CN103981391A - Aluminum-base composite material reinforced by both magnesium borate crystal whisker and silicon carbide particles and preparation method thereof - Google Patents

Aluminum-base composite material reinforced by both magnesium borate crystal whisker and silicon carbide particles and preparation method thereof Download PDF

Info

Publication number
CN103981391A
CN103981391A CN201410047478.XA CN201410047478A CN103981391A CN 103981391 A CN103981391 A CN 103981391A CN 201410047478 A CN201410047478 A CN 201410047478A CN 103981391 A CN103981391 A CN 103981391A
Authority
CN
China
Prior art keywords
magnesium borate
crystal whisker
borate crystal
aluminium
composite material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410047478.XA
Other languages
Chinese (zh)
Other versions
CN103981391B (en
Inventor
金培鹏
王金辉
王明亮
朱云鹏
唐彬彬
吴震
潘志强
崔闯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinghai University
Original Assignee
Qinghai University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinghai University filed Critical Qinghai University
Priority to CN201410047478.XA priority Critical patent/CN103981391B/en
Publication of CN103981391A publication Critical patent/CN103981391A/en
Application granted granted Critical
Publication of CN103981391B publication Critical patent/CN103981391B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The invention relates to the technical field of new materials, and concretely relates to a hybrid double-phase aluminum-base composite material reinforced by both magnesium borate crystal whisker and silicon carbide particles and a preparation method thereof. The aluminum-base composite material reinforced by both magnesium borate crystal whisker and silicon carbide particles comprises, in volume percentage, 3% of magnesium borate crystal whisker, 3% of silicon carbide particles comprises, and the balance aluminium alloy. The preparation method comprises: preparing a hybrid reinforced body; preparing a hybrid aluminium-base composite material ingot casting by employing a stirring casting method; and performing hot extrusion on ingots. The beneficial effects comprise that the hybrid double-phase aluminum-base composite material reinforced by both magnesium borate crystal whisker and silicon carbide particles is prepared by employing the reasonable design technology, the problem of severe settlement phenomenon of silicon carbide particles in the preparation process is improved, the dispersity of the whisker in the composite material is improved, the whisker and the particles give play to cooperative enhancement effect in the composite material, and the mechanical properties of the aluminium-base composite material is effectively improved.

