CN103944497A - Balcony embedded photovoltaic power generation system and manufacturing method thereof - Google Patents
Balcony embedded photovoltaic power generation system and manufacturing method thereof Download PDFInfo
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- CN103944497A CN103944497A CN201410108944.0A CN201410108944A CN103944497A CN 103944497 A CN103944497 A CN 103944497A CN 201410108944 A CN201410108944 A CN 201410108944A CN 103944497 A CN103944497 A CN 103944497A
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- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 4
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- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
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- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 claims description 3
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- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/10—Photovoltaic [PV]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Paints Or Removers (AREA)
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
Abstract
The invention discloses a balcony embedded photovoltaic power generation system which comprises a balcony frame and a guard bar plate (1) fixed to the balcony frame. The guard bar plate (1) is of a layer structure and sequentially comprises a base plate (2), a flexible thin-film battery pack (3) a film layer (4) and a coating layer (5) from interior to exterior, wherein the four layers are fixed into an integral structure, and the base plate (2) is a wood plastic plate and is made of wood plastic composite materials. According to the balcony embedded photovoltaic power generation system, the guard bar plate is directly combined and embedded into the balcony rail frame and plays a role of a balcony coaming, and the aim of photovoltaic power generation through a balcony of a building is achieved.
Description
Technical field
The present invention relates to building energy conservation and photoelectricity building field, particularly relate to a kind of balcony embedded-type photovoltaic generating system.
Background technology
Along with day by day serious in China of haze, the environmental problem taking air pollution as representative has become focus that the whole society pays close attention to and the bottleneck of the comprehensive sustainable development of restriction China's economic society.In global range, environment and energy problem are inseparable.Air pollution is in fact not science, unreasonable causing of energy resource structure, and the consumption of the fossil energy taking coal as representative is China's air-polluting main source exactly specifically.To fundamentally improve air quality, improve atmospheric environment, just must greatly develop the clean energy resource taking solar energy as representative.
By concentrating, to set up the distributed independent power station of attaching most importance to building integrated photovoltaic to development in power station excessive in the at present development of world's photovoltaic industry, and residential housing is one of main place of installing and using photovoltaic generating system.The common way of photovoltaic building is that photovoltaic device is installed on building roof.For the ubiquitous multilayer in city, especially skyscraper house, uses stent-type solar energy photovoltaic panel, has following many restrictions: (1) limited roofing area is difficult to meet user's electricity consumption requirement; (2) a large amount of pitched roofs is not suitable for mounting bracket formula solar energy photovoltaic panel; (3) there is huge potential safety hazard in the roofing installation side of conventional stent photovoltaic system; (4) mounting bracket formula photovoltaic panel system certainly will be destroyed roof waterproof and thermal insulation system.
Summary of the invention
The technical problem to be solved in the present invention be to provide a kind of simple in structure, cost is low, can realize and utilize the balcony of building to carry out the balcony embedded-type photovoltaic generating system of photovoltaic generation.
A kind of balcony embedded-type photovoltaic generating system, comprise balcony framework and guardrail board fixed thereon, described guardrail board is layer structure, comprise successively from the inside to the outside base plate, flexible thin-film battery assembly, rete and dope layer, four layers are fixed into integrative-structure, wherein, described base plate is that wood is moulded plate, is made up of wood plastic composite.
Balcony embedded-type photovoltaic generating system of the present invention, wherein said balcony framework comprises at least two columns and is fixed on the multiple crossbeams between described column, described guardrail board is directly inlayed in the balcony framework that is fixed on described column and crossbeam formation, be fixed with handrail guardrail at the top of described column, described column, crossbeam and handrail guardrail are made by PVC material, and adopting insertion connector to install, the frame that the surrounding of described guardrail board adopts aluminium alloy or carbon fibre material to make is fixed.
Balcony embedded-type photovoltaic generating system of the present invention, wherein said flexible thin-film battery assembly is the hull cell that adopts deposition of transparent conductive film to prepare on the flexible flexible substrate made at high molecular polymer polyimides or plastics, is amorphous silicon flexible solar hull cell, copper indium potassium selenium thin-film solar cells, cadmium telluride diaphragm solar battery, dye-sensitized cell or organic film battery.
Balcony embedded-type photovoltaic generating system of the present invention, the thickness that wherein said wood is moulded plate is 16～30mm, length and width are of a size of 400 × 500mm, 500 × 500mm, 500 × 600mm or 1000 × 1200mm; The lower surface that wood is moulded plate applies organic silicon acrylic coating or nano-fluorine carbon coating, and thickness is 30～80 microns, and described organic silicon acrylic coating is made up of the material of following weight portion:
Deionized water: 500～560 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 30～60 parts;
Coalescents: 32～40 parts;
Antisepticize and mildew preventive: 8～10 parts;
Defoamer: 6～10 parts;
Ethylene glycol: 40～50 parts;
Plasticizer: 0.3～0.5 part;
PH adjusting agent: 8～10 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic substance mould inhibitor, synthetic vegetable esters plasticiser, and described defoamer is PPG, described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium;
Described nano-fluorine carbon coating is made up of the material of following weight portion:
Wherein, described titanium dioxide is the rutile type nano titanic oxide particle through silane coupler surface modification; Described curing agent is taking toluene diisocyanate as raw material, through partial monosomy polymerization, then carries out taking polyalcohol as sealer that capping makes; Described paint thinner is acetone or dimethylbenzene.
Balcony embedded-type photovoltaic generating system of the present invention, wherein said rete is fluorine-containing TPT polyester film or ethene-TFE copolymer film, thickness is 250 microns.
