CN103981770A - Filter paper for gasoline filter and preparation method thereof - Google Patents

Filter paper for gasoline filter and preparation method thereof Download PDF

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Publication number
CN103981770A
CN103981770A CN201410138688.XA CN201410138688A CN103981770A CN 103981770 A CN103981770 A CN 103981770A CN 201410138688 A CN201410138688 A CN 201410138688A CN 103981770 A CN103981770 A CN 103981770A
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parts
filter
crop straw
agricultural crop
modification
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CN201410138688.XA
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CN103981770B (en
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薛卉慧
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Anhui Fengyang Guofeng Ecological Technology Materials Co., Ltd.
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Bengbu Feng Chi Cleaner Co Ltd
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Abstract

The invention discloses a filter paper for a gasoline filter and a preparation method thereof. The filter paper comprises the following raw materials by weight: 60 to 70 parts of jute pulp, 35 to 45 parts of a bamboo pulp fiber, 20 to 25 parts of a polyester fiber, 10 to 15 parts of a phenolic resin, 12 to 15 parts of charcoal powder, 13 to 15 parts of modified crop straw, 10 to 12 parts of talcum powder, 4 to 6 parts of a modification coupling agent, 1 to 3 parts of sodium polymethacrylate, 0.2 to 0.4 part of an anti-oxidant 1010, 2 to 4 parts of nekal BX-78, 1 to 3 parts of ammonium chloride, 0.5 to 1.5 parts of sodium borate, 0.8 to 1.5 parts of sodium laurylsulfate and 2 to 4 parts of chlorinated paraffin. The filter paper provided by the invention is environment friendly and scientific and has a reasonable raw material formula and good component compatibility; a prepared modified crop straw adsorbent has stable performance and wider-spectrum organic matter adsorption capability; the employed modification coupling agent enables pulp to be tightly bonded together, so the filter paper has improved material performance, reduced viscosity, better mechanical properties and good tensile strength, elongation at break, impact resistance, etc.