Description

Magnesium borate crystal whisker and carborundum particle reinforced aluminum matrix composites and preparation method
Technical field
The present invention relates to new material technology field, specifically relate to a kind of magnesium borate crystal whisker and carborundum particle and mix two-phase reinforced aluminum matrix composites and preparation method.
Background technology
More to the matrix material research of single carborundum particle and the enhancing of single magnesium borate crystal whisker at present.But the aluminum matrix composite research that magnesium borate crystal whisker and carborundum particle is mixed to enhancing there is not yet report.Preparation technology and the performance of the magnesium base composite material that Jin Pei roc seminar strengthens magnesium borate crystal whisker have been carried out comprehensive research, find that the introducing of magnesium borate crystal whisker effectively raises mechanical property and the friction and wear behavior of magnesium base composite material, stability under high temperature improves, but the matrix material that this research makes is high-volume fractional, the technique adopting is vacuum pressure THROUGH METHOD, and matrix is magnesium alloy.This seminar utilizes stirring casting method to prepare the aluminum matrix composite that low volume fraction magnesium borate crystal whisker strengthens simultaneously, the friction and wear behavior of matrix material is compared matrix alloy and is improved, but whisker is more serious at the middle agglomeration of matrix alloy, therefore solving the dispersion problem of whisker in matrix alloy, is the key that improves low volume fraction magnesium borate crystal whisker reinforced aluminium base composite material mechanical property.
Improve though Xiao Daihong and Huang Baiyun research shows to utilize its hardness of the relative matrix alloy of aluminum matrix composite that carborundum particle prepared by stirring casting method strengthens and wear resisting property to have significantly, tensile property obviously reduces.This is mainly because carborundum particle exists sharp-pointed corner, hot mispairing between particle and matrix is larger simultaneously, therefore can produce huge internal stress in sharp-pointed forward position, corner, cause serious stress concentration, in the time that matrix material is subject to external force, wedge angle position very easily scratches matrix, thereby produces tiny crack, tiny crack constantly germinates diffusion, thereby the tensile property of matrix material is sharply reduced.While utilizing stirring casting method to prepare matrix material there is sedimentation in particle simultaneously, causes Local enrichment, also can cause disadvantageous effect to the performance that improves matrix material.
Lv Yingbin etc. utilize mixing salt reaction in-situ method to prepare SiC, TiB 2the aluminum matrix composite that two-phase miscellaneous granules strengthens, compares with the matrix material that single particle strengthens, and due to the synergistic enhancing effect that mixes of particle, makes the Young's modulus of hybrid composite and tensile property have obvious lifting.And the sedimentation phenomenon of silicon-carbide particle has obtained obvious inhibition, make the dispersion of particle in matrix material be tending towards even.Byung-Chul Ko and Yeon-Chul Yoo utilize powder metallurgic method to prepare the SiCw of a series of different proportionings and the aluminum matrix composite that SiCp strengthens, mechanical property research to matrix material shows, in the time that the proportioning of SiCw and SiCp is 1:1, matrix material can obtain the highest intensity.
Summary of the invention
The technical problem to be solved in the present invention is the deficiency existing for prior art, and a kind of magnesium borate crystal whisker and carborundum particle reinforced aluminum matrix composites and preparation method are provided.
Preparation method of the present invention is: the preparation of Combination reinforcement; Stirring casting method preparation mixes type aluminum matrix composite ingot casting; Hot extrusion ingot blank.
Magnesium borate crystal whisker of the present invention and carborundum particle reinforced aluminum matrix composites volume fraction proportioning:
Magnesium borate crystal whisker 3% (volume fraction);
Carborundum particle 3% (volume fraction);
Surplus is aluminium alloy;
Aluminium alloy is: 6000 series alloys, and alloy designations is 6061, chemical composition (mass percent wt%): Mg-0.86%, Si-0.65%, Cu-0.25%, Mn-0.15%, Zn-0.25%, Cr-0.15%, Ti-0.15%, Fe-0.7% Al-surplus.
Preparation method of the present invention comprises the steps:
(1) preparation process of mixed type reinforcement
(1.1) calculating of matrix and reinforcement and weighing;
First 6061 aluminium ingots are weighed, then according to the Mass Calculation of aluminium ingot and weigh magnesium borate crystal whisker and carborundum particle, make the volume fraction of two kinds of reinforcements respectively account for 3%;
(1.2) the mixed powder of reinforcement grinds;
By admixed together to load weighted magnesium borate crystal whisker and carborundum particle, hand lapping 30 minutes, tentatively mixes two kinds of reinforcements, and makes macroscopic view reunion carry out preliminary dispersion to whisker and particle together;
(1.3) ultrasonic dispersion;
To mix in the large capacity beaker of latter two reinforcement powder transfer to, and add appropriate alcohol, be that alcohol fully floods reinforcement powder, beaker put into ultrasonic vessel and carry out ultrasonic dispersion 40 minutes;
(1.4) dry