Balcony embedded-type photovoltaic generating system of the present invention, wherein said dope layer is applied and is formed by anti-fouling and self-cleaning coating, described anti-fouling and self-cleaning coating is that particle diameter is nano level photo-catalytic coating, and thickness is 20～70 microns, and photo-catalytic coating is made up of the material of following weight portion:
Solid content is 49% emulsion type synthetic polymer emulsion: 200～340 parts;
Particle diameter is the photo-catalytic nano powder body material of 2～7nm: 20～39 parts;
Deoxygenated water: 650～820 parts;
Thickener: 4～5 parts;
Dispersant: 2～5 parts;
Wetting agent: 12～14 parts;
Coalescents: 25～40 parts;
Defoamer: 5～20 parts;
Coupling agent: 4～7 parts;
Described emulsion type synthetic polymer emulsion is one or more the mixture in VAE emulsion, organic siliconresin emulsion, pure-acrylic emulsion, elasticity pure-acrylic emulsion, benzene emulsion, styrene-acrylic emulsion, acrylate copolymer emulsion, organosilicon-acrylic emulsion, aqueous epoxy resin emulsion, aqueous polyurethane emulsion;
Described photo-catalytic nano powder body material is one or more the mixture in nano titanium oxide, nanometer titanium phosphate, nano silicon, nano-negative ion;
Described thickener is one or more the mixture in cellulose family, silicon dioxide, polyacrylate, polyurethanes;
Described dispersant is one or more the mixture in calgon, ammonium ion type acrylic acid, sodium polyphosphate, PTPP, tetrapotassium pyrophosphate, cithrol 200 or 400, polyacrylate;
Described wetting agent pH value is 5.5～7.5, for lauryl sodium sulfate, pull open one or more the mixture in powder, diisobutyl sodium naphthalene sulfonate, glycerin monostearate;
Described coalescents is Lauryl Alcohol fat, butyl glycol ether, propylene glycol phenylate or toluene alcohol;
Described defoamer is one or more the mixture in phosphoric acid lipid, mineral oils, higher alcohol, PPG, polyethers, organosilicon;
Described coupling agent is one or more the mixture in silane coupler, titanate coupling agent, aluminate coupling agent.
Balcony embedded-type photovoltaic generating system of the present invention, fixes by binding agent between wherein said flexible thin-film battery assembly and described base plate, and described binding agent is flame-proof type polyalcohol binding agent, and its raw material by following weight portion is prepared from:
Polyacrylic acid lipid emulsion: 75～90 parts;
Crosslinking agent: 5～20 parts;
Organophosphor nitrogen based flame retardant: 1～5 part;
Solvent: 1～10 part;
Described polyacrylate emulsion is prepared from by acrylic ester monomer, and described acrylic ester monomer is ethyl acrylate, the mixture of one or more in butyl acrylate, acrylic acid-2-ethyl caproite, methyl methacrylate;
Described crosslinking agent is isocyanates crosslinking agent, toluene di-isocyanate(TDI) or MDI;
Described organophosphor nitrogen based flame retardant is tri-isopropyl benzene base phosphoric acid fat or dimethyl methyl phosphonate;
Described solvent is toluene, dimethylbenzene, positive fourth fat or isopropyl alcohol.
A preparation method for balcony embedded-type photovoltaic generating system, comprises the steps:
Step 1, bore respectively electric lead perforation and open metallic channel at the design attitude of the column of the balcony frame of being made by PVC material, handrail railing tube outer surface, wherein running through for electric power output line, terminal box fixture is set in described column;
The preparation of step 2, base plate: described wood is moulded to the polishing of plate plate surface and four arris and clean out, carry out edging, prepare organic silicon acrylic coating or nano-fluorine carbon coating, and be coated in described wood and mould the lower surface of plate;
The preparation of step 3, photovoltaic layer: prepare photo-catalytic coating, seal up TPT polyester rete or ethene-TFE copolymer rete in the surface coverage of described flexible thin-film battery assembly, and apply the described photo-catalytic coating with anti-pollution function in the outside of described TPT polyester rete or ethene-TFE copolymer film;
Step 4, prepare flame-proof type polyalcohol binding agent, with described flame-proof type polyalcohol binding agent, flexible thin-film battery assembly is pasted to described wood and moulded the upper surface of plate;
Step 5, merging encapsulation: the order according to fexible film photovoltaic cell component, flame-proof type polyalcohol binding agent, base plate stacks gradually, through roll-in and autoclave processing, make each layer assembly and material close adhesion, last again by be fixed on the surrounding of photovoltaic panel with the frame that aluminium alloy or carbon fibre material are made, obtain product.
The preparation method of balcony embedded-type photovoltaic generating system of the present invention, the preparation method of wherein said photo-catalytic nano coating comprises the steps:
(A) each component in raw material is weighed one by one;
(B) wetting agent, dispersant are added in emulsion type synthetic polymer emulsion, with 800 revs/min of abundant stir about 20～30min of rotating speed;
(C) add again photo-catalytic nano powder body material, fully disperse 30～60min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight and add thickener;
(D) last under the condition of 1500 revs/min of rotating speeds, add the deoxygenated water having mixed with coalescents, coupling agent, then add the defoamer of 2/3 remaining weight, be uniformly mixed 10 minutes, obtain photo-catalytic nano coating;
The preparation method of described flame-proof type polyalcohol binding agent comprises the steps:
(a) in the mixer of temperature-adjustable, first add acrylic ester monomer, temperature is risen to 50～60 degree, keep temperature 5～7 hours, make acrylic emulsion;
(b) keep said temperature constant, in the acrylic emulsion of making, add the solvent of 1/3 volume, and stir, be processed into mother liquor first;
(c) be under the condition of 40～50 degree in temperature, the solvent of residue 2/3 volume is evenly mixed with organophosphor nitrogen based flame retardant, make mother liquor second;
(d) being under the condition of 50～60 degree in temperature, mother liquor first and mother liquor second two components are evenly mixed, slowly add subsequently crosslinking agent and stir, finally make flame-proof type polyalcohol binder product.
The preparation method of balcony embedded-type photovoltaic generating system of the present invention, the preparation method of wherein said organosilicon-modified acrylic coating comprises the steps: load weighted fungusproof anti-corrosion agent and ethylene glycol, pH adjusting agent adds in organosilicon-acrylic resin emulsion, with the rotating speed premix of 800 revs/min, fully stir about 20～30min, disperse 10～15min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight, fully disperse 15～20min with the rotating speed of 800 revs/min again, and add and coalescents, the deionized water that plasticizer mixes, add again the defoamer of 2/3 weight, be uniformly mixed, be mixed with organosilicon-modified acrylic coating,
The preparation method of described nano-fluorine carbon coating comprises the steps: proportionally to take nano titanium oxide, joins in coating dilution, disperses to mix, and mixing time is 1 hour; Then add successively fluorocarbon resin and curing agent, stir, make nano-fluorine carbon coating.
