CN103980667A - Thermosetting resin composition of integrated circuit, prepreg and laminate - Google Patents
Thermosetting resin composition of integrated circuit, prepreg and laminate Download PDFInfo
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Abstract
The invention discloses a thermosetting resin composition of an integrated circuit, a prepreg and a laminate. Totaling 100 parts, the resin composition contains the following ingredients in parts by solid weight: (a) 10-50 parts of an allyl modified bismaleimide resin prepolymer, (b) 10-30 parts of an acid-anhydride compound, (c) 5-40 parts of epoxy resin and (d) 20-40 parts of phosphoric active ester. The resin composition disclosed by the invention has a high glass transition temperature, excellent moist heat resistance and a relatively low dielectric constant, can meet the design requirements on multilayer board impedance and is beneficial to application in the field of high-performance printed circuit boards, such as high-density interconnected integrated circuit package.
Description
Technical field
The invention belongs to technical field of electronic materials, relate to a kind of halogen-free resin composition for unicircuit and use prepreg and the veneer sheet of its making, can be applicable to the fields such as high density interconnect integrated antenna package.
Background technology
In recent years, along with the development of electronic technology, electronic product updates more rapid, have higher requirement to printed electronic circuit, and the high multiple stratification of Printed Circuit Board Design, high wiring density changes into one of developing direction for printed electronic circuit.High multiple stratification, high wiring density, this just requires the base mateiral of circuit board manufacturing---copper-clad plate, there is lower thermal expansivity, higher thermotolerance, also to there is lower specific inductivity simultaneously, to in the process of printed circuit design, meet the thermal shocking of bearing in impedance design and the course of processing.
Along with the progressively intensification of environmental pollution, the living environment going from bad to worse, the theme of " environmental protection " is rooted in the hearts of the people gradually, therefore, in copper-clad plate industry, green halogen-free board is developed the main direction of development in recent years especially, and the main technological route that has been applied to halogen-free flameproof of phosphonium flame retardant.At present, the phosphorus flame retardant extensively adopting on copper-clad plate market: be mainly divided into two kinds of response type and addition types.Response type is mainly DOPO compounds, taking phosphorous epoxy resin, phosphorus containing phenolic resin as main, phosphorus content is between 2-10%, but, in practical application, find, adopt phosphorous epoxy resin as matrix resin or adopt the resin combination that phosphorus containing phenolic resin is epoxy curing agent, it has larger water-intake rate and higher specific inductivity, and the humidity resistance of its sheet material of making decreases; Addition type is mainly phosphine nitrile and phosphate compounds, the flame retarding efficiency relative response type of additive flame retardant is on the low side, need to adding more phosphorus content, just to reach UL 94V-0 level fire-retardant, simultaneously, because of its lower fusing point (generally lower than 150 DEG C), in the course of processing of veneer sheet, easily " migration " is to the surface of sheet material.
Therefore, the application of above-mentioned phosphor-containing flame-proof technology, often can not meet the requirement of the resin composition formula design of the humidity resistance of low-k, excellence, seek new halogen-free flame retardants, prepare the copper-clad plate that has halogen-free flameproof and high heat resistance, low-k concurrently, become one of direction of copper-clad plate future development.
Phosphorous active ester is a class novel reaction type fire retardant, as the solidifying agent of epoxy resin, in its solidification process, can not generate the hydroxyl that polarity is higher with epoxy reaction, therefore, its resin system after solidifying has lower water-intake rate and lower specific inductivity.
Therefore, adopt phosphorous active ester to substitute the phosphonium flame retardant of main flow in the market, in improving halogen-free flameproof, can also reduce dielectric properties and the water-intake rate of resin combination, keep the wet-hot aging performance of whole composition excellence.
Summary of the invention
Goal of the invention of the present invention is to provide a kind of compositions of thermosetting resin, prepreg and veneer sheet for unicircuit, with flame retardant properties, thermotolerance and the dielectric properties of improving layer pressing plate.
To achieve the above object of the invention, the technical solution used in the present invention is:
A kind of unicircuit compositions of thermosetting resin, is characterized in that, adds up to 100 parts in solid weight, comprising:
(a) allyl group modified bismaleimide resin prepolymer: 10 ~ 50 parts;
(b) anhydride compound: 10 ~ 30 parts;
(c) epoxy resin: 5 ~ 40 parts;
(d) phosphorous active ester: 20 ~ 40 parts.