Mixing reinforcement powder after ultrasonic is put into a vertical drying oven, 80 DEG C of homo(io)thermism, horizontal blast, dries 24 hours powder;
(2) stirring casting method is prepared as cast condition matrix material ingot casting step
(2.1) melting aluminum alloy;
Will be in advance load weighted 6061 aluminium alloy cast ingots put into a Steel Crucible, be heated to 750 DEG C with medium-frequency induction furnace, after aluminium alloy melts completely, medium-frequency induction furnace power is turned down, and temperature of aluminum liquid is controlled to 640 DEG C, make aluminium liquid keep semi-solid state;
(2.2) mechanical stirring;
Agitator is inserted in aluminium liquid, make it occupy crucible center, turn on agitator, make its rotating speed be controlled at 350r/min, now produce a whirlpool on aluminium liquid surface, mixing reinforcement powder is joined in whirlpool slowly, it is rolled in aluminium liquid with whirlpool, after reinforcement powder adds completely, then continue to stir 20 minutes;
(2.3) supersound process;
One power ultrasonic producer is inserted in aluminium liquid, medium-frequency induction furnace power is tuned up simultaneously, again temperature is elevated to 750 DEG C, open ultrasonic wave, continue ultrasonic 10 minutes;
(2.4) casting
After ultrasonic, close induction furnace, execute Composite Melt and slightly do coolingly, be then cast to one in advance in preheated graphite jig, mold preheating temperature is 300 DEG C, obtains as cast condition matrix material ingot casting after cooling;
(3) hot extrusion ingot blank step
Hot extrusion is carried out on the horizontal light alloy extrusion machine of 200t section bar; Lubricated mould before extruding, heating ingot blank temperature to 400~450 DEG C scope, extrusion mould is heated to 400 DEG C; The ingot blank heating is pushed to container, after insulation 40min, start extruding, extrusion ratio is 10:1, and extruding rate is 0.6m/min, and container diameter is φ 90mm, and extrusion axis, under the effect of main plunger, forces ingot blank in container to flow out nib; Be processed into bar by above hot extrusion process, preparation completes.
A kind of magnesium borate crystal whisker of the present invention and carborundum particle reinforced aluminum matrix composites and preparation method have following beneficial effect compared with prior art: a kind of magnesium borate crystal whisker of the present invention and carborundum particle enhancing aluminum-base composite material and preparation method carry out improved preparation technology for enhancement method in aluminum matrix composite.Prepare magnesium borate crystal whisker and carborundum particle by rational design technology and mixed the aluminum matrix composite that two-phase strengthens.Improved the serious problem of carborundum particle sedimentation phenomenon in preparation process, improved the dispersiveness of whisker in matrix material, whisker and particle have played synergistic enhancing effect in matrix material, have effectively improved the mechanical property of aluminum matrix composite.
Due to magnesium borate crystal whisker and aluminum substrate wettability bad, in the aluminium liquid of melting, be difficult for disperseing, agglomeration is serious, and carborundum particle sedimentation phenomenon in aluminium liquid is serious simultaneously, can cause Local enrichment, thereby cause the Properties of Aluminum Matrix Composites of single enhancing not ideal enough.The present invention is by rational technological design, adopt whisker and carborundum particle two-phase to mix enhancement method, effectively improve the dispersiveness of whisker in aluminum substrate, delay the settling velocity of carborundum particle in aluminium liquid in preparation process, eliminate the enrichment phenomenon of carborundum particle, effectively improved the mechanical property of matrix material.The present invention adopts stirring casting method to prepare magnesium borate crystal whisker and carborundum particle mixes the aluminum matrix composite that two-phase strengthens, the reunion that the characteristic (particle and aluminum substrate have good wettability) of easily disperseing in aluminium liquid by particle in mechanical stirring castingprocesses is broken up whisker, the introducing of whisker has simultaneously increased the dynamic viscosity of aluminum melt, thereby has delayed the settling velocity of particle.Pass through phenetic analysis, find carborundum particle and whisker favorable dispersity in matrix alloy, compare the aluminum matrix composite that single whisker strengthens, in hybrid composite, whisker has better dispersiveness, and the sedimentation phenomenon of carborundum particle has obtained effective inhibition, in matrix material, almost do not find particle rich region.It is more even that interaction between particle and whisker disperses them in matrix, effectively raises the mechanical property of matrix material.
Embodiment
Below in conjunction with embodiment, a kind of magnesium borate crystal whisker of the present invention and carborundum particle reinforced aluminum matrix composites and preparation method's technical scheme are further described.
Embodiment 1.
The proportioning of a kind of magnesium borate crystal whisker and carborundum particle reinforced aluminum matrix composites is: the volume fraction of magnesium borate crystal whisker and two kinds of reinforcements of carborundum particle respectively accounts for 3%, and surplus is aluminium alloy; Wherein aluminium alloy is: 6000 series alloys, and alloy designations is 6061, mass percent wt% is: Mg-0.86%, Si-0.65%, Cu-0.25%, Mn-0.15%, Zn-0.25%, Cr-0.15%, Ti-0.15%, Fe-0.7% Al-surplus.