Balcony embedded-type photovoltaic generating system difference from prior art of the present invention is:
The direct combination of described guardrail board (photovoltaic generation plate) in balcony embedded-type photovoltaic generating system of the present invention is also embedded in terrace fence framework, plays the effect of balcony fence and has realized and utilized the balcony of building to carry out the object of photovoltaic generation.
Balcony embedded-type photovoltaic generating system middle-jiao yang, function of the spleen and stomach table frame of the present invention is PVC material (polyvinyl chloride, the English PVC that is called for short), it is the thermoplastic resin being polymerized under initator effect by vinyl chloride, this material is harder than wood, than more high resilience and high-impact performance of cast iron, long service life; Balcony framework adopts insertion connector to install, and has greatly improved installation rate and operating efficiency;
Base plate is that wood is moulded, be wood plastic composite (Wood-Plastic Composites, WPC), refer to utilize polyethylene, polypropylene and polyvinyl chloride etc., replace common resin adhesive, be mixed into new wood materials with exceeding the useless strings such as more than 35%-70% wood powder, rice husk, stalk, then through the plastic processings such as extruding, mold pressing, injection moulding, the sheet material of producing or section bar.Wood-plastic composite panel is that one is mainly basic material and thermoplastic macromolecule material (plastics) and processing aid etc. by timber (lignose, plant cellulose), the high-tech green material of making through die apparatus heating extrusion molding again after mixing, have performance and the feature of timber and plastics concurrently, can substitute the advanced composite material (ACM) of timber and plastics.Product has following characteristic:
A, fire protection flame retarding, anticorrosive, humidity, do not damaged by worms, long fungi, acid and alkali-resistance, nonhazardous, the premium properties such as pollution-free, maintenance cost is low.Higher than plastics hardness, the life-span is long, can thermoplastic shaping, and intensity is high, energy savings;
B, matter heavily fortified point, amount are light, insulation, smooth surface are smooth, containing formaldehyde and other harmful substances, and nonhazardous, pollution-free;
C, waterproof, protection against the tide.Solve wood-based product to the easy problem of rotten, dilatancy after making moist of water suction in moist and many water environments at all, can use in the not applicable environment of Traditional Wood goods.Do not chap, do not expand, indeformable, without maintenance and maintenance, be convenient to clean, save later period maintenance and upkeep cost;
D, insect protected, termite-proof, effectively stop insects harassing and wrecking, increases the service life.Machinability is good, can order, can dig, can saw, can bore, surface can japanning;
E, good insulation preformance, non-conductive under dampness, avoid photovoltaic system electric leakage to threaten personal safety; A mistake! Do not find Reference source.
F, high fire line.Can be effectively fire-retardant, fire-protection rating reaches B1 level, meets fire from putting out, and does not produce any toxic gas;
G, installation simply, are constructed convenient, do not need numerous and diverse construction technology, save set-up time and expense.
Below in conjunction with accompanying drawing, balcony embedded-type photovoltaic generating system of the present invention is described further.
Brief description of the drawings
Fig. 1 is the stereogram of balcony embedded-type photovoltaic generating system of the present invention;
Fig. 2 is the generalized section of the guardrail board in balcony embedded-type photovoltaic generating system of the present invention.
Embodiment
Embodiment 1
As depicted in figs. 1 and 2, a kind of balcony embedded-type photovoltaic generating system, comprise balcony framework (not shown) and guardrail board 1 fixed thereon, guardrail board 1 is layer structure, comprise successively that from the inside to the outside 5, four layers of base plate 2, flexible thin-film battery assembly 3, rete 4 and dope layers are fixed into integrative-structure, wherein, base plate 2 is moulded plate for wood, is made up of wood plastic composite.Balcony framework comprises at least two columns and is fixed on the multiple crossbeams between column, guardrail board 1 is directly inlayed in the balcony framework that is fixed on column and crossbeam formation, be fixed with handrail guardrail at the top of column, column, crossbeam and handrail guardrail are made by PVC material, and adopting insertion connector to install, the frame that the surrounding of guardrail board 1 adopts aluminium alloy or carbon fibre material to make is fixed.
Flexible thin-film battery assembly 3 is the hull cells that adopt deposition of transparent conductive film to prepare in the flexible flexible substrate of making at high molecular polymer polyimides, for amorphous silicon flexible solar hull cell, the thickness that wood is moulded plate is 16mm, length and width are of a size of 400 × 500mm, mould plate lower surface at wood and apply organic silicon acrylic coating, thickness is 30 microns, and organosilicon-modified acrylic coating is made up of the material of following weight portion:
Deionized water: 500 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 60 parts;
Coalescents: 32 parts;
Antisepticize and mildew preventive: 10 parts;
Defoamer: 6 parts;
Ethylene glycol: 50 parts;
Plasticizer: 0.3 part;
PH adjusting agent: 10 parts;
Wherein, coalescents is Lauryl Alcohol ester, and Antisepticize and mildew preventive is that OBPA contains arsenic organic substance mould inhibitor, synthetic vegetable esters plasticiser, and defoamer is PPG, pH adjusting agent is methane-siliconic acid aqueous solutions of potassium;
Rete 4 is fluorine-containing TPT polyester film, and thickness is 250 microns, and dope layer 5 is applied and formed by anti-fouling and self-cleaning coating, and anti-fouling and self-cleaning coating is that particle diameter is nano level photo-catalytic coating, and thickness is 20 microns, and its material by following weight portion forms:
Solid content is 49% emulsion type synthetic polymer emulsion: 200 parts;
Particle diameter is the photo-catalytic nano powder body material of 2～7nm: 39 parts;
Deoxygenated water: 650 parts;
Thickener: 5 parts;
Dispersant: 2 parts;
Wetting agent: 14 parts;
Coalescents: 25 parts;
Defoamer: 20 parts;
Coupling agent: 4 parts.