In technique scheme, the number-average molecular weight of described allyl group modified bismaleimide resin prepolymer is 1500 ~ 8000g/mol, via 100 parts of bimaleimide resins and 40 ~ 100 parts of allylic cpds, at 130 ~ 160 DEG C, react 40 ~ 100min and make;
The monomer structure of described bimaleimide resin is:
，
Wherein, R base is:
,
or
;
The structural formula of described allylic cpd is:
，
Wherein, R base is:
,
or
.
Preferably, the number-average molecular weight of described allyl group modified bismaleimide resin prepolymer is 2000 ~ 6000g/mol, and the content in its resin combination is preferably 20-45 part.
In technique scheme, described anhydride compound is selected from styrene-maleic anhydride, phenylethylene-maleic anhydride, 3,3 ', 4,4 '-phenyl ether tetracarboxylic dianhydride, 2,3,3', 4'-diphenyl ether tetraformic dianhydride, 3,3', 4,4'-bibenzene tetracarboxylic dianhydride, 2,3,3', 4'-bibenzene tetracarboxylic dianhydride, 3,3 ', 4,4 '-benzophenone tetracarboxylic dianhydride, Bisphenol A Type Diether Dianhydride, 1, one or more in 2,4,5-pyromellitic acid dianhydride, the content in its resin combination is preferably 15-30 part.
In technique scheme, described epoxy resin is selected from: the mixture of one or more of bisphenol A epoxide resin, bisphenol F epoxy resin, o-cresol formaldehyde epoxy resin, bisphenol-A phenolic epoxy resin, phenol novolac epoxy resins, trifunctional phenol-type epoxy resin, tetraphenyl ethane epoxy resin, biphenyl type epoxy resin, naphthalene nucleus type epoxy resin, dicyclopentadiene type epoxy resin, aralkyl novolac epoxy resin, glycidyl amine type epoxy resin, glycidyl ester type epoxy resin, the content in its resin combination is 10-30 part.
In technique scheme, the structural formula of described phosphorous active ester compound is,
，
In formula, R1 is methyl, ethyl or the tertiary butyl;
Y is H or CH
3;
Z is
or
, wherein R is phenyl, naphthyl or C
1～C
5alkyl;
N is 1～10 integer;
X is:
,
,
or
.
The preparation method of above-mentioned active ester compound, by phosphorus compound and p-Hydroxybenzaldehyde, adds the H of 50～70% mass concentrations
2sO
4in, heating at 90～130 DEG C, condensing reflux 3～8hr, then reaction product is passed through to 3～10 alcohol washes, under the vacuum condition of 95～105 DEG C, dry 3～6hr, obtains pre-product; Above-mentioned gained pre-product is dissolved in aromatic series organic solution, add phenylformic acid or naphthyl, benzene alkylbenzoic acid compound, under the temperature condition of 100～120 DEG C, add catalyzer, condensing reflux 2～8hr, after washing, under the vacuum condition of 95～105 DEG C, be dried 3～6hr, obtain required phosphorous active ester compound, esterification yield is 65～85%; Wherein, described phosphorus compound is selected from 9, mix-10-phospho hetero phenanthrene-10-oxide compound of 10-dihydro-9-oxy, 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide compound, 10-(2,5-dihydroxyl naphthyl) one or more mixture in the phospho hetero phenanthrene compound such as-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide compound or 10-(2,5-dihydroxybiphenyl base)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide compound.
Described aromatic organic solvent can be selected from toluene, dimethylbenzene, ethylbenzene, isopropyl benzene.
Described catalyzer is AlCl
3.
In described phosphorous active ester compound, in mass, phosphorus content is 5.2～7.2%.
In technique scheme, the content of phosphorous active ester is preferably 25-40 part.
Further technical scheme, contain curing catalyst, in technique scheme, described curing catalyst is selected from one or more the mixture in acetylacetone cobalt, zinc naphthenate, zinc octoate, glyoxal ethyline, 2-ethyl-4-methylimidazole and 2-phenylimidazole.The content of curing catalyst is 0.01-3 part.
Preferred technical scheme, described resin combination also contains mineral filler, and the consumption of described mineral filler is 0～35% of halogen-free resin composition solid total mass; Described mineral filler is one or more the mixture in aluminium hydroxide, magnesium hydroxide, wollastonite, fine silica powder, magnesium oxide, Calucium Silicate powder, calcium carbonate, clay, kaolin, glass powder, mica powder, titanium dioxide, zinc borate, zinc molybdate.Particle diameter is 0.3～20 μ m, preferentially selects 0.5～5 μ m.Above-mentioned mineral filler can directly drop into or previously prepared fillers dispersed liquid or make lotion and drop in resin combination.