The preparation side of a kind of magnesium borate crystal whisker and carborundum particle reinforced aluminum matrix composites comprises the steps:
(1) preparation process of mixed type reinforcement:
(1.1) calculating of matrix and reinforcement and weighing
First 6061 aluminium ingots are weighed, then according to the Mass Calculation of aluminium ingot and weigh magnesium borate crystal whisker and carborundum particle, make the volume fraction of two kinds of reinforcements respectively account for 3%;
(1.2) the mixed powder of reinforcement grinds
By admixed together to load weighted magnesium borate crystal whisker and carborundum particle, hand lapping 30 minutes, tentatively mixes two kinds of reinforcements, and makes macroscopic view reunion carry out preliminary dispersion to whisker and particle together;
(1.3) ultrasonic dispersion
To mix in the large capacity beaker of latter two reinforcement powder transfer to, and add appropriate alcohol, be that alcohol fully floods reinforcement powder, beaker put into ultrasonic vessel and carry out ultrasonic dispersion 40 minutes;
(1.4) dry
Mixing reinforcement powder after ultrasonic is put into a vertical drying oven, 80 DEG C of homo(io)thermism, horizontal blast, dries 24 hours powder;
(2) stirring casting method is prepared as cast condition matrix material ingot casting step
(2.1) melting aluminum alloy;
Will be in advance load weighted 6061 aluminium alloy cast ingots put into a Steel Crucible, be heated to 750 DEG C with medium-frequency induction furnace, after aluminium alloy melts completely, medium-frequency induction furnace power is turned down, and temperature of aluminum liquid is controlled to 640 DEG C, make aluminium liquid keep semi-solid state;
(2.2) mechanical stirring;
Agitator is inserted in aluminium liquid, make it occupy crucible center, turn on agitator, make its rotating speed be controlled at 350r/min, now produce a whirlpool on aluminium liquid surface, mixing reinforcement powder is joined in whirlpool slowly, it is rolled in aluminium liquid with whirlpool, after reinforcement powder adds completely, then continue to stir 20 minutes;
(2.3) supersound process;
One power ultrasonic producer is inserted in aluminium liquid, medium-frequency induction furnace power is tuned up simultaneously, again temperature is elevated to 750 DEG C, open ultrasonic wave, continue ultrasonic 10 minutes;
(2.4) casting
After ultrasonic, close induction furnace, execute Composite Melt and slightly do coolingly, be then cast to one in advance in preheated graphite jig, mold preheating temperature is 300 DEG C, obtains as cast condition matrix material ingot casting after cooling;
(3) hot extrusion ingot blank step
Hot extrusion is carried out on the horizontal light alloy extrusion machine of 200t section bar; Lubricated mould before extruding, heating ingot blank temperature to 400 DEG C, extrusion mould is heated to 400 DEG C; The ingot blank heating is pushed to container, after insulation 40min, start extruding, extrusion ratio is 10:1, and extruding rate is 0.6m/min, and container diameter is φ 90mm, and extrusion axis, under the effect of main plunger, forces ingot blank in container to flow out nib; Be processed into bar by above hot extrusion process, preparation completes.
The aluminium alloy fundamental property using in the present invention is (under room temperature):
Young's modulus: 69 GPa
Tensile strength: 124 MPa
Proof strength of non-proportional: 116 MPa
Elongation: 25.0%
The magnesium borate crystal whisker fundamental property using in the present invention is:
Mean length: 10 ~ 50 μ m
Mean diameter: 0.2 ~ 6 μ m
Density: 2.91 g/cm 3
Tensile strength: 3.92 GPa
Young's modulus: 264.6 GPa
Carborundum particle fundamental property used in the present invention:
Mean diameter: 10 μ m
Density: 3.2 g/cm 3
Young's modulus: 450 GPa
Thermal expansivity: 8.0 × 10 -6/ DEG C
The performance that mixes type aluminum matrix composite (under room temperature) of preparing in the present invention:
Tensile strength: 245 Mpa
Young's modulus: 117.3 GPa
Density: 2.71~2.73g/cm 3
Elongation: 10.2%
That in the present invention, prepares mixes the performance of type aluminum matrix composite at 150 DEG C of temperature:
Tensile strength: 196 MPa
Proof strength of non-proportional: 182 MPa
Elongation after fracture: 12.3%
That in the present invention, prepares mixes the performance of type aluminum matrix composite at 250 DEG C of temperature:
Tensile strength: 132 MPa
Proof strength of non-proportional: 129 MPa
Elongation after fracture: 15.4%.
Embodiment 2.
It is identical with embodiment 1 that magnesium borate crystal whisker of the present invention and carborundum particle mix two-phase reinforced aluminum matrix composites proportioning.The preparation side that magnesium borate crystal whisker and carborundum particle mix two-phase reinforced aluminum matrix composites comprises the steps:
(1) preparation process of mixed type reinforcement:
(1.1) calculating of matrix and reinforcement and weighing
First 6061 aluminium ingots are weighed, then according to the Mass Calculation of aluminium ingot and weigh magnesium borate crystal whisker and carborundum particle, make the volume fraction of two kinds of reinforcements respectively account for 3%;
(1.2) the mixed powder of reinforcement grinds
By admixed together to load weighted magnesium borate crystal whisker and carborundum particle, hand lapping 30 minutes, tentatively mixes two kinds of reinforcements, and makes macroscopic view reunion carry out preliminary dispersion to whisker and particle together;
(1.3) ultrasonic dispersion
To mix in the large capacity beaker of latter two reinforcement powder transfer to, and add appropriate alcohol, be that alcohol fully floods reinforcement powder, beaker put into ultrasonic vessel and carry out ultrasonic dispersion 40 minutes;