Emulsion type synthetic polymer emulsion is that mass ratio is VAE emulsion, the organic siliconresin emulsion of 5:7:2, the mixture of pure-acrylic emulsion; Photo-catalytic nano powder body material is that mass ratio is the nano titanium oxide of 9:1 and the mixture of nanometer titanium phosphate; Thickener is that mass ratio is the cellulose family of 3:7 and the mixture of silicon dioxide; Dispersant is that mass ratio is the mixture of calgon, ammonium ion type acrylic acid, sodium polyphosphate and the PTPP of 6:1:9:5; Wetting agent pH value is 5.5, for the mass ratio lauryl sodium sulfate that is 8:3:4, pull open the mixture of powder, diisobutyl sodium naphthalene sulfonate; Coalescents is butyl glycol ether; Defoamer is that mass ratio is phosphoric acid lipid, mineral oils, the higher alcohol of 4:1:9:6, the mixture of PPG; Coupling agent is that mass ratio is the mixture in the silane coupler, titanate coupling agent, aluminate coupling agent of 7:6:2.
Between flexible thin-film battery assembly 3 and base plate 2, fix by binding agent, binding agent is flame-proof type polyalcohol binding agent, is prepared from by the raw material of following weight portion:
Polyacrylic acid lipid emulsion: 75 parts;
Crosslinking agent: 20 parts;
Organophosphor nitrogen based flame retardant: 1 part;
Solvent: 10 parts;
Polyacrylate emulsion is prepared from by acrylic ester monomer, and acrylic ester monomer is ethyl acrylate, and crosslinking agent is isocyanates crosslinking agent, and organophosphor nitrogen based flame retardant is tri-isopropyl benzene base phosphoric acid fat, and solvent is toluene.
Embodiment 2
As depicted in figs. 1 and 2, a kind of balcony embedded-type photovoltaic generating system, comprise balcony framework and guardrail board 1 fixed thereon, guardrail board 1 is layer structure, comprise successively that from the inside to the outside 5, four layers of base plate 2, flexible thin-film battery assembly 3, rete 4 and dope layers are fixed into integrative-structure, wherein, base plate 2 is moulded plate for wood, is made up of wood plastic composite.Balcony framework comprises at least two columns and is fixed on the multiple crossbeams between column, guardrail board 1 is directly inlayed in the balcony framework that is fixed on column and crossbeam formation, be fixed with handrail guardrail at the top of column, column, crossbeam and handrail guardrail are made by PVC material, and adopting insertion connector to install, the frame that the surrounding of guardrail board 1 adopts aluminium alloy or carbon fibre material to make is fixed.Flexible thin-film battery assembly 3 is the hull cells that adopt deposition of transparent conductive film to prepare on plastics, for copper indium potassium selenium thin-film solar cells, the thickness that wood is moulded plate is 30mm, length and width are of a size of 500 × 500mm, mould backboard face coated with nano fluorocarbon coating at wood, thickness is 80 microns, and nano-fluorine carbon coating is made up of the material of following weight portion:
Wherein, titanium dioxide is the rutile type nano titanic oxide particle through silane coupler surface modification; Curing agent is taking toluene diisocyanate as raw material, through partial monosomy polymerization, then carries out taking polyalcohol as sealer that capping makes; Paint thinner is acetone.
Rete 4 is ethene-TFE copolymer film, thickness is 250 microns, and dope layer 5 is applied and formed by anti-fouling and self-cleaning coating, and anti-fouling and self-cleaning coating is that particle diameter is nano level photo-catalytic coating, thickness is 70 microns, and photo-catalytic coating is made up of the material of following weight portion:
Solid content is 49% emulsion type synthetic polymer emulsion: 340 parts;
Particle diameter is the photo-catalytic nano powder body material of 2～7nm: 20 parts;
Deoxygenated water: 820 parts;
Thickener: 4 parts;
Dispersant: 5 parts;
Wetting agent: 12 parts;
Coalescents: 40 parts;
Defoamer: 5 parts;
Coupling agent: 7 parts.
Emulsion type synthetic polymer emulsion is styrene-acrylic emulsion, photo-catalytic nano powder body material is nano-negative ion, thickener is polyurethanes, dispersant is cithrol 200 or 400, wetting agent pH value is 7.5, is glycerin monostearate, and coalescents is butyl glycol ether, defoamer is polyethers, and coupling agent is silane coupler.Between flexible thin-film battery assembly 3 and base plate 2, fix by binding agent, binding agent is flame-proof type polyalcohol binding agent, and its raw material by following weight portion is prepared from:
Polyacrylic acid lipid emulsion: 90 parts;
Crosslinking agent: 5 parts;
Organophosphor nitrogen based flame retardant: 5 parts;
Solvent: 1 part;
Polyacrylate emulsion is prepared from by acrylic ester monomer, and acrylic ester monomer is acrylic acid-2-ethyl caproite, and crosslinking agent is toluene di-isocyanate(TDI), and organophosphor nitrogen based flame retardant is dimethyl methyl phosphonate; Solvent is dimethylbenzene.
Embodiment 3
As depicted in figs. 1 and 2, a kind of balcony embedded-type photovoltaic generating system, comprise balcony framework and guardrail board 1 fixed thereon, guardrail board 1 is layer structure, comprise successively that from the inside to the outside 5, four layers of base plate 2, flexible thin-film battery assembly 3, rete 4 and dope layers are fixed into integrative-structure, wherein, base plate 2 is moulded plate for wood, is made up of wood plastic composite.Balcony framework comprises at least two columns and is fixed on the multiple crossbeams between column, guardrail board 1 is directly inlayed in the balcony framework that is fixed on column and crossbeam formation, be fixed with handrail guardrail at the top of column, column, crossbeam and handrail guardrail are made by PVC material, and adopting insertion connector to install, the frame that the surrounding of guardrail board 1 adopts aluminium alloy or carbon fibre material to make is fixed.
