CN103965979B - Nanometer emulsified crude oil preparation synthesis clean type many grades diesel oil emulsification - Google Patents
Nanometer emulsified crude oil preparation synthesis clean type many grades diesel oil emulsification Download PDFInfo
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- CN103965979B CN103965979B CN201310027042.XA CN201310027042A CN103965979B CN 103965979 B CN103965979 B CN 103965979B CN 201310027042 A CN201310027042 A CN 201310027042A CN 103965979 B CN103965979 B CN 103965979B
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- diesel oil
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- 239000002283 diesel fuel Substances 0.000 title claims abstract description 70
- 238000004945 emulsification Methods 0.000 title claims abstract description 50
- 239000010779 crude oil Substances 0.000 title claims abstract description 35
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 19
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 13
- 239000000654 additive Substances 0.000 claims abstract description 39
- 230000000996 additive effect Effects 0.000 claims abstract description 39
- 239000000463 material Substances 0.000 claims abstract description 38
- 150000001875 compounds Chemical class 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 238000012986 modification Methods 0.000 claims abstract description 29
- 230000004048 modification Effects 0.000 claims abstract description 29
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 238000013461 design Methods 0.000 claims abstract description 5
- 239000000725 suspension Substances 0.000 claims abstract description 3
- 238000003860 storage Methods 0.000 claims description 28
- 239000003921 oil Substances 0.000 claims description 8
- 230000001804 emulsifying effect Effects 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000005259 measurement Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 239000000295 fuel oil Substances 0.000 abstract description 8
- 238000004140 cleaning Methods 0.000 abstract description 5
- 239000003208 petroleum Substances 0.000 abstract description 4
- 239000006185 dispersion Substances 0.000 abstract description 3
- 238000011161 development Methods 0.000 abstract description 2
- 230000003137 locomotive effect Effects 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract 1
- 230000008901 benefit Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 239000004064 cosurfactant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 1
- 239000013058 crude material Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Abstract
nullThe present invention relates to a kind of water、Crude oil、Material is dosed in modification、Compound additive nanometer emulsified synthesis clean type many grades diesel oil emulsification，It is characterized in that: the percentage by weight of the component of clean type grade diesel oil emulsification be water percentage by weight in diesel oil emulsification be 15 20%，Crude oil percentage by weight in diesel oil emulsification is 75 50%，It is 10 25% that material percentage by weight in diesel oil emulsification is dosed in modification，Compound additive percentage by weight in diesel oil emulsification is 0 5%，The percentage by weight sum of above-mentioned material is 100%，Above-mentioned four kinds of materials quantitatively send into by design strong vertical Kneeding stirrer is formed the uniform mixed liquor of suspension polymerisation through pump type liquid pulverize homogenizer dispersed phase drop granule dispersion and fining homogenizing after send into nanometer emulsified machine synthesize nanometer emulsified cleaning many grades diesel oil emulsification，It is suitable for automobile、Train、Locomotive、Farm machinery electromotor、Boats and ships、Many grades cleaning that Industrial Boiler uses、Economical、The light diesel fuel being suitable for，Heavy diesel fuel，The fuel oil such as heavy oil.It it is the revolution scientific and technical innovation development of petroleum industry.
Description
The present invention relates to a kind of novel emulsion cleaning fuel, particularly relate to a kind of water, material and compound additive nanometer emulsified preparation synthesis clean type many grades diesel oil emulsification are dosed in crude oil, modification.
Background technology
In the sixties in last century, the U.S. has successfully tried out diesel oil infiltration burning, and oil emulsion in multiple Industrial Boiler and automobile, engine of boat and ship.International burning association in 1981 first session determines that fuel oil infiltration fuel, as one of three big conservation measures, causes the further attention of each industrial country, strengthens the research and development of relevant fuel oil infiltration technology.
Current research work the most all uses chemical emulsification oil preparation to change hydrone surface activity, makes water, oil affinity, but this emulsifying agent price is high, and profit combines instability, has unfavorable factor from economy and applicable effect, and therefore popularization and application have certain resistance.