(1.4) dry
Mixing reinforcement powder after ultrasonic is put into a vertical drying oven, 80 DEG C of homo(io)thermism, horizontal blast, dries 24 hours powder;
(2) stirring casting method is prepared as cast condition matrix material ingot casting step
(2.1) melting aluminum alloy;
Will be in advance load weighted 6061 aluminium alloy cast ingots put into a Steel Crucible, be heated to 750 DEG C with medium-frequency induction furnace, after aluminium alloy melts completely, medium-frequency induction furnace power is turned down, and temperature of aluminum liquid is controlled to 640 DEG C, make aluminium liquid keep semi-solid state;
(2.2) mechanical stirring;
Agitator is inserted in aluminium liquid, make it occupy crucible center, turn on agitator, make its rotating speed be controlled at 350r/min, now produce a whirlpool on aluminium liquid surface, mixing reinforcement powder is joined in whirlpool slowly, it is rolled in aluminium liquid with whirlpool, after reinforcement powder adds completely, then continue to stir 20 minutes;
(2.3) supersound process;
One power ultrasonic producer is inserted in aluminium liquid, medium-frequency induction furnace power is tuned up simultaneously, again temperature is elevated to 750 DEG C, open ultrasonic wave, continue ultrasonic 10 minutes;
(2.4) casting
After ultrasonic, close induction furnace, execute Composite Melt and slightly do coolingly, be then cast to one in advance in preheated graphite jig, mold preheating temperature is 300 DEG C, obtains as cast condition matrix material ingot casting after cooling;
(3) hot extrusion ingot blank step
Hot extrusion is carried out on the horizontal light alloy extrusion machine of 200t section bar; Lubricated mould before extruding, heating ingot blank temperature to 425 DEG C, extrusion mould is heated to 400 DEG C; The ingot blank heating is pushed to container, after insulation 40min, start extruding, extrusion ratio is 10:1, and extruding rate is 0.6m/min, and container diameter is φ 90mm, and extrusion axis, under the effect of main plunger, forces ingot blank in container to flow out nib; Be processed into bar by above hot extrusion process, preparation completes.
Embodiment 3.
It is identical with embodiment 1 that magnesium borate crystal whisker of the present invention and carborundum particle mix two-phase reinforced aluminum matrix composites proportioning.The preparation side that magnesium borate crystal whisker and carborundum particle mix two-phase reinforced aluminum matrix composites comprises the steps:
(1) preparation process of mixed type reinforcement:
(1.1) calculating of matrix and reinforcement and weighing
First 6061 aluminium ingots are weighed, then according to the Mass Calculation of aluminium ingot and weigh magnesium borate crystal whisker and carborundum particle, make the volume fraction of two kinds of reinforcements respectively account for 3%;
(1.2) the mixed powder of reinforcement grinds
By admixed together to load weighted magnesium borate crystal whisker and carborundum particle, hand lapping 30 minutes, tentatively mixes two kinds of reinforcements, and makes macroscopic view reunion carry out preliminary dispersion to whisker and particle together;
(1.3) ultrasonic dispersion
To mix in the large capacity beaker of latter two reinforcement powder transfer to, and add appropriate alcohol, be that alcohol fully floods reinforcement powder, beaker put into ultrasonic vessel and carry out ultrasonic dispersion 40 minutes;
(1.4) dry
Mixing reinforcement powder after ultrasonic is put into a vertical drying oven, 80 DEG C of homo(io)thermism, horizontal blast, dries 24 hours powder;
(2) stirring casting method is prepared as cast condition matrix material ingot casting step
(2.1) melting aluminum alloy;
Will be in advance load weighted 6061 aluminium alloy cast ingots put into a Steel Crucible, be heated to 750 DEG C with medium-frequency induction furnace, after aluminium alloy melts completely, medium-frequency induction furnace power is turned down, and temperature of aluminum liquid is controlled to 640 DEG C, make aluminium liquid keep semi-solid state;
(2.2) mechanical stirring;
Agitator is inserted in aluminium liquid, make it occupy crucible center, turn on agitator, make its rotating speed be controlled at 350r/min, now produce a whirlpool on aluminium liquid surface, mixing reinforcement powder is joined in whirlpool slowly, it is rolled in aluminium liquid with whirlpool, after reinforcement powder adds completely, then continue to stir 20 minutes;
(2.3) supersound process;
One power ultrasonic producer is inserted in aluminium liquid, medium-frequency induction furnace power is tuned up simultaneously, again temperature is elevated to 750 DEG C, open ultrasonic wave, continue ultrasonic 10 minutes;
(2.4) casting
After ultrasonic, close induction furnace, execute Composite Melt and slightly do coolingly, be then cast to one in advance in preheated graphite jig, mold preheating temperature is 300 DEG C, obtains as cast condition matrix material ingot casting after cooling;
(3) hot extrusion ingot blank step
Hot extrusion is carried out on the horizontal light alloy extrusion machine of 200t section bar; Lubricated mould before extruding, heating ingot blank temperature to 450 DEG C, extrusion mould is heated to 400 DEG C; The ingot blank heating is pushed to container, after insulation 40min, start extruding, extrusion ratio is 10:1, and extruding rate is 0.6m/min, and container diameter is φ 90mm, and extrusion axis, under the effect of main plunger, forces ingot blank in container to flow out nib; Be processed into bar by above hot extrusion process, preparation completes.