Flexible thin-film battery assembly 3 is the hull cells that adopt deposition of transparent conductive film to prepare in the flexible flexible substrate of making at high molecular polymer polyimides, for cadmium telluride diaphragm solar battery, the thickness that wood is moulded plate is 21mm, and length and width are of a size of 500 × 600mm.Mould backboard face at wood and apply organic silicon acrylic coating, thickness is 70 microns, and organosilicon-modified acrylic coating is made up of the material of following weight portion:
Deionized water: 530 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 45 parts;
Coalescents: 37 parts;
Antisepticize and mildew preventive: 9 parts;
Defoamer: 8 parts;
Ethylene glycol: 45 parts;
Plasticizer: 0.4 part;
PH adjusting agent: 9 parts;
Wherein, coalescents is Lauryl Alcohol ester, and Antisepticize and mildew preventive is that OBPA contains arsenic organic substance mould inhibitor, synthetic vegetable esters plasticiser, and defoamer is PPG, pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.Rete 4 is fluorine-containing TPT polyester film, and thickness is 250 microns, and dope layer 5 is applied and formed by anti-fouling and self-cleaning coating, and anti-fouling and self-cleaning coating is that particle diameter is nano level photo-catalytic coating, and thickness is 60 microns, and photo-catalytic coating is made up of the material of following weight portion:
Solid content is 49% emulsion type synthetic polymer emulsion: 260 parts;
Particle diameter is the photo-catalytic nano powder body material of 2～7nm: 33 parts;
Deoxygenated water: 720 parts;
Thickener: 4.5 parts;
Dispersant: 3 parts;
Wetting agent: 13 parts;
Coalescents: 36 parts;
Defoamer: 17 parts;
Coupling agent: 5 parts.
Emulsion type synthetic polymer emulsion such as is at the aqueous epoxy resin emulsion of quality and the mixture of aqueous polyurethane emulsion; Photo-catalytic nano powder body material such as is at the nano silicon of quality and the mixture of nano-negative ion; Thickener such as is at the polyacrylate of quality and the mixture of polyurethanes; The mixture of the tetrapotassium pyrophosphate of the quality such as dispersant is, cithrol 200 or 400, polyacrylate; Wetting agent pH value is 6, for etc. the diisobutyl sodium naphthalene sulfonate of quality and the mixture of glycerin monostearate; Coalescents is propylene glycol phenylate, and defoamer such as is at PPG, polyethers, the organosilyl mixture of quality; Coupling agent is titanate coupling agent.Between flexible thin-film battery assembly 3 and base plate 2, fix by binding agent, binding agent is flame-proof type polyalcohol binding agent, and its raw material by following weight portion is prepared from:
Polyacrylic acid lipid emulsion: 82 parts;
Crosslinking agent: 14 parts;
Organophosphor nitrogen based flame retardant: 3 parts;
Solvent: 5 parts;
Polyacrylate emulsion is prepared from by acrylic ester monomer, and acrylic ester monomer is that mass ratio is the ethyl acrylate of 5:7:1:4, the mixture of butyl acrylate, acrylic acid-2-ethyl caproite and methyl methacrylate; Crosslinking agent is MDI, and organophosphor nitrogen based flame retardant is tri-isopropyl benzene base phosphoric acid fat, and solvent is positive fourth fat.
Embodiment 4
Be with the difference of embodiment 3:
Flexible thin-film battery assembly 3 is the hull cells that adopt deposition of transparent conductive film to prepare on plastics, is dye-sensitized cell, and the thickness that wood is moulded plate is 25mm, and length and width are of a size of 1000 × 1200mm.The nano-fluorine carbon coating of moulding backboard face coated with nano level at wood, is made up of the material of following weight portion:
Wherein, titanium dioxide is the rutile type nano titanic oxide particle through silane coupler surface modification; Curing agent is taking toluene diisocyanate as raw material, through partial monosomy polymerization, then carries out taking polyalcohol as sealer that capping makes; Paint thinner is dimethylbenzene.In flame-proof type polyalcohol binding agent, solvent is isopropyl alcohol.In photo-catalytic coating, emulsion type synthetic polymer emulsion is organosilicon-acrylic emulsion, photo-catalytic nano powder body material is nano silicon, thickener is polyacrylate, dispersant is tetrapotassium pyrophosphate, wetting agent pH value is 6.5, for diisobutyl sodium naphthalene sulfonate, defoamer is mineral oils, and coupling agent is titanate coupling agent.Other are with embodiment 3.
Embodiment 5
Be with the difference of embodiment 2:
Flexible thin-film battery assembly 3 is the hull cells that adopt deposition of transparent conductive film to prepare in the flexible flexible substrate of making at high molecular polymer polyimides, is organic film battery.The thickness that wood is moulded plate is 18mm, 500 × 600mm.The lower surface of moulding plate at wood applies organic silicon acrylic coating, and its material by following weight portion forms:
Deionized water: 560 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 30 parts;
Coalescents: 40 parts;
Antisepticize and mildew preventive: 8 parts;
Defoamer: 10 parts;
Ethylene glycol: 40 parts;
Plasticizer: 0.5 part;
PH adjusting agent: 8 parts;
Wherein, coalescents is Lauryl Alcohol ester, and Antisepticize and mildew preventive is that OBPA contains arsenic organic substance mould inhibitor, synthetic vegetable esters plasticiser, and defoamer is PPG, pH adjusting agent is methane-siliconic acid aqueous solutions of potassium.
In photo-catalytic coating, emulsion type synthetic polymer emulsion such as is at elasticity pure-acrylic emulsion, benzene emulsion, styrene-acrylic emulsion, the acrylate copolymer emulsion of quality, the mixture of organosilicon-acrylic emulsion; Photo-catalytic nano powder body material is nano-negative ion, and thickener is silicon dioxide, and dispersant is PTPP, and wetting agent pH value is 7, and for pulling open powder, coalescents is toluene alcohol, and defoamer is organosilicon, and coupling agent is aluminate coupling agent.Other are embodiment 2 simultaneously.
Embodiment 6
Be with the difference of embodiment 1: mould plate lower surface at wood and apply organic silicon acrylic coating, its material by following weight portion forms:
Wherein, titanium dioxide is the rutile type nano titanic oxide particle through silane coupler surface modification; Curing agent is taking toluene diisocyanate as raw material, through partial monosomy polymerization, then carries out taking polyalcohol as sealer that capping makes; Paint thinner is dimethylbenzene.
