CN103979565A - Method for settling and separating mud with high molecular organic dispersant - Google Patents
Method for settling and separating mud with high molecular organic dispersant Download PDFInfo
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- CN103979565A CN103979565A CN201410244902.XA CN201410244902A CN103979565A CN 103979565 A CN103979565 A CN 103979565A CN 201410244902 A CN201410244902 A CN 201410244902A CN 103979565 A CN103979565 A CN 103979565A
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- mud
- clay
- dispersing agent
- ozone
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Abstract
The invention discloses a method for settling and separating mud with a high molecular organic dispersant and belongs to the technical field of mineral separation and purification. The method comprises the following steps: making clay to which the high molecular organic dispersant is added into mud; settling and separating to remove chippings; and carrying out ozone aeration on relatively pure mud at the top. The high molecular dispersant is oxidized through strong oxidizing aeration of ozone, so that stable balance of stable and suspended clay mud is broken and the clay mud can be naturally settled. Soil-water separation of mud is realized, and a clay mineral powder product is obtained.
Description
Technical field
The present invention relates to the method that sedimentation occurs fast for argillaceous mineral and macromolecule dispersing agent mud, be applicable to mineral purification technique field, be particularly related to a kind of for making to have added the settlement separate method of polymer organic dispersing agent mud, a kind of by add the strong oxidizers such as ozone in mud specifically, make because the stability that adds macromolecule dispersing agent to be the clay mud of stable suspersion state is destroyed, thereby realize the method that clay particle is separated from mud.
Background technology
Generally, even the clay mud gravitate fully suspending impact, at short notice will sedimentation, there is mud-water separation.In clay pit ore dressing field, when the purity of clay is not high, in order to remove impurity fragmental products wherein and to promote clay purity, often need in mud, add organic polymer dispersion agent to make suspension and the good mud of stability, can be in the good mud of stability by the settlement separate impurity fragmental products that makes, under action of gravity, be deposited to the bottom of container, realize the object of separating-purifying.But ensuing problem is conventionally all very thorny.Remove the mud (being usually located at the top of container) of impurity chip, needed dehydration to obtain Powdered clay product.But because the clay mud making by organic polymer dispersion agent is conventionally all highly stable, want from mud, to obtain clay powders more difficult.For clay muds such as large stretch of kaolin, montmorillonites, be generally by ultrafiltration or high speed centrifugation, the water in mud to be discharged, leave powder clay.But for the tiny powder clay of nano level, as polygorskite or attapulgite, because the particle diameter ratio the thinnest existing mesh screen of clay mineral is also thin, the method for ultrafiltration can cause loss, reduce the rate of recovery.
Summary of the invention
1, the technical problem that invention will solve
Main purpose of the present invention is for the problem in existing clay pit sedimentation purification, provide a kind of for making to have added the settlement separate method of polymer organic dispersing agent mud, strong oxidation and aeration by ozone makes macromolecule dispersing agent oxidized, thereby break the stable equilibrium of the clay mud of stable suspersion, make the clay mud can natural subsidence.Soil-water of realizing mud is separated.
2, technical scheme
Inventive principle
Ozone, O
3, be a kind of strong oxidizer, can be oxidized most organic compound.Organic dispersing agent, as sodium polyacrylate conventional in clay purification, polyoxyethylene glycol etc. are the chain polymer that molecular weight is huge, the frame shape structure that C-H molecule aggregation becomes is fully disperseed the clay particle in water, forms stable colloid.If adding ozone, O by the stable mud of macromolecule dispersing agent
3strong oxidation can make chain polymer " smash " to become CO
2and H
2o.In aqueous dispersion, by very fast unstability, there is dehydration and the sedimentation of colloid in the clay particle that loses macromolecular scaffold.Isolate the object that sediment has just reached slurry dewatering.
Technology contents:
For making to have added a settlement separate method for polymer organic dispersing agent clay mud, the steps include:
(1) polymer organic dispersing agent is dissolved in the water, preparation is the mixing solutions of 0.2 ‰~0.5 ‰ polymer organic dispersing agents containing mass percent;
(2) in the mixing solutions of step (1) configuration, add the suspension that clay preparation mass percent is 1~15%,, after soaking, with pulping equipment, break into mud;
(3) this mud is placed in to settling leg precipitate and separate 2~24 hours, then removes the chip impurity of settling leg bottom;
(4) pass into ozone, to the remaining mud that is suspended in settling leg top after step (3) is processed, carry out ozonation aerated;
(5) standing after aeration, realize mud-water separation, remove upper strata clear water, obtain high concentration slurry, after doing, make clay breeze.