Claims (2)

1. magnesium borate crystal whisker and a carborundum particle reinforced aluminum matrix composites, is characterized in that: the volume fraction of magnesium borate crystal whisker and two kinds of reinforcements of carborundum particle respectively accounts for 3%, and surplus is aluminium alloy; Wherein aluminium alloy is: 6000 series alloys, and alloy designations is 6061, mass percent wt% is: Mg-0.86%, Si-0.65%, Cu-0.25%, Mn-0.15%, Zn-0.25%, Cr-0.15%, Ti-0.15%, Fe-0.7% Al-surplus.
2. a preparation method for magnesium borate crystal whisker and carborundum particle reinforced aluminum matrix composites, is characterized in that described preparation method comprises the steps:
(1) preparation process of mixed type reinforcement:
(1.1) calculating of matrix and reinforcement and weighing
First 6061 aluminium ingots are weighed, then according to the Mass Calculation of aluminium ingot and weigh magnesium borate crystal whisker and carborundum particle, make the volume fraction of two kinds of reinforcements respectively account for 3%;
(1.2) the mixed powder of reinforcement grinds
By admixed together to load weighted magnesium borate crystal whisker and carborundum particle, hand lapping 30 minutes, tentatively mixes two kinds of reinforcements, and makes macroscopic view reunion carry out preliminary dispersion to whisker and particle together;
(1.3) ultrasonic dispersion
To mix in the large capacity beaker of latter two reinforcement powder transfer to, and add appropriate alcohol, be that alcohol fully floods reinforcement powder, beaker put into ultrasonic vessel and carry out ultrasonic dispersion 40 minutes;
(1.4) dry
Mixing reinforcement powder after ultrasonic is put into a vertical drying oven, 80 DEG C of homo(io)thermism, horizontal blast, dries 24 hours powder;
(2) stirring casting method is prepared as cast condition matrix material ingot casting step
(2.1) melting aluminum alloy;
Will be in advance load weighted 6061 aluminium alloy cast ingots put into a Steel Crucible, be heated to 750 DEG C with medium-frequency induction furnace, after aluminium alloy melts completely, medium-frequency induction furnace power is turned down, and temperature of aluminum liquid is controlled to 640 DEG C, make aluminium liquid keep semi-solid state;
(2.2) mechanical stirring;
Agitator is inserted in aluminium liquid, make it occupy crucible center, turn on agitator, make its rotating speed be controlled at 350r/min, now produce a whirlpool on aluminium liquid surface, mixing reinforcement powder is joined in whirlpool slowly, it is rolled in aluminium liquid with whirlpool, after reinforcement powder adds completely, then continue to stir 20 minutes;
(2.3) supersound process;
One power ultrasonic producer is inserted in aluminium liquid, medium-frequency induction furnace power is tuned up simultaneously, again temperature is elevated to 750 DEG C, open ultrasonic wave, continue ultrasonic 10 minutes;
(2.4) casting
After ultrasonic, close induction furnace, execute Composite Melt and slightly do coolingly, be then cast to one in advance in preheated graphite jig, mold preheating temperature is 300 DEG C, obtains as cast condition matrix material ingot casting after cooling;
(3) hot extrusion ingot blank step
Hot extrusion is carried out on the horizontal light alloy extrusion machine of 200t section bar; Lubricated mould before extruding, heating ingot blank temperature to 400~450 DEG C scope, extrusion mould is heated to 400 DEG C; The ingot blank heating is pushed to container, after insulation 40min, start extruding, extrusion ratio is 10:1, and extruding rate is 0.6m/min, and container diameter is φ 90mm, and extrusion axis, under the effect of main plunger, forces ingot blank in container to flow out nib; Be processed into bar by above hot extrusion process, preparation completes.
CN201410047478.XA 2014-02-11 2014-02-11 Magnesium borate crystal whisker and carborundum particle reinforced aluminum matrix composites and preparation method Expired - Fee Related CN103981391B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410047478.XA CN103981391B (en) 2014-02-11 2014-02-11 Magnesium borate crystal whisker and carborundum particle reinforced aluminum matrix composites and preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410047478.XA CN103981391B (en) 2014-02-11 2014-02-11 Magnesium borate crystal whisker and carborundum particle reinforced aluminum matrix composites and preparation method

