present invention.
Number in the figure: 1 is feeder, 2 is burner, 3 is filtration unit, 4 is analytical equipment, 11 is gas-holder, 12 is the second flowmeter, 21 is stepper motor, 22 is seal, 23 is quartz ampoule, 24 is quartz boat, 25 is tobacco sample, 26 is rotary heating furnace, 27 is controller, 31 is high-temperature resistant filter, 32 is second level filtrator, 33 is cooling line, 331 is cooling water inlet, 332 is coolant outlet, 41 is first flow meter, 42 is oxygen analyser, 410 first operation valves, 420 is gas collection bag, 430 second operation valves, 440 is clarifier.
Below pass through embodiment, and the invention will be further described by reference to the accompanying drawings.
Embodiment:
Embodiment 1: as shown in Figure 1, device disclosed in this invention comprises feeder 1, burner 2, filtration unit 3 and analytical equipment 4.Burner 2 is stablized tobacco sample supply and stable temperature field for providing; Feeder 1 is used to burner 2 that stable and the adjustable air of flow are provided; Filtration unit 3 is directly connected to the outlet side of burner, and the gas producing for purification of combustion, avoids the pollution to analytical equipment 4; After analytical equipment 4 is connected in filtration unit 3, for testing eluting gas oxygen volume content.
In the time of test cigarette burning heat, the air supply speed calculating according to theory and tobacco sample delivery rate, set correlation parameter, by the supply rate of tobacco sample in control combustion device 2 and the gas flow of feeder 1, fuel is supplied with consistent with air supply, thereby made burning in stable combustion with meagre oxygen state.Analytical equipment 4 gathers and analyzes the flue gas installing after filtration after 3 purifications, obtains the oxygen volume factor of flue gas.Then, according to the hot burst size of tested correlation parameter unit of account quality tobacco sample.
As shown in Figure 2, the on-line measurement device of the present embodiment comprises feeder 1, burner 2, filtration unit 3 and analytical equipment 4.Wherein, burner 2 comprises rotary heating furnace 26, controller 27, quartz ampoule 23, quartz boat 24, stepper motor 21, seal 22 and tobacco sample 25.Tobacco sample 25 will be laid on quartz boat 24 uniformly, for guaranteeing homogeneity, tobacco sample can be ground and set to spread with machinery and spill.Stepper motor 21 can enter in rotary heating furnace 26 by promotion quartz boat 24 at the uniform velocity, and its speed is adjustable.One end of quartz ampoule is fire end, and fire end is located in rotary heating furnace, and the other end is non-fire end, and seal 22 can, by the non-fire end sealing of quartz ampoule, have two through holes, for supply air line path and stepper motor transmission path in seal.Feeder 1 comprises gas-holder 11 and the second flowmeter 12, is used to burner 2 that stable and the adjustable air of flow are provided, and in enforcement, the second flowmeter 12 can adopt glass rotameter.Filtration unit 3 is directly connected to the outlet side of stable state tubular type rotary heating furnace, comprises high-temperature resistant filter 31, second level filtrator 32 and cooling line 33.High-temperature resistant filter 31 directly contacts with heating furnace high-temperature gas out, therefore require high temperature resistant; After cooling line 33 is connected to high-temperature resistant filter 31, for the temperature of cooling combustion product; After second level filtrator 32 is connected to cooling line 33, for the gas that further purification of combustion produces, avoid the pollution to analytical equipment 4; Cooling line 33 is generally made as ring texture, and inner chamber is exhaust gases passes, between interior cavity outer wall and pipeline shell, is interlayer, as chilled water runner, have cooling water inlet 331 and coolant outlet 332, the flow direction of chilled water is contrary with the flow direction of flue gas in inner chamber, can improve cooling effect.After analytical equipment 4 is connected in filtration unit 3, comprise first flow meter 41 and oxygen analyser 42.First flow meter 41 is for detection of the volumetric flow rate of eluting gas, and oxygen analyser 42 is for analyzing the temperature of eluting gas and the volume content of oxygen.
In the time of test cigarette burning heat, the air supply speed calculating according to theory and tobacco sample delivery rate, set correlation parameter, by the fltting speed of tobacco sample in the quartz boat 24 of control combustion device 2 and the gas flow of feeder 1, fuel is supplied with consistent with air supply, thereby made burning in stable combustion with meagre oxygen state.Oxygen analyser 42 in analytical equipment 4 gathers and analyzes the flue gas installing after filtration after 3 purifications, obtains oxygen volume factor and the temperature curve over time of flue gas.Then, according to the hot burst size of the oxygen volume factor of the gas flow in quality, the measuring process of the primary oxygen volume factor of gas, tobacco sample and flue gas and temperature computation unit mass tobacco sample.
Embodiment 2: as shown in Figure 3, the off-line measurement device of the present embodiment comprises feeder 1, burner 2, filtration unit 3 and analytical equipment 4.Wherein, the concrete structure of burner 2, feeder 1 and filtration unit 3 and connection order are consistent with the each device in embodiment 1, repeat no more here.
Described analytical equipment 4 comprises the gas collection bag 420 being communicated with second level filtrator by the first pipeline and the oxygen analyser 42 being communicated with gas collection bag by the second pipeline; On the first pipeline, be provided with the first operation valve 410, on the second pipeline, be provided with the second operation valve 430 and clarifier 440.Gas collection bag 420 is for collecting the gas that comes from burner 2.Purification plant, for removing particle and the moisture in gas collection bag gas, is avoided the pollution to oxygen analyser.
In the time of test cigarette burning heat, first calculate and set instrument correlation parameter according to theory, by the fltting speed of tobacco sample in the quartz boat 24 of control combustion device 2 and the gas flow of feeder 1, fuel is supplied with consistent with air supply, thereby made burning in stable combustion with meagre oxygen state.Gas collection bag 420 trappings in analytical equipment 4 come from the gas of burner 2, after all burnt, close the first operation valve 410, open the second operation valve 430, gas flow in gas collection bag enters oxygen analyser 42 after clarifier 440, and records measured result.After experiment, close electricity and close the quartz boat in gas cleaning and filtrating equipment and burner.According to the hot burst size of the tobacco sample of the cubage unit mass of the volume of the time of the flow of the quality of tobacco sample, supply gas, test, captured gas and oxygen.

