CN103965979A - Preparation and synthesis of multi-grade emulsified diesel oil from crude oil through nano-emulsification - Google Patents
Preparation and synthesis of multi-grade emulsified diesel oil from crude oil through nano-emulsification Download PDFInfo
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- CN103965979A CN103965979A CN201310027042.XA CN201310027042A CN103965979A CN 103965979 A CN103965979 A CN 103965979A CN 201310027042 A CN201310027042 A CN 201310027042A CN 103965979 A CN103965979 A CN 103965979A
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- emulsification
- diesel oil
- oil
- clean
- modification
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- 239000002283 diesel fuel Substances 0.000 title claims abstract description 59
- 238000004945 emulsification Methods 0.000 title claims abstract description 52
- 239000010779 crude oil Substances 0.000 title claims abstract description 37
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 17
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims description 11
- 239000000654 additive Substances 0.000 claims abstract description 42
- 230000000996 additive effect Effects 0.000 claims abstract description 42
- 239000000463 material Substances 0.000 claims abstract description 39
- 239000002131 composite material Substances 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 238000012986 modification Methods 0.000 claims abstract description 33
- 230000004048 modification Effects 0.000 claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 239000006185 dispersion Substances 0.000 claims abstract description 5
- 238000010557 suspension polymerization reaction Methods 0.000 claims abstract description 3
- 238000003860 storage Methods 0.000 claims description 29
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000005259 measurement Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 238000013461 design Methods 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000013543 active substance Substances 0.000 claims 1
- 239000000295 fuel oil Substances 0.000 abstract description 8
- 239000003208 petroleum Substances 0.000 abstract description 4
- 238000011161 development Methods 0.000 abstract description 2
- 238000004898 kneading Methods 0.000 abstract description 2
- 230000003137 locomotive effect Effects 0.000 abstract description 2
- 230000001804 emulsifying effect Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 12
- 230000008901 benefit Effects 0.000 description 5
- 239000000446 fuel Substances 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 239000004064 cosurfactant Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 1
- 239000013058 crude material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Liquid Carbonaceous Fuels (AREA)
- Colloid Chemistry (AREA)
Abstract
The invention relates to synthesis of clean multi-grade emulsified diesel oil from water, crude oil, a modification filling material and a composite additive through nano-emulsification. The clean multi-grade emulsified diesel oil is characterized by comprising, by weight, 15 to 20% of water, 75 to 50% of crude oil, 10 to 25% of the modification filling material and 0 to 5% of the composite additive, wherein the above-mentioned four components sum to 100%. The four components of designed weight proportions are sent to a strong kneading mixer to prepare suspension polymerization uniform mixed liquor which is then processed by a pump type liquid crushing and homogenizing device so as to crush, refine and homogenize dispersion phase liquid drops, and the processed mixed liquor is sent to an emulsifying machine for synthesis of the nano-emulsified clean multi-grade emulsified diesel oil. The clean multi-grade emulsified diesel oil is applicable as multi-grade, clean, economic and practicable fuel oil like light diesel fuel, heavy diesel fuel and heavy oil for automobiles, trains, locomotives, engines of farm machinery, ships and industrial boilers and represents revolutionary scientific and technological development in the petroleum industry.
Description
The present invention relates to a kind of novel emulsion clean fuel, particularly relate to a kind of water, crude oil, modification and dose material and many grades of the nanometer emulsified preparation synthesis clean of composite additive type diesel oil emulsification.
Background technology
In the sixties in last century, the U.S. has successfully tried out diesel oil infiltration burning, and oil in water emulsion for multiple Industrial Boiler and automobile, marine engine.The international association's first session of burning in 1981 determines that fuel oil infiltration fuel, as one of three large conservation measuress, causes the further attention of each industrial country, has strengthened the research and development of relevant fuel oil infiltration technology.
Current research work generally all adopts chemical emulsification finish to change water molecules surfactivity, make water, oily affinity, but this emulsifying agent price is high, and profit is in conjunction with unstable, there is unfavorable factor from economy and applicable effect, therefore applied certain resistance.