Description

A kind of filter paper and preparation method thereof for gasoline filter
Technical field
The present invention relates to a kind of gasoline filter filter paper and preparation method thereof, belong to automobile filter field.
Background technology
Cleaner is the important spare part of engine, it act as the particulate such as dust and mechanical admixture in air that filtering enters engine, diesel oil, machine oil, to reduce the wearing and tearing of Cylinder Liner Piston Ring in Engine, crankshaft link rod motion pair and high-pressure oil pump plunger matching parts, optimize the combustion process of engine, reduce the discharge of the organic pollutions such as carbon monoxide; Along with filtering improving constantly of requiring, any by singly plant fibrous filter paper be all more and more difficult to meet use on requirement, so the filter paper being formed by multiple fiber combinations arises at the historic moment, in filter paper production, conventional fiber has wood fibre, chemical fibre, glass fibre etc.
Summary of the invention
The object of the present invention is to provide a kind of gasoline filter filter paper and preparation method thereof,
The present invention adopts following technical scheme:
Gasoline filter filter paper, the weight portion of its constitutive material is: jute pulp 60-70, bamboo pulp fiber 35-45, polyester fiber 20-25, phenolic resins 10-15, charcoal powder 12-15, modification agricultural crop straw 13-15, talcum powder 10-12, modification coupling agent 4-6, sodium polymethacrylate 1-3, antioxidant 1010 0.2-0.4, Nekal BX-78 2-4, ammonium chloride 1-3, Boratex 0.5-1.5, sldium lauryl sulfate 0.8-1.5 and chlorinated paraffin wax 2-4.
Gasoline filter filter paper, the weight portion of its constitutive material is: jute pulp 65, bamboo pulp fiber 40, polyester fiber 22, phenolic resins 12, charcoal powder 14, modification agricultural crop straw 14, talcum powder 11, modification coupling agent 5, sodium polymethacrylate 2, antioxidant 1010 0.3, Nekal BX-78 3, ammonium chloride 2, Boratex 1, sldium lauryl sulfate 1.2 and chlorinated paraffin wax 3.
The preparation method of filter paper for gasoline filter, comprises the following steps:
(1) preparation of modification coupling agent: MTMS is added in absolute ethyl alcohol, described MTMS and absolute ethyl alcohol are according to quality and volume ratio 1:3-5, then add the polyacrylamide of the 1.0-2.0% of MTMS quality, the N of 1.5-2.0%, the N of N '-methylene-bisacrylamide and 0.2-0.3%, N-diisopropylethylamine; The temperature of reaction is 40-60 DEG C, and the time of described reaction is 10-12h, obtains reactant liquor; After reaction, reactant liquor is first disperseed to 2-3 hour under ultrasonic electric power 350W condition, and then disperse 3-5 hour under ultrasonic electric power 250W condition, can obtain;
(2) preparation of modification agricultural crop straw:
(a) take agricultural crop straw by constitutive material formula, grind, adding the mass fraction that 10-15 doubly measures is 5~10%NaOH solution, under the temperature conditions of 60~80 DEG C, activates 3~5h, crosses leaching filter residue;
(b) pure water that adds 5-10 doubly to measure in the filter residue of step (a), and then add 0.6-0.7% Dodecyl trimethyl ammonium chloride, 1.2-1.5% Silane coupling agent KH550 and the 3-5% potassium permanganate of agricultural crop straw powder quality; Stir and react 2-3h, filter, dry;
(c) it is in the Hyperbranched Polymer with Terminal Amido solution of 40-50g/L that the agricultural crop straw powder of step (b) being dried adds concentration; Described agricultural crop straw powder and the quality of Hyperbranched Polymer with Terminal Amido solution and volume ratio are 1:40-50, then add 0.1-0.2% catalyst n, N-dimethyl butylamine, is uniformly mixed reaction 10-12h, filter and use washed with de-ionized water 3-5 time, after freeze drying, obtain;
(3) mix first by weight bamboo pulp fiber, polyester fiber, phenolic resins and charcoal powder, then put into pulper size degradation, obtain the slurry that solid content is 4-6%, then add Nekal BX-78, stir and continue size degradation and obtain mixed slurry;
(4) mixed slurry of the modification agricultural crop straw of the modification coupling agent of step (1), step (2) and step (3) is added in jute pulp, heating stirs, and controls temperature 50-70 DEG C;
(5) in the compound of step (4), add other residue constitutive materials, after fluffer is discongested, then defibrination, after defibrination, gained slurry is sized mixing through adding water, to after solid content 3-5% according to conventional paper technology copy paper, moulding squeezing, be drying to obtain.
Beneficial effect of the present invention:
Filter paper environmental protection science of the present invention, composition of raw materials is reasonable, each group partition inter-capacitive is good, the modification agricultural crop straw performance of the adsorbent of preparation is stable, organic matter is had to the adsorption capacity of wide spectrum, and the modification coupling agent adopting can make to form and combine closely between slurry, filter paper material performance is improved, make reduced viscosity, every mechanical property is better, has and draws high preferably intensity, elongation at break, shock strength texts.
Detailed description of the invention
Embodiment 1: gasoline filter filter paper, the weight portion (jin) of its constitutive material is: jute pulp 65, bamboo pulp fiber 40, polyester fiber 22, phenolic resins 12, charcoal powder 14, modification agricultural crop straw 14, talcum powder 11, modification coupling agent 5, sodium polymethacrylate 2, antioxidant 1010 0.3, Nekal BX-78 3, ammonium chloride 2, Boratex 1, sldium lauryl sulfate 1.2 and chlorinated paraffin wax 3.
The preparation method of filter paper for gasoline filter, comprises the following steps:
(1) preparation of modification coupling agent: MTMS is added in absolute ethyl alcohol, described MTMS and absolute ethyl alcohol are according to quality and volume ratio 1:4, then add 1.5% polyacrylamide of MTMS quality, 1.8% N, N '-methylene-bisacrylamide and 0.25% N, N-diisopropylethylamine; The temperature of reaction is 50 DEG C, and the time of described reaction is 10-12h, obtains reactant liquor; After reaction, reactant liquor is first disperseed to 2-3 hour under ultrasonic electric power 350W condition, and then disperse 3-5 hour under ultrasonic electric power 250W condition, can obtain;
(2) preparation of modification agricultural crop straw:
(a) take agricultural crop straw by constitutive material formula, grind, the mass fraction that adds 12 times of amounts is 10%NaOH solution, under the temperature conditions of 70 DEG C, activates 4h, crosses leaching filter residue;
(b) pure water that adds 5-10 doubly to measure in the filter residue of step (a), and then add 0.65% Dodecyl trimethyl ammonium chloride, 1.3% Silane coupling agent KH550 and 4% potassium permanganate of agricultural crop straw powder quality; Stir and react 2-3h, filter, dry;
(c) it is in the Hyperbranched Polymer with Terminal Amido solution of 45g/L that the agricultural crop straw powder of step (b) being dried adds concentration; Described agricultural crop straw powder and the quality of Hyperbranched Polymer with Terminal Amido solution and volume ratio are 1:45, then add 0.15% catalyst n, N-dimethyl butylamine, is uniformly mixed reaction 10-12h, filter and use washed with de-ionized water 3-5 time, after freeze drying, obtain;
(3) mix first by weight bamboo pulp fiber, polyester fiber, phenolic resins and charcoal powder, then put into pulper size degradation, obtain solid content and be 5% slurry, then add Nekal BX-78, stir and continue size degradation and obtain mixed slurry;
(4) mixed slurry of the modification agricultural crop straw of the modification coupling agent of step (1), step (2) and step (3) is added in jute pulp, heating stirs, and controls temperature 60 C;
(5) in the compound of step (4), add other residue constitutive materials, after fluffer is discongested, then defibrination, after defibrination, gained slurry is sized mixing through adding water, to after solid content 4% according to conventional paper technology copy paper, moulding squeezing, be drying to obtain.
The performance of filter paper that above-described embodiment makes: grammes per square metre: 125g/cm 2; Bursting strength: 310Kpa; Air permeability: 488ml/10cm 2min; Its maximum diameter of hole 48-54 μ m, average pore size 34-38 μ m, becomes paper air permeability at 80-85L/m 2.S between.