The present invention utilizes two kinds of liquid, when the particle diameter of dispersion fluid is little to during close to liquid medium molecular diameter, forms bonding force, and the physical characteristic separated no longer occurs between molecule and molecule.This nanometer emulsified device is just for providing this bonding force to create conditions, make water, oil combines and particle stabilized uniformly reaches water oil emulsifying good result, there is high dynamic stability, again according to light diesel fuel and heavy diesel fuel in country's domestic diesel oil, the national standard of heavy oil different size grade diesel oil adds different modifications and doses material and compound additive and water, the most nanometer emulsified synthesis of oil is applicable to Industrial Boiler heavy oil, boats and ships high-power low-speed diesel, engine and the heavy diesel fuel of generating set medium seed diesel engine, automobile, the cleaning diesel oil of the different grade such as the light diesel fuel of agricultural high-speed diesel engine.
Summary of the invention
nullIt is water、Crude oil、Material is dosed in modification and compound additive oozes kneading by a certain percentage and closes，The all crushing materials participating in mixing，Dispersion reaches nanoscale molecule，Make water、Oil、Material is dosed in modification、The emulsification clean diesel oil of the different grade of particle energy stable bond dispersed emulsifying synthesis of compound additive，Reach the purpose of energy-saving and emission-reduction，Reduce fuel price simultaneously，Improve Business Economic Benefit and improve the social benefit of environment，The nanometer emulsified crude oil preparation synthesis clean diesel oil of present invention design，It is characterized in that: by water、Crude oil、Material is dosed in modification、Compound additive nanometer emulsified preparation synthesis emulsification clean diesel oil，The percentage by weight of component material be water percentage by weight in emulsification clean diesel oil be 15-20%，Crude oil percentage by weight in emulsification clean diesel oil is 50-75%，Change that to dose material percentage by weight in emulsification clean diesel oil be 15-25%，Compound additive percentage by weight in emulsification clean diesel oil is 0-5%，Four kinds of weight of material percentage ratio sums are 100%，Compound additive includes emulsion，Cosurfactant，With other modified additive，The production technology streamline of nanometer emulsified crude oil preparation synthesis clean diesel oil，Main by water storage tank、Water dosing pump、Crude oil storage tank、Crude oil measurement pump、Modification is dosed material storage tank and is dosed material dosing pump、Compound additive storage tank、Compound additive dosing pump、Strongly Kneeding stirrer、Pump type liquid pulverizes homogenizer、Nanometer emulsified machine、Pump is sent in floatingization cleaning diesel oil input、Emulsification clean diesel oil storage tank、Automatic control cabinets etc. form，It is characterized in that: the water of emulsification clean diesel oil composition、Crude oil、Material is dosed in modification and compound additive is separately stored in water storage tank、Crude oil storage tank、Modification is dosed in material storage tank and compound additive storage tank，Under the automatically controlling of automatic control cabinet，Water、Crude oil、Modification is dosed and compound additive，Respectively by water dosing pump、Crude oil measurement pump、Modification is dosed material and compound additive dosing pump and is quantitatively conveyed in strength Kneeding stirrer by design，Uniform mixed liquor is formed in blender，Homogenizer is pulverized again by liquid pump type，Liquid dispersed phase refinement fineness is reached 5-20 μm，Form micron order intimate mixing liquid to send in nanometer emulsified machine，Water in nanometer emulsified machine、Crude oil、Material and compound additive are dosed in modification，Emulsifying synthesis clean type diesel oil goods，Emulsification clean diesel oil storage tank is sent into again by emulsification clean diesel oil delivery pump.
Advantages of the present invention: through simple process technique, just crude oil is made the light diesel fuel that can be used for automobile high-speed diesel engine, diesel oil for medium seed diesel engines such as locomotive, generating set, agricultural machines and the heavy diesel fuel for marine low speed electromotor, heavy oil for Industrial Boiler, improve the utilization ratio of crude resources, reduce diesel production cost, and the economic benefit that obtains and social benefit in energy-saving and emission-reduction and construction of improving the ecological environment.