The present invention utilizes two kinds of liquid, when the particle diameter of disperse phase liquid is little when approaching liquid medium molecular diameter, forms bonding force, and the physical property separating no longer occurs between molecule and molecule.This nanometer emulsified device is just for providing this bonding force to create conditions, make water, oil is in conjunction with the particle stabilized water oil emulsification good result that evenly reaches, there is high kinetic stability, again according to solar oil and heavy gas oil in national domestic diesel oil, the national standard of heavy oil different size grade diesel oil adds different modifications to dose material and composite additive and water, the simultaneously nanometer emulsified synthetic Industrial Boiler heavy oil that is applicable to of oil, boats and ships high-power low-speed diesel, the heavy gas oil of engine and generating set medium-speed diesel, automobile, the clean diesel of the different grades such as the solar oil of agricultural high-speed diesel engine.
Summary of the invention
Water, crude oil, material is dosed in modification and composite additive oozes by a certain percentage kneading and closes, and all crushing materials of participating in mixing, dispersion reaches nano level molecule, makes water, oil, material is dosed in modification, the emulsification clean diesel oil of the synthetic different grades of the dispersed emulsification of particle energy stable bond of composite additive, reach the object of energy-saving and emission-reduction, reduce fuel price simultaneously, improve Business Economic Benefit and the social benefit of improving environment, the nanometer emulsified crude oil preparation synthesis clean diesel oil of the present invention's design, is characterized in that: by water, crude oil, material is dosed in modification, emulsification clean diesel oil is synthesized in the nanometer emulsified preparation of composite additive, the weight percent of component material is that the weight percent of water in emulsification clean diesel oil is 15-20%, the weight percent of crude oil in emulsification clean diesel oil is 50-75%, change that to dose the weight percent of material in emulsification clean diesel oil be 15-25%, the weight percent of composite additive in emulsification clean diesel oil is 0-5%, four kinds of weight of material per-cent sums are 100%, composite additive comprises emulsion, cosurfactant, with other modified additive, the production technique streamline of nanometer emulsified crude oil preparation synthesis clean diesel oil, mainly by water storage tank, water volume pump, crude oil storage tank, crude oil measurement pump, modification is dosed material storage tank and is dosed material volume pump, composite additive storage tank, composite additive volume pump, powerful Kneeding stirrer, pump formula liquid is pulverized clarifixator, nanometer emulsified machine, pump is sent in the input of floatingization clean diesel, emulsification clean diesel oil storage tank, the compositions such as automatic control cabinet, is characterized in that: the water of emulsification clean diesel oil composition, crude oil, material is dosed in modification and composite additive is stored in respectively water storage tank, crude oil storage tank, modification is dosed in material storage tank and composite additive storage tank, under the automatic control of automatic control cabinet, and water, crude oil, modification is dosed and composite additive, respectively by water volume pump, crude oil measurement pump, material is dosed in modification and composite additive volume pump is quantitatively conveyed in powerful Kneeding stirrer by design, in stirrer, form even mixed solution, pulverize clarifixator by liquor pump formula again, liquid dispersion phase refinement fineness is reached to 5-20 μ m, form micron order intimate mixing liquid and send in nanometer emulsified machine, in nanometer emulsified machine water, crude oil, material and composite additive are dosed in modification, emulsification synthesis clean type diesel oil goods, then send into emulsification clean diesel oil storage tank by emulsification clean diesel oil transferpump.
Advantage of the present invention: through simple treatment process, just crude oil is made to the solar oil that can be used for automobile high-speed diesel engine, be used for the diesel oil of the medium-speed diesels such as locomotive, generating set, agricultural machine and the heavy gas oil for marine low speed engine, for the heavy oil of Industrial Boiler, improve the utilising efficiency of crude resources, reduce diesel production cost, and the economic benefit and the social benefit that in energy-saving and emission-reduction and the construction of improving the ecological environment, obtain.