Embodiment 7
A preparation method for balcony embedded-type photovoltaic generating system, comprises the steps:
Step 1, bore respectively electric lead perforation and open metallic channel at the design attitude of the column of the balcony frame of being made by PVC material, handrail railing tube outer surface, wherein running through for electric power output line, terminal box fixture is set in column;
The preparation of step 2, base plate 2: wood is moulded to the polishing of plate plate surface and four arris and clean out, carry out edging, prepare organic silicon acrylic coating or nano-fluorine carbon coating, and be coated in wood and mould the lower surface of plate;
The preparation of step 3, photovoltaic layer: prepare photo-catalytic coating, seal up rete 4 in the surface coverage of flexible thin-film battery assembly 3, rete 4 is TPT polyester film or ethene-TFE copolymer film, and applies the photo-catalytic coating with anti-pollution function in the outside of rete 4;
Step 4, prepare flame-proof type polyalcohol binding agent, with flame-proof type polyalcohol binding agent, flexible thin-film battery assembly 3 is pasted to wood and moulded the upper surface of plate, obtain photovoltaic panel;
Step 5, merging encapsulation: the order according to fexible film photovoltaic cell component 3, flame-proof type polyalcohol binding agent, base plate 2 stacks gradually, through roll-in and autoclave processing, make each layer assembly and material close adhesion, last again by be fixed on the surrounding of photovoltaic panel with the frame that aluminium alloy or carbon fibre material are made, obtain product.
Preparing in order to upper type on the basis of product, preferably, the preparation method of photo-catalytic nano coating comprises the steps:
(A) each component in raw material is weighed one by one;
(B) wetting agent, dispersant are added in emulsion type synthetic polymer emulsion, with 800 revs/min of abundant stir about 20～30min of rotating speed;
(C) add again photo-catalytic nano powder body material, fully disperse 30～60min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight and add thickener;
(D) last under the condition of 1500 revs/min of rotating speeds, add the deoxygenated water having mixed with coalescents, coupling agent, then add the defoamer of 2/3 remaining weight, be uniformly mixed 10 minutes, obtain photo-catalytic nano coating;
The preparation method of flame-proof type polyalcohol binding agent comprises the steps:
(a) in the mixer of temperature-adjustable, first add acrylic ester monomer, temperature is risen to 50～60 degree, keep temperature 5～7 hours, make acrylic emulsion;
(b) keep said temperature constant, in the acrylic emulsion of making, add the solvent of 1/3 volume, and stir, be processed into mother liquor first;
(c) be under the condition of 40～50 degree in temperature, the solvent of residue 2/3 volume is evenly mixed with organophosphor nitrogen based flame retardant, make mother liquor second;
(d) being under the condition of 50～60 degree in temperature, mother liquor first and mother liquor second two components are evenly mixed, slowly add subsequently crosslinking agent and stir, finally make flame-proof type polyalcohol binder product.
The preparation method of organosilicon-modified acrylic coating comprises the steps: load weighted fungusproof anti-corrosion agent and ethylene glycol, pH adjusting agent adds in organosilicon-acrylic resin emulsion, with the rotating speed premix of 800 revs/min, fully stir about 20～30min, disperse 10～15min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight, fully disperse 15～20min with the rotating speed of 800 revs/min again, and add and coalescents, the deionized water that plasticizer mixes, add again the defoamer of 2/3 weight, be uniformly mixed, be mixed with organosilicon-modified acrylic coating,
The preparation method of nano-fluorine carbon coating comprises the steps: proportionally to take nano titanium oxide, joins in coating dilution, disperses to mix, and mixing time is 1 hour; Then add successively fluorocarbon resin and curing agent, stir, make nano-fluorine carbon coating.
Embodiment 8 construction and installation programs
The installation of balcony embedded-type photovoltaic generating system is implemented according to the following steps:
First measure unwrapping wire according to the concrete shape specification of balcony, fixing built-in fitting is also installed balcony column, then inlay photovoltaic balcony guardrail plate, in balcony column, terminal box is installed subsequently, and the electric lead in adjacent photovoltaic panel is carried out to circuit connection combination (connection of serial or parallel connection circuit) by terminal box.After balcony column and balcony baffle plate fix, balcony guardrail handrail is installed again, and utilize handrail hollow pipe that electric lead guiding is connected to inverter, change direct current into alternating current, serve electrical network (grid-connected use) or directly offer building load electricity consumption through being arranged on building distribution box within doors, finally with fluid sealant, photovoltaic balcony baffle plate surrounding is carried out to waterproof sealing processing, and the electric lead in system and terminal box are carried out to the protection of waterproof, antifreeze, anti-high temperature.
Above embodiment is described the preferred embodiment of the present invention; not scope of the present invention is limited; design under the prerequisite of spirit not departing from the present invention; various distortion and improvement that those of ordinary skill in the art make technical scheme of the present invention, all should fall in the definite protection range of the claims in the present invention book.
Claims (10)
1. a balcony embedded-type photovoltaic generating system, it is characterized in that: comprise balcony framework and guardrail board (1) fixed thereon, described guardrail board (1) is layer structure, comprise successively from the inside to the outside base plate (2), flexible thin-film battery assembly (3), rete (4) and dope layer (5), four layers are fixed into integrative-structure, wherein, described base plate (2) is moulded plate for wood, is made up of wood plastic composite.
2. balcony embedded-type photovoltaic generating system according to claim 1, it is characterized in that: described balcony framework comprises at least two columns and is fixed on the multiple crossbeams between described column, described guardrail board (1) is directly inlayed in the balcony framework that is fixed on described column and crossbeam formation, be fixed with handrail guardrail at the top of described column, described column, crossbeam and handrail guardrail are made by PVC material, and adopting insertion connector to install, the frame that the surrounding of described guardrail board (1) adopts aluminium alloy or carbon fibre material to make is fixed.
3. balcony embedded-type photovoltaic generating system according to claim 1, it is characterized in that: described flexible thin-film battery assembly (3) is the hull cell that adopts deposition of transparent conductive film to prepare on the flexible flexible substrate made at high molecular polymer polyimides or plastics, is amorphous silicon flexible solar hull cell, copper indium potassium selenium thin-film solar cells, cadmium telluride diaphragm solar battery, dye-sensitized cell or organic film battery.