Claims (7)

1. a result of combustion of tobacco thermal measurement device, is characterized in that comprising:
Feeder (1), burner (2), filtration unit (3) and analytical equipment (4);
Described burner comprises rotary heating furnace (26) and controller (27) thereof, one end that quartz ampoule (23) is located in described rotary heating furnace is fire end, the other end is non-fire end, be provided with seal (22) at described non-fire end, quartz boat (24) is located in described quartz ampoule and by outside stepper motor (21) and is promoted in quartz ampoule, at the uniform velocity to move, on described seal, be provided with two through holes for supply air line path and stepper motor transmission path, described supply air line is communicated with described feeder;
Described filtration unit (3) comprises the high-temperature resistant filter (31) that is directly connected to described rotary heating furnace outlet side and the second level filtrator (32) being communicated with described analytical equipment, between described high-temperature resistant filter and described second level filtrator, is connected by cooling line (33);
Described analytical equipment (4) comprises the oxygen analyser (42) being communicated with described second level filtrator by pipeline, is provided with first flow meter (41) in described pipeline.
2. a kind of result of combustion of tobacco thermal measurement device according to claim 1, it is characterized in that, described feeder (1) comprises gas-holder (11) and the second flowmeter (12), described gas-holder is by described supply air line to described rotary heating furnace air feed, and described the second flowmeter (12) is located on described supply air line.
3. a kind of result of combustion of tobacco thermal measurement device according to claim 1, is characterized in that, described oxygen analyser (42) is paramagnetic oxygen analyzer, and analyst coverage is at least between 0-25%.
4. a result of combustion of tobacco thermal measurement device, is characterized in that comprising:
Feeder (1), burner (2), filtration unit (3) and analytical equipment (4);
Described burner comprises rotary heating furnace (26) and controller (27) thereof, one end that quartz ampoule (23) is located in described rotary heating furnace is fire end, the other end is non-fire end, be provided with seal (22) at described non-fire end, quartz boat (24) is located in described quartz ampoule and by outside stepper motor (21) and is promoted in quartz ampoule, at the uniform velocity to move, on described seal, be provided with two through holes for supply air line path and stepper motor transmission path, described supply air line is communicated with described feeder;
Described filtration unit (3) comprises the high-temperature resistant filter (31) that is directly connected to described rotary heating furnace outlet side and the second level filtrator (32) being communicated with described analytical equipment, between described high-temperature resistant filter and described second level filtrator, is connected by cooling line (33);
Described analytical equipment (4) comprises the gas collection bag (420) being communicated with described second level filtrator by the first pipeline and the oxygen analyser (42) being communicated with described gas collection bag by the second pipeline; On described the first pipeline, be provided with the first operation valve (410), on described the second pipeline, be provided with the second operation valve (430) and clarifier (440).
5. a kind of result of combustion of tobacco thermal measurement device according to claim 4, it is characterized in that, described feeder (1) comprises gas-holder (11) and the second flowmeter (12), described gas-holder is by described supply air line to described rotary heating furnace air feed, and described the second flowmeter (12) is located on described supply air line.
6. a kind of result of combustion of tobacco thermal measurement device according to claim 4, is characterized in that, described oxygen analyser (42) is paramagnetic oxygen analyzer, and analyst coverage is at least between 0-25%.
7. a kind of result of combustion of tobacco thermal measurement device according to claim 4, is characterized in that, described cooling line (33) outside is provided with chilled water runner, and the flow direction of described chilled water flows to contrary with tobacco sample products of combustion.
CN201410151064.1A 2014-04-15 2014-04-15 Tobacco combustion heat measurement apparatus Pending CN103983663A (en)

