CN103943167A - 一种Ag(V,Nb)/稀土晶体硅太阳电池合金浆料及其制备方法 - Google Patents
一种Ag(V,Nb)/稀土晶体硅太阳电池合金浆料及其制备方法 Download PDFInfo
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- CN103943167A CN103943167A CN201410161164.2A CN201410161164A CN103943167A CN 103943167 A CN103943167 A CN 103943167A CN 201410161164 A CN201410161164 A CN 201410161164A CN 103943167 A CN103943167 A CN 103943167A
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- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 80
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 76
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 58
- 239000000956 alloy Substances 0.000 title claims abstract description 58
- 229910052758 niobium Inorganic materials 0.000 title claims abstract description 55
- 229910021419 crystalline silicon Inorganic materials 0.000 title abstract description 9
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 239000003795 chemical substances by application Substances 0.000 title abstract 6
- 238000004513 sizing Methods 0.000 title abstract 6
- 239000000843 powder Substances 0.000 claims abstract description 132
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 89
- 239000010703 silicon Substances 0.000 claims abstract description 89
- 239000010944 silver (metal) Substances 0.000 claims abstract description 58
- 239000011230 binding agent Substances 0.000 claims abstract description 51
- 239000011521 glass Substances 0.000 claims abstract description 51
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 51
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 49
- 239000010946 fine silver Substances 0.000 claims abstract description 25
- 239000003085 diluting agent Substances 0.000 claims abstract description 15
- 239000002245 particle Substances 0.000 claims description 49
- 238000002360 preparation method Methods 0.000 claims description 45
- RBNWAMSGVWEHFP-UHFFFAOYSA-N trans-p-Menthane-1,8-diol Chemical compound CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 19
- 239000001856 Ethyl cellulose Substances 0.000 claims description 13
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 13
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 claims description 13
- 229920001249 ethyl cellulose Polymers 0.000 claims description 13
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 13
- 239000005011 phenolic resin Substances 0.000 claims description 13
- 229920001568 phenolic resin Polymers 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical group CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 10
- 229910052693 Europium Inorganic materials 0.000 claims description 9
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 9
- 229910052684 Cerium Inorganic materials 0.000 claims description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 abstract description 34
- 239000004332 silver Substances 0.000 abstract description 34
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 33
- 238000007650 screen-printing Methods 0.000 abstract description 12
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 239000002184 metal Substances 0.000 abstract description 9
- 229910001316 Ag alloy Inorganic materials 0.000 abstract description 3
- 238000005036 potential barrier Methods 0.000 abstract description 3
- 229910019714 Nb2O3 Inorganic materials 0.000 abstract 1
- 238000003181 co-melting Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000010955 niobium Substances 0.000 description 74
- 239000002002 slurry Substances 0.000 description 23
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 18
- 238000005245 sintering Methods 0.000 description 11
- 230000001070 adhesive effect Effects 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 229910004298 SiO 2 Inorganic materials 0.000 description 7
- 229910010413 TiO 2 Inorganic materials 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 7
- 229910052797 bismuth Inorganic materials 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- XNRNVYYTHRPBDD-UHFFFAOYSA-N [Si][Ag] Chemical compound [Si][Ag] XNRNVYYTHRPBDD-UHFFFAOYSA-N 0.000 description 3
- 239000002800 charge carrier Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 235000008216 herbs Nutrition 0.000 description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical class CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910000676 Si alloy Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