In described step 1, polymer organic dispersing agent is sodium polyacrylate, polyoxyethylene glycol or polyacrylamide.
The molecular weight 1000 to 1,000,000 of described sodium polyacrylate, polyoxyethylene glycol or polyacrylamide.
Clay described in step 2 is attapulgite clay, kaolin or montmorillonite.
Ozone dosage described in step 4, passes into ozone according to the mass ratio of ozone: dispersion agent=1:1~1:5.
In described step (2), after soaking, with pulping equipment, break into mud, comprise immersion, pair roller, smash slurry, stirring, ultrasonic, clarifixator, molecular mill, colloidal mill method and apparatus, bulk or Powdered clay are fully mixed with into mud with macromolecule dispersing agent.
3, beneficial effect
Innovative point of the present invention and feature are:
(1) of the present invention for smashing the ozone of macromolecule dispersing agent, final fragment residual after completing strong oxidation only has CO
2and H
2o, does not almost destroy the attribute of clay product, does not form new hazardous and noxious substances yet.This use to purification clay is extremely important.
(2) owing to adopting suspension pulping------ozonation aerated to the stable mud suspending---mud in suspension unstability precipitation of sedimentation fragmental products with the conventional clay ore deposit separated very close technique of purifying, original clay purifying technique is without huge transformation.
Embodiment
Embodiment 1:
The sodium polyacrylate that is 1000 by molecular weight is dissolved in 1000 ml waters, is mixed with mass percent concentration and is 0.3 ‰ mixing solutions.By not being dissolved in above-mentioned mixing solutions containing the attapulgite clay of montmorillonite, being mixed with mass percent concentration, it is 1% attapulgite clay water suspensions.After soaking half an hour, with pulping equipment, be broken into mud.This mud is placed in to settling leg precipitate and separate, through 3 hours settlement separate after, remove the higher part mud+throw out of settling leg bottom chip content, remove the chip impurity except settling leg bottom.Mass ratio according to ozone weight: sodium polyacrylate=1:1 passes into ozone, to the residue mud on settling leg top, carries out ozonation aerated.Through 6 hours, after aeration, stop ventilation.After standing 10 hours, the ratio of supernatant liquor has accounted for 40% again, removes upper strata clear water, obtains high concentration slurry, after doing, makes clay breeze.The ratio of supernatant liquor only accounts for the colloid dispersion that 40% explanation causes by dispersion agent sodium polyacrylate and does not exist.If do not implement ozonation aerated, comparative group through 10 hours standing after the ratio of supernatant liquor be almost 0.Wherein after soaking, with pulping equipment, break into mud step, comprise immersion, pair roller, smash slurry, stirring, ultrasonic, clarifixator, molecular mill, colloidal mill method and apparatus, bulk or Powdered clay are fully mixed with into mud with macromolecule dispersing agent.
Embodiment 2:
Step is with embodiment 1, and difference is, the sodium polyacrylate that is 4000 by molecular weight is dissolved in 1000 ml waters, is mixed with mass concentration and is 0.3 ‰ mixing solutions.By not being dissolved in above-mentioned mixing solutions containing the attapulgite clay of montmorillonite, being mixed with mass concentration, it is 3% attapulgite clay water suspensions.After soaking half an hour, with pulping equipment, be broken into mud.Through 6 hours settlement separate after, remove the higher part mud+throw out of settling leg bottom chip content.According to the mass ratio of ozone weight: sodium polyacrylate=1:3, pass into ozone and carry out aeration, to the residue mud on settling leg top, carry out ozonation aerated.Through 8 hours, after aeration, stop ventilation.After standing 10 hours, the ratio of supernatant liquor has accounted for 45% again.The colloid dispersion that explanation is caused by dispersion agent sodium polyacrylate does not exist.
Embodiment 3:
Step is with embodiment 1, and difference is, the sodium polyacrylate that is 1,000,000 by molecular weight is dissolved in 1000 ml waters, is mixed with mass concentration and is 0.2 ‰ mixing solutions.70 grams are not dissolved in containing the attapulgite clay of montmorillonite in above-mentioned mixing solutions, to be mixed with mass concentration be 7% attapulgite clay water suspensions.After soaking half an hour, with pulping equipment, be broken into mud.Through 8 hours settlement separate after, remove the higher part mud+throw out of settling leg bottom chip content.According to the mass ratio of ozone weight: sodium polyacrylate=1:5, pass into ozone and carry out aeration, to the residue mud on settling leg top, carry out ozonation aerated.Through 8 hours, after aeration, stop ventilation.After standing 10 hours, the ratio of supernatant liquor has accounted for 35% again.The colloid dispersion that explanation is caused by dispersion agent sodium polyacrylate does not exist.