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Cited By (6)

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CN104267140A (en) * 2014-09-30 2015-01-07 福建中烟工业有限责任公司 Tobacco pyrolysis and combustion reactor, analysis system and method
CN106770450A (en) * 2016-11-17 2017-05-31 中国烟草总公司郑州烟草研究院 A kind of detection method of charcoal hot type cigarette hot body ignition temperature, Burn-out temperature and firing duration
CN108375637A (en) * 2018-02-06 2018-08-07 陕西中烟工业有限责任公司 A kind of heating of large capacity is not burnt tobacco product simulated experiment analytical equipment and method
CN109425688A (en) * 2017-08-31 2019-03-05 孔燕 Examine profession substance combustion gas examination device
CN109490360A (en) * 2018-12-29 2019-03-19 中国科学技术大学 It is a kind of suitable for large sample amount, more atmosphere can be with differential thermal analysis device
CN111257099A (en) * 2020-01-19 2020-06-09 南京江宁分析仪器有限公司 Thermal decomposition flue gas characteristic experimental device

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104267140A (en) * 2014-09-30 2015-01-07 福建中烟工业有限责任公司 Tobacco pyrolysis and combustion reactor, analysis system and method
CN104267140B (en) * 2014-09-30 2017-01-25 福建中烟工业有限责任公司 Tobacco pyrolysis and combustion reactor, analysis system and method
CN106770450A (en) * 2016-11-17 2017-05-31 中国烟草总公司郑州烟草研究院 A kind of detection method of charcoal hot type cigarette hot body ignition temperature, Burn-out temperature and firing duration
CN106770450B (en) * 2016-11-17 2019-01-22 中国烟草总公司郑州烟草研究院 A kind of detection method of charcoal hot type cigarette heating source combustion characteristics
CN109425688A (en) * 2017-08-31 2019-03-05 孔燕 Examine profession substance combustion gas examination device
CN108375637A (en) * 2018-02-06 2018-08-07 陕西中烟工业有限责任公司 A kind of heating of large capacity is not burnt tobacco product simulated experiment analytical equipment and method
CN108375637B (en) * 2018-02-06 2021-03-30 陕西中烟工业有限责任公司 Large-capacity heating non-combustion tobacco product simulation experiment analysis device and method
CN109490360A (en) * 2018-12-29 2019-03-19 中国科学技术大学 It is a kind of suitable for large sample amount, more atmosphere can be with differential thermal analysis device
CN111257099A (en) * 2020-01-19 2020-06-09 南京江宁分析仪器有限公司 Thermal decomposition flue gas characteristic experimental device
CN111257099B (en) * 2020-01-19 2023-03-10 南京江宁分析仪器有限公司 Thermal decomposition flue gas characteristic experimental device

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