Below in conjunction with drawings and Examples, the present invention is elaborated
Specific implementation method:
Figure of description is production line process flow sheet of the present invention
From accompanying drawing, the present invention includes: water storage tank 1, water volume pump 2, crude oil storage tank 3, crude oil measurement pump 4, material storage tank 5 is dosed in modification, dose material volume pump 6, composite additive storage tank 7, additive volume pump 8, stirrer 9 is closed in powerful control, pump formula liquid is pulverized clarifixator 10, nanometer machine 11, emulsification clean diesel oil transferpump 12, emulsification clean diesel oil storage tank 13, automatic control cabinet 14, it is characterized in that: the component water of emulsification clean diesel oil, crude oil, material is dosed in modification, composite additive is stored in respectively water storage tank 1, crude oil storage tank 3, material storage tank 5 is dosed in modification, in composite additive storage tank 7, under the control of automatic control cabinet 14, by water volume pump 2, crude oil measurement pump 4, material volume pump 6 is dosed in modification, composite additive volume pump 8 by design quantitatively, is delivered in powerful Kneeding stirrer 9 and is formed the even mixed solution of suspension polymerization, and evenly mixed solution is sent in nanometer emulsified machine 11 by pump formula liquid pulverizing clarifixator 10, water in pump formula homogenizer for liquid 10, and material is dosed in modification, the liquid dispersion phase drop particles such as composite additive, pulverized fineness reaches after 5-20 μ m nanometer synthesis clean diesel oil in nanometer emulsified machine 11, send into emulsification clean diesel oil storage tank 13 by emulsification clean diesel oil transferpump 12 again, so far completed the production process of nanometer emulsified many grades of crude oil preparation synthesis clean type diesel oil emulsification.The component characteristics of nanometer emulsified crude oil synthesis clean diesel oil is: the weight percent of water in emulsification clean diesel oil is 15-20%, the weight percent of crude oil in diesel oil emulsification is 50-75%, it is 10-25% that the weight percent of material in diesel oil emulsification dosed in modification, the weight percent of composite additive in diesel oil emulsification is 0-5%, four kinds of weight of material per-cent sums are 100%, composite additive comprises emulsifying agent, cosurfactant, other modified additive, require weight percent by adjusting component in emulsification clean diesel oil and modification to dose the quality of material and the kind of composite additive to realize the emulsification clean diesel oil of synthetic different brands according to diesel oil emulsification brand specification standards.
So far, this manufacturing process has completed water, crude oil, material is dosed in modification, many grades of the nanometer emulsified preparation synthesis clean of composite additive type diesel oil emulsification, comprise the emulsification solar oil that is applicable to automobile high-speed engine, be suitable for engine, generating set medium-speed engine, farm machinery engine, the emulsification heavy gas oil that marine engine is used, be applicable to the emulsification heavy oil of Industrial Boiler, it is the revolution technological innovation of petroleum industry diesel production, valuable petroleum resources are accomplished to maximum effective utilization, a very important scientific and technical innovation achievement to petroleum resources China in short supply, national economy sustainable development is had to profound influence.
Claims (4)
1. material, many grades of the nanometer emulsified preparation synthesis clean of composite additive type diesel oil emulsification are dosed in a water, crude oil, modification, the weight percentages of components that it is characterized in that many grades emulsification clean diesel oil is water, weight percent in emulsification clean diesel oil is 15-20%, the weight percent of crude oil in emulsification clean diesel oil is 50-75%, it is 10-25% that the weight percent of material in emulsification clean diesel oil dosed in modification, the weight percent of composite additive in emulsification clean diesel oil is 0-5%, and the weight percent sum of four kinds of materials is 100%.
2. by a kind of water claimed in claim 1, crude oil, material is dosed in modification, many grades of the nanometer emulsified preparation synthesis clean of composite additive type diesel oil emulsification, it is characterized in that: the production technique streamline of nanometer emulsified preparation synthesis clean type grade diesel oil emulsification comprises water storage tank, water volume pump, crude oil storage tank, crude oil measurement pump, material storage tank is dosed in modification, material volume pump is dosed in modification, composite additive storage tank, composite additive volume pump, powerful Kneeding stirrer, pump formula liquid is pulverized clarifixator, nanometer emulsified machine, diesel oil emulsification transferpump, emulsification clean diesel oil storage tank, automatic control cabinet, the component of emulsification clean diesel oil: water, crude oil, material is dosed in modification, composite additive is stored in respectively water storage tank, crude oil storage tank, material storage tank is dosed in modification, in composite additive storage tank, under the control of automatic control cabinet, by water volume pump, crude oil measurement pump, material volume pump is dosed in modification, composite additive volume pump is quantitatively sent in powerful Kneeding stirrer by design, in stirrer, form the even mixed solution of suspension polymerization, entering pump formula liquid pulverizes in clarifixator again, in pump formula homogenizer for liquid, water, material is dosed in modification, the pulverized fineness of liquid dispersion phase drop particle such as composite additive reach after 5-20 μ m, send in nanometer emulsified machine, synthesis clean type diesel oil emulsification in nanometer emulsified machine.