The prepreg that adopts above-mentioned halogen-free resin composition to make, makes glue by halogen-free resin composition by dissolution with solvents, then strongthener is immersed in above-mentioned glue; By the strongthener heat drying after dipping, obtain described prepreg.
Described solvent is selected from one or more the mixture in acetone, butanone, mibk, N, dinethylformamide, N, N-N,N-DIMETHYLACETAMIDE, ethylene glycol monomethyl ether, propylene glycol monomethyl ether.Described strongthener can adopt natural fiber, organic synthetic fibers, organic fabric or without woven fabrics.
Described prepreg be temperature at 130～190 DEG C, the time be under 3～20min dry preparation obtain.
Adopt above-mentioned prepreg, be covered with tinsel at single or double, hot compacting, obtains described veneer sheet.
The quantity of prepreg is to determine according to the veneer sheet thickness of customer requirement, available one or more.Described tinsel, can be Copper Foil, can be also aluminium foil, and their thickness is not particularly limited.
Because technique scheme is used, the present invention compared with prior art has following advantages:
1. the present invention has designed a kind of four component resin compositions of the halogen-free flameproof low-k taking phosphorous active ester as fire retardant, the application of phosphorous active ester, avoid because of after introducing phosphorous epoxy resin or phosphorus containing phenolic resin and introducing as fire retardant the rising of resin water-intake rate;
2. in the halogen-free resin composition designing in the present invention, the allyl group modified bismaleimide resin of introducing, ensure that resin system has higher Tg and high thermostability, for applying the prepared copper-clad plate of this resin combination in the printed wiring course of processing, provide the guarantee of good thermal characteristics aspect; And the thermal expansivity that can significantly reduce its sheet material, this is conducive to the design of high multilayer printed circuit board material more;
3. in the present invention, acid anhydrides and phosphorous active ester, as the co-curing agent of epoxy resin, under the condition of halogen-free flameproof, can reduce the specific inductivity of resin system significantly;
4. resin combination of the present invention has high second-order transition temperature, excellent humidity resistance, lower specific inductivity, can meet better the design requirements of multi-ply wood impedance aspect, be conducive to the application in the contour performance printed circuit board of high density interconnect integrated antenna package field.
Brief description of the drawings
Fig. 1 be synthesis example one product nmr spectrum (
13c);
Fig. 2 be synthesis example one product nmr spectrum (
1h).
Embodiment
Below in conjunction with embodiment, the invention will be further described:
First carry out the synthetic of raw material.
Synthesis example one:
The preparation 1 of phosphorous active ester compound:
Weigh 10-(2,5-dihydroxy phenyl)-10-hydrogen-9-oxa--10-phospho hetero phenanthrene-10-oxide compound of 0.6mol and the p-Hydroxybenzaldehyde of 0.6mol, add the H of 65% mass concentration
2sO
4, condensing reflux 3～5hr under 100 DEG C of heating conditions, then this mixture is passed through to 4～6 alcohol washes, obtain pre-product; Above-mentioned gained pre-product is dissolved in toluene solution, add 0.2mol phenylformic acid, under the temperature condition of 120 DEG C, add the catalyzer (AlCl of 0.05mol
3), condensing reflux 4hr, then, after washing for several times, under the vacuum condition of 105 DEG C, dry 4hr, obtains required phosphorous active ester compound, and esterification yield is 70～80%, and the phosphorous active ester compound that phosphorus content is 6.4%, is designated as D1, and concrete structure is as follows:
X=
, Y=H, Z=
, R is phenyl, R1=CH
3, n is 3 ~ 5.
The nmr spectrum of above-mentioned product (
13c) as shown in Figure 1,165ppm place peak position is stronger, shows to contain in resin the activated ester composition of tool, nmr spectrum (
1h) as shown in Figure 2,7-8ppm is mainly corresponding peak position on phenyl ring, and 3-4ppm is mainly DOPO and CH
2the corresponding peak position that is connected, this synthetic compound of above explanation meets the constitutional features of phosphorous active ester compound.