Publications (2)

Publication Number Publication Date
CN103981391A true CN103981391A (en) 2014-08-13
CN103981391B CN103981391B (en) 2016-05-18

Family

ID=51273560

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410047478.XA Expired - Fee Related CN103981391B (en) 2014-02-11 2014-02-11 Magnesium borate crystal whisker and carborundum particle reinforced aluminum matrix composites and preparation method

Country Status (1)

Country Link
CN (1) CN103981391B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104233018A (en) * 2014-08-26 2014-12-24 盐城市鑫洋电热材料有限公司 Reinforced aluminum alloy and preparation method thereof
CN104388734A (en) * 2014-11-27 2015-03-04 哈尔滨工业大学 Preparing and molding devices and preparing and molding methods of nano SiC particle enhanced 7075 aluminum matrix composite material semi-solid slurry
CN109396401A (en) * 2018-10-31 2019-03-01 宁波华源精特金属制品有限公司 A kind of automatic pedal
CN110863160A (en) * 2019-11-11 2020-03-06 中国科学院上海硅酸盐研究所 SIALON whisker reinforced aluminum matrix composite material and preparation method thereof
CN113523005A (en) * 2021-07-12 2021-10-22 福建祥鑫股份有限公司 Extrusion method of low-volume-fraction ceramic particle reinforced aluminum-based composite bar