Embodiment 4:
Step is with embodiment 1, and difference is, step is dissolved in polyoxyethylene glycol in 1000 ml waters with embodiment 1., is mixed with mass concentration and is 0.5 ‰ mixing solutions.100 grams of kaolin clays containing the chip such as quartzy mica are dissolved in in above-mentioned dispersion liquid, to be mixed with mass concentration be 10% kaolin clay suspension.After 2 hours soak, with pulping equipment, be broken into mud.Through 2 hours settlement separate after, remove the higher part mud+throw out of settling leg bottom chip content.According to the mass ratio of ozone weight: sodium polyacrylate=1:2, pass into ozone and carry out aeration.Through 3 hours, after aeration, stop ventilation.After standing 10 hours, the ratio of supernatant liquor has accounted for 80% again.The colloid dispersion that explanation is caused by dispersion agent polyoxyethylene glycol does not exist.
Embodiment 5:
Step is with embodiment 1, and difference is, polyacrylamide is dissolved in 1000 ml waters, is mixed with mass concentration and is 0.5 ‰ mixing solutions.150 grams are dissolved in containing the quartzy montmorillonitic clays that wait chip in above-mentioned dispersion liquid, to be mixed with mass concentration be 15% kaolin clay suspension.After 2 hours soak, with pulping equipment, be broken into mud.Through 12 hours settlement separate after, remove the higher part mud+throw out of settling leg bottom chip content.According to the mass ratio of ozone weight: sodium polyacrylate=1:4, pass into ozone and carry out aeration.Through 3 hours, after aeration, stop ventilation.After standing 24 hours, the ratio of supernatant liquor has accounted for 50% again.The colloid dispersion that explanation is caused by dispersion agent polyacrylamide does not exist.
Embodiment 6:
Step is with embodiment 1, and difference is, the sodium polyacrylate that is 2000 by 0.3 gram molecular weight is dissolved in 1000 ml waters, is mixed with mass concentration and is 0.3 ‰ mixing solutions.40 grams are not dissolved in above-mentioned dispersion liquid containing the attapulgite clays of montmorillonite, are mixed with mass concentration and are 4% attapulgite clay water suspensions.After soaking half an hour, with pulping equipment, be broken into mud.Through 24 hours settlement separate after, remove the higher part mud+throw out of settling leg bottom chip content.Mass ratio according to ozone weight: sodium polyacrylate=1:1 passes into ozone, to the residue mud on settling leg top, carries out ozonation aerated.Through 8 hours, after aeration, stop ventilation.After standing 10 hours, the ratio of supernatant liquor has accounted for 50% again, removes upper strata clear water, obtains high concentration slurry, after doing, makes clay breeze.The colloid dispersion that explanation is caused by dispersion agent sodium polyacrylate does not exist.If do not implement ozonation aerated, comparative group through 10 hours standing after the ratio of supernatant liquor be almost 0.
Comprehensive above-described embodiment can be found out, super oxygenizement through ozone, by plaing, disperse and the macromolecule dispersing agents such as sodium polyacrylate of colloid-stabilised effect have destroyed completely, caused thus the unstability of overstable mud, 50% the mud-water separation of seeing in formation settling leg.In contrast be not have ozonation aerated mud mud-water separation rate almost nil.Therefore can say, the clay method of purification of using this patent to provide, can improve 50% of mud-water separation efficiency, has greatly improved purification efficiency, has reduced the running cost of moisture in later stage evaporation mud.
Claims (6)
1. for making to have added a settlement separate method for polymer organic dispersing agent clay mud, the steps include:
(1) polymer organic dispersing agent is dissolved in the water, preparation mass percent is 0.2 ‰~0.5 ‰ mixing solutions;
(2) in the mixing solutions of step (1) configuration, add clay, the suspension that preparation mass percent is 1~15% breaks into mud with pulping equipment after soaking;
(3) this mud is placed in to settling leg precipitate and separate 2~24 hours, then removes the chip impurity of settling leg bottom;
(4) pass into ozone, to the remaining mud that is suspended in settling leg top after step (3) is processed, carry out ozonation aerated;
(5) standing after aeration, realize mud-water separation, remove upper strata clear water, obtain high concentration slurry, after doing, make clay breeze.