The preparation 2 of phosphorous active ester compound:
Weigh the 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide of 0.6mol and the p-Hydroxybenzaldehyde of 0.6mol, add the H of 65% mass concentration
2sO
4, condensing reflux 3～5hr under 105 DEG C of heating conditions, then this mixture is passed through to 4～8 alcohol washes, obtain pre-product; Above-mentioned gained pre-product is dissolved in toluene solution, add 0.2mol phenylformic acid, under the temperature condition of 120 DEG C, add the catalyzer (AlCl of 0.05mol
3), condensing reflux 4hr, then, after washing for several times, under the vacuum condition of 105 DEG C, dry 4hr, obtains required phosphorous active ester compound, and esterification yield is 75～85%, and the phosphorous active ester compound that phosphorus content is 7.2%, is designated as D2, and concrete structure is as follows:
X=
, Y=H, Z=
, R is phenyl, R1=CH
3, n is 3 ~ 5.
Synthesis example two: allyl group modified bismaleimide prepolymer synthetic
By 100 part 4,4 '-diphenyl methane dimaleimide resin and 50 parts of diallyl bisphenol compounds, at 135 DEG C of temperature, reaction 80min, then be cooled to room temperature, obtain required allyl group modified bismaleimide resin prepolymer A1, its molecular weight is 2000 ~ 4000g/mol;
By 100 part 4,4 '-Diphenyl Ether Bismaleimide resin and 100 parts of diallyl bisphenol allylic cpds, at 155 DEG C of temperature, reaction 50min, then be cooled to room temperature, obtain required allyl group modified bismaleimide resin prepolymer A2, its molecular weight is 4000 ~ 6000g/mol.
Embodiment:
According to weight ratio shown in table 1, allyl group modified bismaleimide prepolymer, anhydride compound, epoxy resin, phosphorous active ester compound, curing catalyst and mineral filler and solvent are joined in mixed glue still, controlling glue solids content is 65%, stir, and slaking 8hr, make resin combination composition glue liquid; Then woven fiber glass is immersed in above-mentioned resin combination composition glue liquid; Then the woven fiber glass after dipping is formed to prepreg after 155 ~ 175 DEG C of baking 4 ~ 7min; Prepreg is cut to after certain size 8 prepregs stacks are formed to folded structures, respectively place up and down an electrolytic copper foil at folded structure, send into pressing in vacuum press, program is 150 DEG C/60min+200 DEG C/120min, makes veneer sheet.
Comparative example
According to weight ratio shown in table 1, allyl group modified bismaleimide prepolymer, anhydride compound, epoxy resin, phosphorous epoxy or phosphorus containing phenolic resin, solidifying agent, curing catalyst and mineral filler and solvent are joined in mixed glue still, controlling glue solids content is 65%, stir, and slaking 8hr, make resin combination composition glue liquid; Then woven fiber glass is immersed in above-mentioned resin combination composition glue liquid; Then the woven fiber glass after dipping is formed to prepreg after 165 DEG C of baking 5min; Prepreg is cut to after certain size 8 prepregs stacks are formed to folded structures, respectively place up and down an electrolytic copper foil at folded structure, send into pressing in vacuum press, program is 150 DEG C/60min+200 DEG C/120min, makes veneer sheet.
Table 1 composite formula
In upper table, A component (A1, A2) represents that allyl group modified bismaleimide prepolymer, B component represent that anhydride compound, C component representative ring epoxy resins, D component represent that phosphorous active ester, E component represent that other P contained compounds, F component represent curing catalyst, and G component represents mineral filler.
A component: allyl group modified bismaleimide prepolymer
A1, A2: allyl group modified bismaleimide prepolymer, see synthesis example two;
B component: anhydride compound
B1: styrene-maleic anhydride compound;
B2:3,3', 4,4'-bibenzene tetracarboxylic dianhydride compound;
C component: epoxy resin
C1: biphenyl type epoxy resin;
C2: dicyclopentadiene type epoxy resin;
D component: active ester
D1, D2: phosphorous active ester compound, see synthesis example one.
E component: other P contained compounds
E1: phosphorous epoxy resin, CHIN YEE PE-315, phosphorus content 3.5%wt;
E2: phosphorus containing phenolic resin, Dow 92741 phosphorus content 9.2%wt;
F component: curing catalyst
F: dimethyl-tetraethyl-imidazoles
G component: mineral filler
G: silicon-dioxide, 0.5 ~ 5 micron of particle diameter.
Table 2 is respectively the performance test that embodiment mono-to five and comparative example one to three are carried out, and result is as shown in the table:
The performance data of table 2 embodiment and comparative example
In table, the testing method of each performance is as follows:
(1) second-order transition temperature (Tg):
According to dsc, measure according to the DSC method of IPC-TM-650 2.4.25 defined.