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- 238000005530 etching Methods 0.000 description 2
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- 150000002739 metals Chemical class 0.000 description 2
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 2
- 229910000484 niobium oxide Inorganic materials 0.000 description 2
- LIZIAPBBPRPPLV-UHFFFAOYSA-N niobium silicon Chemical compound [Si].[Nb] LIZIAPBBPRPPLV-UHFFFAOYSA-N 0.000 description 2
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910004205 SiNX Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000006117 anti-reflective coating Substances 0.000 description 1
- 230000003667 anti-reflective effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
Abstract
Description
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CN201410161164.2A CN103943167B (zh) | 2014-04-18 | 2014-04-18 | 一种Ag(V,Nb)/稀土晶体硅太阳电池合金浆料及其制备方法 |
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CN103943167A true CN103943167A (zh) | 2014-07-23 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105679410A (zh) * | 2016-04-26 | 2016-06-15 | 江阴市天邦涂料股份有限公司 | 一种高粘合稳定性的太阳能电池用银铝浆料 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101483207A (zh) * | 2009-01-07 | 2009-07-15 | 范琳 | 一种环保型硅太阳能电池正面栅线电极银导体浆料 |
CN101702416A (zh) * | 2009-10-29 | 2010-05-05 | 彩虹集团公司 | 一种环保型硅基太阳能电池用正银浆料的制备方法 |
US20130000709A1 (en) * | 2008-08-13 | 2013-01-03 | E I Du Pont De Nemours And Company North Carolina State University | Photovoltaic device electrical contacts |
CN103295663A (zh) * | 2012-01-23 | 2013-09-11 | 赫劳斯贵金属北美康舍霍肯有限责任公司 | 太阳能电池触面的导电性厚膜浆料 |
CN103709572A (zh) * | 2011-11-04 | 2014-04-09 | 赫劳斯贵金属北美康舍霍肯有限责任公司 | 导电性浆料的有机载体 |
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2014
- 2014-04-18 CN CN201410161164.2A patent/CN103943167B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130000709A1 (en) * | 2008-08-13 | 2013-01-03 | E I Du Pont De Nemours And Company North Carolina State University | Photovoltaic device electrical contacts |
CN101483207A (zh) * | 2009-01-07 | 2009-07-15 | 范琳 | 一种环保型硅太阳能电池正面栅线电极银导体浆料 |
CN101702416A (zh) * | 2009-10-29 | 2010-05-05 | 彩虹集团公司 | 一种环保型硅基太阳能电池用正银浆料的制备方法 |
CN103709572A (zh) * | 2011-11-04 | 2014-04-09 | 赫劳斯贵金属北美康舍霍肯有限责任公司 | 导电性浆料的有机载体 |
CN103295663A (zh) * | 2012-01-23 | 2013-09-11 | 赫劳斯贵金属北美康舍霍肯有限责任公司 | 太阳能电池触面的导电性厚膜浆料 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105679410A (zh) * | 2016-04-26 | 2016-06-15 | 江阴市天邦涂料股份有限公司 | 一种高粘合稳定性的太阳能电池用银铝浆料 |
CN105679410B (zh) * | 2016-04-26 | 2017-02-15 | 江阴市天邦涂料股份有限公司 | 一种高粘合稳定性的太阳能电池用银铝浆料 |
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Effective date of registration: 20180810 Address after: 215311 No. 2 Dongping Road, Bacheng Town, Kunshan City, Suzhou, Jiangsu, China 2 Patentee after: Suzhou Asia Ao Xin Enterprise Management Consulting Co., Ltd. Address before: 710049 Xianning West Road, Xi'an, Xi'an, Shaanxi Patentee before: Xi'an Jiaotong University |
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Effective date of registration: 20180817 Address after: 336000 Jiangxi Yichun economic and Technological Development Zone Jiangxi Pu Hua Energy Technology Co., Ltd. Patentee after: Jiangxi Pu Hua Energy Technology Co., Ltd. Address before: 215311 No. 2 Dongping Road, Bacheng Town, Kunshan City, Suzhou, Jiangsu, China 2 Patentee before: Suzhou Asia Ao Xin Enterprise Management Consulting Co., Ltd. |
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Effective date of registration: 20180913 Address after: 336000 Yichun economic and Technological Development Zone, Yichun City, Jiangxi Province Patentee after: Yutai (Jiangxi) new energy Co., Ltd. Address before: 336000 Jiangxi Yichun economic and Technological Development Zone Jiangxi Pu Hua Energy Technology Co., Ltd. Patentee before: Jiangxi Pu Hua Energy Technology Co., Ltd. |
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Address after: 336000 Yichun economic and Technological Development Zone, Yichun City, Jiangxi Province Patentee after: Yuze Semiconductor Co., Ltd. Address before: 336000 Yichun economic and Technological Development Zone, Yichun City, Jiangxi Province Patentee before: Yutai (Jiangxi) new energy Co., Ltd. |
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