4. according to the balcony embedded-type photovoltaic generating system described in claim 2 or 3, it is characterized in that: the thickness that described wood is moulded plate is 16～30mm, and length and width are of a size of 400 × 500mm 500 × 500mm, 500 × 600mm or 1000 × 1200mm; The lower surface of moulding plate at described wood applies organic silicon acrylic coating or nano-fluorine carbon coating, and thickness is 30～80 microns, and described organic silicon acrylic coating is made up of the material of following weight portion:
Deionized water: 500～560 parts;
Activity substance content is 42% organosilicon-acrylic resin emulsion: 30～60 parts;
Coalescents: 32～40 parts;
Antisepticize and mildew preventive: 8～10 parts;
Defoamer: 6～10 parts;
Ethylene glycol: 40～50 parts;
Plasticizer: 0.3～0.5 part;
PH adjusting agent: 8～10 parts;
Wherein, described coalescents is Lauryl Alcohol ester, and described Antisepticize and mildew preventive is that OBPA contains arsenic organic substance mould inhibitor, synthetic vegetable esters plasticiser, and described defoamer is PPG, described pH adjusting agent is methane-siliconic acid aqueous solutions of potassium;
Described nano-fluorine carbon coating is made up of the material of following weight portion:
Wherein, described titanium dioxide is the rutile type nano titanic oxide particle through silane coupler surface modification; Described curing agent is taking toluene diisocyanate as raw material, through partial monosomy polymerization, then carries out taking polyalcohol as sealer that capping makes; Described paint thinner is acetone or dimethylbenzene.
5. balcony embedded-type photovoltaic generating system according to claim 4, is characterized in that: described rete (4) is fluorine-containing TPT polyester film or ethene-TFE copolymer film, and thickness is 250 microns.
6. balcony embedded-type photovoltaic generating system according to claim 1, it is characterized in that: described dope layer (5) is applied and formed by anti-fouling and self-cleaning coating, described anti-fouling and self-cleaning coating is that particle diameter is nano level photo-catalytic coating, thickness is 20～70 microns, and photo-catalytic coating is made up of the material of following weight portion:
Solid content is 49% emulsion type synthetic polymer emulsion: 200～340 parts;
Particle diameter is the photo-catalytic nano powder body material of 2～7nm: 20～39 parts;
Deoxygenated water: 650～820 parts;
Thickener: 4～5 parts;
Dispersant: 2～5 parts;
Wetting agent: 12～14 parts;
Coalescents: 25～40 parts;
Defoamer: 5～20 parts;
Coupling agent: 4～7 parts;
Described emulsion type synthetic polymer emulsion is one or more the mixture in VAE emulsion, organic siliconresin emulsion, pure-acrylic emulsion, elasticity pure-acrylic emulsion, benzene emulsion, styrene-acrylic emulsion, acrylate copolymer emulsion, organosilicon-acrylic emulsion, aqueous epoxy resin emulsion, aqueous polyurethane emulsion;
Described photo-catalytic nano powder body material is one or more the mixture in nano titanium oxide, nanometer titanium phosphate, nano silicon, nano-negative ion;
Described thickener is one or more the mixture in cellulose family, silicon dioxide, polyacrylate, polyurethanes;
Described dispersant is one or more the mixture in calgon, ammonium ion type acrylic acid, sodium polyphosphate, PTPP, tetrapotassium pyrophosphate, cithrol 200 or 400, polyacrylate;
Described wetting agent pH value is 5.5～7.5, for lauryl sodium sulfate, pull open one or more the mixture in powder, diisobutyl sodium naphthalene sulfonate, glycerin monostearate;
Described coalescents is Lauryl Alcohol fat, butyl glycol ether, propylene glycol phenylate or toluene alcohol;
Described defoamer is one or more the mixture in phosphoric acid lipid, mineral oils, higher alcohol, PPG, polyethers, organosilicon;
Described coupling agent is one or more the mixture in silane coupler, titanate coupling agent, aluminate coupling agent.
7. balcony embedded-type photovoltaic generating system according to claim 6, it is characterized in that: between described flexible thin-film battery assembly (3) and described base plate (2), fix by binding agent, described binding agent is flame-proof type polyalcohol binding agent, and its raw material by following weight portion is prepared from:
Polyacrylic acid lipid emulsion: 75～90 parts;
Crosslinking agent: 5～20 parts;
Organophosphor nitrogen based flame retardant: 1～5 part;
Solvent: 1～10 part;
Described polyacrylate emulsion is prepared from by acrylic ester monomer, and described acrylic ester monomer is ethyl acrylate, the mixture of one or more in butyl acrylate, acrylic acid-2-ethyl caproite, methyl methacrylate;
Described crosslinking agent is isocyanates crosslinking agent, toluene di-isocyanate(TDI) or MDI;
Described organophosphor nitrogen based flame retardant is tri-isopropyl benzene base phosphoric acid fat or dimethyl methyl phosphonate;
Described solvent is toluene, dimethylbenzene, positive fourth fat or isopropyl alcohol.
8. the preparation method of the balcony embedded-type photovoltaic generating system described in any claim in claim 1-7, is characterized in that: comprise the steps:
Step 1, bore respectively electric lead perforation and open metallic channel at the design attitude of the column of the balcony frame of being made by PVC material, handrail railing tube outer surface, wherein running through for electric power output line, terminal box fixture is set in described column;
The preparation of step 2, base plate (2): described wood is moulded to the polishing of plate plate surface and four arris and clean out, carry out edging, prepare organic silicon acrylic coating or nano-fluorine carbon coating, and be coated in described wood and mould the lower surface of plate;
The preparation of step 3, photovoltaic layer: prepare photo-catalytic coating, seal up rete (4) in the surface coverage of described flexible thin-film battery assembly (3), described rete (4) is TPT polyester film or ethene-TFE copolymer film, and applies the photo-catalytic coating with anti-pollution function in the outside of described rete (4);
Step 4, prepare flame-proof type polyalcohol binding agent, with described flame-proof type polyalcohol binding agent, flexible thin-film battery assembly (3) is pasted to described wood and moulded the upper surface of plate, obtain photovoltaic panel;
Step 5, merging encapsulation: the order according to fexible film photovoltaic cell component (3), flame-proof type polyalcohol binding agent, base plate (2) stacks gradually, through roll-in and autoclave processing, make each layer assembly and material close adhesion, last again by be fixed on the surrounding of described photovoltaic panel with the frame that aluminium alloy or carbon fibre material are made, obtain product.