2. according to claim 1ly for making to have added the settlement separate method of polymer organic dispersing agent clay mud, it is characterized in that, described polymer organic dispersing agent is sodium polyacrylate, polyoxyethylene glycol or polyacrylamide.
3. according to claim 2ly for making to have added the settlement separate method of polymer organic dispersing agent clay mud, it is characterized in that, the molecular weight of described sodium polyacrylate is 1000 to 1,000,000.
4. according to claim 1ly for making to have added the settlement separate method of polymer organic dispersing agent clay mud, it is characterized in that, described clay is attapulgite clay, kaolin or montmorillonite.
5. according to claim 1 for making to have added the settlement separate method of polymer organic dispersing agent clay mud, it is characterized in that described ozone, its dosage passes into ozone according to the mass ratio of ozone: dispersion agent=1:1~1:5.
According to described in claim 1-5 any one for making to have added the settlement separate method of polymer organic dispersing agent clay mud, it is characterized in that, in described step (2), after soaking, with pulping equipment, break into mud, comprise immersion, pair roller, smash slurry, stirring, ultrasonic, clarifixator, molecular mill, colloidal mill method and apparatus, bulk or Powdered clay are fully mixed with into mud with macromolecule dispersing agent.
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Cited By (5)
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CN105984977A (en) * | 2016-05-12 | 2016-10-05 | 浙江海洋大学 | Treatment process of cupriferous waste water |
CN107235495A (en) * | 2017-06-10 | 2017-10-10 | 中国科学院兰州化学物理研究所 | The method that a kind of brilliant beam of depolymerization clay mineral prepares high length-diameter ratio monodimension nanometer material |
CN108910905A (en) * | 2018-09-28 | 2018-11-30 | 芜湖市鹏磊新材料有限公司 | A kind of the ultrasound centrifugation purification and sodium base method of low-grade bentonite |
CN111013552A (en) * | 2019-12-24 | 2020-04-17 | 中南大学 | Clay-based composite material for storing ozone |
CN115321859A (en) * | 2022-07-25 | 2022-11-11 | 武汉理工大学 | Method for separating superfine stone powder and nano clay from limestone mine tailings |
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WO2007092421A2 (en) * | 2006-02-07 | 2007-08-16 | Imerys Pigments, Inc. | A method of treating an aqueous suspension of kaolin |
CN101048468A (en) * | 2004-08-26 | 2007-10-03 | 恩格哈德公司 | Ultrafine hydrous kaolin pigments, methods of making the pigments, and methods of using the pigments in gloss paint formulations |
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Patent Citations (4)
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CN1555347A (en) * | 2001-09-14 | 2004-12-15 | 英默里斯颜料公司 | Integrated process for simultaneous beneficiation, leaching, and dewatering of kaolin clay suspension |
CN101048468A (en) * | 2004-08-26 | 2007-10-03 | 恩格哈德公司 | Ultrafine hydrous kaolin pigments, methods of making the pigments, and methods of using the pigments in gloss paint formulations |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105984977A (en) * | 2016-05-12 | 2016-10-05 | 浙江海洋大学 | Treatment process of cupriferous waste water |
CN107235495A (en) * | 2017-06-10 | 2017-10-10 | 中国科学院兰州化学物理研究所 | The method that a kind of brilliant beam of depolymerization clay mineral prepares high length-diameter ratio monodimension nanometer material |
CN107235495B (en) * | 2017-06-10 | 2019-07-19 | 中国科学院兰州化学物理研究所 | A kind of method that depolymerization clay mineral crystalline substance beam prepares high length-diameter ratio monodimension nanometer material |
CN108910905A (en) * | 2018-09-28 | 2018-11-30 | 芜湖市鹏磊新材料有限公司 | A kind of the ultrasound centrifugation purification and sodium base method of low-grade bentonite |
CN111013552A (en) * | 2019-12-24 | 2020-04-17 | 中南大学 | Clay-based composite material for storing ozone |
CN111013552B (en) * | 2019-12-24 | 2020-12-29 | 中南大学 | Clay-based composite material for storing ozone |
CN115321859A (en) * | 2022-07-25 | 2022-11-11 | 武汉理工大学 | Method for separating superfine stone powder and nano clay from limestone mine tailings |
CN115321859B (en) * | 2022-07-25 | 2023-05-26 | 武汉理工大学 | Method for separating superfine powder and nanoclay from limestone mine tailing mud |
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