Claims (3)

1. a gasoline filter filter paper, is characterized in that the weight portion of its constitutive material is: jute pulp 60-70, bamboo pulp fiber 35-45, polyester fiber 20-25, phenolic resins 10-15, charcoal powder 12-15, modification agricultural crop straw 13-15, talcum powder 10-12, modification coupling agent 4-6, sodium polymethacrylate 1-3, antioxidant 1010 0.2-0.4, Nekal BX-78 2-4, ammonium chloride 1-3, Boratex 0.5-1.5, sldium lauryl sulfate 0.8-1.5 and chlorinated paraffin wax 2-4.
2. gasoline filter filter paper according to claim 1, is characterized in that the weight portion of its constitutive material is: jute pulp 65, bamboo pulp fiber 40, polyester fiber 22, phenolic resins 12, charcoal powder 14, modification agricultural crop straw 14, talcum powder 11, modification coupling agent 5, sodium polymethacrylate 2, antioxidant 1010 0.3, Nekal BX-78 3, ammonium chloride 2, Boratex 1, sldium lauryl sulfate 1.2 and chlorinated paraffin wax 3.
3. a preparation method for filter paper for gasoline filter as claimed in claim 1, is characterized in that comprising the following steps:
(1) preparation of modification coupling agent: MTMS is added in absolute ethyl alcohol, described MTMS and absolute ethyl alcohol are according to quality and volume ratio 1:3-5, then add the polyacrylamide of the 1.0-2.0% of MTMS quality, the N of 1.5-2.0%, the N of N '-methylene-bisacrylamide and 0.2-0.3%, N-diisopropylethylamine; The temperature of reaction is 40-60 DEG C, and the time of described reaction is 10-12h, obtains reactant liquor; After reaction, reactant liquor is first disperseed to 2-3 hour under ultrasonic electric power 350W condition, and then disperse 3-5 hour under ultrasonic electric power 250W condition, can obtain;
(2) preparation of modification agricultural crop straw:
(a) take agricultural crop straw by constitutive material formula, grind, adding the mass fraction that 10-15 doubly measures is 5~10%NaOH solution, under the temperature conditions of 60~80 DEG C, activates 3~5h, crosses leaching filter residue;
(b) pure water that adds 5-10 doubly to measure in the filter residue of step (a), and then add 0.6-0.7% Dodecyl trimethyl ammonium chloride, 1.2-1.5% Silane coupling agent KH550 and the 3-5% potassium permanganate of agricultural crop straw powder quality; Stir and react 2-3h, filter, dry;
(c) it is in the Hyperbranched Polymer with Terminal Amido solution of 40-50g/L that the agricultural crop straw powder of step (b) being dried adds concentration; Described agricultural crop straw powder and the quality of Hyperbranched Polymer with Terminal Amido solution and volume ratio are 1:40-50, then add 0.1-0.2% catalyst n, N-dimethyl butylamine, is uniformly mixed reaction 10-12h, filter and use washed with de-ionized water 3-5 time, after freeze drying, obtain;
(3) mix first by weight bamboo pulp fiber, polyester fiber, phenolic resins and charcoal powder, then put into pulper size degradation, obtain the slurry that solid content is 4-6%, then add Nekal BX-78, stir and continue size degradation and obtain mixed slurry;
(4) mixed slurry of the modification agricultural crop straw of the modification coupling agent of step (1), step (2) and step (3) is added in jute pulp, heating stirs, and controls temperature 50-70 DEG C;
(5) in the compound of step (4), add other residue constitutive materials, after fluffer is discongested, then defibrination, after defibrination, gained slurry is sized mixing through adding water, to after solid content 3-5% according to conventional paper technology copy paper, moulding squeezing, be drying to obtain.
CN201410138688.XA 2014-04-09 2014-04-09 A kind of gasoline filter filter paper and preparation method thereof Active CN103981770B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105568769A (en) * 2016-02-25 2016-05-11 杭州特种纸业有限公司 Diesel filter paper and preparation method thereof
CN105735037A (en) * 2016-02-25 2016-07-06 杭州特种纸业有限公司 Thermosetting air filter paper and preparation method thereof
CN105780595A (en) * 2016-04-26 2016-07-20 杭州特种纸业有限公司 Nanometer air filter paper and preparation method thereof
CN105926344A (en) * 2016-04-26 2016-09-07 杭州特种纸业有限公司 Nanometer quantitative filter paper and production method thereof
CN105937193A (en) * 2016-04-26 2016-09-14 杭州特种纸业有限公司 Nano engine and air filter paper and preparation method thereof
CN105951524A (en) * 2016-04-26 2016-09-21 杭州特种纸业有限公司 Nano machine oil filter paper and preparation method thereof
CN109295797A (en) * 2018-09-26 2019-02-01 扬州市祥华新材料科技有限公司 A kind of preparation method for punching high tenacity paper
CN115300985A (en) * 2022-06-17 2022-11-08 华电电力科学研究院有限公司 Efficient deacidification regeneration treatment method for oil used for power equipment
CN115726221A (en) * 2022-11-22 2023-03-03 杭州特种纸业有限公司 Medium-speed quantitative filter paper and preparation method thereof