With embodiment, the present invention is elaborated below in conjunction with the accompanying drawings
Specific implementation method:
Figure of description 1 is production line process chart of the present invention
nullFrom accompanying drawing，The present invention includes: water storage tank 1、Water dosing pump 2、Crude oil storage tank 3、Crude oil measurement pump 4、Material storage tank 5 is dosed in modification、Dose material dosing pump 6、Compound additive storage tank 7、Additive dosing pump 8、Blender 9 is closed in strength control、Pump type liquid pulverizes homogenizer 10、Nanorize machine 11、Emulsification clean diesel oil delivery pump 12、Emulsification clean diesel oil storage tank 13、Automatic control cabinet 14、It is characterized in that: the component water of emulsification clean diesel oil、Crude oil、Material is dosed in modification、Compound additive is separately stored in water storage tank 1、Crude oil storage tank 3、Material storage tank 5 is dosed in modification、In compound additive storage tank 7，Under the control of automatic control cabinet 14，By water dosing pump 2、Crude oil measurement pump 4、Material dosing pump 6 is dosed in modification、Compound additive dosing pump 8 is by design quantitatively，Deliver to strength Kneeding stirrer 9 forms the uniform mixed liquor of suspension polymerisation，Uniformly mixed liquor is sent in nanometer emulsified machine 11 by pump type liquid pulverizing homogenizer 10，Water in pump type homogenizer for liquid 10，Material is dosed in modification、The liquid dispersed phase droplet particles such as compound additive，Pulverized fineness reaches after 5-20 μm nanometer synthesis clean diesel oil in nanometer emulsified machine 11，Emulsification clean diesel oil storage tank 13 is sent into again by emulsification clean diesel oil delivery pump 12，So far the production process of nanometer emulsified crude oil preparation synthesis clean type many grades diesel oil emulsification is completed.The component characteristics of nanometer emulsified crude oil synthesis clean diesel oil is: water percentage by weight in emulsification clean diesel oil is 15-20%, crude oil percentage by weight in diesel oil emulsification is 50-75%, it is 10-25% that material percentage by weight in diesel oil emulsification is dosed in modification, compound additive percentage by weight in diesel oil emulsification is 0-5%, four kinds of weight of material percentage ratio sums are 100%, compound additive includes emulsifying agent, cosurfactant, other modified additive, require that the kind of the percentage by weight by adjusting component in emulsification clean diesel oil and the modified quality and compound additive dosing material realizes synthesizing the emulsification clean diesel oil of different brands according to diesel oil emulsification brand specification standards.
So far, this manufacturing process completes a water, crude oil, material is dosed in modification, compound additive nanometer emulsified preparation synthesis clean type many grades diesel oil emulsification, including the emulsifying light diesel fuel being applicable to automobile high-speed electromotor, it is suitable for engine, generating set medium-speed engine, farm machinery electromotor, the emulsifying heavy diesel fuel of engine of boat and ship, it is applicable to the emulsification heavy oil of Industrial Boiler, it it is the revolution technological innovation of petroleum industry diesel production, valuable petroleum resources are accomplished effective utilization of maximum, it it is a very important scientific and technical innovation achievement to China that petroleum resources are in short supply, national economy sustainable development there is profound influence.