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384087A (en) * 1992-04-06 1995-01-24 Ametek, Specialty Metal Products Division Aluminum-silicon carbide composite and process for making the same
CN1314825C (en) * 2002-09-05 2007-05-09 费维栋 Brake facing made of magnesium borate crystal whisker and ceramic particle reinforced aluminium base composite material and its preparation process
CN101792876A (en) * 2010-03-26 2010-08-04 南京工业大学 Aluminum-based composite material for composite pan bottom of stainless steel pan and preparation method thereof
JP2013023760A (en) * 2011-07-26 2013-02-04 Isuzu Motors Ltd Method for manufacturing composite material of silicon carbide particle-reinforced aluminum-silicon-based aluminum alloy
CN103103374A (en) * 2013-02-04 2013-05-15 哈尔滨工业大学 Method for preparing aluminum matrix composite through high pressure solidification after semi-solid mechanical stirring
CN103484707A (en) * 2013-09-23 2014-01-01 同济大学 Preparation method for SiC particle reinforced aluminum-based composite material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384087A (en) * 1992-04-06 1995-01-24 Ametek, Specialty Metal Products Division Aluminum-silicon carbide composite and process for making the same
CN1314825C (en) * 2002-09-05 2007-05-09 费维栋 Brake facing made of magnesium borate crystal whisker and ceramic particle reinforced aluminium base composite material and its preparation process
CN101792876A (en) * 2010-03-26 2010-08-04 南京工业大学 Aluminum-based composite material for composite pan bottom of stainless steel pan and preparation method thereof
JP2013023760A (en) * 2011-07-26 2013-02-04 Isuzu Motors Ltd Method for manufacturing composite material of silicon carbide particle-reinforced aluminum-silicon-based aluminum alloy
CN103103374A (en) * 2013-02-04 2013-05-15 哈尔滨工业大学 Method for preparing aluminum matrix composite through high pressure solidification after semi-solid mechanical stirring
CN103484707A (en) * 2013-09-23 2014-01-01 同济大学 Preparation method for SiC particle reinforced aluminum-based composite material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104233018A (en) * 2014-08-26 2014-12-24 盐城市鑫洋电热材料有限公司 Reinforced aluminum alloy and preparation method thereof
CN104388734A (en) * 2014-11-27 2015-03-04 哈尔滨工业大学 Preparing and molding devices and preparing and molding methods of nano SiC particle enhanced 7075 aluminum matrix composite material semi-solid slurry
CN109396401A (en) * 2018-10-31 2019-03-01 宁波华源精特金属制品有限公司 A kind of automatic pedal
CN110863160A (en) * 2019-11-11 2020-03-06 中国科学院上海硅酸盐研究所 SIALON whisker reinforced aluminum matrix composite material and preparation method thereof
CN113523005A (en) * 2021-07-12 2021-10-22 福建祥鑫股份有限公司 Extrusion method of low-volume-fraction ceramic particle reinforced aluminum-based composite bar

Also Published As

Publication number Publication date
CN103981391B (en) 2016-05-18

Similar Documents

Publication Publication Date Title
CN106521252B (en) Train brake disk enhancing aluminum-base composite material by silicon carbide particles and preparation method
Singla et al. Development of aluminium based silicon carbide particulate metal matrix composite
Aravindan et al. Evaluation of physical and mechanical properties of AZ91D/SiC composites by two step stir casting process
Lin et al. Effects of Mg content on microstructure and mechanical properties of SiCp/Al-Mg composites fabricated by semi-solid stirring technique
Sharma et al. Production of AMC by stir casting–an overview
CN103981391A (en) Aluminum-base composite material reinforced by both magnesium borate crystal whisker and silicon carbide particles and preparation method thereof
CN102108455B (en) Preparation method of aluminum-base composite material
CN107955889A (en) One kind utilizes interior raw nanometer TiB2The method of particle strengthening aluminium alloy
CN102676883B (en) Silicon carbide reinforced aluminum-based composite material and preparation method thereof
CN110284032B (en) Preparation method of high-entropy alloy particle reinforced magnesium-based composite material
CN109321767B (en) Method for preparing hybrid particle reinforced aluminum matrix composite material by composite reinforcement method
CN106566966A (en) Magnesium base composite material with high-entropy alloy as reinforcing base and preparation method of magnesium base composite material
CN109609814B (en) High-strength aluminum alloy with high elastic modulus mixed with double-scale ceramic particles and preparation method thereof
CN107723496B (en) The preparation method of Al-Si metal matrix composite
CN110453113B (en) Method for reinforcing aluminum alloy composite material by cesium oxide modified graphene
CN105463265A (en) Preparation method for silicon carbide particle reinforced aluminum-based composite material
CN111690840A (en) Amorphous phase silicate particle and SiC particle reinforced aluminum matrix composite material and preparation
CN110964933A (en) Preparation method of graphene/aluminum and aluminum alloy composite material
Singh et al. A comprehensive review on the new developments consideration in a stir casting processing of aluminum matrix composites
CN101967575A (en) Preparation method of Al5Ti1B intermediate alloy
CN102899517B (en) In-situ SiC-TiC particle mixing enhanced aluminum-based composite material and preparation process thereof
Loukus et al. Heat treatment effects on the mechanical properties and microstructure of preform-based squeeze cast aluminum metal matrix composites
CN110343895B (en) In situ TiB2Preparation method of particle-reinforced AlCu-based composite material
CN111304506A (en) Micro-nano TiB2Preparation method of particle-reinforced magnesium-lithium-based composite material
CN111020300A (en) Preparation method of thermal cracking resistant binary nanoparticle reinforced aluminum matrix composite

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160518

Termination date: 20180211

CF01 Termination of patent right due to non-payment of annual fee