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Publication number Priority date Publication date Assignee Title
US20040234760A1 (en) * 2003-05-19 2004-11-25 Rayonier Products And Financial Services Company Superabsorbent cellulosic fiber and method of making same
CN1594731A (en) * 2003-09-10 2005-03-16 王家君 Fine fiber reinforced paper
CN102877368A (en) * 2012-09-20 2013-01-16 蚌埠凤凰滤清器有限责任公司 High temperature resistant flame retardant filter paper used for diesel filter and preparation method thereof
CN102877373A (en) * 2012-09-25 2013-01-16 蚌埠凤凰滤清器有限责任公司 Preparation method for modified nacrite-containing filter paper for fuel filter
CN102899970A (en) * 2012-09-25 2013-01-30 蚌埠凤凰滤清器有限责任公司 Preparation process of reed pulp filter paper

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040234760A1 (en) * 2003-05-19 2004-11-25 Rayonier Products And Financial Services Company Superabsorbent cellulosic fiber and method of making same
CN1594731A (en) * 2003-09-10 2005-03-16 王家君 Fine fiber reinforced paper
CN102877368A (en) * 2012-09-20 2013-01-16 蚌埠凤凰滤清器有限责任公司 High temperature resistant flame retardant filter paper used for diesel filter and preparation method thereof
CN102877373A (en) * 2012-09-25 2013-01-16 蚌埠凤凰滤清器有限责任公司 Preparation method for modified nacrite-containing filter paper for fuel filter
CN102899970A (en) * 2012-09-25 2013-01-30 蚌埠凤凰滤清器有限责任公司 Preparation process of reed pulp filter paper

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105568769A (en) * 2016-02-25 2016-05-11 杭州特种纸业有限公司 Diesel filter paper and preparation method thereof
CN105735037A (en) * 2016-02-25 2016-07-06 杭州特种纸业有限公司 Thermosetting air filter paper and preparation method thereof
CN105780595A (en) * 2016-04-26 2016-07-20 杭州特种纸业有限公司 Nanometer air filter paper and preparation method thereof
CN105926344A (en) * 2016-04-26 2016-09-07 杭州特种纸业有限公司 Nanometer quantitative filter paper and production method thereof
CN105937193A (en) * 2016-04-26 2016-09-14 杭州特种纸业有限公司 Nano engine and air filter paper and preparation method thereof
CN105951524A (en) * 2016-04-26 2016-09-21 杭州特种纸业有限公司 Nano machine oil filter paper and preparation method thereof
CN109295797A (en) * 2018-09-26 2019-02-01 扬州市祥华新材料科技有限公司 A kind of preparation method for punching high tenacity paper
CN115300985A (en) * 2022-06-17 2022-11-08 华电电力科学研究院有限公司 Efficient deacidification regeneration treatment method for oil used for power equipment
CN115300985B (en) * 2022-06-17 2023-11-24 华电电力科学研究院有限公司 Efficient acid removal regeneration treatment method for oil for power equipment
CN115726221A (en) * 2022-11-22 2023-03-03 杭州特种纸业有限公司 Medium-speed quantitative filter paper and preparation method thereof

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Denomination of invention: A filter paper for gasoline filter and its preparation method

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