Claims (3)
1. dosed material, the many grades of clean type of compound additive nanometer emulsified preparation synthesis by water, crude oil, modification for one kind
Diesel oil emulsification, it is characterised in that water percentage by weight in diesel oil emulsification is 15-20%, and crude oil is in diesel oil emulsification
Percentage by weight be 50-75%, it is 10-25% that material percentage by weight in diesel oil emulsification is dosed in modification, compound adds
Adding agent percentage by weight in diesel oil emulsification is 0-5%, and the percentage by weight sum of four kinds of materials is 100%；Nanometer
The production technology streamline of clean type many grades diesel oil emulsification of emulsifying preparation synthesis includes water storage tank, water dosing pump, former
Oil tank, crude oil measurement pump, modification are dosed and are expected that storage tank, modification are dosed material dosing pump, compound additive storage tank, are combined
Additive dosing pump, strongly Kneeding stirrer, pump type liquid pulverize homogenizer, nanometer emulsified machine, diesel oil emulsification conveying
Pump, emulsification clean diesel oil storage tank, automatic control cabinet；The component of emulsification clean diesel oil: water, crude oil, modification dose material,
Compound additive is separately stored in water storage tank, crude oil storage tank, modification are dosed in material storage tank, compound additive storage tank,
Under the control of automatic control cabinet, water dosing pump, crude oil measurement pump, modification dose material dosing pump, compound additive meter
Amount pump is quantitatively sent in strength Kneeding stirrer by design, forms suspension polymerisation and uniformly mix in strength Kneeding stirrer
Liquid, enters back into pump type liquid and pulverizes in homogenizer, in pump type liquid pulverizes homogenizer, and liquid dispersed phase droplet particles
After pulverized fineness reaches 5-20 μm, send in nanometer emulsified machine, synthesis clean type emulsifying in nanometer emulsified machine
Diesel oil.
2. the one as described in claim 1 is dosed material, the nanometer emulsified preparation of compound additive by water, crude oil, modification
Synthesis clean type many grades diesel oil emulsification, it is characterised in that compound additive include emulsion, surfactant and its
Its modified additive.
3. the one as described in claim 1 is dosed material, the nanometer emulsified preparation of compound additive by water, crude oil, modification
Clean type many grades diesel oil emulsification of synthesis, it is characterised in that: according to diesel oil emulsification brand specification standards requirement, pass through
Adjusting the percentage by weight of component in diesel oil emulsification and the modified quality dosing material, the kind adjusting compound additive is come real
Now synthesize the emulsification clean diesel oil of different brands.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310027042.XA CN103965979B (en) | 2013-01-24 | 2013-01-24 | Nanometer emulsified crude oil preparation synthesis clean type many grades diesel oil emulsification |
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| CN201310027042.XA CN103965979B (en) | 2013-01-24 | 2013-01-24 | Nanometer emulsified crude oil preparation synthesis clean type many grades diesel oil emulsification |
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| CN103965979A CN103965979A (en) | 2014-08-06 |
| CN103965979B true CN103965979B (en) | 2016-07-27 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105752921B (en) * | 2014-12-14 | 2018-11-27 | 亚申科技研发中心（上海）有限公司 | Oiling base station |
| CN105331396A (en) * | 2015-11-03 | 2016-02-17 | 谭人凤 | Energy-saving and emission-reducing nano oil production system and method |
| CN108659895A (en) * | 2017-04-01 | 2018-10-16 | 深圳华联世纪生物工程股份有限公司 | Biological alcohol-based fuel high heating value biogasoline formula and method |
| CN108659894A (en) * | 2017-04-01 | 2018-10-16 | 深圳华联世纪生物工程股份有限公司 | A kind of biological alcohol-based fuel formulations cleaning diesel fuel formulation and technique |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070038661A (en) * | 2005-10-06 | 2007-04-11 | 엔바로테크 주식회사 | Clean oil including water homogeneous-dispersely mixed therewith and method thereof |
| CN101250444A (en) * | 2008-04-01 | 2008-08-27 | 何耀波 | Utilization formula of renewable environment protection green novel energy source fuel oil |
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| DE102009048223A1 (en) * | 2009-10-05 | 2011-06-16 | Fachhochschule Trier | Process for the in-situ production of fuel-water mixtures in internal combustion engines |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070038661A (en) * | 2005-10-06 | 2007-04-11 | 엔바로테크 주식회사 | Clean oil including water homogeneous-dispersely mixed therewith and method thereof |
| CN101250444A (en) * | 2008-04-01 | 2008-08-27 | 何耀波 | Utilization formula of renewable environment protection green novel energy source fuel oil |
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