9. the preparation method of balcony embedded-type photovoltaic generating system according to claim 8, is characterized in that: the preparation method of described photo-catalytic nano coating comprises the steps:
(A) each component in raw material is weighed one by one;
(B) wetting agent, dispersant are added in emulsion type synthetic polymer emulsion, with 800 revs/min of abundant stir about 20～30min of rotating speed;
(C) add again photo-catalytic nano powder body material, fully disperse 30～60min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight and add thickener;
(D) last under the condition of 1500 revs/min of rotating speeds, add the deoxygenated water having mixed with coalescents, coupling agent, then add the defoamer of 2/3 remaining weight, be uniformly mixed 10 minutes, obtain photo-catalytic nano coating;
The preparation method of described flame-proof type polyalcohol binding agent comprises the steps:
(a) in the mixer of temperature-adjustable, first add acrylic ester monomer, temperature is risen to 50～60 degree, keep temperature 5～7 hours, make acrylic emulsion;
(b) keep said temperature constant, in the acrylic emulsion of making, add the solvent of 1/3 volume, and stir, be processed into mother liquor first;
(c) be under the condition of 40～50 degree in temperature, the solvent of residue 2/3 volume is evenly mixed with organophosphor nitrogen based flame retardant, make mother liquor second;
(d) being under the condition of 50～60 degree in temperature, mother liquor first and mother liquor second two components are evenly mixed, slowly add subsequently crosslinking agent and stir, finally make flame-proof type polyalcohol binder product.
10. the preparation method of balcony embedded-type photovoltaic generating system according to claim 8, is characterized in that:
The preparation method of described organosilicon-modified acrylic coating comprises the steps: load weighted fungusproof anti-corrosion agent and ethylene glycol, pH adjusting agent adds in organosilicon-acrylic resin emulsion, with the rotating speed premix of 800 revs/min, fully stir about 20～30min, disperse 10～15min with the rotating speeds of 1500 revs/min, in the process stirring, add the defoamer of 1/3 weight, fully disperse 15～20min with the rotating speed of 800 revs/min again, and add and coalescents, the deionized water that plasticizer mixes, add again the defoamer of 2/3 weight, be uniformly mixed, be mixed with organosilicon-modified acrylic coating,
The preparation method of described nano-fluorine carbon coating comprises the steps: proportionally to take nano titanium oxide, joins in coating dilution, disperses to mix, and mixing time is 1 hour; Then add successively fluorocarbon resin and curing agent, stir, make nano-fluorine carbon coating.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106189617A (en) * | 2016-07-20 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | High temperature resistant plastic-wood material compositions and high temperature resistant mould wood and preparation method thereof |
| CN108546464A (en) * | 2018-03-13 | 2018-09-18 | 青岛东方雨虹建筑材料有限公司 | A kind of electrostatic precipitation battery plate self-cleaning coating and its spraying method |
| CN109606127A (en) * | 2018-12-20 | 2019-04-12 | 刘山平 | A kind of new-energy automobile |
| CN114605896A (en) * | 2022-03-11 | 2022-06-10 | 旭贞新能源科技(上海)有限公司 | High-transmittance self-cleaning coating suitable for surface of photovoltaic panel |
| CN116355487A (en) * | 2021-12-21 | 2023-06-30 | Dic株式会社 | Coating agent for electrochemical cell packaging, laminate using same, packaging material, and package |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1113130A (en) * | 1997-06-24 | 1999-01-19 | Ykk Architect Prod Kk | Handrail structure of building |
| CN1879225A (en) * | 2003-11-12 | 2006-12-13 | 安东尼·莫拉利 | Solar rail or railing system |
| CN203081242U (en) * | 2013-01-09 | 2013-07-24 | 黄长杰 | Solar photovoltaic power generation balcony railing integral window |
| CN203475749U (en) * | 2013-08-22 | 2014-03-12 | 烟台斯坦普精工建设有限公司 | Foam glass heat-preservation photovoltaic and decoration integrated board |
| CN203827252U (en) * | 2014-03-22 | 2014-09-10 | 烟台斯坦普精工建设有限公司 | Balcony inlaid photovoltaic power generation system |
-
2014
- 2014-03-22 CN CN201410108944.0A patent/CN103944497B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1113130A (en) * | 1997-06-24 | 1999-01-19 | Ykk Architect Prod Kk | Handrail structure of building |
| CN1879225A (en) * | 2003-11-12 | 2006-12-13 | 安东尼·莫拉利 | Solar rail or railing system |
| CN203081242U (en) * | 2013-01-09 | 2013-07-24 | 黄长杰 | Solar photovoltaic power generation balcony railing integral window |
| CN203475749U (en) * | 2013-08-22 | 2014-03-12 | 烟台斯坦普精工建设有限公司 | Foam glass heat-preservation photovoltaic and decoration integrated board |
| CN203827252U (en) * | 2014-03-22 | 2014-09-10 | 烟台斯坦普精工建设有限公司 | Balcony inlaid photovoltaic power generation system |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106189617A (en) * | 2016-07-20 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | High temperature resistant plastic-wood material compositions and high temperature resistant mould wood and preparation method thereof |
| CN108546464A (en) * | 2018-03-13 | 2018-09-18 | 青岛东方雨虹建筑材料有限公司 | A kind of electrostatic precipitation battery plate self-cleaning coating and its spraying method |
| CN108546464B (en) * | 2018-03-13 | 2021-06-01 | 青岛东方雨虹建筑材料有限公司 | Self-cleaning coating for electrostatic dust removal electroplate and spraying method thereof |
| CN109606127A (en) * | 2018-12-20 | 2019-04-12 | 刘山平 | A kind of new-energy automobile |
| CN116355487A (en) * | 2021-12-21 | 2023-06-30 | Dic株式会社 | Coating agent for electrochemical cell packaging, laminate using same, packaging material, and package |
| CN114605896A (en) * | 2022-03-11 | 2022-06-10 | 旭贞新能源科技(上海)有限公司 | High-transmittance self-cleaning coating suitable for surface of photovoltaic panel |
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