(2) stripping strength (PS):
According to " after the thermal stresses " experiment condition in IPC-TM-650 2.4.8 method, the stripping strength of test metal cap rock.
(3) wicking thermotolerance:
Use the two sides band copper sample of 50 × 50mm, immerses in the scolding tin of 288 DEG C, record the time of sample layering foaming.
(4) wicking thermotolerance after moist processing:
The base material sample of 3 100 × 100mm is kept after 5hr in 121 DEG C, the pressure cooking treatment unit of 105Kpa, immerse 2min in the solder bath of 288 DEG C, observe sample whether the phenomenons such as layering bubbling occur, 3 all there is not layering bubbling and are designated as 3/3,2 there is not layering bubbling and are designated as 2/3,1 there is not layering bubbling and is designated as 1/3,0 and layering bubbling does not occur is designated as 0/3.
(5) heat decomposition temperature Td:
Measure according to IPC-TM-650 2.4.26 method.
(6) specific inductivity:
Use flat band method according to IPC-TM-650 2.5.5.9, measure the specific inductivity under 1GHz.
(7) dielectric loss angle tangent:
Use flat band method according to IPC-TM-650 2.5.5.9, measure the dielectric loss factor under 1GHz.
(8) drop impact toughness (veneer sheet fragility):
Use Apparatus for Impacting at low-temp, Apparatus for Impacting at low-temp height of the fall 45cm, whereabouts weight weight 1kg.
The judge that toughness is good and bad: cross bar is clear, illustrates that the toughness of product is better, and with character, ☆ represents; Cross bar is fuzzy, illustrates that the poor toughness of product, fragility are large, and with character, ◎ represents; Cross bar readability illustrates that toughness of products is general between clear and fuzzy, and with character, ◇ represents.
(9) thermally stratified layer time T-300:
Measure according to IPC-TM-650 2.4.24 method.
(10) resistance to flame (flame retardancy):
Measure according to UL94 method.
From upper table data, synthetic phosphorous active ester in the present invention's design is incorporated in resin combination, the copper-clad plate of made has more excellent dielectric properties, lower specific inductivity, there is better humidity resistance, avoid resin system because of after introducing phosphorous epoxy resin or phosphorus containing phenolic resin and introducing as fire retardant (comparative example), the rising of resin water-intake rate.Equally, the introducing of allyl group modified bismaleimide resin in the present invention, ensure that resin system has higher Tg and high thermostability, for applying the prepared copper-clad plate of this resin combination in the printed wiring course of processing, the guarantee of good thermal characteristics aspect is provided, and this is conducive to the design of high multilayer printed circuit board material more.
Claims (10)
1. a unicircuit compositions of thermosetting resin, is characterized in that, adds up to 100 parts in solid weight, comprising:
(a) allyl group modified bismaleimide resin prepolymer: 10 ~ 50 parts;
(b) anhydride compound: 10 ~ 30 parts;
(c) epoxy resin: 5 ~ 40 parts;
(d) phosphorous active ester: 20 ~ 40 parts.
2. unicircuit compositions of thermosetting resin according to claim 1, it is characterized in that: described allyl group modified bismaleimide resin prepolymer is the prepolymer of allylic cpd and bimaleimide resin, and its number-average molecular weight is 1500 ~ 8000g/mol;
Described allylic cpd is selected from one or more in diallyl bisphenol, diallyl bisphenol S, allyl phenoxy resin, allyl phenol urea formaldehyde, diallyl phenyl ether;
Described bimaleimide resin is selected from 4,4 '-diphenyl methane dimaleimide resin, 4,4 '-Diphenyl Ether Bismaleimide resin, 4,4 '-hexichol sec.-propyl bimaleimide resin, 4, one or more in 4 '-sulfobenzide bimaleimide resin.
3. according to the unicircuit compositions of thermosetting resin described in claim 1, it is characterized in that: described anhydride compound is selected from styrene-maleic anhydride phenylethylene-maleic anhydride, 3,3 ', 4,4 '-phenyl ether tetracarboxylic dianhydride, 2,3,3', 4'-diphenyl ether tetraformic dianhydride, 3,3', 4,4'-bibenzene tetracarboxylic dianhydride, 2,3,3', 4'-bibenzene tetracarboxylic dianhydride, 3,3 ', 4,4 '-benzophenone tetracarboxylic dianhydride, Bisphenol A Type Diether Dianhydride, one or more in 1,2,4,5-pyromellitic acid dianhydride.