3. dose material, nanometer emulsified many grades of the clean diesel oil emulsification that is mixed with of composite additive by a kind of water, crude oil, modification described in claim, it is characterized in that composite additive comprises emulsion, tensio-active agent, other modified additive.
4. dose material, many grades of the nanometer emulsified synthesis clean type of composite additive diesel oil emulsification by a kind of water claimed in claim 1, crude oil, modification, it is characterized in that: according to the requirement of diesel oil emulsification brand specification standards, the quality of dosing material by adjusting the weight percent of component in diesel oil emulsification and modification, the kind of adjusting composite additive realizes the emulsification clean diesel oil of synthetic different brands.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310027042.XA CN103965979B (en) | 2013-01-24 | 2013-01-24 | Nanometer emulsified crude oil preparation synthesis clean type many grades diesel oil emulsification |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310027042.XA CN103965979B (en) | 2013-01-24 | 2013-01-24 | Nanometer emulsified crude oil preparation synthesis clean type many grades diesel oil emulsification |
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| Publication Number | Publication Date |
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| CN103965979A true CN103965979A (en) | 2014-08-06 |
| CN103965979B CN103965979B (en) | 2016-07-27 |
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| CN201310027042.XA Expired - Fee Related CN103965979B (en) | 2013-01-24 | 2013-01-24 | Nanometer emulsified crude oil preparation synthesis clean type many grades diesel oil emulsification |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105331396A (en) * | 2015-11-03 | 2016-02-17 | 谭人凤 | Energy-saving and emission-reducing nano oil production system and method |
| CN105752921A (en) * | 2014-12-14 | 2016-07-13 | 亚申科技研发中心（上海）有限公司 | Oiling base station |
| CN108659894A (en) * | 2017-04-01 | 2018-10-16 | 深圳华联世纪生物工程股份有限公司 | A kind of biological alcohol-based fuel formulations cleaning diesel fuel formulation and technique |
| CN108659895A (en) * | 2017-04-01 | 2018-10-16 | 深圳华联世纪生物工程股份有限公司 | Biological alcohol-based fuel high heating value biogasoline formula and method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070038661A (en) * | 2005-10-06 | 2007-04-11 | 엔바로테크 주식회사 | Clean oil including water homogeneous-dispersely mixed therewith and method thereof |
| CN101250444A (en) * | 2008-04-01 | 2008-08-27 | 何耀波 | Utilization formula of renewable environment protection green novel energy source fuel oil |
| US20120180741A1 (en) * | 2009-10-05 | 2012-07-19 | Fachhochschule Trier | Method for the in situ production of fuel/water mixtures in combustion engines |
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2013
- 2013-01-24 CN CN201310027042.XA patent/CN103965979B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070038661A (en) * | 2005-10-06 | 2007-04-11 | 엔바로테크 주식회사 | Clean oil including water homogeneous-dispersely mixed therewith and method thereof |
| CN101250444A (en) * | 2008-04-01 | 2008-08-27 | 何耀波 | Utilization formula of renewable environment protection green novel energy source fuel oil |
| US20120180741A1 (en) * | 2009-10-05 | 2012-07-19 | Fachhochschule Trier | Method for the in situ production of fuel/water mixtures in combustion engines |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105752921A (en) * | 2014-12-14 | 2016-07-13 | 亚申科技研发中心（上海）有限公司 | Oiling base station |
| CN105752921B (en) * | 2014-12-14 | 2018-11-27 | 亚申科技研发中心（上海）有限公司 | Oiling base station |
| CN105331396A (en) * | 2015-11-03 | 2016-02-17 | 谭人凤 | Energy-saving and emission-reducing nano oil production system and method |
| CN108659894A (en) * | 2017-04-01 | 2018-10-16 | 深圳华联世纪生物工程股份有限公司 | A kind of biological alcohol-based fuel formulations cleaning diesel fuel formulation and technique |
| CN108659895A (en) * | 2017-04-01 | 2018-10-16 | 深圳华联世纪生物工程股份有限公司 | Biological alcohol-based fuel high heating value biogasoline formula and method |
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| Publication number | Publication date |
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| CN103965979B (en) | 2016-07-27 |
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Granted publication date: 20160727 |