4. according to the unicircuit compositions of thermosetting resin described in claim 1, it is characterized in that: described epoxy resin is selected from: bisphenol A epoxide resin, bisphenol F epoxy resin, o-cresol formaldehyde epoxy resin, bisphenol-A phenolic epoxy resin, phenol novolac epoxy resins, trifunctional phenol-type epoxy resin, tetraphenyl ethane epoxy resin, biphenyl type epoxy resin, naphthalene nucleus type epoxy resin, dicyclopentadiene type epoxy resin, aralkyl novolac epoxy resin, glycidyl amine type epoxy resin, the mixture of one or more of glycidyl ester type epoxy resin.
5. according to the unicircuit compositions of thermosetting resin described in claim 1, it is characterized in that: the structural formula of described phosphorous active ester compound is,
，
In formula, R1 is methyl, ethyl or the tertiary butyl;
Y is H or CH
3;
Z is
or
, wherein R is phenyl, naphthyl or C
1～C
5alkyl;
N is 1～10 integer;
X is:
,
,
or
.
6. according to the unicircuit compositions of thermosetting resin described in claim 5, it is characterized in that: in described phosphorous active ester compound, in mass, phosphorus content is 5.2～7.2%.
7. according to the unicircuit compositions of thermosetting resin described in claim 1, it is characterized in that: contain curing catalyst, described curing catalyst is selected from one or more the mixture in acetylacetone cobalt, zinc naphthenate, zinc octoate, glyoxal ethyline, 2-ethyl-4-methylimidazole and 2-phenylimidazole.
8. according to the unicircuit compositions of thermosetting resin described in claim 1, it is characterized in that: contain mineral filler, described mineral filler is one or more the mixture in aluminium hydroxide, magnesium hydroxide, wollastonite, fine silica powder, magnesium oxide, Calucium Silicate powder, calcium carbonate, clay, kaolin, glass powder, mica powder, titanium dioxide, zinc borate, zinc molybdate.
9. a prepreg that adopts unicircuit as claimed in claim 1 compositions of thermosetting resin to make, it is characterized in that: unicircuit claimed in claim 1 compositions of thermosetting resin dissolution with solvents is made to glue, then strongthener is immersed in above-mentioned glue; By the strongthener heat drying after dipping, obtain described prepreg.
10. a veneer sheet that adopts unicircuit as claimed in claim 1 compositions of thermosetting resin to make, it is characterized in that: the single or double at least one the prepreg being obtained by claim 9 is covered with tinsel, hot compacting, obtains described veneer sheet.
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| CN114656749A (en) * | 2020-12-23 | 2022-06-24 | 广东生益科技股份有限公司 | Thermosetting resin composition and application thereof |
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| CN104761870A (en) * | 2015-04-03 | 2015-07-08 | 广东汕头超声电子股份有限公司覆铜板厂 | Halogen-free low-dielectric-loss epoxy resin composition and prepreg and laminated board prepared by using halogen-free low-dielectric-loss epoxy resin composition |
| CN105778499A (en) * | 2016-04-26 | 2016-07-20 | 广东生益科技股份有限公司 | Thermosetting resin composition and application thereof |
| CN113736256A (en) * | 2020-05-29 | 2021-12-03 | 台光电子材料股份有限公司 | Resin composition and product thereof |
| CN113736256B (en) * | 2020-05-29 | 2023-04-07 | 台光电子材料股份有限公司 | Resin composition and product thereof |
| CN114605780A (en) * | 2020-12-09 | 2022-06-10 | 广东生益科技股份有限公司 | Thermosetting resin composition, and prepreg, laminated board, circuit substrate and printed circuit board comprising thermosetting resin composition |
| CN114605780B (en) * | 2020-12-09 | 2023-09-12 | 广东生益科技股份有限公司 | Thermosetting resin composition, prepreg comprising thermosetting resin composition, laminated board, circuit substrate and printed circuit board |
| CN114656749A (en) * | 2020-12-23 | 2022-06-24 | 广东生益科技股份有限公司 | Thermosetting resin composition and application thereof |
| CN114656749B (en) * | 2020-12-23 | 2024-03-29 | 广东生益科技股份有限公司 | Thermosetting resin composition and application thereof |
| CN112778701A (en) * | 2020-12-30 | 2021-05-11 | 广东生益科技股份有限公司 | Halogen-free flame-retardant resin composition and application thereof |
| CN112778701B (en) * | 2020-12-30 | 2023-02-28 | 广东生益科技股份有限公司 | Halogen-free flame-retardant resin composition and application thereof |
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